CN101914978B - Water-proof coiled material with self-adhesive layer structure - Google Patents
Water-proof coiled material with self-adhesive layer structure Download PDFInfo
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- CN101914978B CN101914978B CN 201010272656 CN201010272656A CN101914978B CN 101914978 B CN101914978 B CN 101914978B CN 201010272656 CN201010272656 CN 201010272656 CN 201010272656 A CN201010272656 A CN 201010272656A CN 101914978 B CN101914978 B CN 101914978B
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Abstract
The invention relates to a water-proof coiled material with a self-adhesive layer structure. The water-proof coiled material comprises a surface film, a lapping surface plastic edge film, a first asphalt layer, a first environment-friendly wide-temperature-variation self-adhesive layer and a bottom film, wherein a bottom film is compounded on the lower surface of the first environment-friendly wide-temperature-variation self-adhesive layer; the first asphalt layer and the surface film (1) are sequentially compounded on the upper surface of the first environment-friendly wide-temperature-variation self-adhesive layer; the surface film is narrower than the first asphalt layer; blank edges used for the lapping surface plastic edge film are reserved on the two side edges of the first asphalt layer respectively; the blank edges are lapping edges; and the lapping surface plastic edge film is compounded on the lapping edges. The self-adhesive layer of the water-proof coiled material of the invention is aqueous, does not have toxicity or smell, has high bonding strength with a substrate, high water-proofness and high weather resistance, is not influenced by temperature variation and can be stored and used for a long time. The coiled material has the advantages of simple and convenient production process and small equipment investment and is an advanced and practical substitute product for self-adhesive asphalt or modified asphalt water-proof coiled material.
Description
Technical field
The present invention relates to a kind of architectural waterproof material, especially relate to a kind of pitch or modified asphalt waterproof coiled material of the self-adhesive layer structural formula that becomes with the wide temperature of environmental protection.
Background technology
At present, in China's buildings waterproof industry, a kind of main waterproofing materials of extensive use with pitch or with the modified asphalt waterproof coiled material of the material modification productions such as SBS, APP, during in the early stage production application of this material construction, be everlasting the back side of coiled material with blowtorch heat fused bitumen layer after, directly stick in the basic units such as cement, common brick, or with prefabricated liquid asphalt as adhesive, be coated on the coiled material that bonds in the substrate.
Through application test in a few years, find that this construction and application method not only wastes time and energy, and, because of low with the adhesion strength of basic unit, easily throw off with substrate after a period of time, play drum and separate, cause seepage, have a strong impact on waterproof quality and the application life of building.
In recent years, some manufacturers add the softening pitch of part mineral oil one after another in pitch or modified bitumen, make its pitch in use still be soft state, and has certain viscosity, simultaneously, also when asphalt heating, add some resinae tackify materials, increase the viscosity of pitch.And when producing the coiled material moulding, its surperficial roll-in one deck Anti-adhering plastic film or antiseized kraft is not so that can be adhered to one another in the rolling packing.When application and construction, throw off Anti-adhering plastic film or the antiseized kraft on surface, directly paste in the basic unit after exposing pitch, be called self-adhesive modified asphalt waterproof rolling material.This autohesion modified asphalt waterproof coiled material heats with blowtorch no longer at the scene or is coated with prefabricated liquid asphalt as adhesive, working procedure and labour intensity have been reduced, improved operating efficiency, the exhaust emission that has produced when also having changed the blowtorch heating flame, improved the work-yard environment, useful construction workman's physical and mental health.But, in actual production and in using, also exist some problems, as:
1. because the temperature height is very large to the viscous effects of pitch or modified bitumen, even have too temperature and the proportional increase and decrease of viscosity through pitch or modified bitumen behind softening and the tackify.When temperature raises, can make the very fast raising of viscosity of pitch or modified bitumen, when drop in temperature, the viscosity of pitch or modified bitumen is descended rapidly, cause being difficult to bonding with substrate.Temperature Change throughout the year is very large, and the temperature of winter, Xia Liangji differs up to upper Baidu, and this brings very large difficulty for production and the storage time of autohesion modified asphalt waterproof coiled material.For this reason, one production producer only has by the variations in temperature in the four seasons or by the seasonal change adjustment prescription (seeing the following form 1) of different days normal temperatures, output also can only be pressed row according to client's order time and construction period, can not be planned formulate annual productive target, the overall development of company is subject to certain restriction;
2. when in sale, transportation and construction application process, running into some reason, in the time of the product of at a time section production normally can not being used to site construction by the period, will affect product quality because of adhesive property decline, cause waste;
3. when self-adhesive modified asphalt waterproof rolling material is used for building roof or other exposure portion, since the sun be exposed to the sun and round the clock, the variation of the four seasons temperature difference, softening oil in the pitch can be overflowed rapidly, so that pitch or modified asphalt layer sclerosis are dry and cracked, reduce or lose viscosity, cause the adhesion stress of coiled material and substrate to descend and throw off, cause seepage, affect waterproof quality and the application life of building.
4. in application and construction; as running into quick variation and the change of construction period of temperature, Anti-adhering plastic film or the antiseized barrier paper that often can be compounded on pitch or the modified bitumen are difficult to take off, or are difficult to the extreme phenomenon of bonding with substrate; thereby, the quality of impact construction and the progress of engineering.
5. the adhesion strength of the technical indicator of peel strength and practical application often conflicts in the examination criteria.Detection data under normal temperature (23 ± 2 ℃) are to meet standard-required fully; and often can receive in actual applications the user the not high complaint of adhesion strength is proposed; therefore; the customer requirements transposing or the return of goods that have; the compensation that requires because causing damage that has is appreciated; corporate image and product brand are caused bad impact, also cause very large waste.
The changes in material of table 1 self-adhesive modified asphalt waterproof rolling material Various Seasonal
Summary of the invention
The object of the invention is to, overcome above-mentioned defective from viscous bitumen or modified asphalt waterproof coiled material existence; Thereby, provide a kind of high with aqueous non-toxic, adhesion strength, be not subjected to influence of temperature change, pitch or the modified asphalt waterproof coiled material of the wide temperature change of the environmental protection self-adhesive layer structure that can store for a long time.
