CN108782571A - A kind of insecticides and its application method - Google Patents
A kind of insecticides and its application method Download PDFInfo
- Publication number
- CN108782571A CN108782571A CN201810787025.9A CN201810787025A CN108782571A CN 108782571 A CN108782571 A CN 108782571A CN 201810787025 A CN201810787025 A CN 201810787025A CN 108782571 A CN108782571 A CN 108782571A
- Authority
- CN
- China
- Prior art keywords
- insecticides
- rynaxypyr
- rice borer
- tolfenpyrads
- striped rice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The present invention is a kind of insecticides containing four Tolfenpyrads, Rynaxypyr or bromine cyanogen insect amide, belong to chemical prevention field, it is made of four Tolfenpyrad of active ingredient, Rynaxypyr or bromine cyanogen insect amide and its auxiliary agent, has good synergistic effect to prevention lepidoptera pest especially striped rice borer.The insecticides indoor biometrics are 20 to the synergic ratio of striped rice borer:1~1:20.The present invention has synergistic effect notable, and preventive effect is good, and dosage is low, and to environment and target organisms safety, the features such as being controlled a medicine, this composition simultaneous can control other homoptera pests more(Such as planthopper, Bemisia tabaci), have good effect to the drug resistance of medicament to slowing down striped rice borer.
Description
Technical field
The invention belongs to Chemical Control of Harmful Insects fields, and in particular to a kind of prevention lepidoptera pest, especially striped rice borer
Compounded pesticides.
Background technology
Striped rice borer(Chilo suppressalisWalker)Belong to Lepidoptera, Pyralidae, popular name borer, borer, moth
Stalk worm etc. is that one of Occurrence the most serious is endangered on China's rice, tillering stage it is aggrieved cause withered sheath, withered heart seedling,
Insect bite strain and dead ears are caused ear period is aggrieved, the general time underproduction 3%~5%, the underproduction is more than 3 one-tenth when serious.Occur in recent years
Quantity is in the situation obviously risen.Striped rice borer is in addition to hazard rice, moreover it is possible to endanger wild rice stem, corn, sorghum, sugarcane, rape, silkworm
The weeds such as beans, wheat and reed, barnyard grass, Leersia Sw.Domestic each rice region is distributed, wide but main compared with yellow rice borer and pink rice borer distribution
Will with the Yangtze river basin and on the south rice region occur heavier, reach Heilungkiang Keshan County in distribution in China north, south is to Hainan Island.If not into
The reasonable effectively preventing striped rice borer of row, China's rice injured area will further expand.
Four Tolfenpyrads are a kind of new and effective insecticides, have the characteristics that ultra high efficiency, low toxicity, low-residual, nuisanceless,
It is high to the activity of the larva of lepidopterous insects and other many pests.
Rynaxypyr, common first names health is wide, is used to prevent the Lepidopteras such as striped rice borer, rice leaf roller evil all the time
Worm, but due to the increase of dosage, rice is vertical and striped rice borer is increasingly severe to the resistance of Rynaxypyr.
Bromine cyanogen insect amide also known as cyanogen insect amide belong to ryanodine receptor inhibitor insecticides, can effectively prevent Lepidoptera
Equal pests.
So far, not yet find that four Tolfenpyrads and Rynaxypyr or the insecticides of bromine cyanogen insect amide are anti-
Control the report of striped rice borer.
Invention content
The object of the present invention is to provide a kind of insecticides of prevention striped rice borer, pass through four Tolfenpyrads and chlorine worm benzene
The insecticide centainly matched is made in the mixture of formamide or bromine cyanogen insect amide, and for preventing striped rice borer, effect is good, and dosage is low,
It can be very good the resistance for delaying striped rice borer to medicament.
