CN101703051B - Insecticidal composition containing cyanogen insect amide and molosultap and application thereof - Google Patents
Insecticidal composition containing cyanogen insect amide and molosultap and application thereof Download PDFInfo
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- CN101703051B CN101703051B CN 200910227086 CN200910227086A CN101703051B CN 101703051 B CN101703051 B CN 101703051B CN 200910227086 CN200910227086 CN 200910227086 CN 200910227086 A CN200910227086 A CN 200910227086A CN 101703051 B CN101703051 B CN 101703051B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
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Abstract
The invention disclose an insecticidal composition using cyanogen insect amide and molosultap as effective components, prepared into aqueous emulsion (EW), micro emulsion (ME), suspending agent (SC), wettable powder (WP) or water dispersivity grain (WDG) by adding solvents and latent solvents, emulsifying agents, dispersing agents, antifreezing agents, defoaming agents, thickening agents, stabilizing agents or adhesives according to the method known by technicians in the technical field. The weight ratio of the cyanogen insect amide and the molosultap is 1:0.1-200, and the sum of the weights of the cyanogen insect amide and the molosultap is 2.2-70% of the total weight of the insecticidal composition. The composition has the remarkable synergized effect on the veneficium of insects, has the characteristics of broad insecticidal spectrum, high efficiency, quick effect, low poison to mammals and natural enemies, less insecticide amount, low agricultural cost, no cross resistance between insecticides and the like, and overcomes and defers the generation of the insecticide resistance of injurious insects. The composition effectively prevents and controls agricultural injurious insects and is particularly suitable for preventing and controlling rice injurious insects.
Description
Technical field
The present invention relates to a kind of Pesticidal combination that contains cyanogen insect amide and desinsection list and uses thereof.
Background technology
Cyanogen insect amide (cyantraniliprole), commodity are called cyazypyr
TMThe experiment code name is DPX-HGW86; Chemical name is 3-bromo-N-(4-cyanic acid-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides, is a kind of novel O-formammidotiazol-benzamide insecticide that du pont company develops.Cyanogen insect amide belongs to insect ryania acceptor inhibitor; Mainly discharge to show and tag and stomach poison function through the intracellular calcium ion of inducing insect ryania receptor modulators; Can be used for the control of various crop insects such as paddy rice, vegetables, cotton, beet; Especially the control to various lepidoptera pests has special efficacy, other commercialization insecticide varieties that its control efficiency obviously is superior to using in the current production, and there are not cross resistance in other insecticides.Based on this; Cyanogen insect amide is described as efficient pesticides of new generation in the world, but owing to complex synthetic route, cost height and Intellectual Property Rights, still can't produce in China at present; This to a great extent limit its promote the use of, particularly some economically less developed regions more are difficult to promote.
Desinsection list (monosultap), chemical name are 2-N, TMSDMA N dimethylamine base-1; Two (sodium thiosulfate base) propane of 3-; In agricultural production, having used the old kind of agricultural chemicals in year surplus in the of ten, belonged to sandworm toxin insecticide, is a kind of nAChR inhibitor; Insect had strong tag, stomach toxicity, stifling and systemic action; Various pests such as the snout moth's larva of rice, rice leaf roller, armyworm, leafhopper class, plant hopper are all had good effect, are the specific drugs of the snout moth's larva of rice and rice leaf folder, and production cost and agricultural cost are all very low.But this medicament dosage is big, quick-acting is relatively poor relatively, has made insect produce serious pesticide resistance, is badly in need of seeking mutually composite with it medicament, to change the mode of action, reduces pesticide resistance, prolongs the service life of this medicine.
The inventor discovery cyanogen insect amide and desinsection list in the process that research cyanogen insect amide and desinsection list are mixed are mixed; Not only keep the insecticidal effect of original medicament, and have obvious synergistic effect, reduce the pest resistance to insecticide risk and obviously reduce effect such as agricultural cost.Through looking into the new Pesticidal combination of not seeing relevant cyanogen insect amide and desinsection list at present as yet.
Summary of the invention
The Pesticidal combination that the purpose of this invention is to provide a kind of cyanogen insect amide and desinsection list.
The present invention adopts the modern survey technology of giving birth to; And the co-toxicity coefficient method screening of utilization Sun Y P&Johnson E R (1960) to obtain with cyanogen insect amide and desinsection list be the Pesticidal combination of active ingredient; Through adding solvent and cosolvent, emulsifier, dispersant, antifreezing agent, antifoaming agent, thickener, stabilizing agent or the adhesive of Different Weight, be mixed with aqueous emulsion (EW) or microemulsion (ME), suspending agent (SC), wetting powder (WP), water-dispersible granules (WDG) according to those skilled in the art of the present technique's known method.The weight ratio of cyanogen insect amide and desinsection list is 1: 0.1～200, and the weight sum of cyanogen insect amide and desinsection list is 2.2～70% of a Pesticidal combination gross weight.
