CN108707718A - It is a kind of using high temperature coal gas of converter and to improve the device and its application method of calorific value - Google Patents

It is a kind of using high temperature coal gas of converter and to improve the device and its application method of calorific value Download PDF

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Publication number
CN108707718A
CN108707718A CN201810619486.5A CN201810619486A CN108707718A CN 108707718 A CN108707718 A CN 108707718A CN 201810619486 A CN201810619486 A CN 201810619486A CN 108707718 A CN108707718 A CN 108707718A
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China
Prior art keywords
charcoal
converter
gas
reactor
coal gas
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Pending
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CN201810619486.5A
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Chinese (zh)
Inventor
廖相巍
任伟
李金莲
王亮
韩子文
张立国
张伟
王再义
童晓宇
邓伟
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Angang Steel Co Ltd
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Angang Steel Co Ltd
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Priority to CN201810619486.5A priority Critical patent/CN108707718A/en
Publication of CN108707718A publication Critical patent/CN108707718A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/38Removal of waste gases or dust
    • C21C5/40Offtakes or separating apparatus for converter waste gases or dust
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C2100/00Exhaust gas
    • C21C2100/02Treatment of the exhaust gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The present invention relates to a kind of using high temperature coal gas of converter and improves the device of calorific value, including movable gas hood, fixed flue, charcoal damages reactor, watercooling elbow, dedusting slot, the movable gas hood is arranged in the top of converter, one end of fixed flue connects movable gas hood, the other end connects charcoal and damages reactor, the lower end of charcoal damage reactor is separately connected watercooling elbow, the lower section of watercooling elbow is equipped with dedusting slot, it is equipped with flue gas analyzer in the tail portion of watercooling elbow, it is not less than the coke of 10mm filled with lumpiness in charcoal damages reactor, machine presses charcoal, semicoke is one such or several, the upper and lower ends that reactor is damaged in charcoal are separately installed with valve.The method of the present invention is simple and practicable, reaction unit is damaged by the way that charcoal is arranged on the basis of original gasification cooling pipe, reaction is damaged by the charcoal largely to absorb heat, reduce high temperature coal gas of converter temperature, it is allowed to be reduced to 800-950 DEG C from 1500-1600 DEG C, Sync enrichment CO, is allowed to content and is increased to 80% or more from the 50-70% of coal gas of converter, is conducive to subsequent use.