The technical solution adopted by the present invention is as follows:
A kind of insecticides containing four Tolfenpyrads, it is characterised in that:It is made of effective constituents A and B and auxiliary material component,
Middle A is four Tolfenpyrads, and B is Rynaxypyr or bromine cyanogen insect amide, and the total weight percentage composition of active ingredient is 1% ~ 90%.
Insecticides according to claim 1, it is characterised in that:The matter of A and B in the insecticides
Amount is than being 20:1~1:20.
Insecticides according to claim 1, it is characterised in that:The matter of A and B in the insecticides
Amount is than being 10:1~1:5.
Insecticides according to claim 1, it is characterised in that:The dosage form of the insecticides is breast
Oil, suspending agent, water-dispersible granules, wettable powder, aqueous emulsion, micro-capsule suspension.
When the present invention is missible oil, the weight percentage of each component is:
Four Tolfenpyrads:1-45%
Rynaxypyr or bromine cyanogen insect amide:1-10%
Solvent:3-30%
Emulsifier:5-15%
The specific procedure of processing of this insecticides missible oil is:By above-mentioned formula solvent by four Tolfenpyrads, chlorine worm benzoyl
Amine or bromine cyanogen insect amide dissolving, are added emulsifier, stir evenly in a stirring kettle, you can prepare the cream preparation of this composition.
When the present invention is wettable powder, the weight percentage of each component is:
Rynaxypyr or bromine cyanogen insect amide 1-70%
Four Tolfenpyrad 1-10%
Dispersant 3-10%
Wetting agent 1-8%
Filler polishing is to 100%
The specific procedure of processing of this insecticides wettable powder is:By above-mentioned formula by Rynaxypyr or bromine cyanogen worm acyl
Amine and four Tolfenpyrads and dispersant, wetting agent and filler mixing, uniform stirring, is mixed after airslide disintegrating mill in a stirring kettle
It closes uniform, you can the wettable powder of manufacturing cost inventive composition.
When the present invention is water dispersible granules, the weight percentage of each component is:
Rynaxypyr or bromine cyanogen insect amide 1-55%
Four Tolfenpyrad 1-10%
Dispersant 2-8%
Wetting agent 2-8%
Disintegrant 2-4%
Filler polishing is to 100%
The specific procedure of processing of this insecticides water dispersible granules is:By above-mentioned formula by Rynaxypyr or bromine cyanogen worm acyl
Amine, four Tolfenpyrads and dispersant, wetting agent, disintegrant and filler are uniformly mixed, and are crushed with micro jet, through pinching
Close, be then added in fluidized-bed granulation dryer be granulated, dried, sieve after through sampling analysis, it is obtained of the present invention
The water dispersible granules of insecticides.
When the present invention is suspending agent, the weight percentage of each component is:
Rynaxypyr or bromine cyanogen insect amide 1-40%
Four Tolfenpyrad 1-40%
Dispersant 3-6%
Wetting agent 1 ~ 4%
Antifreezing agent 0.5-4%
Thickener 0.1-3%
Antifoaming agent 0.1-1%
Water polishing is to 100%
The procedure of processing of this insecticides suspending agent is:First auxiliary agent is mixed, is uniformly mixed through high speed shear, chlorine worm is added
Benzamide or bromine cyanogen insect amide and four Tolfenpyrad active compounds grind 3 ~ 4 hours in sand mill, make diameter of particle all at 5 μm
Hereinafter, insecticides suspending agent of the present invention is made.
When the invention is aqueous emulsion, the weight percentage of each component is:
Rynaxypyr or bromine cyanogen insect amide 1-55%
Four Tolfenpyrad 1-10%
Emulsifier 2-6%
Solvent 3-5%
Antifreezing agent 1-3%
Thickener 0.1-5%
Antifoaming agent 0.1-1%
Water polishing is to 100%
The procedure of processing of this composition pesticide aqueous emulsion is:By Rynaxypyr or bromine cyanogen insect amide and four Tolfenpyrads, molten
Agent and emulsifier are added together, and are dissolved into uniform oil phase;Water, antifreezing agent etc. are mixed into uniform water phase;At a high speed
Stirring is lower, and water phase is added in oil phase simultaneously, and high speed shear 5-10min forms oil-in-water type aqueous emulsion.Obtain institute of the present invention
The insecticides aqueous emulsion stated.
