CN1087793A - Technology for making bone powder containing high-calcium - Google Patents
Technology for making bone powder containing high-calcium Download PDFInfo
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- CN1087793A CN1087793A CN92113520A CN92113520A CN1087793A CN 1087793 A CN1087793 A CN 1087793A CN 92113520 A CN92113520 A CN 92113520A CN 92113520 A CN92113520 A CN 92113520A CN 1087793 A CN1087793 A CN 1087793A
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Abstract
A kind of animal fresh bone that makes is through cleaning → freezing → bone paste (bone mud) that process such as pulverizings → mixing stirring process, further bioactivation processing and obtain a kind of all nutritional labelings in the skeletal tissue that make again, the particularly collagen in the sclerotin, phosphoprotein and the whole active dissolutions of hydroxyl calcium phosphate, the manufacturing process of the bone powder containing high-calcium that can fully be absorbed by human body.
Description
The present invention relates to a kind of method of manufacturing technology that makes the bone powder containing high-calcium that nutrition in the aggregate can fully absorb by human body that to be raw material with the animal fresh bone process by bioactivation.
At present, medical circle, nutrition bound pair are developed serial high-nutrition food both at home and abroad, electuary is very paid attention to, particularly replenish mineral matters such as necessary for human body calcium, phosphorus, zinc, iron, sodium, potassium, copper, the natural nutrient food, the electuary that reach other trace element, amino acid, vitamin are just more paid close attention to.Calcium is one of most active element in the human body, it neural, muscle stress, in the process such as keep of blood clotting, cell adhesion, the transmission of nerve impulse, the rhythm and pace of moving things aroused in interest, effect is very important, and pregnant woman's calcium deficiency is unfavorable for that calcium storage, bone calcification and the tooth in the fetus body forms; The long-term calcium deficiency of children is suffered from rickets easily; Teenager's calcium deficiency can cause bone growth bad; The elderly's calcium deficiency is prone to osteoporosis, osteoproliferation, scapulohumeral periarthritis, hypertension, calculosis, diabetes, artery sclerosis, sexual disorder, senile dementia, we can say that the many and long-term calcium deficiency of the various uncomfortable disease of tormenting the elderly and children is relevant, see Fig. 2 from present domestic and international statistics, be calcium demand (dotted line) in human body meals every day and actual provision amount (solid line) relatively, as can be seen the human body calcium deficiency problem that become international.Because calcium plays an important role to health, so industrially developed country attaches great importance to national requirement to calcium nutrition, focus development high calcium content food.
Animal fresh bone is nutritious and amount is inexpensive greatly, is a kind of food resource of good economy.In animal fresh bone, remove and include all nutritions that fresh meat has, on calcium, phosphorus and other content of elements also considerably beyond fresh meat, simultaneously, fat and cholesterol level are again well below fresh meat and goods thereof, therefore, in the food of supplement calcium, calcium is by providing ideal in the animal fresh bone.
In recent years, pay much attention to utilization research both at home and abroad to the animal bone, develop many animal sclerotin products, processing technology is constantly reformed, and no longer just is processed into gelatine, bone meal but develops to the direction of in-depth processing, not long ago, the former Soviet Union has published " food processing " book, summarized the former Soviet Union and other developed country in the book, development aspect the comprehensive utilization of animal bone is processed into edible bone essence to bone; The additive calcium phosphorus composition of condensed food; Edible gelatin etc., and to states such as Poland, Britain, the U.S. on bone processing technology, production line, product purpose, effect, economic implications, all made detailed description.
Summarize and analyze, can divide three major types both at home and abroad to animal bone comprehensive Utilization Ways:
1. animal skeleton can be made into bone protein, protolysate, gelatine, edible with glue, food calcium phosphorus preparation through chemical treatment.
2. animal skeleton can be made into grease, bone paste, bone food through mechanical treatment.
3. animal skeleton can be made into bone marrow oil, food grease, commercial grease and bone essence (replacing the meat essence), marrow powder (food additive), meat meal tankage (feed addictive), peptone (biochemical reagents) through high-temperature process.
