CN1087591C - Pesticide composition - Google Patents
Pesticide composition Download PDFInfo
- Publication number
- CN1087591C CN1087591C CN99105949A CN99105949A CN1087591C CN 1087591 C CN1087591 C CN 1087591C CN 99105949 A CN99105949 A CN 99105949A CN 99105949 A CN99105949 A CN 99105949A CN 1087591 C CN1087591 C CN 1087591C
- Authority
- CN
- China
- Prior art keywords
- humic acid
- humate
- sodium
- pesticide
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical group C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000004021 humic acid Substances 0.000 claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 Alkyl betaine Chemical compound 0.000 claims description 30
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 15
- 239000011591 potassium Substances 0.000 claims description 15
- 229910052700 potassium Inorganic materials 0.000 claims description 15
- 239000005842 Thiophanate-methyl Substances 0.000 claims description 13
- 229960001952 metrifonate Drugs 0.000 claims description 13
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims description 13
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims description 13
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 12
- 239000006013 carbendazim Substances 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000001384 succinic acid Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 18
- 150000003839 salts Chemical class 0.000 abstract description 18
- 239000003899 bactericide agent Substances 0.000 abstract description 11
- 230000002195 synergetic effect Effects 0.000 abstract description 11
- 239000007900 aqueous suspension Substances 0.000 abstract description 10
- 239000004563 wettable powder Substances 0.000 abstract description 7
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 6
- 239000002917 insecticide Substances 0.000 abstract description 6
- 230000012010 growth Effects 0.000 abstract description 4
- 239000002552 dosage form Substances 0.000 abstract description 3
- 239000003175 pesticide synergist Substances 0.000 abstract 2
- 238000004166 bioassay Methods 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 230000004936 stimulating effect Effects 0.000 abstract 1
- 230000001502 supplementing effect Effects 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 description 23
- 239000000843 powder Substances 0.000 description 22
- 239000003814 drug Substances 0.000 description 18
- 235000015424 sodium Nutrition 0.000 description 13
- 201000010099 disease Diseases 0.000 description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 7
- 239000012747 synergistic agent Substances 0.000 description 7
- 238000009736 wetting Methods 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000005946 Cypermethrin Substances 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 239000005807 Metalaxyl Substances 0.000 description 5
- 239000005916 Methomyl Substances 0.000 description 5
- 239000005663 Pyridaben Substances 0.000 description 5
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 5
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 5
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 description 5
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229960005424 cypermethrin Drugs 0.000 description 5
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 5
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 5
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 5
- 229950001327 dichlorvos Drugs 0.000 description 5
- XFMJUIKWKVJNDY-UHFFFAOYSA-N diethoxyphosphorylsulfanylmethylbenzene Chemical compound CCOP(=O)(OCC)SCC1=CC=CC=C1 XFMJUIKWKVJNDY-UHFFFAOYSA-N 0.000 description 5
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 5
- 239000000417 fungicide Substances 0.000 description 5
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 5
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 5
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 5
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 5
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 5
- 229950001664 phoxim Drugs 0.000 description 5
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 5
- JYQUHIFYBATCCY-UHFFFAOYSA-N quinalphos Chemical compound C1=CC=CC2=NC(OP(=S)(OCC)OCC)=CN=C21 JYQUHIFYBATCCY-UHFFFAOYSA-N 0.000 description 5
- MSHXTAQSSIEBQS-UHFFFAOYSA-N s-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydron;chloride Chemical compound [Cl-].NC(=O)SCC([NH+](C)C)CSC(N)=O MSHXTAQSSIEBQS-UHFFFAOYSA-N 0.000 description 5
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
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- 239000002184 metal Substances 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 241001249129 Scirpophaga incertulas Species 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
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- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
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- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 1
- 241001530056 Athelia rolfsii Species 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 208000032843 Hemorrhage Diseases 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001622642 Parnara bada Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001525654 Phyllocnistis citrella Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 241001161749 Stenchaetothrips biformis Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- TWWCNXGLDZPFQV-XXAVUKJNSA-N [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O Chemical compound [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O TWWCNXGLDZPFQV-XXAVUKJNSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
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- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide synergist and a pesticide composition thereof. The pesticide synergist is humic acid and its salt, and when the compounding ratio is 3-10%, it can be compounded with various insecticides and bactericides into various dosage forms, such as water agent, wettable powder, water suspension agent, etc., and indoor bioassay and field test show that said synergist not only has strong synergistic action for pesticide, but also has the functions of stimulating crop growth and supplementing essential elements for crop growth.