The object of the present invention is achieved like this:
The waterproof roll of a kind of self-adhesive layer structural formula provided by the invention comprises facial mask 1, faying surface plastic edge film 2, the first bitumen layer 3-1 and counterdie 6; It is characterized in that, comprise that also the wide temperature of the first environmental protection becomes self-adhesive layer 5-1; The wide temperature of described the first environmental protection becomes the compound described counterdie 6 of soffit of self-adhesive layer 5-1, and the wide temperature of this first environmental protection becomes upper surface compound described the first bitumen layer 3-1 of order and the described facial mask 1 of self-adhesive layer 5-1; Wherein, described the first bitumen layer 3-1 is narrow for the Width of this facial mask 1, the dual-side of this first bitumen layer 3-1 leaves respectively a lay edges (i.e. not compound described facial mask 1 on the dual-side of this first bitumen layer 3-1) that is used for faying surface plastic edge film 2, described lay edges is overlap edge, and on described overlap edge compound described faying surface plastic edge film 2;
Described bitumen layer 3-1 is that pitch is made, and its thickness is 0.3-5.0mm;
The thickness that the wide temperature of described the first environmental protection becomes self-adhesive layer 5-1 is 0.2-3.0mm; The bonding adhesive of the wide temperature change of this environmental protection self-adhesive layer 5-1 is prepared by following methods:
1) adhesive formulation
The A component is: deionized water 90.0-130.0 weight portion;
The B component is: deionized water 9.0-22.0 weight portion, sulfate 0.5-1.5 weight portion and polymerizer 0.1-1.0 weight portion mix;
The C component is: deionized water 98.0-128.5 weight portion, sulfate 0.2-5.0 weight portion and polymerizer 2.5-4.5 weight portion mix;
The D component is: acrylate 150.0-260.0 weight portion, methacrylic acid 3.0-10.0 weight portion, rosin fat 0.2-5.0 and organosilicon 2.0-5.0 weight portion mix; Or be
Acrylate 150.0-260.0 weight portion, acetate 8.0-120.0 weight portion, methyl methacrylate 3.0-10.0 weight portion, rosin fat 0.2-5.0 weight portion and organosilicon 2.0-5.0 weight portion mix;
Also comprise first rosin fat is dissolved in the D component, again with the C component in the container of corresponding weight portion, to carry out under the rotating speed of 300-500 rev/min (hereinafter to be referred as r/min) pre-emulsification 30-60 minute, obtain even milky pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add the 10%-30% by the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, the wide temperature of environmental protection that obtains water-based becomes the bonding adhesive that self-adhesive layer is used.
In above-mentioned technical scheme, comprise that also the wide temperature of the second environmental protection becomes self-adhesive layer 5-2; The wide temperature of two compound the first environmental protection of surface difference at described the first bitumen layer 3-1 becomes self-adhesive layer 5-1 and the wide temperature change of described environmental protection self-adhesive layer 5-2, the compound described counterdie 6 of soffit at the wide temperature change of this first environmental protection self-adhesive layer 5-1 becomes the compound described facial mask 1 of self-adhesive layer 5-2 upper surface in the wide temperature of this second environmental protection; Wherein, it is narrow that the wide temperature of described the second environmental protection of the Width of this facial mask 1 becomes self-adhesive layer 5-2, the dual-side that becomes self-adhesive layer 5-2 in the wide temperature of the second environmental protection leaves respectively an overlap edge that is used for faying surface plastic edge film 2, and on described overlap edge compound described faying surface plastic edge film 2.
In above-mentioned technical scheme, also comprise a tire basic unit 4 and the second bitumen layer 3-2; Two surfaces in described tire basic unit 4 apply respectively the first bitumen layer 3-1 and the second bitumen layer 3-2, at the wide temperature change self-adhesive layer 5-1 of another surface compound described first environmental protection of order and the described counterdie 6 of the first bitumen layer 3-1; At the described facial mask 1 of another surface recombination of the second bitumen layer 3-2, wherein, described the second bitumen layer 3-2 is narrow for the Width of this facial mask, leave respectively an overlap edge that is used for faying surface plastic edge film 2 at the dual-side of the second bitumen layer 3-2, and on described overlap edge compound described faying surface plastic edge film 2.
In above-mentioned technical scheme, comprise that also the wide temperature of the second environmental protection becomes self-adhesive layer 5-2; Respectively compound the first bitumen layer 3-1 and the second bitumen layer 3-2 on two surfaces of described tire basic unit 4; The wide temperature of another compound the second environmental protection of surface order at this second bitumen layer 3-2 becomes self-adhesive layer 5-2 and described facial mask 1, wherein, it is narrow that the wide temperature of described the second environmental protection of the Width of this facial mask 1 becomes self-adhesive layer 5-2, the dual-side that becomes self-adhesive layer 5-2 in the wide temperature of the second environmental protection leaves respectively an overlap edge that is used for faying surface plastic edge film 2, and on described overlap edge compound described faying surface plastic edge film 2; The wide temperature of another compound the first environmental protection of surface order at this first bitumen layer 3-1 becomes self-adhesive layer 5-1, becomes the compound described counterdie 6 of soffit of self-adhesive layer 5-1 in the wide temperature of this first environmental protection.
In above-mentioned technical scheme, described facial mask 1 is the kraft that PE antiadhesion barrier, aluminium foil film or single face that single face scribbles silicone oil scribble silicone oil.
In above-mentioned technical scheme, described counterdie 6 is two-sided antiseized PE plastic foil or the antiseized kraft that scribbles silicone oil.
In above-mentioned technical scheme, described faying surface plastic edge film 2 is two-sided antiseized PET films that scribble silicone oil, and the width of described faying surface plastic edge film 2 is 50-150mm.
In above-mentioned technical scheme, the material of described tire basic unit 4 is polyester blank or glass fiber blank.
In above-mentioned technical scheme, the pitch in the described bitumen layer is manufactured by petroleum bitumen, adds SBS, APP or other materials in the described petroleum bitumen again, also can add various powder stuffings and auxiliary agent.
In above-mentioned technical scheme, described sulfate is anhydrous sodium sulfate, potassium peroxydisulfate or ammonium persulfate.
In above-mentioned technical scheme, described polymerizer is surfactant; Described surfactant is sodium lauryl sulfate, neopelex or OPEO.
In above-mentioned technical scheme, described acrylate is butyl acrylate or methyl methacrylate.
In above-mentioned technical scheme, described tackifying resin is rosin fat, esterase, terpene resin or with the rosin liquid behind the alkali soap.
In above-mentioned technical scheme, described acetate is vinylacetate or butyl acetate.
In above-mentioned technical scheme, described organosilicon is vinyl front three ethylsiloxane, acrylic trimethoxy silane, octamethylcy-clotetrasiloxane or dimethyl cyclosiloxane.