When the present invention is micro-capsule suspension, the weight percentage of component is:
Rynaxypyr or bromine cyanogen insect amide 1-40%
Four Tolfenpyrad 1-10%
Capsule skin material 0.5-4%
Solvent 1-3%
Dispersant 1-4%
Emulsifier 2-4%
Thickener 1-2%
PH adjusting agent 0-2%
Water polishing is to 100%
(1)Rynaxypyr or bromine cyanogen insect amide and four Tolfenpyrads are dissolved in solvent, it is equal that the stirring of capsule skin material is added
It is even to obtain oil phase;(2)Emulsifier is added in water, adjuvant is uniformly mixing to obtain water phase;(3)Water phase is added in oil phase, high
Speed homogenizing forms oil-in-water emulsion;(4)Under 450 revs/min of speed conditions, polyamine is added and participates in interface polymerization reaction, reaction
Temperature rises to 25 DEG C-70 DEG C, keeps 2-24 hours solidification encystation;(5)Be added dispersant, thickener, stir evenly be made it is micro-
Capsule suspending agent.
Emulsifier of the present invention is that alkylbenzene naphthalene sulfonate, alkyl phenol polyoxyethylene ether phosphate, diphenyl phenol are poly-
Ethylene oxide polyethenoxy ether, styrenated phenol polyoxyethylene ether, APES formaldehyde condensation product, diphenyl phenol polyoxy second
In alkene polyformaldehyde condensation product, castor oil ethylene oxide adduct, NNO, NP, agriculture breast 500, agriculture breast 600, Tween-80, polyvinyl alcohol
One or more.
Dispersant of the present invention is lignosulfonates, fatty acid amide N methyl taurine sodium salt, alkyl phenol polyoxy second
One in alkene ether sulphate, polyoxyethylene polyoxypropylene block copolymer, alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether
Kind is several.
Wetting agent of the present invention is selected from:Lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, alkyl
It is one or more in benzene sulfonic acid sodium salt, polyoxyethylene tristyrene phenyl phosphate, spaonin powder.
Disintegrant of the present invention is selected from:Bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, bicarbonate
It is one or more in sodium.
Filler of the present invention is selected from:Kaolin, diatomite, bentonite, attapulgite, white carbon, starch, lightweight carbon
It is one or more in sour calcium.
Thickener of the present invention is aluminium-magnesium silicate, xanthans, hydroxymethyl cellulose, gum arabic, polyvinyl pyrrole
One kind in alkanone or several.
Antifreezing agent of the present invention is selected from:One or more of ethylene glycol, propylene glycol, glycerine, polyethylene glycol.
Antifoaming agent of the present invention is selected from:Silicone oil, silicone compound, C10-20 saturated fat acids compound, C8-
One or more of 10 aliphatic alcohols compounds and polyoxyethylene glycerol ether.
Capsule skin material of the present invention is tolyl isocyanate, the more toluene diisocyanates of polymethylene, diphenylmethyl
One or more of alkane diisocyanate, Lauxite.
Solvent of the present invention be toluene, dimethylbenzene, ethyl alcohol, N,N-dimethylformamide, chloroform, cyclohexanone,
One or more of hexamethylene, acetone.
PH adjusting agent of the present invention mainly has hydrochloric acid, glacial acetic acid, citric acid, sodium hydroxide, ammonium hydroxide, ethylenediamine, three
One kind in ethanol amine, triethylamine.
