CN108774144A - Double ten alkyl methyls propyl ammonium iodides and its application - Google Patents
Double ten alkyl methyls propyl ammonium iodides and its application Download PDFInfo
- Publication number
- CN108774144A CN108774144A CN201810811198.XA CN201810811198A CN108774144A CN 108774144 A CN108774144 A CN 108774144A CN 201810811198 A CN201810811198 A CN 201810811198A CN 108774144 A CN108774144 A CN 108774144A
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- China
- Prior art keywords
- double
- propylene oxide
- added
- formula
- alkyl
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/62—Quaternary ammonium compounds
- C07C211/63—Quaternary ammonium compounds having quaternised nitrogen atoms bound to acyclic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/20—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of quaternary ammonium compounds
Abstract
The present invention provides double ten alkyl methyls propyl ammonium iodides and its applications, including water 25-30%, trimethylammonium 10-15%, hydrochloric acid 6-15%, double ten chains essence 20-25%, propylene oxide 6-8%, iodine 5-8%, OP-10 15-20%, phosphoric acid 2-5%；Mixing is added in hydrochloric acid, double ten chains essences, water by a certain percentage successively by formula rate to be sufficiently stirred, add the trimethylaluminum solution of formula ratio, cool down, the propylene oxide of formula ratio half is added, it is rapidly heated, remaining propylene oxide is added, continues heating and carries out reaction liter ten alkyl methyls quaternary ammonium salts in pairs；It cools, iodine, OP-10, phosphoric acid addition is sufficiently mixed successively by formula rate, entire reactant is stirred to and is uniformly mixed.The present invention has stronger killing effect, and the toxin that energy bacterium for degrading corruption generates to bacterium, has the effect of apparent sterilizing to environment, plays the role of purifying water.
Description
Technical field
The present invention relates to water purification agent formula technique fields, more particularly, to double ten alkyl methyls propyl ammonium iodides and its answer
With.
Background technology
When fishery cultivating, cultivating pool is residual since production operation shortage is strictly regulated under the conditions of current oxygen―increasing reagent
Bait, excreta, biological corpse, fishing nutriment and drugs used in aquiculture, the pole in closing or semi-enclosed aquaculture ecosystem
Easily form pollution so that water nutrition increases, and lower water column anoxic, depositional environment sulfide, organic matter and reducing substances contain
Amount increases, left drug savings, harmful microorganism or bites dirty biology procreation, and breeding ecological is unbalance, and all kinds of diseases frequently occur.Such as
Fruit water quality is contaminated, and after irrigating, crops can also be contaminated.
In recent years, with the progress of water technology, coagulant research and development achieve very fast development, purifying agent
Development emerges one after another, and inorganic water purification agent can substantially be summarized as molysite and aluminium salt two major classes, and organic polymer coagulant is with polypropylene
Amide is representative, and inorganic coagulant and organic coagulants respectively have advantage and disadvantage in practical applications, also respectively has the limitation of application, even
Sometimes, different degrees of secondary pollution is will produce, is unfavorable for the recycling after water process.NEW TYPE OF COMPOSITE water purification agent exists
On purification mechanism, the advantages of integrating a variety of purification mechanisms, have both organic and inorganic water purification agent；On molecular structure, it is in totally
Chain structure, active branch is soluble easily in water, performance stablize, be affected by temperature it is small, especially to sewage condition adaptability
By force, there is specific aim to mine system engineering processing.But the cost for producing this composite water purifying agent at present is too high, enables most of mines
Mountain enterprise cannot receive.
Researching and developing a kind of new water purification agent to accord with the demands of the market thus, to be existing technical staff should solve the problems, such as, open
In the information of the background technology part, it is only intended to increase understanding of the overall background of the invention, and is not construed as recognizing
Or imply that information composition has been the prior art well known to persons skilled in the art in any form.
Invention content
Technical problem to be solved by the present invention lies in, double ten alkyl methyl propyl ammonium iodides and its application are provided,
It is characterized in that：Raw material include water 25-30%, trimethylammonium 10-15%, hydrochloric acid 6-15%, double ten chains essence 20-25%, epoxy third
Alkane 6-8%, iodine 5-8%, OP-10 15-20%, phosphoric acid 2-5%；
Preparation process is as follows：
Hydrochloric acid is added mix and is sufficiently stirred by step 1 by a certain percentage successively by formula rate with double ten chain essences, water, warm
The trimethylaluminum solution of formula ratio is added in degree after rising,
Step 2 cools down, and the propylene oxide of formula ratio half is added after cooling, is rapidly heated, and after temperature stabilization, then adds
Enter remaining propylene oxide, continue heating and reacted, fully reaction rises ten alkyl methyls quaternary ammonium salts in pairs；
Step 3 cools, by formula rate successively by iodine, OP-10, phosphoric acid addition be sufficiently mixed, entire reaction process otherwise
Disconnected stirring, be stirred to entire reactant be uniformly mixed both water purification agent.
Preferably, double ten alkyl methyl propyl ammonium iodide water purification agent chemical constitution formulas are：C24H52IN。
Preferably, the skeleton symbol is：。
Advantageous effect of the present invention：
The present invention has stronger killing effect, and the toxin that energy bacterium for degrading corruption generates to bacterium, has to environment and significantly kills
The effect of bacterium sterilizes, plays the role of purifying water.