The effect that the present invention is useful is:
1. the water-proof coiled material product steady quality of self-adhesive layer structural formula provided by the invention, the adhesion strength of self-adhesive layer and substrate is high, can not be acted upon by temperature changes, throughout the year can both construction application; Specifications all meets or surpasses national standard;
2. it is tasteless that the waterproof roll of this self-adhesive layer structural formula has aqueous non-toxic, meets the requirement of environmental protection coiled material product, is of value to the healthy of workman of producing and construct, and is of value to environment, is of value to society, has good practical value and social benefit;
3. the self-adhesive layer in this coiled material also has good water-proof function, hot strength, elongation per unit length and far above the ageing-resistant performance of pitch or modified asphalt layer, also has certain thickness, has correspondingly improved product quality and the application life of existing waterproof roll;
4. the long shelf-life of the waterproof roll of this self-adhesive layer structural formula can not affect adhesion strength and cause waste because of the increase of resting period, has also effectively avoided user's complaint, has improved the influence power of product and company;
5. the production technology of making coiled material of the present invention is simple, as long as on existing waterproof roll production line, slightly transform, just but the wide temperature of production environmental protection becomes self-adhesive layer pitch or modified asphalt waterproof coiled material, and the scrap build input seldom is conducive to this technology and applies in practice.
Description of drawings
Fig. 1 is the longitudinal profile structural representation of the waterproof roll of a kind of self-adhesive layer structural formula of the present invention; (annotating: without tire one-side band self-adhesive layer structural formula)
Fig. 2 is the longitudinal profile structural representation of the waterproof roll of another self-adhesive layer structural formula of the present invention; (annotating: without tire double-sided belt self-adhesive layer structural formula)
Fig. 3 is the longitudinal profile structural representation of the waterproof roll of another kind of self-adhesive layer structural formula of the present invention; (annotating: tire one-side band self-adhesive layer structural formula is arranged)
Fig. 4 is the longitudinal profile structural representation of the waterproof roll of another kind of self-adhesive layer structural formula of the present invention; (annotating: tire double-sided belt self-adhesive layer structural formula is arranged)
Fig. 5 is the surface structure schematic diagram of the waterproof roll of a kind of self-adhesive layer structural formula with facial mask and faying surface plastic edge film of the present invention;
Fig. 6 is the horizontal section structural representation of the waterproof roll of Fig. 4;
Description of reference numerals:
Facial mask-1 faying surface plastic edge film-2
The first bitumen layer 3-1 the second bitumen layer 3-2
The wide temperature of tire basic unit-4 the first environmental protection becomes self-adhesive layer-5-1
The wide temperature of the second environmental protection becomes self-adhesive layer-5-2 counterdie-6
Concrete embodiment
The present invention is further illustrated below in conjunction with drawings and Examples:
Embodiment 1
With reference to figure 1 and Fig. 5, make of the present invention a kind of without tire, a surface becomes the waterproof roll of self-adhesive layer with the wide temperature of environmental protection.
The facial mask 1 of present embodiment, faying surface plastic edge film 2 adopt facial mask and the limit coating materials of the waterproof roll use of buying on the market, and wherein, the width of facial mask 1 is 800mm, and the width of faying surface plastic edge film 2 is 120mm.The first bitumen layer 3-1 and the second bitumen layer 3-2 adopt 90# petroleum bitumen.The faying surface plastic edge film 2 that present embodiment uses is antiseized PET films that the surface bought on the market scribbles silicone oil.The facial mask 1 of present embodiment is carried by self-adhesive layer, and the wide temperature of the first environmental protection of present embodiment becomes the compound counterdie 6 of soffit of self-adhesive layer 5-1, and the wide temperature of this first environmental protection becomes upper surface compound described the first bitumen layer 3-1 of order and the described facial mask 1 of self-adhesive layer 5-1; Wherein, the Width first bitumen layer 3-1 of this facial mask 1 is narrow, the narrow 240mm of Width the first bitumen layer 3-1 of facial mask 1; Namely leave respectively the lay edges (i.e. not compound described facial mask 1 on the dual-side of this first bitumen layer 3-1) that is used for faying surface plastic edge film 2 of a wide 120mm at the dual-side of this first bitumen layer 3-1, described lay edges is overlap edge, and on described overlap edge compound described faying surface plastic edge film 2.When application and construction, faying surface plastic edge film 2 is thrown off, good bond together with the compound overlapping overlap joint of the first self-adhesive layer 5-1, form whole waterproofing course, recombination site between faying surface plastic edge film 2 and the facial mask 1 as shown in Figure 5, faying surface plastic edge film 2 width can be can than blank hem width 1-10cm.
Wherein, the thickness of the first bitumen layer 3-1 is 0.3,4.0mm or 5.0mm can; The thickness that the wide temperature of the first environmental protection becomes self-adhesive layer 5-1 into 0.2,1.0mm, 1.5mm, 2.0mm, 2.3mm or 3.0mm be all passable.
The bonding adhesive of the wide temperature change of the first environmental protection that present embodiment uses self-adhesive layer 5-1 is made by following methods:
1) at first, according to the adhesive formulation weighing:
The A component is: measure deionized water 110.0 weight portions;
The B component is: measure deionization 15.0 weight portions, persulfuric acid and receive 1.0 weight portions and polymerizer 0.2 weight portion and mix;
The C component is: measure deionized water 120.0 weight portions, potassium peroxydisulfate 0.5 weight portion, polymerizer 3.8 weight portions and anhydrous sodium sulfate 1.5 weight portions and mix;
The D component is: take by weighing butyl acrylate 200.0 weight portions, methacrylic acid 5.0 weight portions, rosin fat 0.9 weight portion, vinylacetate 18.0 weight portions, methyl methacrylate 5.0 weight portions and organosilicon 2.0 weight portions and mix; Or first rosin fat 0.9 weight portion is dissolved in the D component, and then mix with the C component that configures, to carry out pre-emulsification under the rotating speed of 300r/min 60 minutes, obtain milky even pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of drop bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add by 15% of the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive.