The insecticides of the present invention compared with prior art, generate following advantageous effect:It (1), should compared with single dose
Composition is to striped rice borer notable synergistic, hence it is evident that improves control effect, significantly reduces drug cost;(2)Striped rice borer can be slowed down
To the drug resistance of medicament, extend the service life of medicament;(3)Have quick-acting and long-acting functions concurrently to striped rice borer;It (4) can be substantially
Degree reduces field dosage, effectively reduces environmental pollution and pesticide residue;(5) toxicity to other non-target organisms is reduced.
Experimental data
One, reagent agent:Four Tolfenpyrad active compounds;Rynaxypyr active compound;Bromine cyanogen insect amide active compound;
Two, for trying pest:Striped rice borer(2 ages)
Three, assay method:
The method being combined using Toxicity Determination and field trial.
Co-toxicity coefficient of the compounding agent to striped rice borer of different ratio is obtained by Toxicity Determination first, then passes through field
Its clear control effect of the test of pesticide effectiveness, determines the formula rate and optimum amount of compounding agent.
Toxicity Determination:Using dip method.Active compound is calculated into dosage by active ingredient, mother liquor is configured to, adds clear water dilute
5 ~ 7 gradient concentrations are interpreted as, are control with clear water processing, each processing sets 3 repetitions.Select the almost the same children of growth conditions
Worm 20, input fill in the experiment bucket of liquid, are capped gauze(Prevention escape), it is placed in 25 DEG C of insulating boxs, is investigated after 24 h
Death condition records dead borer population, and data are handled with DPS statistical softwares.
Field efficacy:There to be the formula of synergistic effect that missible oil is made obtained by indoor bioassay(EC), suspending agent(SE), can
Wet powder(WP), water-dispersible granules(WDG), aqueous emulsion(EW), micro-capsule suspension(CS)It is tested.Cell is arranged to spray
After dispenser agent, examines preventive effect and determine suitable dosage.
Table 1, table 2 give the toxicity test result of 3 kinds of medicaments and mixture to striped rice borer;
By table 1, table 2 as can be seen that four Tolfenpyrads, Rynaxypyr or bromine cyanogen insect amide show very well striped rice borer
Indoor virulence effect, LC50Respectively 0.133 mg/L, 4.176 mg/L, 3.694 mg/L, Rynaxypyr and tetrazolium worm
The compounding of amide is 20:1~1:120 are all higher than to the co-toxicity coefficient of striped rice borer in 20 ranges, it is shown that good synergistic effect;
The compounding of bromine cyanogen insect amide and four Tolfenpyrads is 20:1~1:120 are all higher than to the co-toxicity coefficient of striped rice borer in 20 ranges, display
Good synergistic effect.
1 Rynaxypyr of table and four Tolfenpyrad different proportion mixtures are to striped rice borer(3 ages)Virulence
2 bromine cyanogen insect amide of table is with four Tolfenpyrad different proportion mixtures to striped rice borer(3 ages)Virulence
Specific implementation mode
The present invention is elaborated below by embodiment, by Rynaxypyr and four Tolfenpyrads with 20:1~1:
20 ratios are processed into dosage form, and the percentage in embodiment is weight percentage;But the present invention is not limited thereto.
Embodiment 1:30% Rynaxypyr, four Tolfenpyrad missible oil
Four Tolfenpyrads 3%, Rynaxypyr 27%, n-butanol 10%, cyclohexanone 10%, solvent naphtha 20%, agriculture breast 600# 3%, castor
Sesame oil polyethylene glycol condensation product 4%, dimethylformamide complements to 100%, stirs evenly, and 30% Rynaxypyr four is made
Tolfenpyrad missible oil.
Embodiment 2:55% Rynaxypyr, four Tolfenpyrad wettable powder
Four Tolfenpyrads 5%, Rynaxypyr 50%, fatty acid amide N methyl taurine sodium salt 8%, spaonin powder 8%, ammonium sulfate
5%, silica 1 5%, precipitated calcium carbonate is mended to 100%, is crushed with airslide disintegrating mill after mixing, and 55% chlorine worm benzoyl is made
Four Tolfenpyrad wettable powder of amine.
