CN108715071A - A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials - Google Patents
A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials Download PDFInfo
- Publication number
- CN108715071A CN108715071A CN201810468328.4A CN201810468328A CN108715071A CN 108715071 A CN108715071 A CN 108715071A CN 201810468328 A CN201810468328 A CN 201810468328A CN 108715071 A CN108715071 A CN 108715071A
- Authority
- CN
- China
- Prior art keywords
- parts
- coiled materials
- sided self
- antioxidant
- waterproof coiled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/308—Heat stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/734—Dimensional stability
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials, and the waterproof roll includes polyester isolated film, modified asphalt layer, red polyester film.The red polyester film thickness is 0.1-0.2 ㎜；The modified pitch layer thickness is 0.7-1.6 ㎜；The polyester isolated film thickness is 0.03-0.05 ㎜.The modified asphalt layer, including following components：90# pitches, 10# pitches, second line of distillation oil, SBS, SBR, SIS, cement, talcum powder, light calcium carbonate powder, Petropols, coumarone indene resin, hydrogenated terpene resin, graphene, dodecyl dihydroxy ethyl glycine betaine, fluorocarbon resin, butyl octanol salicylate, antioxidant D NP, antistripping agent, antioxidant.Against weather of the present invention is good, and coiled material ontology adaptive temperature answers machine strong.
Description
Technical field
The present invention relates to a kind of cross-level double-sided self-adhesive waterproof coiled materials, and in particular to a kind of cross-level double-sided self-adhesive asphaltic base
Red core polyester film waterproof roll and its production technology, belong to architectural waterproof material field.
Background technology
SAM cross-level double-sided self-adhesive waterproof coiled materials are a kind of high-performance waterproofing coiled materials.It is with synthetic rubber, high-quality heavy traffic paving asphalt
Deng for base-material, high-quality polyethylene film, red polyester film.As top surface or without film（Double-sided self-adhesive）, use is peelable
Painting silicon fiml or apply silicon crimped paper as a kind of self-adhesive waterproof web made of anti-sticking isolated material.
SAM cross-levels double-sided self-adhesive waterproof coiled materials are low to basal plane requirement, can construct on moisture substrate；It shortens the construction period, save
About cost；It can be realized with basal plane full viscous, the advantages that bonding is reliable, safety and environmental protection is standby to be received by the market.But the high score in present market
Subclass wet-laying waterproof roll is mostly PE, HDPE film class wet-laying waterproof roll, although these materials meet the mark of wet-laying waterproof roll
It is accurate《GB/ T23457-2009》, but have certain defect due to material, such as：Tensile property is relatively relatively low, mechanical performance
The problems such as difference, service life.Material body against weather is poor.
Therefore, a kind of tensile property height is invented, mechanical performance is strong, and ageing-resistant against weather wet-laying SAM cross-levels are two-sided
Adhesive waterproof coil has far-reaching social effect.
The prior art has following defect：（1）The tensile property of wet-laying waterproof roll is poor；（2）The stripping of wet-laying waterproof roll
It is low from intensity；（3）The tearing strength of wet-laying waterproof roll is low；（4）Heat aging property is poor,（5）Against weather is poor（6）Adapt to temperature
Spend difference in change.
Invention content
For prior art problem, the present invention provides a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials, following to realize
Goal of the invention：1, the tensile property of wet-laying waterproof roll is improved；2, the peel strength of wet-laying waterproof roll is improved；3, it improves
The tearing strength of wet-laying waterproof roll；4, the heat aging property of wet-laying waterproof roll is improved, 5. against weathers, 6. improve volume
Material ontology adaptive temperature answers machine.
To achieve the above object, the invention is realized by the following technical scheme：
For SAM cross-levels double-sided self-adhesive waterproof coiled materials using red polyester film as carrier, the waterproof roll includes that polyester isolation is thin
Film, modified asphalt layer, red polyester film.