The manufacturing process of the waterproof roll of the self-adhesive layer structural formula of present embodiment can adopt following technique to realize: the material after preparing material advances people's reactor and adds thermal response, reacted material is the bitumen layer raw material, flow directly in the waterproof roll production line without tyre forming machine, by being the bitumen layer of 1000mm specification without tyre forming machine extrusion molding width, in the time of along with the bitumen layer of extrusion molding, close the self-adhesive layer 5-1 that the wide temperature of the first environmental protection becomes at its soffit roller, it is the facial mask 1 that surface that self-adhesive layer itself carries scribbles silicone oil below the self-adhesive layer, simultaneously roller unification of the upper surface of its first bitumen layer 3-1 aspect film 1 and in the faying surface plastic edge film 2 on facial mask 1 both sides, the first bitumen layer 3-1 roll extrusion of common and extrusion molding together, the thickness of this first bitumen layer 3-1 is 0.5,1.0,1.6,2.0,2.7,3.0-3.5mm can, the self-adhesive layer waterproof roll that the wide temperature of the environmental protection of moulding becomes is through the water circulation rolling after cooling, cutting, packing, this is that those skilled in the art can be implemented.
With reference to figure 3 and 5, make the waterproof roll of self-adhesive layer structural formula of the present invention, this has the self-adhesive layer waterproof roll that becomes with the wide temperature of environmental protection of tire is as tire basic unit 4 by the non-woven polyester fabrics of buying on one deck market, the upper and lower surface of this tire basic unit 4 applies respectively first floor bitumen layer 3-1 and second layer pitch 3-2, at the self-adhesive layer 5-1 of the wide temperature change of another surface recombination first environmental protection of described the first bitumen layer 3-1, and the counterdie that scribbles silicone oil 6 of the self-adhesive layer 5-1 soffit of the wide temperature change of the first environmental protection is combined with each other; The compound facial mask 1 in the centre position of another upper surface of described second layer bitumen layer 3-2, the Width second layer bitumen layer 3-2 that is facial mask 1 is narrow, the width that is facial mask 1 is 100mm, the compound faying surface plastic edge film 2 on the both sides of facial mask 1, the width of the faying surface plastic edge film 2 of described dual-side is respectively 50-150mm.
Described the first bitumen layer 3-1 and the second bitumen layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with SBS resin and powder stuffing or with APP resin and powder stuffing or with the modified bitumen of rubber powder and powder stuffing modification, its thickness is respectively 0.5-3.0mm;
The thickness of the self-adhesive layer that the wide temperature of described environmental protection becomes is 0.2-2.0mm;
The wide temperature change of the environmental protection that present embodiment uses self-adhesive layer bonding adhesive is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 105.0 weight portions;
The B component is: deionization 20.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.5 weight portion;
The C component is: deionized water 123.5 weight portions, ammonium persulfate 0.5 weight portion, polymerizer 3.0 weight portions and anhydrous sodium sulfate 1.5 weight portions;
The D component is: butyl acrylate 230.0 weight portions, methacrylic acid 5.0 weight portions, rosin fat 1.3 weight portions and vinylacetate 10.0 weight portions, first rosin fat 1.3 weight portions are dissolved in the D component, and then mix with the C component that configures, to carry out pre-emulsification under the rotating speed of 500r/min 30 minutes, obtain
++ milky even pre-emulsion;
2) bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add by 30% of the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive.
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the waterproof roll of self-adhesive layer can adopt following technique to realize: the material after preparing material advances people's reactor and adds thermal response, reacted material is the raw material of the first bitumen layer 3-1 and the second bitumen layer 3-2, flow directly into being coated with in the oil sump in the waterproof roll production line, be the first bitumen layer 3-1 and the second bitumen layer 3-2 of 1000mm specification by two roller extrusion molding width with tire base 4, in the time of along with extrusion molding, the self-adhesive layer 5 that wide temperature becomes is protected in soffit roller cyclization at the first bitumen layer 3-1, it is the facial mask 1 that surface that self-adhesive layer carries scribbles silicone oil below the self-adhesive layer 5, the upper surface of the second bitumen layer 3-2 is the faying surface plastic edge film 2 on roller unification aspect film 1 and facial mask 1 both sides simultaneously also, the first bitumen layer 3-1 common and extrusion molding is in the same place with the second bitumen layer 3-2 roll-in, the thickness of this first bitumen layer 3-1 and the second bitumen layer 3-2 is respectively 0.5,1.0,1.6,2.0mm can, the self-adhesive layer waterproof roll that the wide temperature of the environmental protection of moulding becomes is through the water circulation rolling after cooling, cutting, packing.
Embodiment 3
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the self-adhesive layer waterproof roll is identical with embodiment 2 with product structure, and its difference is the glass fiber tire of described tire basic unit 4 for buying on the market;
Described the first bitumen layer 3-1 and the second bitumen layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with APP resin and powder stuffing or with the modified bitumen of SBS resin and powder stuffing modification, its thickness is 0.5-3.5mm;
The thickness of the self-adhesive layer 5-1 that the wide temperature of described the first environmental protection becomes is 0.2-1.5mm;
The bonding adhesive that the self-adhesive layer 5-1 that the wide temperature of present embodiment the first environmental protection becomes uses is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 115.0 weight portions;
The B component is: deionization 21.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.3 weight portion;
The C component is: deionized water 110.0 weight portions, ammonium persulfate 0.5 weight portion, polymerizer 3.5 weight portions and anhydrous sodium sulfate 1.0 weight portions;
The D component is: butyl acrylate 207.0 weight portions, methacrylic acid 5.0 weight portions, vinylacetate 5.0 weight portions, terpene resin 5.0 weight portions and methyl methacrylate 3.0 weight portions, first terpene resin 5.0 weight portions are dissolved in the D component, and then mix with the C component that configures, to carry out pre-emulsification under the rotating speed of 400r/min 35 minutes, obtain milky even pre-emulsion;
2). bonding adhesive is synthetic:
In the four-hole boiling flask that agitator, thermometer, Liquid dropping bottle and temp auto-controlled water-bath are housed, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, begin to drip by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～85 ℃ of temperature, drip off with 150～180 minutes, continue to be incubated 120～150 minutes again; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive.