Wherein gelatine and meat meal tankage assorted bone or the dried bones of adopting extract gelatine by bright bone more, and productive rate is low and pair product utilization is unfavorable, and meat meal tankage is several years ago domestic feed addictive of developping production, but because value of the product is low, produce often loss.Peptone is replaced by other industrial products.Therefore, process this several prods, do not bring into play due benefit with bright bone.
At present, abroad be devoted to bright bone processed food and food additive.Product mainly contains bone protein product and hydrolysate thereof, marrow powder, calcium phosphorus preparation, bone essence and bone mud.
(1) animal fresh bone is processed calcareous goods, and existing both at home and abroad method can be summed up as three kinds: the one, and processing marrow powder (food additive); The 2nd, extract calcareous and make calcium phosphorus preparation (food additives); The 3rd, it is directly edible that bright bone processing skeletonization is stuck with paste (bone mud).
The marrow powder is the food additive that the bone marrow oil that will extract mixes with edible bone powder by a certain percentage, generally contains protein 20%, fat 5%, calcium 20%, phosphorus 10%, and product is a powdery, and its production process is as follows:
Bright bone → wash → steam → drying → abrasive dust → blending → concentrate → edible oil and fat
↓
The marrow powder
The bright bone of processing marrow powder suitable animal is an ox bone, sends out brown with the product color that pig bone and sheep bone process, and smell is heavy, poor stability.The process key is to control flavour, fineness and the calcium acid ratio of product well.
It is pasty state that bone is stuck with paste (bone mud) product, contains protein 12%, lipid 9.6%, calcium 3.1%, ash 11%, moisture content 66.7%, and its production process is as follows:
Bright bone → cleaning → freezing → broken → mixing water mixes → freezing → finished product
It is short that this product is confined to shelf life, is subject to secondary pollution, and range of application is restricted.The aggregate that the processing bone is stuck with paste is pig bone, poultry bone and fish-bone preferably, and the ox bone sclerotin is harder, and product has gritty sense more.
Calcium phosphorus preparation is the product of paying that extracts bone protein.About 20% by the mineral matter calcic of taking off in the bone, use the food grade phosphate reaction, generate the complex salt of calcium phosphate, and it is dry to purify, and obtains edible calcium phosphorus preparation, product is mainly as food additives.
(2) extract the edible protein product by the animal bone
Animal fresh bone is handled the bone protein product or the edible gelatin that can obtain multiple physical characteristic through proper method, current research goes out acid system backflow demineraliting material technology and extracts bone albumen, product can be directly and in food processing, also further process for producing edible gelatin or protolysate.Represent technology to be:
Remove the meat on degrease and the bone earlier, through suitably broken, be suspended in then and carry out mineral removal treatment in the dilute hydrochloric acid solution, demineralization is to finish in a series of cylinders.And the concentration of hydrochloric acid difference of each cylinder fully contacts with skeletal grain with adverse current in the hydrochloric acid solution in every cylinder, keeps 4～5 hours, and the skeletal grain after the demineralization is through washing, and centrifugal dehydration is also dry, is product bone albumen.The leftover bits and pieces mineral matter can be produced calcium phosphorus preparation.
(3) extract the bone essence by animal fresh bone
The bone essence is the elite product of bone just, and extraction process roughly has following three kinds: steam high pressure extraction method, water-steam high pressure extraction method, hot-water extraction method.
More than be to be the general introduction of various bone system products of development of raw materials and manufacturing process thereof with bright bone both at home and abroad at present.Therefrom as can be seen, all biasing toward with steaming pressurization waits the method for high temperature high pressure " extraction " that bone is processed, thereby make protein in the animal fresh bone, vitamin and other many important nutritional labelings forfeitures or go to pot, and can not fully keep better and the utilization that is absorbed by the body.