It is to be further improved to above-mentioned technical proposal below：
The red polyester film thickness is 0.1-0.2 ㎜；The modified pitch layer thickness is the ㎜ of 0 .7-1.6；Described
Polyester isolated film thickness is 0.03-0.05 ㎜.
The modified asphalt layer, including following components：90# pitches, 10# pitches, second line of distillation oil, SBS, SBR, SIS, water
Mud, talcum powder, light calcium carbonate powder, Petropols, coumarone indene resin, hydrogenated terpene resin, graphene, dodecyl dihydroxy ethyl beet
Alkali, fluorocarbon resin, butyl octanol salicylate, antioxidant D NP, antistripping agent, antioxidant.
The raw material components of the modified asphalt layer, in terms of mass parts, including：
200-240 parts of 90# pitches, 80-100 parts of 10# pitches, 33-35 parts of second line of distillation oil, SBS10-12 parts, SBR14-20 parts,
SIS20-23 parts, 40-50 parts of cement, 30-40 parts of talcum powder, 10-15 parts of light calcium carbonate powder, 12-14 parts of Petropols, coumarone indene resin
3-6 parts, 4.5-6.5 parts of hydrogenated terpene resin, 2-4 parts of graphene, 1.5-2.5 parts of dodecyl dihydroxy ethyl glycine betaine, fluorine carbon
3-4 parts of resin, 2-3 parts of butyl octanol salicylate, 1-2 parts of antioxidant D NP, 3-5 parts of antistripping agent, antioxidant 1.3-1.6
Part.
The SBR is powder styrene butadiene rubber, and minimum resist cold is -40 DEG C, and heat-resisting highest is 150 DEG C, and ordinary rubber is minimum resistance to
It is -20 DEG C to tremble with fear, and heat-resisting highest is 100 DEG C, the 63%-75% of amount containing butadiene-styrene rubber.
The SBS：Fugitive constituent≤1%；Solution mass flow rate is 0 .1-5g/10min；Tensile strength >=
20MPa；Elongation at break >=680%；The .2% of ash content≤0.
The SIS：Solution mass flow rate is 2-14g/10min；Tensile strength >=7MPa；Elongation at break >=
1000%；The .7% of ash content≤0；
The Petropols are C 5 hydrogenated petroleum resin, 96-105 DEG C of softening point；Viscosity≤250（190℃ mPa .s）；
Flash-point：≥ 190℃；Burning point >=210 DEG C；
The antistripping agent is any one in Carlow amine, AR-68, TJ066；
The cement grade is 425 or 425R；
The antioxidant is three monooctyl esters or three last of the ten Heavenly stems esters；
The coumarone indene resin：Fluent material, 75-135 DEG C of softening point, relative density are the .07 of 1 .05-1, glass transition temperature
56 DEG C, refractive index 1.60 ~ 1.65.
The talcum powder is 400 mesh talcum powder；
The light calcium carbonate powder is 600 mesh light calcium carbonate powders.
A kind of production technology of SAM cross-levels double-sided self-adhesive waterproof coiled materials, including wet-laying modified pitch layer sizing preparation,
Coat modified pitch layer sizing, high temperature ultrasonic processing, overlay film and cooling and shaping step.
The preparation process of the wet-laying modified pitch layer sizing：
Material-compound tank is added in 90# pitches and 10# pitches, when being warming up to 240-250 DEG C, 2-3h is stirred, is then cooled to 200 DEG C and opens
Beginning is added SBS, SBR, SIS and keeps the temperature at 200 DEG C, stirs 2-3h.Be added Petropols, coumarone indene resin, antistripping agent,
Antioxidant stirs 30min；It is cooled to 140 DEG C and cement, talcum powder, light calcium carbonate powder, second line of distillation oil is added, stir 1h.Then add successively
Enter hydrogenated terpene resin, graphene, dodecyl dihydroxy ethyl glycine betaine, stirs 30-40min；Then heat to 180-190
DEG C, fluorocarbon resin, butyl octanol salicylate, antioxidant D NP are sequentially added, 20-30min is stirred.