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the waterproof roll of self-adhesive layer can adopt following technique to realize: the material after preparing material advances people's reactor and adds thermal response, reacted material is the raw material of the first bitumen layer 3-1 and the second bitumen layer 3-2, flow directly into being coated with in the oil sump in the waterproof roll production line, with tire base 4 be the first bitumen layer 3-1 and the second bitumen layer 3-2 of 1000mm specification by two roller extrusion molding width, in the time of along with extrusion molding, the self-adhesive layer 5 that wide temperature becomes is protected in soffit roller cyclization at the first bitumen layer 3-1, the kraft 6 that surface that self-adhesive layer carries scribbles silicone oil below the self-adhesive layer 5, the upper surface of the second bitumen layer 3-2 is the faying surface plastic edge film 2 on roller unification aspect film 1 and facial mask 1 both sides simultaneously also, the first bitumen layer 3-1 common and extrusion molding is in the same place with the second bitumen layer 3-2 roll-in, the thickness of this first bitumen layer 3-1 and the second bitumen layer 3-2 is respectively 0.5,1.0,1.6,2.0mm can, the self-adhesive layer waterproof roll that the wide temperature of the environmental protection of moulding becomes is through rolling after cooling, cutting, packing, this is that those skilled in the art can be implemented.
The composition of raw materials of used modified bitumen and preparation method are as follows in the present embodiment:
The raw material that the bitumen layer used in above-described embodiment is used all is can practical petroleum bitumen in the waterproof roll of buying on the market; Add thermal response by adding SBS resin and powder stuffing or APP resin and powder stuffing or rubber powder and powder stuffing in petroleum bitumen and obtain the modified bitumen raw material; Wherein concrete modifying process is that whole raw materials are put into the material reaction still, under 160.0-200.0 ℃ of temperature stirring reaction 60-150 minute and get final product; The proportioning of present embodiment medium pitch is: petroleum bitumen 30.0-100.0 weight portion, modifier 2.0-20.0 weight portion, powder stuffing 10.0-50.0 weight portion and auxiliary agent 3.0-15.0 weight portion; Used pitch is 10# petroleum bitumen in the present embodiment, and modifier is SBS resin or APP resin or rubber powder, and auxiliary agent is aromatic naphtha, and powder stuffing is French chalk or light calcium powder or flyash, and this is that those skilled in the art can be implemented.
Embodiment 4
Referring to figs. 2 and 5, make of the present invention a kind of without tire, two surfaces become the waterproof roll of self-adhesive layer with the wide temperature of environmental protection.
The facial mask 1 of present embodiment, faying surface plastic edge film 2 adopt facial mask and the faying surface plastic edge coating materials of the waterproof roll use of buying on the market, and wherein, the width of facial mask 1 is 850mm, and the width of faying surface plastic edge film 2 is 100mm.
The first bitumen layer 3-1 and the second bitumen layer 3-2 adopt 90# petroleum bitumen or with add SBS or APP, rubber powder, calcium carbonate and talcous modified bitumen.The faying surface plastic edge film 2 that present embodiment uses is antiseized PET films that two surfaces bought on the market scribble silicone oil.The counterdie 6 of present embodiment is carried by self-adhesive layer, namely there is the wide temperature of the first environmental protection to become self-adhesive layer 5-1 at this counterdie 6, become self-adhesive layer 5-1 upper surface sequential applications the first bitumen layer 3-1 in the wide temperature of this first environmental protection, the wide temperature of the second environmental protection becomes self-adhesive layer 5-2 and facial mask 1, when but facial mask 1 applies at the wide temperature change of the second environmental protection self-adhesive layer 5-2, all be not coated with full, namely the dual-side on the wide temperature change of the second environmental protection self-adhesive layer 5-2 is respectively reserved the lay edges of 100mm width, this lay edges is overlap edge (overlap edge of reserving is partly without composite plastic facial mask 1), be used for compound faying surface plastic edge film 2 at this overlap edge, when application and construction, faying surface plastic edge film 2 is thrown off, good bond together with the wide temperature change compound overlapping overlap joint of self-adhesive layer 5-1 of the first environmental protection of soffit, form whole waterproofing course, the recombination site between faying surface plastic edge film 2 and the facial mask 1 as shown in Figure 5.
Wherein, the thickness of bitumen layer is 0.3,4.0mm or 5.0mm can; The thickness that the wide temperature of described environmental protection becomes self-adhesive layer 5 into 0.2,1.0mm, 1.5mm, 2.0mm, 2.3mm or 3.0mm be all passable.
The bonding adhesive that the self-adhesive layer 5-2 that the wide temperature change self-adhesive layer 5-1 of the first environmental protection and the wide temperature of the second environmental protection become in the present embodiment uses is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 90.0 weight portions;
The B component is: deionization 25.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.4 weight portion;
The C component is: deionized water 130.0 weight portions, potassium peroxydisulfate 0.5 weight portion, polymerizer 3.2 weight portions and anhydrous sodium sulfate 1.3 weight portions;
The D component is: butyl acrylate 157.0 weight portions, methacrylic acid 5.0 weight portions, vinylacetate 50.0 weight portions, esterase 3.0 weight portions and organosilicon 4.0 weight portions, first esterase 3.0 weight portions are dissolved in the D component, and then mix with the C component that configures, under the rotating speed of mixed solution with 400r/min, carry out pre-emulsification 40 minutes, and obtained milky even pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add by 20% of the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive;
Embodiment 5
With reference to Figure 4 and 5, make the self-adhesive layer waterproof roll that the wide temperature of environmental protection of the present invention becomes, this has the self-adhesive layer waterproof roll that becomes with the wide temperature of environmental protection of tire is as tire basic unit 4 by the non-woven polyester fabrics of buying on one deck market, the upper and lower surface of this tire basic unit 4 applies respectively the first bitumen layer 3-1 and second layer bitumen layer 3-2, the self-adhesive layer 5-1 that becomes in the wide temperature of another surface recombination first environmental protection of described the first bitumen layer 3-1, the counterdie 6 that scribbles silicone oil at the self-adhesive layer 5-1 soffit of the wide temperature change of this first environmental protection is combined with each other; Another upper surface of described second layer bitumen layer 3-2 is compounded with the self-adhesive layer 5-2 that the wide temperature of the second environmental protection becomes, and the compound facial mask 1 in another surperficial centre position of the self-adhesive layer 5-2 of the wide temperature change of this second environmental protection, the narrow 220mm of self-adhesive layer 5-2 that the wide temperature of this second environmental protection of the Width of facial mask 1 becomes, the overlap edge of the 110mm that the self-adhesive layer 5-2 both sides that the wide temperature of the second environmental protection becomes are reserved, and on this overlap edge compound faying surface plastic edge film 2, the width of the faying surface plastic edge film 2 of described dual-side is respectively 110mm.