Description

It is a kind of using high temperature coal gas of converter and to improve the device and its application method of calorific value
Technical field
The present invention relates to coal gas of steel-smelting revolving furnace to utilize technical field, is related specifically to a kind of using high-order coal gas of converter and carry The device and its application method of high calorific value of gas.
Background technology
When pneumatic steelmaking, 1500 DEG C of high-temperature flue gas of generation, through gasifying, cooling stack is cooled to 850 DEG C -- and 1000 DEG C are laggard Enter devaporizer.After rough dedusting, fine dedusting is carried out into electric precipitator.Traditional its work of Steam Dust now Principle is:The operation principle of devaporizer is to send water and gas by a certain percentage in converter coal gas dry-process purifying recovery system Into specific two-phase flow nozzle, it is injected directly into devaporizer after being atomized into fine steam-water mixing composition granule, and absorb heat The rapid evaporation of amount, makes high-temperature flue gas cool down rapidly, converter gas is dropped to 200 DEG C or so, while flue gas from 800 DEG C -1000 DEG C The dust of middle 20%-30% is condensed into larger particle and is deposited in ash bucket.
Authorization Notice No. CN101736116A discloses a kind of high temperature coal gas of converter discharged from converter and enters coal gas of converter After flue, in the way of breeze blowing, make the CO in coal gas2C+CO occurs with the coal dust of addition2The endothermic reaction of=2CO, makes Coal gas of converter temperature declines, and the mode that coal dust is added is to use nitrogen or richness CO2Exhaust gas is as injection gas to the side of breeze blowing Formula.Can be to the rapid effective cooling of coal gas of converter progress in flue using the invention, and recycle segment converter coal gas In CO2, while subsequent technique metallic conduit dusting can be prevented, low input, it is efficient simultaneously, reach energy-saving and environmental protection, subtract The purpose of row has greater significance.Authorization Notice No. CN103776272A disclose be the coal gas of high temperature that is discharged from converter first High temperature sensible heat utilization is carried out into high-temperature residual heat recovery system, via being transported to after high-temperature flue gas ceramic filter dust pelletizing system more than low temperature Heat recovery system carries out UTILIZATION OF VESIDUAL HEAT IN.Then, coal gas of converter is sent to CO2In absorption system, CO2It is absorbed and is obtained rich in CO2 Absorbing liquid, remove CO2It is enriched with CO in coal gas of converter afterwards, can be used for hot-blast stove waste heat sky as metallurgical important energy source after collection Gas, coke oven, station boiler and heater for rolling steel etc..The purification of both the above coal gas of converter, cooling, CO enrichments mode compared with Good solves the problems, such as that high temperature converter coal gas high-temperature, dust are more, CO concentration is low, and still, there is also some problems, such as spray coal Powder then needs N2Carrier gas is done, the purity for purifying rear converter coal gas is influenced, meanwhile, gas solid/liquid/gas reactions are too fierce, bring security risk, And use CO2Liquid enrichment CO is absorbed, very big influence, while the chemical reaction heat application effect of high temperature coal gas of converter can be brought on environmental protection Fruit will not be fine, for this purpose, the angle that we are enriched with higher than 1000 DEG C with flue gas from reaction temperature, proposes the side of built-in formed coke Formula come carry out converter fume cooling, CO enrichment processing mode.
Invention content
The object of the present invention is to provide a kind of using high temperature coal gas of converter and improves the device and its application method of calorific value, profit With the calorific value of high temperature coal gas of converter, the CO in coal gas of converter is consumed2, it is enriched with CO, improves coal gas of converter utilization ratio.
In order to achieve the above object, the present invention is realized using following technical scheme:
It is a kind of using high temperature coal gas of converter and to improve the device of calorific value, including movable gas hood, fixed flue, charcoal damage reaction Device, watercooling elbow, dedusting slot, the movable gas hood are arranged in the top of converter, and one end of fixed flue connects movable gas hood, separately One end connects charcoal and damages reactor, and the lower end of charcoal damage reactor is separately connected watercooling elbow, and the lower section of watercooling elbow is equipped with dedusting slot, It is equipped with flue gas analyzer in the tail portion of watercooling elbow, coke, machine pressure in charcoal damages reactor filled with lumpiness not less than 10mm Charcoal, semicoke are one such or several, and the upper and lower ends that reactor is damaged in charcoal are separately installed with valve.
The quantity of the charcoal damage reactor is no less than 1.
A kind of application method using high temperature coal gas of converter and the device that improves calorific value, the specific method is as follows:
1) the high temperature coal gas of converter generated from converter reaches charcoal by movable gas hood and fixed flue and damages reactor, and in charcoal It damages and charcoal damage reaction occurs in reactor, temperature is reduced to 950 DEG C -800 DEG C from 1500 DEG C -1600 DEG C, then water cooled elbow row Go out and carries out subsequent processes;
2) when handling high temperature coal gas of converter, the two charcoals damage reactor being set up in parallel only opens 1, the damage reaction of open charcoal Device upper part gas fume valve and lower part gas fume valve are in the open state, make coal gas of converter that charcoal damage reaction, another charcoal occur Damage reactor is in preparation or service mode, the gas fume valve of upper and lower ends are closed;
3) when preparing to close coal gas of converter processing system, it is first shut off lower part gas fume valve, turns off top gas fume valve, And when opening the set system, operation is opposite;Flue gas analyzer after positioned at watercooling elbow detects CO in flue gas2Concentration is more than When 2%, the charcoal closed in use damages reactor, is transformed into another charcoal damage reactor and works on.
Compared with prior art, the beneficial effects of the invention are as follows:
A kind of using high temperature coal gas of converter and to improve the device and its application method of calorific value, method is simple and practicable, by Charcoal is set on the basis of original gasification cooling pipe and damages reaction unit, reaction is damaged by the charcoal largely to absorb heat, reduces high temperature and turns Producer gas temperature, be allowed to be reduced to 800-950 DEG C from 1500-1600 DEG C, and Sync enrichment CO is allowed to content from coal gas of converter 50-70% is increased to 80% or more, is conducive to subsequent use.
Description of the drawings
Fig. 1 is the process diagram of the present invention.
In figure:1- converters, 2- movable gas hoods, 3- fix flue, 4- charcoals damage reactor, 5- watercooling elbows, the tops 6- flue gas Valve, the lower parts 7- gas fume valve, 8- coke, 9- dedustings slot, 10- flue gas analyzers.
Specific implementation mode
The specific implementation mode of the present invention is described further with reference to embodiment:
See Fig. 1, it is a kind of using high temperature coal gas of converter and to improve the device of calorific value, including movable gas hood 2, fixed flue 3, charcoal Reactor 4, watercooling elbow 5, dedusting slot 9 are damaged, the movable gas hood 2 is arranged in the top of converter 1, and one end of fixed flue 3 connects Movable gas hood 2 is connect, the other end connects charcoal and damages reactor 4, and the lower end of charcoal damage reactor 4 is separately connected watercooling elbow 5, watercooling elbow 5 lower section is equipped with dedusting slot 9, and flue gas analyzer 10 is equipped in the tail portion of watercooling elbow 5, and block is filled in charcoal damages reactor 4 Degree is one such or several not less than the coke of 10mm, machine pressure charcoal, semicoke, and the upper and lower ends that reactor 4 is damaged in charcoal are pacified respectively Equipped with valve.
The quantity of the charcoal damage reactor 4 is no less than 1.
Charcoal damages reactor 4, and when the flow velocity of coal gas of converter is 10m/s-20m/s, charcoal damage 4 length of reactor is not less than 10.3m is not higher than 15m;When the flow velocity of coal gas of converter is 5m/s-10m/s, charcoal damages 4 length of reactor and is not less than 5.2m, not high In 7.8m;When the flow velocity of coal gas of converter is less than 5m/s, charcoal damages 4 length of reactor and is not less than 3.1m, is not higher than 4m.
A kind of application method using high temperature coal gas of converter and the device that improves calorific value, the specific method is as follows:
1) the high temperature coal gas of converter generated from converter 1 reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, and In charcoal damage reaction occurs in charcoal damage reactor 4, temperature is reduced to 950 DEG C -800 DEG C from 1500 DEG C -1600 DEG C, then water cooled curved First 5 are discharged and carry out subsequent processes;
2) when handling high temperature coal gas of converter, two charcoals arranged side by side damage reactor 4 only opens 1, and open charcoal damages reactor 4 Upper part gas fume valve 6 and lower part gas fume valve 7 are in the open state, make coal gas of converter that charcoal damage reaction, another charcoal occur Damage reactor is in preparation or service mode, the gas fume valve of upper and lower ends are closed;
3) when preparing to close coal gas of converter processing system, it is first shut off lower part gas fume valve 7, turns off top gas fume valve 6, and when opening the set system, operation is opposite;Flue gas analyzer 10 after positioned at watercooling elbow 5 detects CO in flue gas2It is dense When degree is more than 2%, the charcoal closed in use damages reactor 4, is transformed into another charcoal damage reactor 4 and works on.
Embodiment 1:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 11.5m/s, and infrared measurement of temperature flue-gas temperature is 1552 DEG C, CO a concentration of 53% in converter gas, then in charcoal It damages and charcoal damage reaction occurs in reactor 4, which damages 4 long 11.2m of reactor, and 8 lumpiness of built-in coke is 40mm, and charcoal damages reactor 4 A diameter of 3m, temperature are reduced to 850 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.To exit flue gas into Row is analyzed, and CO concentration rises to 82%, CO in exiting flue gas2Concentration drops to 2.1%.