The coating modified pitch layer sizing：
After wet-laying modified pitch layer sizing is cooled to 120 ± 5 DEG C, introduces and apply oil sump；
It opens and applies oil pump, modified pitch layer sizing enters support food tray, keeps the amount of modified pitch layer sizing in support food tray sufficient；Make red
Color polyester film depresses oiling pressure roller, by position of the red polyester film in coiled material, adjusts position of oil scraper, make by applying oil sump
The modified pitch layer thickness of red polyester film both sides is the ㎜ of 0 .7-1.6.
The high temperature ultrasonic processing：Coiled material after oiling is subjected to high temperature ultrasonic processing, temperature is 89-95 DEG C, ultrasound
Frequency is：100-110KHz；Processing time is 40-50min.
The overlay film and cooling and shaping：
After high temperature ultrasonic is handled, using overlay film, cooling and shaping；
The overlay film：Polyester insulating film tiling is driven to be covered in modified pitch layer surface, two-sided overlay film, overlay film by red polyester film
When, adjust polyester insulating film position；
The cooling and shaping：When production line is run, opens damping roller and cool the circulatory system, adjust each chill roll water supply, it is cold
But water temperature≤40 DEG C；
In production line operational process, according to upper and lower overlay film, cooling situation, is adjusted in due course using deviation-rectifying system and apply polyester insulating film position
It sets with polyester insulating film in the position of cooling water pressure pipe and water flow.
Finally, coiled material after molding is crimped, is then inserted in waterproof roll packaging bag, be put into warehouse area to be checked, it is to be tested
It is put into finished product area after conjunction, a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials are made.
Advantageous effect：
（1）Waterproof roll pulling force of the present invention is 230 ~ 250N/50 ㎜, and the prior art is 150N/50 ㎜；It is extended when maximum pull
Rate is 120 ~ 160%, the prior art 30%.
（2）The peel strength of wet-laying waterproof roll of the present invention is 1.7-2.0 N/mm.
（3）The tearing strength of wet-laying waterproof roll of the present invention is 17-20 N.
（4）The heat aging property of wet-laying waterproof roll of the present invention is pulling force conservation rate 94-98%（70 DEG C, 168h）, stretch
Long rate conservation rate 94-97%（70 DEG C, 168h）.
（5）Against weather is strong, is used in high temperature area or low temp area or awful weather area, the service life is above 50 years.
（6）Coiled material ontology adaptive temperature answers machine strong, and thermal stability is high, and size changing rate is less than 1.5%.
Specific implementation mode
A kind of 1 SAM cross-levels double-sided self-adhesive waterproof coiled materials of embodiment
A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials are：Double-sided adhesive asphaltic base red polyester film carcass wet-laying waterproof
Coiled material；
The waterproof roll includes following three parts：
First part is red polyester film, as carrier；Red polyester film thickness is 0.18 ㎜；
Second part is two layers of modified asphalt layer, as wet-laying self-adhesive modified asphalt coating sizing material, and wet-laying self-adhesive modified asphalt applies
Layer sizing thickness is 1.5 ㎜；
Part III is two layers polyester isolation film, and polyester insulating film thickness is 0.03 ㎜.
The raw material components of the wet-laying modified pitch layer sizing, in terms of mass parts, including：200 parts of 90# pitches, 10# pitches
100 parts, second line of distillation oil 33 parts, SBS10 parts, SBR14 parts, SIS22 parts, 40 parts of cement, 30 parts of talcum powder, 10 parts of light calcium carbonate powder, stone
12 parts of oleoresin, 3 parts of coumarone indene resin, 4.5 parts of hydrogenated terpene resin, 2 parts of graphene, dodecyl dihydroxy ethyl glycine betaine
1.5 parts, 3 parts of fluorocarbon resin, 2 parts of butyl octanol salicylate, 1.2 parts of antioxidant D NP, 3 parts of antistripping agent, antioxidant 1.3
Part.