Embodiment 3:30% Rynaxypyr, four Tolfenpyrad water dispersible granules
Four Tolfenpyrads 15%, Rynaxypyr 15%, fatty acid amide N methyl taurine sodium salt 4%, Methyl fatty amide benzene sulphur
Sour sodium 3%, polyoxyethylene tristyrene phenyl phosphate 5%, urea 2%, bentonite are supplied to 100%, and 30% chlorine is made in mixing granulation
Four Tolfenpyrad water dispersible granules of worm benzamide.
Embodiment 4:42% Rynaxypyr, four Tolfenpyrad suspending agent
Four Tolfenpyrads 2%, Rynaxypyr 40%, alkyl phenol polyoxyethylene ether 4%, NNO3%, aluminium-magnesium silicate 1%, xanthans
0.15%, ethylene glycol 1%, polyoxyethylene glycerol ether 0.5%, water supplies to 100%, puts into sand mill after evenly mixing, be ground to grain
42% Rynaxypyr, four Tolfenpyrad suspending agent is made in 5 μm of diameter.
Embodiment 5:30% Rynaxypyr, four Tolfenpyrad aqueous emulsion
Four Tolfenpyrads 5%, Rynaxypyr 25%, NP-10 4%, dimethylformamide 5%, cyclohexanone 3%, aluminium-magnesium silicate 3%,
Urea 2%, polyoxyethylene glycerol ether 0.5%, water are supplied to 100%.Active compound is dissolved with solvent, delays solution under constant rotational speed
Slowly it is added in water phase, 30% Rynaxypyr, four Tolfenpyrad aqueous emulsion is made.
Embodiment 6:30% Rynaxypyr, four Tolfenpyrad micro-capsule suspension
Four Tolfenpyrads 5%, Rynaxypyr 25%, dimethylformamide 5%, 0.5 % of methyl diphenylene diisocyanate gather
Vinyl alcohol 2%, fatty acid amide N methyl taurine sodium salt 1%, hexamethylene diamine 1%, gum arabic 2%, water complements to 100%, by above-mentioned
30% Rynaxypyr, four Tolfenpyrad micro-capsule suspension is made in method.
Embodiment 7:14% bromine cyanogen insect amide, four Tolfenpyrad granule
Four Tolfenpyrads 6%, bromine cyanogen insect amide 8%, fatty acid amide N methyl taurine sodium salt 4%, Methyl fatty amide benzene sulfonic acid sodium salt
3%, polyoxyethylene tristyrene phenyl phosphate 5%, urea 2%, attapulgite supplies to 100%, and mixing extruder grain is made 14%
Four Tolfenpyrad water dispersible granules of bromine cyanogen insect amide.
Embodiment 8:22% bromine cyanogen insect amide, four Tolfenpyrad micro-capsule suspension
Four Tolfenpyrads 8%, bromine cyanogen insect amide 14%, dimethylformamide 5%, 0.5 % of methyl diphenylene diisocyanate, poly- second
Enol 2%, fatty acid amide N methyl taurine sodium salt 1%, hexamethylene diamine 1%, gum arabic 2%, water complements to 100%, by above-mentioned side
Legal system obtains 22% bromine cyanogen insect amide, four Tolfenpyrad micro-capsule suspension
The use of the method that above-mentioned composition pesticide prevents striped rice borer is to add water to be made into suspension spray in striped rice borer early period of origination to make
With or uniformly spread fertilizer over the fields on beach, prevent striped rice borer.
Visible above, Rynaxypyr or bromine cyanogen insect amide, four Tolfenpyrads, two kinds of medicament mixtures are in prevention striped rice borer
Aspect has good application prospect.
In addition to this, which can also be fabricated to ultra low volume liquids for the skills such as air-spraying and thermal fog, aerosol formulations
The dosage form that art personnel are readily apparent that is used for the prevention of striped rice borer.