When the present invention was mixed with aqueous emulsion, the solvent of interpolation was one or more the mixture in water, the xylol, and solvent load accounts for 20～60% of composition total weight; Cosolvent is one or more the mixture in methyl alcohol, acetone, pyrrolidones, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and the cosolvent consumption accounts for 1～5% of composition total weight; Emulsifier is one or more the mixture in APES, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, APES phosphate, polyoxyethylene polyoxypropylene block copolymer, phenethyl phenol polyethenoxy polyethenoxy ether, alkylbenzenesulfonate, the lignosulfonates, and the emulsifier consumption accounts for 10～30% of composition total weight; Dispersant is polyvinyl alcohol, gum Arabic or its mixture, and dispersant dosage accounts for 5～10% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 1～8% of composition total weight; Antifoaming agent can be one or more the mixture in organic silicone oil, the epoxidized soybean oil, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight.
When the present invention was mixed with microemulsion, the solvent of interpolation was one or more the mixture in water, toluene, the xylol, and solvent load accounts for 20～60% of composition total weight; Cosolvent is one or more the mixture in methyl alcohol, pyrrolidones, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and the cosolvent consumption accounts for 1～5% of composition total weight; Emulsifier is one or more the mixture in alkylbenzenesulfonate, alkyl two polyoxy vinyl sulfonates, APES phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, phenethyl phenol polyethenoxy ether phosphate, polyoxyethylene polyoxypropylene block copolymer, APES, castor oil polyoxyethylene polyethenoxy ether, the styrenated phenol APEO, and the emulsifier consumption accounts for 10～30% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 1～8% of composition total weight; Stabilizing agent is one or more the mixture in urea, soluble starch, cresyl glycidyl ether, the phenyl glycidyl ether, and stabilizing agent dosage accounts for 0.5～10% of composition total weight; Antifoaming agent is one or more the mixture in organic silicone oil, epoxidized soybean oil, the methyl alcohol, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight.
When the present invention was mixed with suspending agent, the solvent of interpolation was one or more the mixture in water, xylol, cyclohexanone, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and solvent load accounts for 20～60% of composition total weight; Wetting dispersing agent is one or more the mixture in lignosulfonates, alkylsulfonate, aliphatic alcohol sulfate, alkylaryl sulfonates, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt, polyoxyethylene fatty acid ester, APES phosphate, polyoxyethylene polyoxypropylene block copolymer, APES, the AEO, and the wetting dispersing agent consumption accounts for 0.5～40% of composition total weight; Thickener is one or more the mixture in CMC, polyvinyl alcohol, xanthans, gum Arabic, polyvinylpyrrolidone, bentonite, the aluminium-magnesium silicate, and the thickener consumption accounts for 0.2～5% of composition total weight; Stabilizing agent is one or more the mixture in urea, soluble starch, sodium sorbate, pyrogallic acid, cresyl glycidyl ether, the phenyl glycidyl ether, and stabilizing agent dosage accounts for 0.5～10% of composition total weight; Antifoaming agent is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, the epoxidized soybean oil, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 0.1～5% of composition total weight.
When the present invention is mixed with wetting powder; The dispersant that adds is one or several the mixture in lignosulfonates, fatty acid amide N methyl taurine sodium salt, APES sulphate, fatty acid ester sulphate, polyoxyethylene polyoxypropylene block copolymer, APES, the AEO, and dispersant dosage accounts for 5～35% of composition total weight; Wetting agent is one or several the mixture among dodecyl benzene sulfonate, bay alcohol radical sulphate, farming breast 2000, SOPA230, SOPA270, SOPA235, the wetting and penetrating agent F, and the wetting agent consumption accounts for 5～30% of composition total weight; Carrier is one or more the mixture in kaolin, bentonite, diatomite, atlapulgite, white carbon black, the precipitated calcium carbonate, and the carrier consumption accounts for 15～75% of composition total weight.
