CN108753210A - A kind of preparation method of sprayable wallpaper binder - Google Patents
A kind of preparation method of sprayable wallpaper binder Download PDFInfo
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- CN108753210A CN108753210A CN201810648681.0A CN201810648681A CN108753210A CN 108753210 A CN108753210 A CN 108753210A CN 201810648681 A CN201810648681 A CN 201810648681A CN 108753210 A CN108753210 A CN 108753210A
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- Prior art keywords
- parts
- added
- binder
- wallpaper
- sprayable
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of sprayable wallpaper binder, including following operating procedure:(1)Lanthanum chloride, ytterbium chloride are added to the water, after being mixed evenly, aphthenic acids is added thereto, after being mixed evenly, after the temperature of mixture is risen to 70-75 DEG C, isothermal holding obtains binder additives after 2-3 hours;(2)Sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl aryl polyoxyethylene ether, sodium vinyl sulfonate are added into vinyl acetate, after being mixed evenly, continue that binder additives, water are added thereto, mixture is heated up, continue that methyl methacrylate, glycidyl methacrylate, bis- (2- ethylhexyls) esters of maleic acid are added thereto, after being mixed evenly, copolyreaction obtains sprayable wallpaper binder.Binder produced by the present invention, rate of drying is fast, and cohesive force is strong, and mobile performance is excellent, is suitble to spraying operation, greatly improves the efficiency of wallpaper construction.
Description
Technical field
The invention belongs to wallpaper binder preparing technical fields, and in particular to a kind of preparation side of sprayable wallpaper binder
Method.
Background technology
Wallpaper is also referred to as wallpaper, is a kind of for papering the indoor hardware fitting of metope, be widely used in house, office,
The interior decoration etc. of hotel.Material is not limited to paper, also includes other materials.Because having, color is various, pattern is rich
The incomparable feature of a variety of other house decorative materials such as rich, luxurious style, safety and environmental protection, easy for construction, affordable,
Therefore it is obtained in developed countries and regions such as America and Europe, Japan considerable degree of universal.Wallpaper is divided into many classes, and such as overlay film wallpaper applies
Cloth wallpaper, embossing wallpaper etc..Usually body paper, then the working process through different processes, such as coating, print are produced with bleached wood pulp
Modeling is covered on brush, embossing or surface, is dispatched from the factory after last cut, packaging, has certain intensity, toughness, the appearance of beauty and well
Water repelling property.In the prior art, wallpaper is during construction, be using by binder brushing on wallpaper, this behaviour
Make that method is time-consuming and laborious, commercially available common sprayable binder, solvent content is more, slow drying speed, can be to the construction of wallpaper
It adversely affects, therefore is badly in need of a kind of sprayable binder that suitable wallpaper uses.
Invention content
In order to solve the above technical problem, the present invention provides a kind of preparation methods of sprayable wallpaper binder.
The present invention is achieved by the following technical solutions.
A kind of preparation method of sprayable wallpaper binder, including following operating procedure:
(1)By weight, 23-27 parts of lanthanum chlorides, 15-20 parts of ytterbium chlorides are added in 160-180 parts of water, are mixed equal
After even, 55-60 parts of aphthenic acids are added thereto, after being mixed evenly, after the temperature of mixture is risen to 70-75 DEG C, heat preservation
After processing 2-3 hours, binder additives are obtained;
(2)By weight, by 44-51 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 4-9 parts of alkyl aryl polyoxyethylene ethers, 10-
14 parts of sodium vinyl sulfonates are added into 300-350 parts of vinyl acetate, and after being mixed evenly, continuation is added thereto
13-18 parts of binder additives, 480-500 parts of water, when the temperature of mixture is risen to 60 DEG C, 188- is added in continuation thereto
Bis- (2- ethylhexyls) esters of 192 parts of methyl methacrylates, 11-16 parts of glycidyl methacrylate, 66-75 parts of maleic acids,
After being mixed evenly, after the temperature of mixture is risen to 78-85 DEG C, after copolyreaction 2-3 hours, it is viscous to obtain sprayable wallpaper
Tie agent.
Specifically, above-mentioned steps(1)In lanthanum chloride be Lanthanum trichloride hexahydrate, purity 99%, ytterbium chloride be six hydration chlorine
Change ytterbium, purity 99.5%.
Specifically, above-mentioned steps(2)In, methyl methacrylate and glycidyl methacrylate are before use, adopt
The sodium hydroxide solution for being 0.5% with mass fraction washs three times repeatedly, is then evaporated under reduced pressure again, obtains pure methyl-prop
E pioic acid methyl ester and glycidyl methacrylate.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows:
A kind of preparation method of sprayable wallpaper binder provided by the invention, easy to operate, of low cost, bonding obtained
Agent, rate of drying is fast, and cohesive force is strong, and mobile performance is excellent, is suitble to spraying operation, greatly improves the efficiency of wallpaper construction.