Description
The present invention relates to a kind of pesticide synergistic agent and composition pesticide thereof.
The use of synthetic organic pesticide, greatly reduced the loss that damage by disease and insect brings to agricultural production, obtained huge economic benefit, but the use of organic agricultural chemicals, also brought very big negative effect to agricultural production, outstanding behaviours is in residue of pesticide, damage by disease and insect pesticide resistance, three aspects such as the wildness again of damage by disease and insect.For alleviating or eliminating the negative effect of using organic agricultural chemicals to bring, the use of pesticide synergistic agent is an important channel, it can reduce the usage amount of agricultural chemicals significantly improving pesticide efficacy, administering the drug-fast while of damage by disease and insect, reduces agricultural chemicals residual in environment.Humic acid is the big molecule organic monoacid of a class, obtains from weathered coal, and the source is abundant, cheap and easy to get.Hydrogen ion on the acidic group of humic acid can be replaced by sodium, potassium, ammonium plasma, and forms univalent metal salt or ammonium salt.Also can generate divalent metal salt with divalent metal or divalent alkaline-earth metal ion.Humic acid is used widely at aspects such as medicine, industry, livestock breeding.Pharmaceutically, run epilepsy, newborn baby of mainly hemorrhage in order to treatment nosebleed, women's qi and blood pain and all sores, metal-inflicted wound, the children's of humic acid rest the head on thorn disease etc., also have to make that Chinese patent drug uses, as sodium humate tablet, electuary and ointment; Industrial, the purification humic acid can improve cold starting performance, prolongation discharge time and the battery life of accumulator as the cathode expansion agent of lead accumulator.In concrete works, can improve concrete workability, save cement, improve intensity.On petroleum industry as oil drilling mud oar inorganic agent etc.; Aspect livestock breeding, as feed addictive, can improve the immunity of domestic animal, poultry with humic acid, strengthen premunition.Humic acid is mainly used in foliage-spray on agricultural, the compoiste fertilizer batching, aspects such as anti-drought water-retaining agent, use the back proof, the humic acid foliage-spray has the promotion crop growth, the function of preventing and curing diseases, use with organic manure or anti-drought water-retaining agent, can improve soil drought-resistant water-preserving ability, the structure of improving the soil promotes plant growth.But the application study of humic acid aspect pesticide synergistic also seldom, do not find to utilize the agricultural chemicals of humic acid as synergist on the market as yet.
The objective of the invention is to be mixed with various suitable dosage forms as pesticide synergistic agent and with humic acid and salt thereof and agricultural chemicals, be used for prevention and elimination of disease and pests with humic acid.
Below narrate main contents of the present invention:
Humic acid synergist of the present invention is humic acid and salt thereof, and it can be in humic acid, sodium humate, humic acid potassium, ammonium humate, copper humate, calcium humate and the humic acid magnesium one or more.
Humic acid synergist of the present invention can be mixed with the different formulations of pesticide with Multiple Pesticides and proper auxiliary agent thereof.Agricultural chemical insecticide of the present invention can be any one or the multiple former medicine in chlorophos, flolimat, nuvacron, dichlorvos, marathon, orthene, chlopyrifos, quinalphos, phoxim, Methomyl, carbosulfan, peace gram force, isoprocarb, cypermethrin, time, Belmark, decis, Padan, dimehypo, bensultap, the pyridaben etc.; Bactericide of the present invention can be the U.S. series bactericidal agent of carbendazim, thiophanate methyl, dyson fungicides, good fortune, enemy can pine, any kind or multiple former medicine in the tpn, aliette, kitazine, metalaxyl, triazolone, Sukeling, Isoprothiolane etc.
Be described in detail implementation method of the present invention below:
1. pesticide synergistic agent humic acid of the present invention and salt thereof can be mixed with aqua with agricultural chemicals and proper assistant, and the percentage by weight of its each component is:
Humic acid and salt 3-10% thereof
Agricultural chemicals 20-50%
Water 35-60%
Cosolvent, emulsifier 10-15%
The described humic acid and the salt thereof of this aqua, it can be a kind of or youngster's kind in humic acid, sodium humate, humic acid potassium, ammonium humate, copper humate, calcium humate and the humic acid magnesium.