Specific implementation mode：
Embodiment 1, formula：Raw material include water 26%, trimethylammonium 12%, hydrochloric acid 7%, double ten chains essences 22%, propylene oxide
7%, iodine 6%, OP-10 16%, phosphatase 24 %；
Preparation process is as follows：
Hydrochloric acid is added mix and is sufficiently stirred by step 1 by a certain percentage successively by formula rate with double ten chain essences, water, warm
The trimethylaluminum solution of formula ratio is added in degree after rising,
Step 2 cools down, and the propylene oxide of formula ratio half is added after cooling, is rapidly heated, and after temperature stabilization, then adds
Enter remaining propylene oxide, continue heating and reacted, fully reaction rises ten alkyl methyls quaternary ammonium salts in pairs；
Step 3 cools, by formula rate successively by iodine, OP-10, phosphoric acid addition be sufficiently mixed, entire reaction process otherwise
Disconnected stirring, be stirred to entire reactant be uniformly mixed both water purification agent.
Embodiment 2, raw material include water 25%, trimethylammonium 10%, hydrochloric acid 6%, double ten chains essences 20%, propylene oxide 8%,
Iodine 8%, OP-10 20%, phosphoric acid 3%；
Preparation process is as follows：
Hydrochloric acid is added mix and is sufficiently stirred by step 1 by a certain percentage successively by formula rate with double ten chain essences, water, warm
The trimethylaluminum solution of formula ratio is added in degree after rising,
Step 2 cools down, and the propylene oxide of formula ratio half is added after cooling, is rapidly heated, and after temperature stabilization, then adds
Enter remaining propylene oxide, continue heating and reacted, fully reaction rises ten alkyl methyls quaternary ammonium salts in pairs；
Step 3 cools, by formula rate successively by iodine, OP-10, phosphoric acid addition be sufficiently mixed, entire reaction process otherwise
Disconnected stirring, be stirred to entire reactant be uniformly mixed both water purification agent.
Bactericidal effect of the present invention is experiments have shown that data report is as follows：
Test method：Randomly drawing sample, experimental study：Staphylococcus aureus, Vibrio splindidus, breathes out Vickers at tarda
Vibrios, water mo(u)ld, bacillus coagulans, clostridium butyricum, bacillus subtilis, Su Yun bacillus/waxy, microalgae sterilization and suppression
The experiment of making.
Experimental result is as follows：
Test result shows:It is most strong to Vibrio splindidus, bacillus coagulans, clostridium butyricum and microalgae inhibition.
All above-mentioned this intellectual properties of primarily implementation, there is no this new products of implementation of setting limitation other forms
And/or new method.Those skilled in the art will utilize this important information, the above modification, to realize similar execution feelings
Condition.But all modifications or transformation belong to the right of reservation based on new product of the present invention.The above, be only the present invention compared with
Good embodiment is not that the invention has other forms of limitations, any person skilled in the art possibly also with
The technology contents make modifications or to change or modify the equivalent equivalent Example of the disclosure above.But it is every without departing from skill of the present invention
Art plan content, according to the technical essence of the invention to any simple modification, equivalent variations and remodeling made by above example,
Still fall within the protection domain of technical solution of the present invention.
Claims (3)
1. pair ten alkyl methyl propyl ammonium iodides and its application, it is characterised in that：Raw material include water 25-30%, trimethylammonium 10-
15%, hydrochloric acid 6-15%, double ten chains essence 20-25%, propylene oxide 6-8%, iodine 5-8%, OP-10 15-20%, phosphoric acid 2-5%；
Preparation process is as follows：
Hydrochloric acid is added mix and is sufficiently stirred by step 1 by a certain percentage successively by formula rate with double ten chain essences, water, warm
The trimethylaluminum solution of formula ratio is added in degree after rising,
Step 2 cools down, and the propylene oxide of formula ratio half is added after cooling, is rapidly heated, and after temperature stabilization, then adds
Enter remaining propylene oxide, continue heating and reacted, fully reaction rises ten alkyl methyls quaternary ammonium salts in pairs；
Step 3 cools, by formula rate successively by iodine, OP-10, phosphoric acid addition be sufficiently mixed, entire reaction process otherwise
Disconnected stirring is stirred to entire reactant and is uniformly mixed.
2. double ten alkyl methyl propyl ammonium iodides according to claim 1 and its application, it is characterised in that：Double ten alkyl first
Base propyl ammonium iodide water purification agent chemical constitution formula is：C24H52IN。
3. double ten alkyl methyl propyl ammonium iodides according to claim 2 and its application, it is characterised in that：The structure letter
Formula is：。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810811198.XA CN108774144A (en) | 2018-07-23 | 2018-07-23 | Double ten alkyl methyls propyl ammonium iodides and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810811198.XA CN108774144A (en) | 2018-07-23 | 2018-07-23 | Double ten alkyl methyls propyl ammonium iodides and its application |
Publications (1)
| Publication Number | Publication Date |
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| CN108774144A true CN108774144A (en) | 2018-11-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810811198.XA Pending CN108774144A (en) | 2018-07-23 | 2018-07-23 | Double ten alkyl methyls propyl ammonium iodides and its application |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103891772A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Compound sterilizing agent |
| WO2015189856A1 (en) * | 2014-06-10 | 2015-12-17 | Council Of Scientific & Industrial Research | Cationic lipid cordiarimide hybrid compounds and a process for preparation thereof |
| CN107619076A (en) * | 2017-11-08 | 2018-01-23 | 山东利水环保科技有限公司 | The formula of the special water purification agent of aquaculture class |
-
2018
- 2018-07-23 CN CN201810811198.XA patent/CN108774144A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103891772A (en) * | 2014-04-21 | 2014-07-02 | 成都科宏达科技有限公司 | Compound sterilizing agent |
| WO2015189856A1 (en) * | 2014-06-10 | 2015-12-17 | Council Of Scientific & Industrial Research | Cationic lipid cordiarimide hybrid compounds and a process for preparation thereof |
| CN107619076A (en) * | 2017-11-08 | 2018-01-23 | 山东利水环保科技有限公司 | The formula of the special water purification agent of aquaculture class |
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