Embodiment 2:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 17m/s, and infrared measurement of temperature flue-gas temperature is 1583 DEG C, CO in converter gas2A concentration of 53%, then damaged in charcoal Charcoal damage reaction occurs in reactor 4, which damages 4 long 12m of reactor, and built-in coke, machine pressure charcoal average lumpiness are 53mm, and charcoal damage is anti- 4 a diameter of 2m of device, temperature is answered to be reduced to 912 DEG C, then water cooled elbow 5 is discharged and carries out subsequent dust removal process.To exit Flue gas is analyzed, and CO concentration rises to 81%, CO in exiting flue gas2Concentration drops to 3.2%.
Embodiment 3:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 20m/s, and infrared measurement of temperature flue-gas temperature is 1534 DEG C, then CO a concentration of 55% in converter gas is damaged in charcoal Charcoal damage reaction occurs in reactor 4, which damages the long 14m of reactor, and built-in semicoke average lumpiness is 44mm, and it is straight that charcoal damages reactor 4 Diameter is 5m, and temperature is reduced to 875 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.Exit flue gas is carried out It analyzes, CO concentration rises to 88%, CO in exiting flue gas2Concentration drops to 4.5%.
Embodiment 4:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 8m/s, and infrared measurement of temperature flue-gas temperature is 1562 DEG C, and CO a concentration of 50% in converter gas is then anti-in charcoal damage It answers and charcoal damage reaction occurs in device 4, which damages 4 long 6.3m of reactor, and 8 average lumpiness of built-in coke is 30mm, and it is straight that charcoal damages reactor 4 Diameter is 3m, and temperature is reduced to 833 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.Exit flue gas is carried out It analyzes, CO concentration rises to 86.5%, CO in exiting flue gas2Concentration drops to 1.2%.
Embodiment 5:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 6m/s, and infrared measurement of temperature flue-gas temperature is 1600 DEG C, and CO a concentration of 53% in converter gas is then anti-in charcoal damage It answers and charcoal damage reaction occurs in device 4, which damages 4 long 6.3m of reactor, and 8 average lumpiness of built-in coke is 15mm, and it is straight that charcoal damages reactor 4 Diameter is 3m, and temperature is reduced to 862 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.Exit flue gas is carried out It analyzes, CO concentration rises to 83.4%, CO in exiting flue gas2Concentration drops to 0.7%.
Embodiment 6:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor, initial converter coal The flow velocity of gas is 9m/s, and infrared measurement of temperature flue-gas temperature is 1528 DEG C, then CO a concentration of 52% in converter gas is damaged in charcoal and reacted Charcoal damage reaction occurs in device 4, which damages 4 long 7.3m of reactor, and 8 average lumpiness of built-in coke is 40mm, and charcoal damages 4 diameter of reactor For 3m, temperature is reduced to 902 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.Exit flue gas is divided It analyses, CO concentration rises to 84%, CO in exiting flue gas2Concentration drops to 3.2%.
Embodiment 7:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 3m/s, and infrared measurement of temperature flue-gas temperature is 1577 DEG C, and CO a concentration of 51% in converter gas is then anti-in charcoal damage It answers and charcoal damage reaction occurs in device 4, which damages 4 long 3.6m of reactor, and 8 average lumpiness of coke built in 4 is 40mm, and charcoal damages reactor 4 A diameter of 2m, temperature are reduced to 811 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.To exit flue gas into Row is analyzed, and CO concentration rises to 89.4%, CO in exiting flue gas2Concentration drops to 4.6%.
Embodiment 8:
The coal gas of converter generated from converter reaches charcoal by movable gas hood 2 and fixed flue 3 and damages reactor 4, initial converter The flow velocity of coal gas is 4.4m/s, and infrared measurement of temperature flue-gas temperature is 1590 DEG C, then CO a concentration of 52% in converter gas is damaged in charcoal Charcoal damage reaction occurs in reactor 4, which damages 4 long 3.8m of reactor, and 8 average lumpiness of built-in coke is 15mm, and charcoal damages reactor 4 A diameter of 2m, temperature are reduced to 837 DEG C, and then water cooled elbow 5 is discharged and carries out subsequent dust removal process.To exit flue gas into Row is analyzed, and CO concentration rises to 82.1%, CO in exiting flue gas2Concentration drops to 5.2%.
Comparative example:
The coal gas of converter generated from converter reaches outer smokejack by movable gas hood and fixed flue, initial coal gas of converter Flow velocity is 10.2m/s, and infrared measurement of temperature flue-gas temperature is 1583 DEG C, CO a concentration of 53% in converter gas, through cooling duct of gasifying Subsequent dust removal process is discharged and carried out with watercooling elbow, and flue-gas temperature is down to 920 DEG C.Exit flue gas is analyzed, is exported CO in flue gas2A concentration of 47%, CO a concentration of 19.8%.
Table 1:Embodiment parameters statistical form
It can be seen from the data in Table 1 that this set coal gas of converter processing unit is enriched CO, the CO in flue gas has been handled2, together When, the temperature of flue gas is also effectively reduced, subsequent dedusting is conducive to.