When the present invention is mixed with water-dispersible granules; The wetting agent that adds is one or several the mixture in fatty acid amide N methyl taurine sodium salt, lignosulfonates, APES sulphate, alkylnaphthalene sulfonate, fatty acid ester sulphate, APES, the AEO, and the wetting agent consumption accounts for 5～30% of composition total weight; Dispersant is one or several the mixture in ethoxylated dodecyl alcohol, alkylaryl APEO, polyoxyethylene polyoxypropylene block copolymer, naphthalenesulfonic acid-formaldehyde condensate, dioctyl sodium sulphosuccinate, the acrylate homopolymer sodium salt, and dispersant dosage accounts for 5～10% of composition total weight; Binding agent is one or more the mixture in starch, polyvinyl acetate, polyvinyl alcohol, polyethylene glycol, sodium silicate, gelatin, cyclodextrin, the gum Arabic, and the binding agent consumption accounts for 1～10% of composition total weight; Disintegrant is one or more the mixture in urea, magnesium chloride, aluminium chloride, sodium chloride, the ammonium sulfate, and the disintegrant consumption accounts for 5～10% of composition total weight; Carrier is one or more the mixture in kaolin, diatomite, atlapulgite, white carbon black, bentonite, clay, precipitated calcium carbonate, talcum powder, the montmorillonite, and the carrier consumption accounts for 15～70% of composition total weight.
The preparation that the present invention is mixed with through processing; After converting water dilution, can adopt spraying, atomizing, dust, spread fertilizer over the fields or mode such as irrigation imposes on Different Crop and occasion pest control, it is excellent especially to prevent and treat snout moth's larva of rice effect; The control mythimna separata is had significant synergies; Compare with single agent, the insecticidal effect of paddy rice paddy stem borer and rice leaf roller is significantly higher than the effect of corresponding single agent agricultural chemicals, and can overcomes or delay the drug-fast generation of harmful insect.Especially old kind desinsection list; Dosage is big when using separately, and general every mu of effective ingredient consumption is more than 50 grams, adopts the present invention; Every mu of effective ingredient consumption is merely 4～20 grams and just can effectively prevents and treats various insects; Be not merely the old farmer's medicine kind desinsection list that has used on the market for many years and opened up new application, prolonged the safe operating life of old farmer's medicine kind, and greatly reduce production and use cost.
Embodiment
In order to understand essence of the present invention better, below in conjunction with embodiment the present invention is described further, but never is limited to following embodiment.
Embodiment 1: take by weighing cyanogen insect amide 10g, desinsection list 1g, lignosulfonates 10g, polyoxyethylene polyoxypropylene block copolymer 9g, APES 2g, polyoxyethylene sorbitol acid anhydride ester 2g, propane diols 2g, polyvinyl alcohol 2g, methyl alcohol 3g, dimethyl formamide 2g, epoxidized soybean oil 1g, xylol 5g and deionized water 51g earlier.Then, stir down in normal temperature and high speed shear oil phase is added aqueous phase, mix and make its average liquid, promptly obtain 11% aqueous emulsion product directly less than 2 μ m.
Embodiment 2: take by weighing cyanogen insect amide 2g, desinsection list 0.2g, phenyl phenol polyoxyethylene ether phosphate 10g, polyoxyethylene fatty acid ester 10g, polyoxyethylene polyoxypropylene block copolymer 5g, alkylbenzenesulfonate 5g, organic silicone oil 3g, gum Arabic 5g, sorbierite 2g, acetone 2g, dimethyl sulfoxide (DMSO) 3g, pyrrolidones 1g and deionized water 51.8g earlier.Then, stir down in normal temperature and high speed shear oil phase is added aqueous phase, mix and make its average liquid, promptly obtain 2.2% aqueous emulsion product directly less than 2 μ m.
Embodiment 3: take by weighing cyanogen insect amide 1g, desinsection list 10g, phenethyl phenol polyethenoxy ether phosphate 10g, polyoxyethylene polyoxypropylene block copolymer 10g, phenethyl phenol polyethenoxy polyethenoxy ether 5g, polyvinyl alcohol 2g, ethylene glycol 1g, ethyl acetate 3g, methyl alcohol 2g, epoxidized soybean oil 1g, deionized water 55g earlier.Then, stir down in normal temperature and high speed shear oil phase is added aqueous phase, mix and make its average liquid, promptly obtain 11% aqueous emulsion product directly less than 2 μ m.
Embodiment 4: take by weighing cyanogen insect amide 10g, desinsection list 10g, dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 5g, polyoxyethylene polyoxypropylene block copolymer 5g, APES 4g, ethyl acetate 5g, polyethylene glycol 5g, epoxidized soybean oil 2g and deionized water 48g.Under normal temperature and high speed shear mixing and emulsifying, each component being mixed makes its average liquid footpath promptly obtain transparent and uniform 20% microemulsion product less than 0.1 μ m.