Though the processing bone is stuck with paste processing such as the method that do not adopt HTHP, but owing to just depend on mechanical treatment to make, calcareous (hydroxyl calcium phosphate) in the os osseum can not get activation, collagen in the cartilage, phosphoprotein etc. can not dissolve fully, so make human body to effectively the absorption of nutritional labeling is very low in the sclerotin, and the bright bone that the processing bone is stuck with paste is confined to the softer animal fresh bone of sclerotin, and shelf life of products is very short.
Or the like these all reduced the value of animal fresh bone comprehensive utilization, can not be fully with fully activation and being absorbed by the body effectively such as calcium contained in the bright bone, P elements, various mineral matter and other trace element of necessary for human body, amino acid, vitamin.
Purpose of the present invention is exactly to make animal fresh bone through cleaning → freezing → bone paste (bone mud) that process such as pulverizings → mixing stirring process, further bioactivation processing and obtain a kind of all nutritional labelings in the skeletal tissue that make again, the particularly collagen in the sclerotin, phosphoprotein and the whole active dissolutions of hydroxyl calcium phosphate, the manufacturing process of the bone powder containing high-calcium that can fully be absorbed by human body.
The object of the present invention is achieved like this: with animal fresh bone A
Cut 4 through cleaning 1 → freezing 2 → cutting 3 → hinge → semi-finished product bone paste A that stirring 5 on the rocks → corase grind 6 → technologies such as correct grinding 7 are made, it is characterized in that: the semi-finished product bone is stuck with paste A send in the I order reaction still 8, add to account for and expect that bone weighs 50% water, under 90 ℃～100 ℃ temperature conditions, keep about 10 minutes, when the still temperature is cooled to 55 ℃～65 ℃, add an amount of Neutrase 0.5L bio protease, slowly stir, and maintain about 60 ℃ of temperature, after 30 minutes, the bone fat B that breaks away from from bone separates out through still top, the meat meter C that takes off from bone filters out at the bottom of still, and main pasty material enters II order reaction still 10;
In II order reaction still 10, control still temperature is between 60 ℃～65 ℃, add suitable quantity of water simultaneously, slowly evenly stir, about 5 minutes after, add edible diluted acid, control pH value 4-6 adds an amount of Papain bio protease, evenly stirs about 60 minutes, isolate liquid D 1, residue is sent in the III order reaction still 10, IV order reaction still 11 of two series connection;
In III order reaction still 10, add suitable quantity of water, control still temperature about 65 ℃, add edible diluted acid, make material pH≤2 o'clock, kept 45 minutes, isolate liquid D 2, residual residue enters in the IV order reaction still 11, with III order reaction still the same terms under, repeat the reaction of III order reaction still 10, make residual residue be dissolved as liquid D fully
3;
Obtain product D by reaching reactor 10, the 11 medium bioactivations reactions of carrying out in the reactor 8, in the reactor 9
1, D
2, D
3Send in the homogenizer 12, add and fill out batching E and proper amount of edible alkali, carry out homogeneous and mix and the remaining food acids that neutralizes the bone powder containing high-calcium meter F that is activated fully
0;
Bone powder containing high-calcium meter F
0, aftertreatment technologys such as drying 13, grinding 14, sterilization 15 obtain bone powder containing high-calcium powder F.
Above-mentioned technology for making bone powder containing high-calcium, it is characterized in that: in I order reaction still 8, add an amount of Nautrase 0.5L bio protease and be account for the material bone heavy 0.2%～0.4%, in II order reaction still 9, add an amount of Papain bio protease and be account for the material bone heavy 0.3%～0.5%, to add Neutrase 0.5L bio protease optimum value be to account for 0.3% of material sclerotin, institute add Papain bio protease optimum value be account for expect bone heavy 0.4%.
The manufacturing process of above-mentioned bone powder containing high-calcium, it is characterized in that adding edible diluted acid is watery hydrochloric acid, adding with alkali be NaOH.
In I order reaction still 8, isolate bone fat B
And gravy C
It is characterized in that, under 98 ℃ of temperature conditions, obtain product B, C after the pasteurized process through 15 seconds respectively.