Claims (3)

  1. Using high temperature coal gas of converter and improve the device of calorific value 1. a kind of, which is characterized in that including movable gas hood, fixed flue, Charcoal damages reactor, watercooling elbow, dedusting slot, and the movable gas hood is arranged in the top of converter, and one end connection of fixed flue is lived Dynamic petticoat pipe, the other end connect charcoal and damage reactor, and the lower end of charcoal damage reactor is separately connected watercooling elbow, is set below watercooling elbow There is dedusting slot, flue gas analyzer is equipped in the tail portion of watercooling elbow, filled with lumpiness not less than 10mm's in charcoal damages reactor Coke, machine pressure charcoal, semicoke are one such or several, and the upper and lower ends that reactor is damaged in charcoal are separately installed with valve.
  2. A kind of using high temperature coal gas of converter and the device of calorific value is improved 2. according to claim 1, which is characterized in that described The quantity of charcoal damage reactor is no less than 1.
  3. 3. a kind of application method for the device for utilizing high temperature coal gas of converter as defined in claim 1 and improving calorific value, It is characterized in that, the specific method is as follows:
    1) the high temperature coal gas of converter generated from converter reaches charcoal by movable gas hood and fixed flue and damages reactor, and anti-in charcoal damage It answers and charcoal damage reaction occurs in device, temperature is reduced to 950 DEG C -800 DEG C from 1500 DEG C -1600 DEG C, and then water cooled elbow is discharged simultaneously Carry out subsequent processes;
    2) when handling high temperature coal gas of converter, two charcoals damage reactor of setting arranged side by side only opens 1, and open charcoal damages reactor Upper part gas fume valve and lower part gas fume valve are in the open state, make coal gas of converter that charcoal damage reaction, another charcoal damage occur Reactor is in preparation or service mode, the gas fume valve of upper and lower ends are closed;
    3) when preparing to close coal gas of converter processing system, it is first shut off lower part gas fume valve, turns off top gas fume valve, and beaten When opening the set system, operation is opposite;Flue gas analyzer after positioned at watercooling elbow detects CO in flue gas2Concentration is more than 2% When, the charcoal closed in use damages reactor, is transformed into another charcoal damage reactor and works on.
CN201810619486.5A 2018-06-14 2018-06-14 It is a kind of using high temperature coal gas of converter and to improve the device and its application method of calorific value Pending CN108707718A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109603334A (en) * 2019-01-16 2019-04-12 广西玉柴机器股份有限公司 A kind of high-temperature smoke dust removal method and device
CN109824476A (en) * 2019-03-26 2019-05-31 东北大学 A kind of association system and method for converter gas processing and methanol preparation
CN110129511A (en) * 2019-04-19 2019-08-16 首钢京唐钢铁联合有限责任公司 A method of improving RECOVERY OF CONVERTER GAS amount and calorific value

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55127127A (en) * 1979-03-22 1980-10-01 Nippon Steel Corp Recovery of waste gas in converter
CN102391892A (en) * 2011-09-21 2012-03-28 首钢总公司 Blast furnace gas enrichment apparatus and method
CN105779684A (en) * 2014-12-23 2016-07-20 鞍钢股份有限公司 Converter coal gas recycling system and recycling method thereof
CN105779683A (en) * 2014-12-23 2016-07-20 鞍钢股份有限公司 Recovery system and recovery method for converter gas

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55127127A (en) * 1979-03-22 1980-10-01 Nippon Steel Corp Recovery of waste gas in converter
CN102391892A (en) * 2011-09-21 2012-03-28 首钢总公司 Blast furnace gas enrichment apparatus and method
CN105779684A (en) * 2014-12-23 2016-07-20 鞍钢股份有限公司 Converter coal gas recycling system and recycling method thereof
CN105779683A (en) * 2014-12-23 2016-07-20 鞍钢股份有限公司 Recovery system and recovery method for converter gas

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109603334A (en) * 2019-01-16 2019-04-12 广西玉柴机器股份有限公司 A kind of high-temperature smoke dust removal method and device
CN109824476A (en) * 2019-03-26 2019-05-31 东北大学 A kind of association system and method for converter gas processing and methanol preparation
CN109824476B (en) * 2019-03-26 2020-08-28 东北大学 Combined device for converter flue gas treatment and methanol preparation and use method thereof
CN110129511A (en) * 2019-04-19 2019-08-16 首钢京唐钢铁联合有限责任公司 A method of improving RECOVERY OF CONVERTER GAS amount and calorific value

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