The SBR is powder styrene butadiene rubber, and butadiene-styrene rubber content is 65-70%；
The SBS：Fugitive constituent≤1%；Solution mass flow rate is 0 .1-5g/10min；Tensile strength >=20MPa；It pulls
Disconnected elongation >=680%；The .2% of ash content≤0.
The SIS：Solution mass flow rate is 2-14g/10min；Tensile strength >=7MPa；Elongation at break >=
1000%；The .7% of ash content≤0.
The cement is Portland cement, marked as 425；
The antioxidant is three last of the ten Heavenly stems esters；
The talcum powder is 400 mesh talcum powder；
The light calcium carbonate powder is 600 mesh light calcium carbonate powders.
A kind of 2 SAM cross-levels double-sided self-adhesive waterproof coiled materials of embodiment
The waterproof roll includes following three parts：
First part is red polyester film, as carrier；Red polyester film thickness is 0.17 ㎜；
Second part is upper layer and lower layer modified asphalt layer, is wet-laying self-adhesive modified asphalt coating sizing material, wet-laying self-adhesive modified asphalt
Coating sizing material thickness is 1.6 ㎜；
Part III is two layers polyester isolation film, and polyester insulating film thickness is 0.04 ㎜.
The modified asphalt layer, in terms of mass parts, including：220 parts of 90# pitches, 80 parts of 10# pitches, second line of distillation oil 34
Part, SBS11 parts, SBR17 parts, SIS21 parts, 45 parts of cement, 35 parts of talcum powder, 13 parts of light calcium carbonate powder, 13 parts of Petropols, coumarone
3 parts of resin, 5.5 parts of hydrogenated terpene resin, 3 parts of graphene, 2.2 parts of dodecyl dihydroxy ethyl glycine betaine, fluorocarbon resin 3.5
Part, 2.5 parts of butyl octanol salicylate, 1.8 parts of antioxidant D NP, 4 parts of antistripping agent, 1.5 parts of antioxidant.
The SBR is powder styrene butadiene rubber, and butadiene-styrene rubber content is 65-70%；
The SBS：Fugitive constituent≤1%；Solution mass flow rate is 0 .1-5g/10min；Tensile strength >=20MPa；It pulls
Disconnected elongation >=680%；The .2% of ash content≤0.
The SIS：Solution mass flow rate is 2-14g/10min；Tensile strength >=7MPa；Elongation at break >=
1000%；The .7% of ash content≤0；
The cement is Portland cement, marked as 425R；
The antioxidant is three last of the ten Heavenly stems esters；
The talcum powder is 400 mesh talcum powder；
The light calcium carbonate powder is 600 mesh light calcium carbonate powders
A kind of 3 double-sided adhesive asphaltic base red polyester film carcass wet-laying waterproof roll of embodiment
The waterproof roll includes following three parts：
First part is red polyester film, as carrier；Red polyester film thickness is 0.16 ㎜；
Second part is two layers of modified asphalt layer, as wet-laying self-adhesive modified asphalt coating sizing material, and wet-laying self-adhesive modified asphalt applies
Layer sizing thickness is 1.6 ㎜；
Part III is two layers polyester isolated film, and polyester isolated film thickness is 0.05 ㎜.
The raw material components of the modified asphalt layer, in terms of mass parts, including：240 parts of 90# pitches, subtract 100 parts of 10# pitches
35 parts of two wires oil, 12 parts of SBS, 20 parts of SBR, 23 parts of SIS, 50 parts of cement, 40 parts of talcum powder, 15 parts of light calcium carbonate powder, oil
14 parts of resin, 6 parts of coumarone indene resin, 6.5 parts of hydrogenated terpene resin, 4 parts of graphene, dodecyl dihydroxy ethyl glycine betaine
2.5 parts, 4 parts of fluorocarbon resin, 3 parts of butyl octanol salicylate, 2 parts of antioxidant D NP, 5 parts of antistripping agent, antioxidant 1.6
Part.