The described agricultural chemicals of this aqua can be a chlorophos, flolimat, nuvacron, dichlorvos, marathon, orthene, chlopyrifos, quinalphos, phoxim, Methomyl, carbosulfan, the peace gram force, isoprocarb, cypermethrin, time, Belmark, decis, Padan, dimehypo, bensultap, in the insecticides such as pyridaben any one or multiple former medicine and/or carbendazim, thiophanate methyl, dyson fungicides, the U.S. series bactericidal agent of good fortune, the enemy can be loose, tpn, aliette, kitazine, metalaxyl, triazolone, Sukeling, in the bactericide such as Isoprothiolane any one or multiple former medicine.
The described cosolvent of this aqua is any in ethanol, methyl alcohol, the ethyl acetate.
The described emulsifier of this aqua be among alkyl betaine, OP series emulsifier, 656H and the 656L any or several.
2. pesticide synergistic agent humic acid of the present invention and salt thereof can be mixed with soluble powder with agricultural chemicals and proper assistant, and the percentage by weight of its each component is:
Humic acid and salt 5-7% thereof
Agricultural chemicals 30-50%
Hydrotropy thing 30-50%
Wetting agent, emulsifier 15-20%.
Humic acid of this soluble powder and salt thereof, it can be in humic acid, sodium humate, humic acid potassium, ammonium humate, copper humate, calcium humate and the humic acid magnesium one or more.
The described agricultural chemicals of this soluble powder can be a chlorophos, flolimat, nuvacron, dichlorvos, marathon, orthene, chlopyrifos, quinalphos, phoxim, Methomyl, carbosulfan, the peace gram force, isoprocarb, cypermethrin, time, Belmark, decis, Padan, dimehypo, bensultap, in the insecticides such as pyridaben any one or multiple former medicine and/or carbendazim, thiophanate methyl, dyson fungicides, the U.S. series bactericidal agent of good fortune, the enemy can be loose, tpn, aliette, kitazine, metalaxyl, triazolone, Sukeling, in the bactericide such as Isoprothiolane any one or multiple former medicine.
The described wetting agent of this soluble powder is any in saponin, lignosulfonates, the alkylsulfonate.
The described emulsifier of this soluble powder is one or more in DBSA acid sodium, DBSA acid calcium, the polyoxyethylene glyceryl ester.
The described hydrotropy thing of this soluble powder is the known material of personnel in the present technique fields such as sodium sulphate, stone carbon black.
3. pesticide synergistic agent humic acid of the present invention and salt thereof can be mixed with wetting powder with agricultural chemicals and suitable adjuvants, and the percentage by weight of each component is:
Humic acid and salt 5-10% thereof
Agricultural chemicals 30-50%
Carrier 30 as one kind-50%
Wetting agent, emulsifier, dispersant 15-20%.
Humic acid of this wetting powder and salt thereof, it can be in humic acid, sodium humate, humic acid potassium, ammonium humate, copper humate, calcium humate and the humic acid magnesium one or more.
The described agricultural chemicals of this wetting powder can be a chlorophos, flolimat, nuvacron, dichlorvos, marathon, orthene, chlopyrifos, quinalphos, phoxim, Methomyl, carbosulfan, the peace gram force, isoprocarb, cypermethrin, time, Belmark, decis, Padan, dimehypo, bensultap, in the insecticides such as pyridaben any one or multiple former medicine and/or carbendazim, thiophanate methyl, dyson fungicides, the U.S. series bactericidal agent of good fortune, the enemy can be loose, tpn, aliette, kitazine, metalaxyl, triazolone, Sukeling, in the bactericide such as Isoprothiolane any one or multiple former medicine.
The described wetting agent of this wetting powder is any in saponin, lignin sulfonic acid salt, alkyl sulfonates, laruyl alcohol, the alkylphenol polyoxyethylene succinate sodium sulfonate.
The described emulsifier of this wetting powder is any in dodecyl benzene sulfonate, alkyl betaine, succinic acid one monooctyl ester sodium sulfonate, the nekal.
The described dispersant of this wetting powder is any in two polyphosphate sodiums, sodium silicate, carboxymethyl cellulose, yellow first glue, the polyaryl phenol polyethenoxy ether phosphate.
The described carrier of this wetting powder can be the known material that is used for carrier of bentonite and those skilled in that art.