Step(1)In binder additives obtained, be naphthenic acid rare earth, the mobility of binder can be effectively promoted, even if not
Enough solvents are added, the operation of spraying can be also completed, rate of drying is fast after spraying, will not generate shadow to the decoration performance of wallpaper
It rings.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following embodiment carries out the present invention
It is further described.It should be appreciated that specific embodiment party example described herein is only used to explain the present invention, it is not used to limit
The fixed present invention.
Embodiment 1
A kind of preparation method of sprayable wallpaper binder, including following operating procedure:
(1)By weight, 23 parts of lanthanum chlorides, 15 parts of ytterbium chlorides are added in 160 parts of water, after being mixed evenly, Xiang Qi
55 parts of aphthenic acids of middle addition, after being mixed evenly, after the temperature of mixture is risen to 70 DEG C, isothermal holding obtains after 2 hours
Binder additives;
(2)By weight, by 44 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 4 parts of alkyl aryl polyoxyethylene ethers, 10 parts of ethylene
Base sodium sulfonate is added into 300 parts of vinyl acetate, after being mixed evenly, continues that 13 parts of binder additions are added thereto
Agent, 480 parts of water when the temperature of mixture is risen to 60 DEG C, continue that 188 parts of methyl methacrylates, 11 parts of first are added thereto
Bis- (2- ethylhexyls) esters of base Glycidyl Acrylate, 66 parts of maleic acids, after being mixed evenly, the temperature of mixture is risen to
After 78 DEG C, after copolyreaction 2 hours, sprayable wallpaper binder is obtained.
Specifically, above-mentioned steps(1)In lanthanum chloride be Lanthanum trichloride hexahydrate, purity 99%, ytterbium chloride be six hydration chlorine
Change ytterbium, purity 99.5%.
Specifically, above-mentioned steps(2)In, methyl methacrylate and glycidyl methacrylate are before use, adopt
The sodium hydroxide solution for being 0.5% with mass fraction washs three times repeatedly, is then evaporated under reduced pressure again, obtains pure methyl-prop
E pioic acid methyl ester and glycidyl methacrylate.
Embodiment 2
A kind of preparation method of sprayable wallpaper binder, including following operating procedure:
(1)By weight, 25 parts of lanthanum chlorides, 18 parts of ytterbium chlorides are added in 170 parts of water, after being mixed evenly, Xiang Qi
58 parts of aphthenic acids of middle addition, after being mixed evenly, after the temperature of mixture is risen to 73 DEG C, isothermal holding obtains after 2.5 hours
To binder additives;
(2)By weight, by 48 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 7 parts of alkyl aryl polyoxyethylene ethers, 12 parts of ethylene
Base sodium sulfonate is added into 330 parts of vinyl acetate, after being mixed evenly, continues that 15 parts of binder additions are added thereto
Agent, 490 parts of water when the temperature of mixture is risen to 60 DEG C, continue that 190 parts of methyl methacrylates, 13 parts of first are added thereto
Bis- (2- ethylhexyls) esters of base Glycidyl Acrylate, 70 parts of maleic acids, after being mixed evenly, the temperature of mixture is risen to
After 80 DEG C, after copolyreaction 2.5 hours, sprayable wallpaper binder is obtained.
Specifically, above-mentioned steps(1)In lanthanum chloride be Lanthanum trichloride hexahydrate, purity 99%, ytterbium chloride be six hydration chlorine
Change ytterbium, purity 99.5%.
Specifically, above-mentioned steps(2)In, methyl methacrylate and glycidyl methacrylate are before use, adopt
The sodium hydroxide solution for being 0.5% with mass fraction washs three times repeatedly, is then evaporated under reduced pressure again, obtains pure methyl-prop
E pioic acid methyl ester and glycidyl methacrylate.
Embodiment 3
A kind of preparation method of sprayable wallpaper binder, including following operating procedure:
(1)By weight, 27 parts of lanthanum chlorides, 20 parts of ytterbium chlorides are added in 180 parts of water, after being mixed evenly, Xiang Qi
60 parts of aphthenic acids of middle addition, after being mixed evenly, after the temperature of mixture is risen to 75 DEG C, isothermal holding obtains after 3 hours
Binder additives;
(2)By weight, by 51 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 9 parts of alkyl aryl polyoxyethylene ethers, 14 parts of ethylene
Base sodium sulfonate is added into 350 parts of vinyl acetate, after being mixed evenly, continues that 18 parts of binder additions are added thereto
Agent, 500 parts of water when the temperature of mixture is risen to 60 DEG C, continue that 192 parts of methyl methacrylates, 16 parts of first are added thereto
Bis- (2- ethylhexyls) esters of base Glycidyl Acrylate, 75 parts of maleic acids, after being mixed evenly, the temperature of mixture is risen to
After 85 DEG C, after copolyreaction 3 hours, sprayable wallpaper binder is obtained.
Specifically, above-mentioned steps(1)In lanthanum chloride be Lanthanum trichloride hexahydrate, purity 99%, ytterbium chloride be six hydration chlorine
Change ytterbium, purity 99.5%.