Embodiment 5～7: the composition ME that can prepare following different content by embodiment 4 similar methods
| Embodiment | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Cyanogen insect amide (g) | 5 | ?2 | 0.1 |
| Desinsection list (g) | 25 | ?20 | 20 |
| Solvent (g) | Methyl alcohol 3, toluene 2 | Xylol 6, ethyl acetate 4 | DMF 8, pyrrolidones 2 |
| Emulsifier (g) | Castor oil polyoxyethylene polyethenoxy ether 8, styrenated phenol APEO 8, alkylbenzenesulfonate 10 | Alkyl two polyoxy vinyl sulfonates 5, phenethyl phenol polyethenoxy polyethenoxy ether 10, polyoxyethylene polyoxypropylene down section copolymer 5 | Polyoxyethylene polyoxypropylene down section copolymer 6, diphenyl phenol polyethenoxy polyethenoxy ether 6, dodecyl benzene sulfonate 4 |
| Stabilizing agent (g) | Tolyl glycidic alcohol 5 | Urea 1, methyl alcohol 3 | Phenyl glycidyl ether 2, soluble starch 2 |
| Antifreezing agent (g) | Glycerine 2 | Ethylene glycol 2, sorbierite 2 | Sorbierite 2, propane diols 1 |
| Antifoaming agent (g) | Organic silicone oil 1 | Epoxidized soybean oil 1 | Epoxidized soybean oil 1 |
| Deionized water (g) | 31 | ?39 | 45.9 |
| Composition levels | 30％ | 22％ | 20.1％ |
Embodiment 8: take by weighing cyanogen insect amide 10g, desinsection list 1g, sodium lignin sulfonate 10g, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt 10g, cresyl glycidyl ether 1g, gum Arabic 1g, polyvinylpyrrolidone 4g, polyethylene glycol 5g and water 57g.With above-mentioned each component mix and in ball mill ball mill grinding formed thick dispersion liquid in 4 hours, make its average grain diameter can obtain 11% required suspending agent product through the wet method ultramicro grinding again less than 5 μ m.
Embodiment 9～11: the composition SC for preparing following different content by embodiment 8 similar methods
| Embodiment | Embodiment 9 | Embodiment 10 | Embodiment 11 |
| Cyanogen insect amide (g) | ?0.3 | 0.1 | 1 |
| Desinsection list (g) | ?29.7 | 19.9 | 24 |
| Wetting dispersing agent (g) | APES phosphate 5, polyoxyethylene polyoxypropylene block copolymer 5, lignosulfonates 8 | AEO 10, alkylaryl APEO 10, alkylaryl sulfonates 8, | APES 10, aliphatic alcohol sulfate 5, polyoxyethylene fatty acid ester 5 |
| Tackifier (g) | Carboxymethyl cellulose salt 2, polyvinyl alcohol 3 | Soluble starch 2 | Xanthans 1, carboxymethyl cellulose salt 1 |
| Antifreezing agent (g) | Propane diols 2, glycerine 2 | Glycerine 2, sorbierite 2 | Ethylene glycol 1, polyethylene glycol 1 |
| Antifoaming agent (g) | Organic silicone oil 1, methyl alcohol 2 | Ethanol 2, epoxidized soybean oil 1 | Organic silicone oil 2 |
| Stabilizing agent (g) | Pyrogallic acid 1, urea 1 | Soluble starch 1, cresyl glycidyl ether 1 | Phenyl glycidyl ether 1, sodium sorbate 1 |
| Solvent (g) | Ethyl acetate 2, xylol 2 | Methyl alcohol 3, dimethyl formamide 2 | Dimethyl sulfoxide (DMSO) 1, cyclohexanone 1 |
| Deionized water (g) | ?34 | 36 | 45 |
| Composition levels | ?30％ | 20％ | 25％ |
Embodiment 12: take by weighing cyanogen insect amide 0.1g, desinsection list 19.9g, sodium lignin sulfonate 10g, dodecyl benzene sulfonate 10g and kaolin 60g; It is fully mixed, and mixture is pulverized in airslide disintegrating mill and can be made the 20% wetting powder product that average grain diameter is 20 μ m.
Embodiment 13～15: the composition WP for preparing following different content by embodiment 12 similar methods
| Embodiment | Embodiment 13 | Embodiment 14 | Embodiment 15 |
| Cyanogen insect amide (g) | ?10 | ?1 | ?0.5 |
| Desinsection list (g) | ?10 | ?14 | ?35.5 |
| Wetting agent (g) | Dodecyl benzene sulfonate 10, SOPA2305, SOPA2355 | Bay alcohol radical sulphate 15, SOPA 2705, moistening penetrating agent JFC 5 | Neopelex 10, farming breast 2,000 10 |
| Dispersant (g) | Fatty acid ester sulphate 6, APES sulphate 6, APES 10 | Fatty acid amide N methyl taurine sodium salt 6, alkylnaphthalene sulfonate formaldehyde condensation products 6, polyoxyethylene polyoxypropylene base ether down section copolymer 5 | Lignosulfonates 8, polyoxyethylene polyoxypropylene base ether down section copolymer 6, AEO 6 |
| Filler (g) | Diatomite 28, precipitated calcium carbonate 10 | Bentonite 33, white carbon 10 | Atlapulgite 24 |
| Composition levels | ?20％ | ?24％ | ?36％ |
Embodiment 16: take by weighing cyanogen insect amide 1g, desinsection list 19g, APES sulphate 5g, ethoxylated dodecyl alcohol 15g, sodium silicate 2g, polyethylene glycol 4g, starch 2g, urea 2g, atlapulgite 10g and kaolin 42g.Mixture is carried out granulation after the ultra-fine grinding, drying, screening, and promptly to obtain average grain diameter be 20% water-dispersible granules product about 4 μ m.