Key reaction mechanism of the present invention:
1. the composition of bone and composition:
In the total classification of biology, skeletal tissue belongs to connective tissue, comprises os osseum, cartilage and bone three parts.It is two-layer that os osseum structure is divided into, and extexine be the bone tissue of densification, the spongy tissue that the inside then is made up of at plate many bones, wherein marrow abrim.Cartilage mainly is made up of collagen, phosphoprotein.Animal skeleton (mainly referring to the livestock and poultry bone) outside phosphoprotein, calcium, phosphorus, iron, the fat, also contains trace element and V such as potassium, sodium, magnesium, copper, chromium, zinc except containing collagen
A,
V
C, V
D, V
E
Be example (seeing Table) only with the pig bone, these compositions and contain scale as can be seen:
Pig bone mud analysis of components result (mean value)
2. the feature of the raw cook reaction mainly adopted of the present invention:
Keep original nutrient contents in the skeletal tissue, make the little molecule of big molecule strand disconnection formation in the bone by bioactivation, and human body can fully be absorbed, be no more than 100 ℃ because of the course of reaction temperature again, long-time reaction temperature is no more than 70 ℃ (protein is 70 ℃ of beginning sex change) and guarantees that like this protein and vitamin can not be subjected to very havoc, simultaneously, takes the multi-stage biochemical reactive mode, make the almost all dissolvings of material bone composition, increased the absorption by human body rate.
Action of main parameters and according to:
" under 90 ℃～100 ℃, kept 10 minutes " in technical process reactor 8 mainly is to give heat to reduce the required time of hydrolysis." adding protease N eutrase when being cooled to 60 ℃ " is because under this temperature conditions, this bioenzyme activity is the strongest, thereby the meat fat on the bone is broken away from, and " 98 ℃ of pasteurizations, 15S) " except sterilizing, has the effect that makes enzyme deactivation.
In the technical process reactor 9, " temperature in the maintenance reactor 2 is at 60 ℃～65 ℃ " are because Papain protease makes the fastest of collagenic protein solubilising under this temperature." pH=5 " is in order to make the Papain activity the strongest.
The biochemical reaction that carries out in I, II order reaction still 8,9 mainly is the collagen with sclerotin, and the large biological molecule such as grade of phosphoprotein is hydrolyzed into amino acid and other hydrolysate under the enzyme effect, and its basic process is:
1. peptide bond opens
2. proton exchange
Wherein R ', R " represent large biological molecules such as collagen, phosphoprotein.
" adding HCl liquid " to " pH≤2 " in the technical process reactor 10,11 is that some dissolution velocity is the fastest in pH≤2 owing to the water insoluble hydrochloric acid that is soluble in of the hydroxyl calcium phosphate in the bone.
The biochemical reaction that carries out in III, IV order reaction still 10,11 mainly is that the insoluble calcium salts such as hydroxyl calcium phosphate with big molecular complex are reacted the ion product that generates solubility, and basic process is
Ca（OH）PO
3+H
+→Ca
2++PO
- 3+H
2O
In the technical process homogenizer 12 " with among the NaOH and superfluous HCl be health, local flavor and make enzyme deactivation for food.
Because biochemical process process of the present invention is all carried out at low temperatures, therefore, not only makes the big molecule activation in the skeletal tissue, but also has fully kept the effective nutrition in the skeletal tissue.
The diagram brief description:
Fig. 1 is a manufacturing process flow schematic diagram of the present invention.
Fig. 2 is the comparison function curve map of theoretical calcium demand (dotted line) and actual provision amount (solid line) in human body meals every day.Abscissa-consumer group, ordinate-calcium amount (gram).
The bone ginseng that Fig. 3 makes for technology of the present invention on nutrient content with the comparison diagram of other calcium products.Abscissa-product category, ordinate-nutrient content ratio.