Described the first bitumen layer 3-1 and the second bitumen layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with SBS resin and powder stuffing or with APP resin and powder stuffing or with the modified bitumen of rubber powder and powder stuffing modification, its thickness is respectively 0.5-3.0mm;
The thickness of the self-adhesive layer that the wide temperature of described environmental protection becomes is 0.2-2.0mm;
The bonding adhesive that the self-adhesive layer 5-2 that the wide temperature change self-adhesive layer 5-1 of the first environmental protection and the wide temperature of the second environmental protection become in the present embodiment uses is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 100.0 weight portions;
The B component is: deionization 32.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.2 weight portion;
The C component is: deionized water 115.0 weight portions, ammonium persulfate 0.5 weight portion, polymerizer 3.6 weight portions and anhydrous sodium sulfate 1.2 weight portions;
The D component is: butyl acrylate 180.0 weight portions, methacrylic acid 5.0 weight portions, alkali soap rosin liquid 4.0 weight portions; First alkali soap rosin liquid 4.0 weight portions are dissolved in the D component, and then mix with the C component that configures, under the rotating speed of mixed solution with 430r/min, carried out pre-emulsification 35 minutes, obtain milky even pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add by 25% of the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive.
Embodiment 6
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the self-adhesive layer waterproof roll is identical with embodiment 5 with product structure, and its difference is the glass fiber tire of described tire basic unit 4 for buying on the market;
Described the first bitumen layer 3-1 and the second bitumen layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with APP resin and powder stuffing or with the modified bitumen of SBS resin and powder stuffing modification, its thickness is 0.5-3.5mm;
The thickness that the wide temperature of described the first environmental protection becomes the self-adhesive layer 5-2 of self-adhesive layer 5-1 and the wide temperature change of the second environmental protection is 0.2-1.5mm;
The bonding adhesive that the self-adhesive layer 5-2 that the wide temperature change self-adhesive layer 5-1 of the first environmental protection and the wide temperature of the second environmental protection become in the present embodiment uses is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 123.0 weight portions;
The B component is: deionization 24.2 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.3 weight portion;
The C component is: deionized water 100.0 weight portions, ammonium persulfate 0.5 weight portion, polymerizer 3.3 weight portions and anhydrous sodium sulfate 1.0 weight portions;
The D component is: butyl acrylate 235.0 weight portions, methacrylic acid 5.0 weight portions, rosin fat 0.7 weight portion and methyl methacrylate 5.0 weight portions, first rosin fat 0.7 weight portion is dissolved in the D component, and then mix with the C component that configures, under the rotating speed of mixed solution with 480r/min, carry out pre-emulsification 36 minutes, and obtained milky even pre-emulsion;
2). bonding adhesive is synthetic:
In the four-hole boiling flask that agitator, thermometer, Liquid dropping bottle and temp auto-controlled water-bath are housed, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, begin to drip by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～85 ℃ of temperature, drip off with 150～180 minutes, continue to be incubated 120～150 minutes again; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive.
Embodiment 7
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the self-adhesive layer waterproof roll is identical with embodiment 1, and its difference is that the upper surface in described the first pitch or modified asphalt layer 3 also is compounded with the wide temperature change of one second environmental protection self-adhesive layer 5-2; The another side that the wide temperature of described the second environmental protection becomes self-adhesive layer 5-2 is the faying surface plastic edge film 2 of facial mask and its dual-side.
Described the first pitch or modified asphalt layer 3-1 and the second pitch or modified asphalt layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with APP resin and powder stuffing or with the modified bitumen of SBS resin and powder stuffing modification, its thickness is 0.5-3.5mm;
The thickness that the wide temperature of described environmental protection becomes self-adhesive layer is 0.2-1.5mm;
The bonding adhesive that the wide temperature change of the first environmental protection self-adhesive layer 5-1 uses in the present embodiment is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 97.0 weight portions;
The B component is: deionization 25.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.4 weight portion;
The C component is: deionized water 122.0 weight portions, potassium peroxydisulfate 0.5 weight portion, polymerizer 3.0 weight portions and anhydrous sodium sulfate 1.5 weight portions;
The D component is: butyl acrylate 100.0 weight portions, methacrylic acid 5.0 weight portions, vinylacetate 100.0 weight portions and terpene resin 11.0 weight portions, first terpene resin 11.0 weight portions are dissolved in the D component, and then mix with the C component that configures, under the rotating speed of mixed solution with 500r/min, carry out pre-emulsification 30 minutes, and obtained milky even pre-emulsion;
2). bonding adhesive is synthetic:
In the four-hole boiling flask that agitator, thermometer, Liquid dropping bottle and temp auto-controlled water-bath are housed, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, begin to drip by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～85 ℃ of temperature, drip off with 150～180 minutes, continue to be incubated 120～150 minutes again; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive;
Embodiment 8
The manufacturing process that the wide temperature of the environmental protection of present embodiment becomes the self-adhesive layer waterproof roll is identical with embodiment 2, and its difference is that the upper surface at described the first bitumen layer 3-2 also is compounded with the wide temperature change of one second environmental protection self-adhesive layer 5-2; The another side that the wide temperature of described the second environmental protection becomes self-adhesive layer 5-2 is the faying surface plastic edge film 2 of facial mask and its dual-side.
Described the first bitumen layer 3-1 and the second pitch or modified asphalt layer 3-2 are with petroleum bitumen that can be practical in the waterproof roll of buying on the market or with APP resin and powder stuffing or with the modified bitumen of SBS resin and powder stuffing modification, its thickness is 0.5-3.5mm;
The thickness that the wide temperature of described environmental protection becomes self-adhesive layer is 0.2-1.5mm;
The bonding adhesive that the self-adhesive layer 5-2 that the wide temperature change self-adhesive layer 5-1 of the first environmental protection and the wide temperature of the second environmental protection become in the present embodiment uses is made by following methods:
1) adhesive raw materials prescription
The A component is: deionized water 120.0 weight portions;
The B component is: deionization 10.0 weight portions, persulfuric acid are received 1.0 weight portions and polymerizer 0.5 weight portion;
The C component is: deionized water 118.0 weight portions, potassium peroxydisulfate 0.5 weight portion, polymerizer 3.0 weight portions and anhydrous sodium sulfate 1.0 weight portions;
The D component is: butyl acrylate 80.0 weight portions, methacrylic acid 5.0 weight portions, vinylacetate rosin fat 1.5 weight portions, 70.0 weight portions and organosilicon 2.0 weight portions, first vinylacetate rosin fat 1.5 weight portions are dissolved in the D component, and then mix with the C component that configures, under the rotating speed of mixed solution with 400r/min, carry out pre-emulsification 30 minutes, and obtained milky even pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add by 18% of the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, obtain milky aqueous adhesive;
In the preparation method of above-described embodiment 1-8, also comprise first C component and D component in the container of corresponding weight portion, to carry out under the rotating speed of 300-500r/min pre-emulsification 30-60 minute, are obtained the technique of milky even pre-emulsion; Namely in step 2) bonding adhesive synthetic in, it is just passable directly to drip the pre-emulsion that is obtained by step 1).