Embodiment 17～20: the composition WDG for preparing following different content by embodiment 16 similar methods
| Embodiment | Embodiment 17 | Embodiment 18 | Embodiment 19 | Embodiment 20 |
| Cyanogen insect amide (g) | 1 | 1 | 0.1 | 0.2 |
| Desinsection list (g) | 49 | 69 | 20.4 | 25.8 |
| Wetting agent (g) | Sodium lignin sulfonate 5g, naphthalene sulfonic acid-formaldehyde condensation product 5 | Fatty acid amide N methyl taurine sodium salt 6, APES 6 | Sodium alkyl benzene sulfonate 15, AEO 10 | Sodium alkyl benzene sulfonate 15 fatty acid sulphate 15 |
| Dispersant (g) | Alkylnaphthalene sulfonate formaldehyde condensation products 5, dodecyl polyoxyethylene ether phosphate 5 | Polyoxyethylene polyoxypropylene block copolymer 3, acrylate homopolymer sodium salt 2 | Dioctyl sodium sulphosuccinate 5, alkylaryl APEO 5 | Acrylate homopolymer sodium salt 2, polyoxyethylene polyoxypropylene block copolymer 3 |
| Binding agent (g) | Sodium silicate 1, gelatin 1 | Polyvinyl alcohol 0.5, starch 0.5 | Polyvinyl acetate 1, gum Arabic 0.5 | Gelatin 1.5, cyclodextrin 0.5 |
| Disintegrant (g) | Urea 1 | Urea 0.5, magnesium chloride 0.5 | Ammonium sulfate 1, sodium chloride 1 | Aluminium chloride 0.5, urea 0.5 |
| Carrier (g) | Bentonite 15, white carbon 12 | Clay 7, atlapulgite 4 | Talcum powder 21, diatomite 20 | Montmorillonite 10, precipitated calcium carbonate 26 |
| Composition levels | 50％ | 70％ | 20.5％ | 26％ |
Embodiment 21: cyanogen insect amide and desinsection list are mixed to proportioning screening and the toxicity test of armyworm (Mythimna separata)
Adopt infusion process will supply the reagent agent to be made into certain density mother liquor, it is for use to be diluted to 5 concentration with clear water again, establishes clear water and is contrast.Get fresh and tender maize leaves and be cut into the fragment of the long big or small basically identical of about 50mm, the blade that shears flood 10 seconds in the confession reagent liquid for preparing, after taking-up lets it dry naturally, put into the culture dish (Ф 90mm) that is lined with filter paper in advance.In ware, insert mythimna separata 3 instar larvaes then, 10 in every ware, every concentration repeats for 3 times.Dispose, cover the ware lid, place the recovery indoor cultivation, routine observation, inspection record death condition behind 48hr is calculated lethality (%), and obtains virulence regression equation formula, correlation coefficient (r) and the lethal concentration of 50 (LC according to the probit value analytical method
50).Co-toxicity coefficient (CTC) method that adopts Sun& Johnson (1960) to propose is estimated synergy.Usually, CTC represented to have synergistic effect greater than 120 o'clock, expression tool summation action between CTC is in 80～120, and CTC is less than being expressed as antagonism at 80 o'clock.The computing formula of co-toxicity coefficient is following:
The percentage composition of B in ATI * mixture of percentage composition+medicament B of A in ATI * mixture of theoretical toxicity index (TTI)=medicament A
The toxicity test result that cyanogen insect amide and desinsection list are mixed to armyworm sees table 1.It is thus clear that; Cyanogen insect amide and desinsection list are mixed with the ratio of 1: 0.1,1: 0.5,1: 1,1: 10,1: 20,1: 50,1: 100 and 1: 200 armyworm are all shown as obvious synergistic effect, and co-toxicity coefficient is respectively 151.15,124.88,179.79,200.58,163.17,157.68,141.02 and 122.20.