Specifically, above-mentioned steps(2)In, methyl methacrylate and glycidyl methacrylate are before use, adopt
The sodium hydroxide solution for being 0.5% with mass fraction washs three times repeatedly, is then evaporated under reduced pressure again, obtains pure methyl-prop
E pioic acid methyl ester and glycidyl methacrylate.
Comparative example 1
Step(2)In do not add binder additives, remaining operating procedure is identical with embodiment 1.
The binder made from each embodiment and comparative example carries out construction test to wallpaper respectively, and table 1 is construction test
As a result,
1 sprayable wallpaper binder construction effect of table
As shown in Table 1, sprayable wallpaper binder made from the present embodiment, rate of drying is fast, will not soak wallpaper, greatly carry
The construction effect of wallpaper is risen.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention
Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention
In sharp claimed range.
Claims (3)
1. a kind of preparation method of sprayable wallpaper binder, which is characterized in that including following operating procedure:
(1)By weight, 23-27 parts of lanthanum chlorides, 15-20 parts of ytterbium chlorides are added in 160-180 parts of water, are mixed equal
After even, 55-60 parts of aphthenic acids are added thereto, after being mixed evenly, after the temperature of mixture is risen to 70-75 DEG C, heat preservation
After processing 2-3 hours, binder additives are obtained;
(2)By weight, by 44-51 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 4-9 parts of alkyl aryl polyoxyethylene ethers, 10-
14 parts of sodium vinyl sulfonates are added into 300-350 parts of vinyl acetate, and after being mixed evenly, continuation is added thereto
13-18 parts of binder additives, 480-500 parts of water, when the temperature of mixture is risen to 60 DEG C, 188- is added in continuation thereto
Bis- (2- ethylhexyls) esters of 192 parts of methyl methacrylates, 11-16 parts of glycidyl methacrylate, 66-75 parts of maleic acids,
After being mixed evenly, after the temperature of mixture is risen to 78-85 DEG C, after copolyreaction 2-3 hours, it is viscous to obtain sprayable wallpaper
Tie agent.
2. a kind of preparation method of sprayable wallpaper binder according to claim 1, which is characterized in that above-mentioned steps
(1)In lanthanum chloride be Lanthanum trichloride hexahydrate, purity 99%, ytterbium chloride be six hydrous ytterbium chlorides, purity 99.5%.
3. a kind of preparation method of sprayable wallpaper binder according to claim 1, which is characterized in that above-mentioned steps
(2)In, methyl methacrylate and glycidyl methacrylate are before use, be all made of the hydroxide that mass fraction is 0.5%
Sodium solution washs three times repeatedly, is then evaporated under reduced pressure again, and pure methyl methacrylate and glycidyl are obtained
Propyl ester.
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CN201810648681.0A CN108753210A (en) | 2018-06-22 | 2018-06-22 | A kind of preparation method of sprayable wallpaper binder |
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CN201810648681.0A CN108753210A (en) | 2018-06-22 | 2018-06-22 | A kind of preparation method of sprayable wallpaper binder |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103215825A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive |
WO2014064020A1 (en) * | 2012-10-24 | 2014-05-01 | Akzo Nobel Chemicals International B.V. | Water-redispersible polymer powder comprising a triester |
CN104559849A (en) * | 2014-11-25 | 2015-04-29 | 桐乡嘉力丰实业股份有限公司 | Wallpaper mural adhesive and preparation method of wallpaper mural adhesive |
CN105111972A (en) * | 2015-09-23 | 2015-12-02 | 句容市兴武包装有限公司 | Preparation method of adhesive for cigarette packaging |
CN106752992A (en) * | 2017-01-22 | 2017-05-31 | 江苏旭泽技术有限公司 | A kind of pressure sensitive adhesive, its preparation method, application method and application |
CN107022325A (en) * | 2017-04-27 | 2017-08-08 | 无锡市福享天下科技有限公司 | Senior wallpaper wall paper adhesive |
-
2018
- 2018-06-22 CN CN201810648681.0A patent/CN108753210A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014064020A1 (en) * | 2012-10-24 | 2014-05-01 | Akzo Nobel Chemicals International B.V. | Water-redispersible polymer powder comprising a triester |
CN103215825A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive |
CN104559849A (en) * | 2014-11-25 | 2015-04-29 | 桐乡嘉力丰实业股份有限公司 | Wallpaper mural adhesive and preparation method of wallpaper mural adhesive |
CN105111972A (en) * | 2015-09-23 | 2015-12-02 | 句容市兴武包装有限公司 | Preparation method of adhesive for cigarette packaging |
CN106752992A (en) * | 2017-01-22 | 2017-05-31 | 江苏旭泽技术有限公司 | A kind of pressure sensitive adhesive, its preparation method, application method and application |
CN107022325A (en) * | 2017-04-27 | 2017-08-08 | 无锡市福享天下科技有限公司 | Senior wallpaper wall paper adhesive |
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Application publication date: 20181106 |
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