4. pesticide synergistic agent humic acid of the present invention and salt thereof can be mixed with aqueous suspension agent with agricultural chemicals and suitable adjuvants, and the percentage by weight of each component is:
Humic acid and salt 5-10%
Agricultural chemicals 30-50%
Water 40-60%
Suspending agent, wetting agent 5-10%
The humic acid of aqueous suspension agent of the present invention and salt thereof, it can be in humic acid, sodium humate, humic acid potassium, ammonium humate, copper humate, calcium humate and the humic acid magnesium one or more.
The described agricultural chemicals of aqueous suspension agent of the present invention can be a chlorophos, flolimat, nuvacron, dichlorvos, marathon, orthene, chlopyrifos, quinalphos, phoxim, Methomyl, carbosulfan, the peace gram force, isoprocarb, cypermethrin, time, Belmark, decis, Padan, dimehypo, bensultap, in the insecticides such as pyridaben any one or multiple former medicine and/or carbendazim, thiophanate methyl, dyson fungicides, the U.S. series bactericidal agent of good fortune, the enemy can be loose, tpn, aliette, kitazine, metalaxyl, triazolone, Sukeling, in the bactericide such as Isoprothiolane any one or multiple former medicine.
The described suspending agent of aqueous suspension agent of the present invention is any in the formaldehyde condensation products, nekal, oleic acid methylamino ethylsulfonic acid sodium, yellow first glue, polycarboxylate sodium salt of sodium lignin sulfonate or calcium, alkyl naphthalene sulfonate.
The described wetting agent of aqueous suspension agent of the present invention be in neopelex, lauryl sodium sulfate, dioctyl sodium sulfosuccinate, nekal, the alkyl polyoxyethylene ether sulfonate any or several.
The present invention can provide by following embodiment;
Embodiment one: take by weighing sodium humate 3kg, ammonium humate 3kg, humic acid potassium 4kg, add water 60kg, after being stirred to sodium humate and dissolving fully, add former medicine of 20kg dimehypo and 10kg alkyl betaine again, be stirred to dissolving fully, promptly get 20% Synergetic bisultap aqua.With 1000 times of dilutions of this agent, can effectively prevent and treat rice-stem borer, paddy stem borer, rice leaf roller, rice plant skipper, rice thrips, scotellaris etc.Cabbage caterpillar, diamond-back moth, phyllocnistis citrella stainton also there is good preventive effect.
Embodiment two: take by weighing 2kg ammonium humate, 1kg humic acid potassium, 2kg sodium humate, be crushed to 95% and cross 120 mesh sieves, add 40kg trichlorphon original powder, 20kg sodium sulphate, the white carbon black of 20kg, 5kg sodium lignin sulfonate, 5kg dodecyl sodium sulfate, 1kg carboxymethyl cellulose, 4kg sodium silicate, mix, packing can be made into 40% synergy chlorophos soluble powder.This agent is mainly used in the control of pests with chewing mouthparts such as vegetables, fruit tree, tea, mulberry, cotton, paddy rice, wheat, forest.
Embodiment three: take by weighing 3kg humic acid potassium, 3kg calcium humate, be crushed to 95% mistake, 200 mesh sieves, add the 40kg carbendazim original powder, 43kg bentonite, 1.0kg carboxymethyl cellulose, 5kg sodium lignin sulfonate, the yellow first glue of 5kg can make 40% synergy carbendazol wettable powder.Its 800-1500 times dilution can be used for preventing and treating gibberella zeaze petch of wheat and barley, fruit white rot of grape.Also can be used for preventing and treating the various diseases of fruit tree, and fruit tree nutritional deficiency disease is had good result of treatment.
Embodiment four: take by weighing 3kg humic acid potassium, 3kg ammonium humate, succinic acid dialkyl group disulfonate acid 2.5kg, polyoxyethylene groups ether polymer 2.5kg, water 49kg, the former powder of thiophanate methyl (crossing 300 orders) 40kg after the homogenize, promptly gets 40% thiophanate methyl aqueous suspension agent behind the mixing in colloid mill.Should (preparation) good preventive effect all be arranged, and can be crop potassium and nitrogen element are provided, stimulate plant growth rice blast, banded sclerotial blight, stinking smut, cotton disease.
Embodiment five: the mensuration of the Synergistic fertilizer preparation co-toxicity coefficient of various formulations of the present invention.