Table 1 cyanogen insect amide and desinsection list are mixed to the toxicity test result (48hr) of armyworm
| Supply the reagent agent | The active ingredient weight ratio | Regression equation (Y=a+bx) | Correlation coefficient (r) | LC 50 (mg/L) | CTC |
| Cyanogen insect amide (C) | -- | Y＝2.1289+2.6858x | 0.9784 | 1.94 | -- |
| Desinsection list (B) | -- | Y＝-1.3053+2.9079x | 0.9829 | 147.34 | -- |
| C∶B | 1∶0.1 | Y＝4.7342+1.7813x | 0.9931 | 1.41 | 151.15 |
| C∶B | 1∶0.5 | Y＝4.5936+1.9155x | 0.9757 | 1.63 | 124.88 |
| C∶B | 1∶1 | Y＝4.3419+2.0041x | 0.9464 | 2.13 | 179.79 |
| C∶B | 1∶10 | Y＝3.2089+1.8414x | 0.9879 | 9.39 | 200.58 |
| C∶B | 1∶20 | Y＝2.4834+1.9425x | 0.9913 | 19.75 | 163.17 |
| C∶B | 1∶50 | Y＝3.7745+2.0456x | 0.9907 | 37.74 | 157.68 |
| C∶B | 1∶100 | Y＝1.6582+1.8808x | 0.9454 | 59.81 | 141.02 |
| C∶B | 1∶200 | Y＝0.4371+2.1893x | 0.9714 | 121.39 | 122.20 |
Embodiment 22: the drug effect test of field zone of cyanogen insect amide-desinsection list mixture control paddy rice paddy stem borer
Result of the test is seen table 2.It is thus clear that cyanogen insect amide-desinsection list mixture has good control efficiency to the paddy rice paddy stem borer.When dispenser dosage is 5,10 and 20g a.i./mu, behind the medicine 7 with the control efficiency of 20d, each embodiment product reaches respectively more than 85% and 98%, obviously is superior to cyanogen insect amide 2g a.i./mu and the desinsection list 50g a.i./mu control efficiency to the paddy rice paddy stem borer.
Table 2. cyanogen insect amide-desinsection list mixture is to the field efficacy fruit (Yongzhou, 2009.9) of paddy rice paddy stem borer
Annotate: data are to repeat mean values 3 times in the table, and are not remarkable with being illustrated on the P=0.05 level difference with same letter person behind the column of figure.Following table together.
Embodiment 23: the drug effect test of field zone of cyanogen insect amide-desinsection list mixture control rice leaf roller
Result of the test is seen table 3.It is thus clear that cyanogen insect amide-desinsection list mixture has good control efficiency to the paddy rice rice leaf roller.Behind the medicine 7,20 and the control efficiency of 30d, each embodiment product reached more than 90%, obviously is superior to cyanogen insect amide 2g a.i./mu and the desinsection list 50g a.i./mu control efficiency to rice leaf roller when dispenser dosage was 5,10 and 16g a.i./mu.
Table 3. cyanogen insect amide-desinsection list mixture is to the field efficacy fruit (Changsha, 2009.9) of rice leaf roller
Claims (7)
1. the Pesticidal combination of cyanogen insect amide and desinsection list; It is characterized in that with cyanogen insect amide [3-bromo-N-(4-cyanic acid-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides] and desinsection list [2-N; TMSDMA N dimethylamine base-1; Two (sodium thiosulfate base) propane of 3-] be desinsection effective active composition; Be mixed with aqueous emulsion or microemulsion, suspending agent, wetting powder, water-dispersible granules, the weight ratio of cyanogen insect amide and desinsection list is 1: 0.1～200, and the weight sum of cyanogen insect amide and desinsection list is 2.2～70% of a Pesticidal combination gross weight.
2. the Pesticidal combination of cyanogen insect amide according to claim 1 and desinsection list; It is characterized in that adding solvent, cosolvent, emulsifier, dispersant, antifreezing agent, when antifoaming agent is mixed with aqueous emulsion; The solvent that adds is one or more the mixture in water, the xylol, and solvent load accounts for 20～60% of composition total weight; Cosolvent is one or more the mixture in methyl alcohol, acetone, pyrrolidones, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and the cosolvent consumption accounts for 1～5% of composition total weight; Emulsifier is one or more the mixture in APES, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid ester, APES phosphate, polyoxyethylene polyoxypropylene block copolymer, phenethyl phenol polyethenoxy polyethenoxy ether, alkylbenzenesulfonate, the lignosulfonates, and the emulsifier consumption accounts for 10～30% of composition total weight; Dispersant is polyvinyl alcohol, gum Arabic or its mixture, and dispersant dosage accounts for 5～10% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 1～8% of composition total weight; Antifoaming agent can be one or more the mixture in organic silicone oil, the epoxidized soybean oil, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight.