The SBR is powder styrene butadiene rubber, and butadiene-styrene rubber content is 65-70%；
The SBS：Fugitive constituent≤1%；Solution mass flow rate is 0 .1-5g/10min；Tensile strength >=20MPa；It pulls
Disconnected elongation >=680%；The .2% of ash content≤0.
The SIS：Solution mass flow rate is 2-14g/10min；Tensile strength >=7MPa；Elongation at break >=
1000%；
The .7% of ash content≤0
The cement is Portland cement, marked as 425
The antioxidant is three last of the ten Heavenly stems esters；
The talcum powder is 400 mesh talcum powder.
The light calcium carbonate powder is 600 mesh light calcium carbonate powders.
Indexs measure is carried out to the wet-laying waterproof roll of embodiment 1-3, the results are shown in Table 1；
Table 1
To sum up, waterproof roll pulling force of the present invention is 230 ~ 250N/50 ㎜, and the prior art is 150N/50 ㎜；It is extended when maximum pull
Rate is 120 ~ 160%, the prior art 30%.The peel strength of waterproof roll is 1.7-2.0 N/mm, tearing strength 17-20
N, heat aging property are pulling force conservation rate 94-98%（70 DEG C, 168h）, percent retention of elongation 94-97%（70 DEG C, 168h）；Heat
Stability is high, and size changing rate is less than 1.5%.It is used in high temperature area or low temp area or awful weather area, the service life is above
50 years.
In addition to specified otherwise, ratio of the present invention is mass ratio, and the percentage is mass percent.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
It, for those skilled in the art, still can be with although describing the invention in detail with reference to the foregoing embodiments
Technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features.It is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in the guarantor of the present invention
Within the scope of shield.The above is the citing of best mode for carrying out the invention, wherein the part that do not address in detail is this field
The common knowledge of those of ordinary skill；Protection scope of the present invention is based on the contents of the claims, any based on the present invention's
Technical inspiration and the equivalent transformation carried out, also within protection scope of the present invention.
Claims (10)
1. a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials, it is characterised in that：The waterproof roll includes that polyester isolation is thin
Film, modified asphalt layer, red polyester film.
2. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 1, it is characterised in that：The red polyester film thickness
Degree is 0.1-0.2 ㎜；The modified pitch layer thickness is the ㎜ of 0 .7-1.6；The polyester isolated film thickness is
0.03—0.05㎜。
3. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 1, it is characterised in that：
The modified asphalt layer, including following components：90# pitches, 10# pitches, second line of distillation oil, SBS, SBR, SIS, cement,
Talcum powder, light calcium carbonate powder, Petropols, coumarone indene resin, hydrogenated terpene resin, graphene, dodecyl dihydroxy ethyl glycine betaine,
Fluorocarbon resin, butyl octanol salicylate, antioxidant D NP, antistripping agent, antioxidant.
4. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 1, it is characterised in that：
The raw material components of the modified asphalt layer, in terms of mass parts, including：
200-240 parts of 90# pitches, 80-100 parts of 10# pitches, 33-35 parts of second line of distillation oil, SBS10-12 parts, SBR14-20 parts,
SIS20-23 parts, 40-50 parts of cement, 30-40 parts of talcum powder, 10-15 parts of light calcium carbonate powder, 12-14 parts of Petropols, coumarone indene resin
3-6 parts, 4.5-6.5 parts of hydrogenated terpene resin, 2-4 parts of graphene, 1.5-2.5 parts of dodecyl dihydroxy ethyl glycine betaine, fluorine carbon
3-4 parts of resin, 2-3 parts of butyl octanol salicylate, 1-2 parts of antioxidant D NP, 3-5 parts of antistripping agent, antioxidant 1.3-1.6
Part.
5. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 3, it is characterised in that：
The SBR is powder styrene butadiene rubber, and minimum resist cold is -40 DEG C, and heat-resisting highest is 150 DEG C, ordinary rubber is minimum resist cold for -
20 DEG C, heat-resisting highest is 100 DEG C, the 63%-75% of amount containing butadiene-styrene rubber；
The SBS：Fugitive constituent≤1%；Solution mass flow rate is 0 .1-5g/10min；Tensile strength >=20MPa；It pulls
Disconnected elongation >=680%；The .2% of ash content≤0.
6. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 3, it is characterised in that：
The SIS：Solution mass flow rate is 2-14g/10min；Tensile strength >=7MPa；Elongation at break >=
1000%；The .7% of ash content≤0；
The Petropols are C 5 hydrogenated petroleum resin, 96-105 DEG C of softening point；Viscosity≤250（190℃ mPa .s）；
Flash-point：≥ 190℃；Burning point >=210 DEG C.
7. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 3, it is characterised in that：
The antistripping agent is any one in Carlow amine, AR-68, TJ066；
The cement grade is 425 or 425R；
The antioxidant is three monooctyl esters or three last of the ten Heavenly stems esters.
8. according to a kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 3, it is characterised in that：
The coumarone indene resin：Fluent material, 75-135 DEG C of softening point, relative density are the .07 of 1 .05-1, glass transition temperature
56 DEG C, refractive index 1.60 ~ 1.65；
The talcum powder is 400 mesh talcum powder；
The light calcium carbonate powder is 600 mesh light calcium carbonate powders.
9. according to a kind of preparation process of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 1, it is characterised in that：Including wet
Spread preparation, coating modified pitch layer sizing, high temperature ultrasonic processing, overlay film and the cooling and shaping step of modified pitch layer sizing；
The preparation process of the wet-laying modified pitch layer sizing：
Material-compound tank is added in 90# pitches and 10# pitches, when being warming up to 240-250 DEG C, 2-3h is stirred, is then cooled to 200 DEG C and opens
Beginning is added SBS, SBR, SIS and keeps the temperature at 200 DEG C, stirs 2-3h；
Petropols, coumarone indene resin, antistripping agent, antioxidant is added and stirs 30min；It is cooled to 140 DEG C and cement, talcum is added
Powder, light calcium carbonate powder, second line of distillation oil, stir 1h；
Then hydrogenated terpene resin, graphene, dodecyl dihydroxy ethyl glycine betaine are sequentially added, 30-40min is stirred；Then
It is warming up to 180-190 DEG C, sequentially adds fluorocarbon resin, butyl octanol salicylate, antioxidant D NP, stirs 20-30min.
10. according to a kind of preparation process of SAM cross-levels double-sided self-adhesive waterproof coiled materials of claim 1, it is characterised in that：
The coating modified pitch layer sizing：
After wet-laying modified pitch layer sizing is cooled to 120 ± 5 DEG C, introduces and apply oil sump；
It opens and applies oil pump, modified pitch layer sizing enters support food tray, keeps the amount of modified pitch layer sizing in support food tray sufficient；Make red
Color polyester film depresses oiling pressure roller, by position of the red polyester film in coiled material, adjusts position of oil scraper, make by applying oil sump
The modified pitch layer thickness of red polyester film both sides is the ㎜ of 0 .7-1.6；
The high temperature ultrasonic processing：Coiled material after oiling is subjected to high temperature ultrasonic processing, temperature is 89-95 DEG C, supersonic frequency
For：100-110KHz；Processing time is 40-50min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810468328.4A CN108715071A (en) | 2018-05-16 | 2018-05-16 | A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810468328.4A CN108715071A (en) | 2018-05-16 | 2018-05-16 | A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108715071A true CN108715071A (en) | 2018-10-30 |
Family
ID=63900081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810468328.4A Pending CN108715071A (en) | 2018-05-16 | 2018-05-16 | A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108715071A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116332603A (en) * | 2023-03-30 | 2023-06-27 | 安徽皖科新科技发展有限公司 | Tunnel grouting material, and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000001891A1 (en) * | 1998-07-06 | 2000-01-13 | Daniel Doligez | Anti-moisture complex for fibre and plastic film grid |