The bone ginseng that Fig. 4 makes for technology of the present invention on the human absorptivity with the comparison diagram of other goods.Abscissa-product category, ordinate-human absorptivity
Fig. 5 joins at calcium content (with Ca for the bone that technology of the present invention makes
2+Concentration calculating) go up comparison diagram with other products.Abscissa-product category, ordinate-calcium content (percentage by weight).
Now reach embodiment in conjunction with the accompanying drawings system technical process of the present invention be described in detail in detail:
Embodiment 1:(wherein raw material can adopt various animal skeletons) raw material employing Fresh Os Sus domestica
As shown in Figure 1, technical process of the present invention mainly is divided into three parts: earlier with Fresh Os Sus domestica through cleaning 1, freezing 2, cutting 3, hinge cuts 4, the semi-finished product bone paste A that existing technologies such as 7 grades (not describing in detail at this) are made is roughly ground in stirring 5 on the rocks, then bone is stuck with paste raw material and is sent in the reactor 8 of Gong the heating that agitating device is housed, add entry an amount of (account for material bone heavy 50%), under 90 ℃～100 ℃, kept 10 minutes, when being cooled to 55 ℃～65 ℃, adding bio protease Neutrase 0.5L(and account for 0.3% heavy slowly stirring of material bone, and maintain under 60 ℃, after 30 minutes, open reactor 8 bottom valves, filter out gravy C
0, meat C
0By the bottling of pasteurization (98 ℃, 5 seconds) back.Open reactor 8 upper valve, take out bone fat B
0, by the bottling of pasteurization (98 ℃, 15 seconds) back.Open rest materials another valve outflow through the bottom in the reactor 8, send in the reactor 9, the temperature in the process reactor 9 is between 60 ℃～65 ℃, add suitable quantity of water simultaneously, slowly evenly stir, after 5 minutes, add edible diluted acid (watery hydrochloric acid), stir while adding, end when making pH=5, add then bio protease Papain(account for the material bone heavy 0.4%), evenly stirred 60 minutes, open bottom valve, with the liquid D after filtering
1Send in the rose homogenizer 12, residue is sent in the reactor 10, adds suitable quantity of water and heat in reactor 10, makes temperature rise to 65 ℃, adds edible dilute hydrochloric acid liquid slowly, evenly stirs, and to pH≤2 o'clock only, keeps 45 minutes, opens bottom valve, with liquid D
2Leach and send in the homogenizer 12, residual residue is sent in the reactor 11, through with reactor 10 in after the same response situation, residual residue is all dissolvings almost, the liquid D of outflow
3Send in the homogenizer 12.After treating that all materials that biochemical reaction generates enter in the homogenizer, other is filled out batching E(seasoning, blending, food additives such as anticorrosion, fresh-keeping, anti-oxidant) send into homogenizer after, add and account for the material bone and weigh edible NaOH about 0.3%, the HCl that neutralization is superfluous.So far, all biochemical reaction finishes, and gets the plain pig bone ginseng of high calcium juice F
0; At last with the plain pig bone ginseng of height juice F
0Drying 13 pulverizes 14, obtains the plain pig bone ginseng of high calcium powder F after the processing of technical process such as sterilization 15.(productive rate weighs 40% for accounting for the material bone).
Bio protease (accounting for the material bone gives birth to)
Raw material Nertrase 0.5L Papain product
With embodiment 1, desired process conditions are identical with reference to accompanying drawing 1 for concrete process for making.
By the bone powder containing high-calcium that the process of animal fresh bone processing is made of the present invention, compare as follows with other high calcium food:
As shown in Figure 3, the contained general ratio of nutrient content of bone ginseng is 1: 0.45: 0.20 as can be seen: 0.15: 0.08.
As shown in Figure 4, human body participates in the contained calcium absorptivity of other calcium food additives to bone and compares as can be seen: bone ginseng＞activity＞egg-shell meal＞oyster shell whiting＞calcium tablet.