Certainly; the present invention also can have other various embodiments; in the situation that does not deviate from spirit of the present invention and essence thereof; those of ordinary skill in the art work as can make according to the present invention various corresponding changes and modification, but these corresponding changes and distortion all should belong to the protection domain of the appended claim of the present invention.
Claims (10)
1. the waterproof roll of a self-adhesive layer structural formula comprises facial mask (1), faying surface plastic edge film (2), the first bitumen layer (3-1) and counterdie (6); It is characterized in that, comprise that also the wide temperature of the first environmental protection becomes self-adhesive layer (5-1); The wide temperature of described the first environmental protection becomes the compound described counterdie of soffit (6) of self-adhesive layer (5-1), and the wide temperature of this first environmental protection becomes upper surface order compound described the first bitumen layer (3-1) and the described facial mask (1) of self-adhesive layer (5-1); Wherein, described the first bitumen layer of the Width of this facial mask (1) (3-1) is narrow, the dual-side of this first bitumen layer (3-1) leaves respectively a lay edges that is used for faying surface plastic edge film (2), described lay edges is overlap edge, and on described overlap edge compound described faying surface plastic edge film (2);
Described the first bitumen layer (3-1) is made for pitch, and its thickness is 0.3-5.0mm;
The thickness that the wide temperature of described the first environmental protection becomes self-adhesive layer (5-1) is 0.2-3.0mm; The bonding adhesive of the wide temperature change self-adhesive layer of this environmental protection (5-1) is prepared by following methods:
1) adhesive formulation
The A component is: deionized water 90.0-130.0 weight portion;
The B component is: deionized water 9.0-22.0 weight portion, sulfate 0.5-1.5 weight portion and polymerizer 0.1-1.0 weight portion mix;
The C component is: deionized water 98.0-128.5 weight portion, sulfate 0.2-5.0 weight portion and polymerizer 2.5-4.5 weight portion mix;
The D component is: acrylate 150.0-260.0 weight portion, methacrylic acid 3.0-10.0 weight portion, rosin fat 0.2-5.0 and organosilicon 2.0-5.0 weight portion mix; Or be
Acrylate 150.0-260.0 weight portion, acetate 8.0-120.0 weight portion, methyl methacrylate 3.0-10.0 weight portion, rosin fat 0.2-5.0 weight portion and organosilicon 2.0-5.0 weight portion mix;
Also comprise first rosin fat is dissolved in the D component, again with the C component in cell therefor, to carry out under 300-500 rev/min the rotating speed pre-emulsification 30-60 minute, obtain milky pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add the 10%-30% by the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, the wide temperature of environmental protection that obtains water-based becomes the bonding adhesive that self-adhesive layer is used.
2. by the waterproof roll of self-adhesive layer structural formula claimed in claim 1, it is characterized in that, comprise that also the wide temperature of the second environmental protection becomes self-adhesive layer (5-2); The wide temperature of two compound the first environmental protection of surface difference in described the first bitumen layer (3-1) becomes self-adhesive layer (5-1) and the wide temperature change of described environmental protection self-adhesive layer (5-2), at the compound described counterdie of soffit (6) of the wide temperature change self-adhesive layer of this first environmental protection (5-1), become self-adhesive layer (5-2) the compound described facial mask of upper surface (1) in the wide temperature of this second environmental protection; Wherein, it is narrow that the wide temperature of described the second environmental protection of the Width of this facial mask (1) becomes self-adhesive layer (5-2), the dual-side that becomes self-adhesive layer (5-2) in the wide temperature of the second environmental protection leaves respectively an overlap edge that is used for faying surface plastic edge film (2), and on described overlap edge compound described faying surface plastic edge film (2).
3. by the waterproof roll of self-adhesive layer structural formula claimed in claim 1, it is characterized in that, also comprise a tire basic unit (4) and the second bitumen layer (3-2); Apply respectively the first bitumen layer (3-1) and the second bitumen layer (3-2) on two surfaces of described tire basic unit (4), at the wide temperature change self-adhesive layer (5-1) of another surface compound described first environmental protection of order and the described counterdie (6) of the first bitumen layer (3-1); The described facial mask of another surface recombination (1) in the second bitumen layer (3-2), wherein, described the second bitumen layer of the Width of this facial mask (3-2) is narrow, leave respectively an overlap edge that is used for faying surface plastic edge film (2) at the dual-side of the second bitumen layer (3-2), and on described overlap edge compound described faying surface plastic edge film (2).
4. by the waterproof roll of self-adhesive layer structural formula claimed in claim 3, it is characterized in that, comprise that also the wide temperature of the second environmental protection becomes self-adhesive layer (5-2); Two surface difference compound the first bitumen layer (3-1) and the second bitumen layer (3-2) in described tire basic unit (4); The wide temperature of another compound the second environmental protection of surface order in this second bitumen layer (3-2) becomes self-adhesive layer (5-2) and described facial mask (1), wherein, it is narrow that the wide temperature of described the second environmental protection of the Width of this facial mask (1) becomes self-adhesive layer (5-2), the dual-side that becomes self-adhesive layer (5-2) in the wide temperature of the second environmental protection leaves respectively an overlap edge that is used for faying surface plastic edge film (2), and on described overlap edge compound described faying surface plastic edge film (2); The wide temperature of another compound the first environmental protection of surface order in this first bitumen layer (3-1) becomes self-adhesive layer (5-1), becomes the compound described counterdie of soffit (6) of self-adhesive layer (5-1) in the wide temperature of this first environmental protection.