| CN201190377Y (en) * | 2008-04-30 | 2009-02-04 | 潍坊市宏源防水材料有限公司 | Waterproof roll of self-adhering polymer modified bitumen polyester tyre |
| CN105619929A (en) * | 2015-12-21 | 2016-06-01 | 潍坊市宏源防水材料有限公司 | Double-sided adhesive asphalt-base and PET (polyethylene terephthalate)-carrier wet-laid waterproof roll and production process thereof |
-
2018
- 2018-05-16 CN CN201810468328.4A patent/CN108715071A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000001891A1 (en) * | 1998-07-06 | 2000-01-13 | Daniel Doligez | Anti-moisture complex for fibre and plastic film grid |
| CN201190377Y (en) * | 2008-04-30 | 2009-02-04 | 潍坊市宏源防水材料有限公司 | Waterproof roll of self-adhering polymer modified bitumen polyester tyre |
| CN105619929A (en) * | 2015-12-21 | 2016-06-01 | 潍坊市宏源防水材料有限公司 | Double-sided adhesive asphalt-base and PET (polyethylene terephthalate)-carrier wet-laid waterproof roll and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116332603A (en) * | 2023-03-30 | 2023-06-27 | 安徽皖科新科技发展有限公司 | Tunnel grouting material, and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105619929B (en) | A kind of both-sided adhesive asphaltic base pet vector wet-laying waterproof roll and its production technology | |
| CN101921545B (en) | Asphalt waterproof paint for building and preparation method thereof | |
| CN103740122B (en) | A kind of self-adhesive polymer modified bituminous polyester fiber waterproof sheet material and preparation method thereof | |
| CN104553130B (en) | Fusible elastomer modified asphalt waterproof roll | |
| CN108003833B (en) | Self-adhesive glue, preparation method thereof and anti-pollution self-adhesive asphalt waterproof coiled material | |
| CN102220020B (en) | High-molecular polymer asphalt for road crack repair, manufacturing method and crack-bonding belt | |
| CN110746930B (en) | Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and passive self-adhesive asphalt waterproof coiled material special for building | |
| CN106633965B (en) | A kind of weather-proof high extension roofing self-adhering polymer waterproof roll and preparation method thereof | |
| CN106183268A (en) | A kind of pre-laying water-proof coiled material of self-adhesion macromolecule and preparation method thereof | |
| CN102604553A (en) | Reaction-type high-strength laminated film waterproof roll | |
| CN107474793B (en) | Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material | |
| CN102304330A (en) | Clean and environmentally-friendly hot melt adhesive capable of being operated at low temperature as well as preparation method and application thereof | |
| CN103692719B (en) | Composite pre-laid waterproof coiled material | |
| CN109749658A (en) | One kind is from viscous bitumen, heat insulation type without tyre water-proof coiled material and preparation method thereof | |
| CN108587509A (en) | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof | |
| CN109130440A (en) | Composite self-adhering shale face modified asphalt waterproof coiled material and preparation method thereof | |
| CN109777331B (en) | Hot-melt pressure-sensitive adhesive, preparation method and application thereof | |
| CN105735572A (en) | Wetly paved waterproof roll with mineral aggregate surface and preparation method therefor | |
| CN108715071A (en) | A kind of SAM cross-levels double-sided self-adhesive waterproof coiled materials | |
| CN105238347A (en) | Self-adhesive glue, FPF macromolecular self-adhesive waterproof coiled material and manufacturing process therefor | |
| CN107964366B (en) | Non-curing rubber asphalt waterproof coating | |
| CN110106715A (en) | One kind overlaying self-adhered polymer modified bitumen waterproofing membrane and preparation method thereof | |
| CN103373030B (en) | A kind of hydrophilic antiadhesion barrier and preparation method | |
| CN207607201U (en) | There is the process units of tire self-adhered polymer modified bitumen waterproofing membrane | |
| CN101914978B (en) | Water-proof coiled material with self-adhesive layer structure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181030 |