Northwest Agricultural University's plant protection chemical protection of plant is teaching and research to be studied carefully 20% Synergetic bisultap aqua of the present invention; 40% synergy chlorophos soluble powder; 40% synergy carbendazol wettable powder; 40% synergy thiophanate methyl aqueous suspension agent has carried out the mensuration of co-toxicity coefficient; 20% Synergetic bisultap aqua and 40% synergy chlorophos soluble powder adopt diamond-back moth and cotton bollworm to be the examination worm respectively; test method is a dip method; 40% synergy carbendazol wettable powder and 40% synergy thiophanate methyl aqueous suspension agent adopt apple anthracnose for supplying the examination bacterial classification, and growth rate method is measured.Test data adopts returning of probit value analysis, obtain return agenda and cause death in dense LC
50With effectively in dense EC
50, obtain its malicious number CTC of each synergy proportioning again with Sun Yunpei, CTC＞120 are synergy.
Table 1 20% Synergetic bisultap aqua is to the toxicity test of diamond-back moth
| Medicament | Regression equation | LC 50mg/L | CTC |
| 20% Synergetic bisultap aqua | y＝0.2776+1.3734x | 2745.1 | 198.4 |
| 25% dimehypo water solution | y＝-0.5931+1.4970x | 5446.4 |
Table 2 40% synergy chlorophos soluble powder is to the toxicity test of bollworm
| Medicament | Regression equation | LC 50mg/L | CTC |
| 40% synergy chlorophos soluble powder | y＝0.3114+1.3975x | 2264.42 | 181.4 |
| 80% chlorophos soluble powder | y＝0.5061+1.2436x | 4108.02 |
Table 3 40% synergy carbendazim wettable powder is to the toxicity test of apple anthracnose
| Medicament | Regression equation | EC 50mg/L | CTC |
| 40% synergy carbendazim wettable powder | y＝6.8200+1.0003x | 0.0152 | 211.8 |
| 40% carbendazim wettable powder | y＝6.4142+0.9480x | 0.0322 |
Table 4 40% synergy thiophanate methyl aqueous suspension agent is to the toxicity test of apple anthracnose
| Medicament | Regression equation | EC 50mg/L | CTC |
| 40% synergy thiophanate methyl suspending agent | y＝4.0496+0.9135x | 0.01097 | 173.0 |
| 36% thiophanate methyl is entreated floating agent | y＝3.4323+1.2264x | 0.01898 |
Evidence: humic acid has very strong synergistic effect to agricultural chemicals, damage by disease and insect is being reached under the prerequisite of identical control efficiency, and the consumption of agricultural chemicals can reduce 10-50%.Based on this, the present invention makes humic acid and salt thereof and mixed pesticide in the synergistic complex agricultural chemicals of various suitable dosage forms.Characteristics such as synergistic complex agricultural chemicals of the present invention not only has damage by disease and insect preventive effect height, and environmental pollution is little, and after using, stimulate plant growth in addition, strengthen crop immunity, provide the function of the required trace element of plant growing, a medicine multiple-effect, multi-functional.
Claims (4)
1, a kind of composition pesticide is characterized in that the component of said composition and percentage by weight are:
Sodium humate 3%
Ammonium humate 3%
Humic acid potassium 4%
Dimehypo 20%
Water 60%
Alkyl betaine 10%
2, a kind of composition pesticide is characterized in that the component of said composition and percentage by weight are:
Sodium humate 2%
Ammonium humate 2%
Humic acid potassium 1%
Chlorophos 40%
Sodium sulphate 20%
White carbon black 20%
Wooden sodium sulfonate 5%
Carboxymethyl cellulose 1%
Dodecyl sodium sulfate 5%
Sodium silicate 4%
3, a kind of composition pesticide is characterized in that the component of said composition and percentage by weight are:
Calcium humate 3%
Humic acid potassium 3%
Carbendazim 40%
Bentonite 43%
Wooden sodium sulfonate 5%
Carboxymethyl cellulose 1%
Yellow first glue 5%
4, a kind of composition pesticide is characterized in that the component of said composition and percentage by weight are:
Ammonium humate 3%
Humic acid potassium 3%
Thiophanate methyl 40%
Water 49%
Succinic acid dialkyl group disulfonate acid 2.5%
Polyoxyethylene groups ether polymer 2.5%
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| Application Number | Priority Date | Filing Date | Title |
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