As shown in Figure 5, for the bone ginseng calcium content figure that compares with the other products calcium content, can find out that therefrom calcium content is (with Ca
2+Concentration is calculated): his calcium tablet＞high calcium candy＞many calcium biscuits＞calcic sausage of bone ginseng＞fourth dimension calcium tablet＞plain mother＞dimension of calcium, wherein fourth dimension calcium tablet, the plain mother of calcium, to tie up his calcium tablet be additional human calcium's medicine.High calcium candy, high calcium biscuit, calcic sausage are calcic food.This shows, join by the bone that the process to animal fresh bone processing that the present invention taked is made, though be from nutrition, calcium absorb to go up, and calcium ion concentration on, all be higher than other high calcium food far away, and easily dissolving, can be made into the bone powder containing high-calcium drink, bone ginseng electuary and food additives (being used to make solid food :) as biscuit, bread, cake, candy etc.By product, bone fat can be used for making high fatty foods, and gravy can be used for manufacturing tinned food etc.
Claims (5)
1, a kind of manufacturing process of bone powder containing high-calcium is with animal fresh bone A
0Cut 4 through cleaning 1 → freezing 2 → cutting 3 → hinge → semi-finished product bone paste A that stirring 5 on the rocks → corase grind 6 → technologies such as correct grinding 7 are made, it is characterized in that: the semi-finished product bone is stuck with paste A send in the I order reaction still 8, add to account for and expect that bone weighs 50% water, under 90 ℃～100 ℃ temperature conditions, keep about 10 minutes, when the still temperature is cooled to 55 ℃～65 ℃, add an amount of Neutrase 0.5L bio protease, slowly stir, and maintain about 60 ℃ of temperature, after 30 minutes, the bone fat B that from bone, breaks away from
0Separate out the meat meter C that from bone, takes off through still top
0Filter out at the bottom of still, main pasty material enters II order reaction still 10;
In II order reaction still 10, control still temperature is between 60 ℃～65 ℃, add suitable quantity of water simultaneously, slowly evenly stir, about 5 minutes after, add edible diluted acid, control pH value 4-6 adds an amount of Papain bio protease, evenly stirs about 60 minutes, isolate liquid D 1, residue is sent in the III order reaction still 10, IV order reaction still 11 of two series connection;
In III order reaction still 10, add suitable quantity of water, control still temperature about 65 ℃, add edible diluted acid, make material pH≤2 o'clock, kept 45 minutes, isolate liquid D
2, residual residue enters in the IV order reaction still 11, with III order reaction still the same terms under, repeat the reaction of III order reaction still 10, make residual residue be dissolved as liquid D fully
3
By in the reactor 8, in the reactor 9 and reactor 10,11 is medium carries out the bioactivation reaction and obtain product D
1, D
2, D
3Send in the homogenizer 12, add and fill out batching E and proper amount of edible alkali, carry out homogeneous and mix and the remaining food acids that neutralizes the bone powder containing high-calcium meter F that is activated fully
0
Behind the bone powder containing high-calcium meter, aftertreatment technologys such as drying 13, grinding 14, sterilization 15 obtain bone powder containing high-calcium powder F.
2, the manufacturing process of bone powder containing high-calcium according to claim 1, it is characterized in that: in I order reaction still 8, add an amount of Nautrase 0.5L bio protease and be account for the material bone heavy 0.2%～0.4%, in II order reaction still 9, add an amount of Papain bio protease and be account for the material bone heavy 0.3%～0.5%.
3, the manufacturing process of bone powder containing high-calcium according to claim 1 and 2, it is characterized in that: to add Neutrase 0.5L bio protease optimum value be to account for 0.3% of material sclerotin, institute add Papain bio protease optimum value be account for expect bone heavy 0.4%.
4, the manufacturing process of bone powder containing high-calcium according to claim 1 is characterized in that: adding edible diluted acid is watery hydrochloric acid, adding with alkali be NaOH.