Claims (4)
1. a kind of insecticides containing four Tolfenpyrads, it is characterised in that:It is made of effective constituents A and B and auxiliary material component,
Wherein A is four Tolfenpyrads, and B is Rynaxypyr or bromine cyanogen insect amide, the total weight percentage composition of active ingredient is 1% ~
90%。
2. insecticides according to claim 1, it is characterised in that:The quality of A and B in the insecticides
Than being 20:1~1:20.
3. insecticides according to claim 1, it is characterised in that:The quality of A and B in the insecticides
Than being 10:1~1:10.
4. insecticides according to claim 1, it is characterised in that:The dosage form of the insecticides is breast
Oil, suspending agent, water-dispersible granules, wettable powder, aqueous emulsion, micro-capsule suspension.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810787025.9A CN108782571A (en) | 2018-07-18 | 2018-07-18 | A kind of insecticides and its application method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810787025.9A CN108782571A (en) | 2018-07-18 | 2018-07-18 | A kind of insecticides and its application method |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108782571A true CN108782571A (en) | 2018-11-13 |
Family
ID=64076872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810787025.9A Pending CN108782571A (en) | 2018-07-18 | 2018-07-18 | A kind of insecticides and its application method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108782571A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103068235B (en) * | 2010-06-18 | 2016-04-20 | 拜耳知识产权有限责任公司 | There is the active ingredient combination of desinsection and acaricidal properties |
-
2018
- 2018-07-18 CN CN201810787025.9A patent/CN108782571A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103068235B (en) * | 2010-06-18 | 2016-04-20 | 拜耳知识产权有限责任公司 | There is the active ingredient combination of desinsection and acaricidal properties |
Non-Patent Citations (1)
Title |
---|
杨吉春等: ""2014年公开的新农药品种"", 《农药》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101703051B (en) | Insecticidal composition containing cyanogen insect amide and molosultap and application thereof | |
CN104472511B (en) | A kind of molluscicide compositions containing the methaldehyde and emamectin benzoate | |
CN104621152A (en) | Seed coating agent containing spirotetramat | |
US11612165B2 (en) | Pesticide composition for controlling Spodoptera frugiperda | |
CN104604909A (en) | Seed coating containing benfuracarb | |
CN103155929B (en) | Binary pesticide composition and application thereof | |
CN105638690B (en) | A kind of composition pesticide containing emamectin benzoate and niclosamide ethanolamine salt | |
CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
CN104585224A (en) | Pesticide composition containing fluensulfone and pyrethroid insecticide | |
CN108782571A (en) | A kind of insecticides and its application method | |
CN110521729A (en) | A kind of composition pesticide and its application | |
CN103155935B (en) | Binary pesticide composition | |
CN105831147B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and lambda-cyhalothrin and application thereof | |
CN106665614A (en) | Weeding composition containing penoxsulam, bispyribac-sodium and mefenacet | |
CN108719295A (en) | A kind of molluscicide composition containing Tea Saponin | |
CN110495468A (en) | A kind of coating agent for seed and its application method with bird dispelling function | |
CN109287651A (en) | A kind of medicament composition containing Biphenthrin | |
CN115363031B (en) | Herbicide composition containing Lancotrione-sodium salt and propanil | |
CN107136116A (en) | A kind of molluscicide composition containing emamectin benzoate | |
CN112021319B (en) | Weeding composition containing pentoxazone and dithiopyr | |
CN108029692B (en) | Compound composition containing sulfur fluorine oxime ether and application thereof | |
CN105660646A (en) | Agricultural insecticide composition and application thereof | |
CN110731349A (en) | insecticide composition containing tebuconazole amide | |
CN106665625A (en) | Insecticidal composition and application thereof | |
CN105746567B (en) | A kind of agricultural pesticide composition and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181113 |