3. the Pesticidal combination of cyanogen insect amide according to claim 1 and desinsection list; It is characterized in that adding solvent, cosolvent, emulsifier, antifreezing agent, stabilizing agent, when antifoaming agent is mixed with microemulsion; The solvent that adds is one or more the mixture in water, toluene, the xylol, and solvent load accounts for 20～60% of composition total weight; Cosolvent is one or more the mixture in methyl alcohol, pyrrolidones, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and the cosolvent consumption accounts for 1～5% of composition total weight; Emulsifier is one or more the mixture in alkylbenzenesulfonate, alkyl two polyoxy vinyl sulfonates, APES phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, phenethyl phenol polyethenoxy ether phosphate, polyoxyethylene polyoxypropylene block copolymer, APES, castor oil polyoxyethylene polyethenoxy ether, the styrenated phenol APEO, and the emulsifier consumption accounts for 10～30% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 1～8% of composition total weight; Stabilizing agent is one or more the mixture in urea, soluble starch, cresyl glycidyl ether, the phenyl glycidyl ether, and stabilizing agent dosage accounts for 0.5～10% of composition total weight; Antifoaming agent is one or more the mixture in organic silicone oil, epoxidized soybean oil, the methyl alcohol, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight.
4. the Pesticidal combination of cyanogen insect amide according to claim 1 and desinsection list; It is characterized in that adding solvent, wetting dispersing agent, thickener, stabilizing agent, antifoaming agent, when antifreezing agent is mixed with suspending agent; The solvent that adds is one or more the mixture in water, xylol, cyclohexanone, ethyl acetate, dimethyl formamide, the dimethyl sulfoxide (DMSO), and solvent load accounts for 20～60% of composition total weight; Wetting dispersing agent is one or more the mixture in lignosulfonates, alkylsulfonate, aliphatic alcohol sulfate, alkylaryl sulfonates, polyaryl phenol polyoxy ethyl ether phosphate alkylamine salt, polyoxyethylene fatty acid ester, APES phosphate, polyoxyethylene polyoxypropylene block copolymer, APES, the AEO, and the wetting dispersing agent consumption accounts for 0.5～40% of composition total weight; Thickener is one or more the mixture in CMC, polyvinyl alcohol, xanthans, gum Arabic, polyvinylpyrrolidone, bentonite, the aluminium-magnesium silicate, and the thickener consumption accounts for 0.2～5% of composition total weight; Stabilizing agent is one or more the mixture in urea, soluble starch, sodium sorbate, pyrogallic acid, cresyl glycidyl ether, the phenyl glycidyl ether, and stabilizing agent dosage accounts for 0.5～10% of composition total weight; Antifoaming agent is one or more the mixture in organic silicone oil, methyl alcohol, ethanol, the epoxidized soybean oil, and the antifoaming agent consumption accounts for 0.5～8% of composition total weight; Antifreezing agent is one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, and the antifreezing agent consumption accounts for 0.1～5% of composition total weight.
5. the Pesticidal combination of cyanogen insect amide according to claim 1 and desinsection list; It is characterized in that adding dispersant, wetting agent, when carrier is mixed with wetting powder; The dispersant that adds is one or several the mixture in lignosulfonates, fatty acid amide N methyl taurine sodium salt, APES sulphate, fatty acid ester sulphate, polyoxyethylene polyoxypropylene block copolymer, APES, the AEO, and dispersant dosage accounts for 5～35% of composition total weight; Wetting agent is one or several the mixture among dodecyl benzene sulfonate, bay alcohol radical sulphate, farming breast 2000, SOPA230, SOPA270, SOPA235, the wetting and penetrating agent F, and the wetting agent consumption accounts for 5～30% of composition total weight; Carrier is one or more the mixture in kaolin, bentonite, diatomite, atlapulgite, white carbon black, the precipitated calcium carbonate, and the carrier consumption accounts for 15～75% of composition total weight.
6. the Pesticidal combination of cyanogen insect amide according to claim 1 and desinsection list; It is characterized in that adding wetting agent, dispersant, binding agent, disintegrant, when carrier is mixed with water-dispersible granules; The wetting agent that adds is one or several the mixture in fatty acid amide N methyl taurine sodium salt, lignosulfonates, APES sulphate, alkylnaphthalene sulfonate, fatty acid ester sulphate, APES, the AEO, and the wetting agent consumption accounts for 5～30% of composition total weight; Dispersant is one or several the mixture in ethoxylated dodecyl alcohol, alkylaryl APEO, polyoxyethylene polyoxypropylene block copolymer, naphthalenesulfonic acid-formaldehyde condensate, dioctyl sodium sulphosuccinate, the acrylate homopolymer sodium salt, and dispersant dosage accounts for 5～10% of composition total weight; Binding agent is one or more the mixture in starch, polyvinyl acetate, polyvinyl alcohol, polyethylene glycol, sodium silicate, gelatin, cyclodextrin, the gum Arabic, and the binding agent consumption accounts for 1～10% of composition total weight; Disintegrant is one or more the mixture in urea, magnesium chloride, aluminium chloride, sodium chloride, the ammonium sulfate, and the disintegrant consumption accounts for 5～10% of composition total weight; Carrier is one or more the mixture in kaolin, diatomite, atlapulgite, white carbon black, bentonite, clay, precipitated calcium carbonate, talcum powder, the montmorillonite, and the carrier consumption accounts for 15～70% of composition total weight.