5, the manufacturing process of bone powder containing high-calcium according to claim 1 is isolated bone fat B in I order reaction still 8
And gravy C
, it is characterized in that: under 98 ℃ of temperature conditions, obtain product B, C after the pasteurized process through 15 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92113520A CN1030369C (en) | 1992-12-05 | 1992-12-05 | Technology for making bone powder containing high-calcium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92113520A CN1030369C (en) | 1992-12-05 | 1992-12-05 | Technology for making bone powder containing high-calcium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1087793A true CN1087793A (en) | 1994-06-15 |
| CN1030369C CN1030369C (en) | 1995-11-29 |
Family
ID=4946447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92113520A Expired - Lifetime CN1030369C (en) | 1992-12-05 | 1992-12-05 | Technology for making bone powder containing high-calcium |
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| Country | Link |
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| CN (1) | CN1030369C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047923C (en) * | 1995-01-23 | 2000-01-05 | 邹永宏 | Bone emulsion, method for preparing same and use thereof |
| CN1064252C (en) * | 1997-08-01 | 2001-04-11 | 天津天狮集团有限公司 | Hypoglycemic high calcium granule and its prodn. |
| CN1069031C (en) * | 1998-02-16 | 2001-08-01 | 陈勇 | Complexing calcium and its prodn. method |
| CN102450653A (en) * | 2010-10-22 | 2012-05-16 | 曹吉祥 | Animal spleen dry powder |
| CN101455402B (en) * | 2009-01-08 | 2012-07-25 | 中国肉类食品综合研究中心 | Livestock bone ionization calcium and preparation method thereof |
| CN104041833A (en) * | 2014-06-18 | 2014-09-17 | 湖北工业大学 | Fermented sauced bone meal and preparation method thereof |
| CN104161273A (en) * | 2014-08-18 | 2014-11-26 | 李春林 | Bone paste food for improving sclerotin of children, pregnant women and old people |
| CN107198251A (en) * | 2016-09-29 | 2017-09-26 | 天津天狮生物发展有限公司 | A kind of composition for increasing adult's bone density and preparation method thereof |
| CN109717476A (en) * | 2019-02-25 | 2019-05-07 | 江苏诺普乐生物科技有限公司 | A kind of high calcium yeast powder and a kind of high calcium yeast powder, preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101429531B (en) * | 2008-12-17 | 2011-08-31 | 安徽怡康生物科技有限公司 | Method for extracting biological sclerotin calcium phosphate |
-
1992
- 1992-12-05 CN CN92113520A patent/CN1030369C/en not_active Expired - Lifetime
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047923C (en) * | 1995-01-23 | 2000-01-05 | 邹永宏 | Bone emulsion, method for preparing same and use thereof |
| CN1064252C (en) * | 1997-08-01 | 2001-04-11 | 天津天狮集团有限公司 | Hypoglycemic high calcium granule and its prodn. |
| CN1069031C (en) * | 1998-02-16 | 2001-08-01 | 陈勇 | Complexing calcium and its prodn. method |
| CN101455402B (en) * | 2009-01-08 | 2012-07-25 | 中国肉类食品综合研究中心 | Livestock bone ionization calcium and preparation method thereof |
| CN102450653A (en) * | 2010-10-22 | 2012-05-16 | 曹吉祥 | Animal spleen dry powder |
| CN104041833A (en) * | 2014-06-18 | 2014-09-17 | 湖北工业大学 | Fermented sauced bone meal and preparation method thereof |
| CN104041833B (en) * | 2014-06-18 | 2016-04-20 | 湖北工业大学 | Fragrant bone meal of a kind of fermentation sauce and preparation method thereof |
| CN104161273A (en) * | 2014-08-18 | 2014-11-26 | 李春林 | Bone paste food for improving sclerotin of children, pregnant women and old people |
| CN107198251A (en) * | 2016-09-29 | 2017-09-26 | 天津天狮生物发展有限公司 | A kind of composition for increasing adult's bone density and preparation method thereof |
| CN109717476A (en) * | 2019-02-25 | 2019-05-07 | 江苏诺普乐生物科技有限公司 | A kind of high calcium yeast powder and a kind of high calcium yeast powder, preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN1030369C (en) | 1995-11-29 |
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