5. by the waterproof roll of claim 2 or 4 described self-adhesive layer structural formulas, it is characterized in that the thickness that the wide temperature of described the second environmental protection becomes self-adhesive layer (5-2) is 0.2-3.0mm; The bonding adhesive of the wide temperature change self-adhesive layer of this second environmental protection (5-2) is prepared by following methods:
1) adhesive formulation
The A component is: deionized water 90.0-130.0 weight portion;
The B component is: deionized water 9.0-22.0 weight portion, sulfate 0.5-1.5 weight portion and polymerizer 0.1-1.0 weight portion mix;
The C component is: deionized water 98.0-128.5 weight portion, sulfate 0.2-5.0 weight portion and polymerizer 2.5-4.5 weight portion mix;
The D component is: acrylate 150.0-260.0 weight portion, methacrylic acid 3.0-10.0 weight portion, rosin fat 0.2-5.0 and organosilicon 2.0-5.0 weight portion mix; Or be:
Acrylate 150.0-260.0 weight portion, acetate 8.0-120.0 weight portion, methyl methacrylate 3.0-10.0 weight portion, rosin fat 0.2-5.0 weight portion and organosilicon 2.0-5.0 weight portion mix;
Also comprise first rosin fat is dissolved in the D component, again with the C component in cell therefor, to carry out under 300-500 rev/min the rotating speed pre-emulsification 30-60 minute, obtain milky pre-emulsion;
2). bonding adhesive is synthetic:
Agitator is being housed, thermometer, in the four-hole boiling flask of Liquid dropping bottle and temp auto-controlled water-bath, the material that adds the A component in the step 1) that weighs up, begin to heat up, pour the B component of step 1) when rising to 75-80 ℃ into, continue to heat, when temperature recovery to 80～85 ℃, add the 10%-30% by the pre-emulsion full dose of the C component of step 1) preparation and D component, continue again to heat, when temperature recovery to 80～85 ℃, drip remainingly by the C component of step 1) preparation and the pre-emulsion of D component, all components are under 75～90 ℃ of temperature, drip off with 120～150 minutes, continue again insulation 60～150 minutes; Then, be cooled to below 40 ℃, with ammonia neutralization pH value to 6～8, filter discharging with 100 eye mesh screens again, the wide temperature of environmental protection that obtains water-based becomes the bonding adhesive that self-adhesive layer is used.
6. by the waterproof roll of claim 1,2,3 or 4 described self-adhesive layer structural formulas, it is characterized in that described facial mask (1) is the kraft that PE antiadhesion barrier, aluminium foil film or single face that single face scribbles silicone oil scribble silicone oil.
7. by the waterproof roll of claim 1,2,3 or 4 described self-adhesive layer structural formulas, it is characterized in that described counterdie (6) is two-sided antiseized PE plastic foil or the antiseized kraft that scribbles silicone oil.
8. by the waterproof roll of self-adhesive layer structural formula claimed in claim 1, it is characterized in that described sulfate is anhydrous sodium sulfate, potassium peroxydisulfate or ammonium persulfate;
Described polymerizer is surfactant, and described surfactant is sodium lauryl sulfate, neopelex or OPEO;
Described acrylate is butyl acrylate or methyl methacrylate;
Described acetate is vinylacetate or butyl acetate;
Described organosilicon is vinyl front three ethylsiloxane, acrylic trimethoxy silane, octamethylcy-clotetrasiloxane or dimethyl cyclosiloxane.
9. by the waterproof roll of claim 3 or 4 described self-adhesive layer structural formulas, it is characterized in that the material of described tire basic unit is polyester blank or glass fiber blank or without tire.
10. by the waterproof roll of claim 1,2,3 or 4 described self-adhesive layer structural formulas, it is characterized in that the pitch in the described bitumen layer is petroleum bitumen; Add SBS, APP material, powder stuffing or auxiliary agent in the described petroleum bitumen;
Described faying surface plastic edge film (2) is the two-sided antiseized PET film that scribbles silicone oil, and the width of described faying surface limit film (2) is 50-150mm.
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| CN 201010272656 CN101914978B (en) | 2010-09-03 | 2010-09-03 | Water-proof coiled material with self-adhesive layer structure |
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| CN 201010272656 CN101914978B (en) | 2010-09-03 | 2010-09-03 | Water-proof coiled material with self-adhesive layer structure |
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| CN102729582A (en) * | 2011-04-01 | 2012-10-17 | 北京立高防水工程有限公司 | Production equipment of modified asphalt waterproofing membrane with/without substrate and with wide temperature shift self-adhesive layer |
| CN102924931A (en) * | 2011-08-08 | 2013-02-13 | 赵金叶 | Novel pavement crack pouring material |
| CN102559135A (en) * | 2012-02-09 | 2012-07-11 | 深圳市卓宝科技股份有限公司 | Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive |
| CN104150952B (en) * | 2014-06-20 | 2016-01-13 | 南京友西科技股份有限公司 | A kind of take sewer oil as concrete impermeability test sealing compound of preparation of raw material and preparation method thereof |
| CN105459538A (en) * | 2015-12-02 | 2016-04-06 | 上海优珀斯材料科技有限公司 | Moisture-proof and anti-adhesion film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100400612C (en) * | 2005-09-19 | 2008-07-09 | 北京高盟化工有限公司 | Prepn of water-base composite acrylic adhesive |
| CN101575475A (en) * | 2009-06-05 | 2009-11-11 | 陈伟忠 | Coating material for surface coating of waterproof membrane and preparation method thereof |
| CN101581137A (en) * | 2009-06-05 | 2009-11-18 | 陈伟忠 | Waterproof roll with multilayer structure |
| CN101597944A (en) * | 2009-07-07 | 2009-12-09 | 北京科顺建筑材料有限公司 | A kind of self-adhesive waterproof tile block for building |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0762807A (en) * | 1993-08-31 | 1995-03-07 | Takenaka Komuten Co Ltd | Waterproofing asphalt roofing |
| JPH0882050A (en) * | 1994-09-05 | 1996-03-26 | Tajima Roofing Co Ltd | Waterproof sheet and asphalt waterproof working method using the waterproof sheet |
-
2010
- 2010-09-03 CN CN 201010272656 patent/CN101914978B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100400612C (en) * | 2005-09-19 | 2008-07-09 | 北京高盟化工有限公司 | Prepn of water-base composite acrylic adhesive |
| CN101575475A (en) * | 2009-06-05 | 2009-11-11 | 陈伟忠 | Coating material for surface coating of waterproof membrane and preparation method thereof |
| CN101581137A (en) * | 2009-06-05 | 2009-11-18 | 陈伟忠 | Waterproof roll with multilayer structure |
| CN101597944A (en) * | 2009-07-07 | 2009-12-09 | 北京科顺建筑材料有限公司 | A kind of self-adhesive waterproof tile block for building |
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