7. according to the purposes of each described cyanogen insect amide in the claim 1～6 and desinsection list insecticides, it is characterized in that the virulence of insect is had synergistic effect, co-toxicity coefficient is applicable to the various insects of control crops greater than 100.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910227086 CN101703051B (en) | 2009-12-03 | 2009-12-03 | Insecticidal composition containing cyanogen insect amide and molosultap and application thereof |
| PCT/CN2010/078759 WO2011066770A1 (en) | 2009-12-03 | 2010-11-16 | Insecticidal composition containing cyantraniliprole and monosultap |
| JP2012540271A JP5525060B2 (en) | 2009-12-03 | 2010-11-16 | Insecticidal composition comprising cyantranylprolol and monosultap |
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| CN 200910227086 CN101703051B (en) | 2009-12-03 | 2009-12-03 | Insecticidal composition containing cyanogen insect amide and molosultap and application thereof |
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| CN101703051B true CN101703051B (en) | 2012-10-17 |
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| CN (1) | CN101703051B (en) |
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| US7768812B2 (en) | 2008-01-15 | 2010-08-03 | Micron Technology, Inc. | Memory cells, memory cell programming methods, memory cell reading methods, memory cell operating methods, and memory devices |
| CN101703051B (en) * | 2009-12-03 | 2012-10-17 | 湖南化工研究院 | Insecticidal composition containing cyanogen insect amide and molosultap and application thereof |
| US8759809B2 (en) | 2010-10-21 | 2014-06-24 | Micron Technology, Inc. | Integrated circuitry comprising nonvolatile memory cells having platelike electrode and ion conductive material layer |
| CN102405931B (en) * | 2011-11-20 | 2013-08-14 | 广东中迅农科股份有限公司 | Pesticide composition containing cyantraniliprole and phoxim and having synergistic effect |
| AU2013235495A1 (en) * | 2012-03-23 | 2014-10-09 | Dow Agrosciences Llc | Tankmix additive concentrates containing triglyceride fatty acid esters and methods of use |
| CN102626069B (en) * | 2012-03-29 | 2013-07-31 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN102626072B (en) * | 2012-03-29 | 2013-07-31 | 广西田园生化股份有限公司 | Ultra-low-volume liquid containing cyantraniliprole and esbiothrin pesticide |
| CN102630696A (en) * | 2012-04-05 | 2012-08-15 | 广西田园生化股份有限公司 | Insecticidal composite containing Cyantraniliprole and anabasine compounds |
| CN103109826A (en) * | 2013-02-02 | 2013-05-22 | 广东中迅农科股份有限公司 | Composition of cyantraniliprole and nereistoxin-type pesticide |
| CN103858910A (en) * | 2013-12-19 | 2014-06-18 | 北京燕化永乐生物科技股份有限公司 | Insecticide composition containing metaflumizone |
| CN104285951A (en) * | 2014-09-25 | 2015-01-21 | 北京燕化永乐生物科技股份有限公司 | Compound insecticide |
| CN104542605A (en) * | 2014-12-15 | 2015-04-29 | 邓方坤 | Spreadable granule containing nereistoxin pesticides and cyantraniliprole |
| CN105519539A (en) * | 2015-12-29 | 2016-04-27 | 江苏天容集团股份有限公司 | An insecticide composition containing cyantraniliprole and monosultap |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1829707A (en) * | 2003-01-28 | 2006-09-06 | 杜邦公司 | Cyano anthranilamide insecticides |
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
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| DE10356550A1 (en) * | 2003-12-04 | 2005-07-07 | Bayer Cropscience Ag | Drug combinations with insecticidal properties |
| AU2006254140A1 (en) * | 2005-06-03 | 2006-12-07 | Basf Aktiengesellschaft | Pesticidal mixture |
| CN101703051B (en) * | 2009-12-03 | 2012-10-17 | 湖南化工研究院 | Insecticidal composition containing cyanogen insect amide and molosultap and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1829707A (en) * | 2003-01-28 | 2006-09-06 | 杜邦公司 | Cyano anthranilamide insecticides |
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
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| JP2013512198A (en) | 2013-04-11 |
| WO2011066770A1 (en) | 2011-06-09 |
| CN101703051A (en) | 2010-05-12 |
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