CN108659642A - A kind of mosquito-proof environment-friendly materials of anti-corrosion and preparation method thereof - Google Patents

A kind of mosquito-proof environment-friendly materials of anti-corrosion and preparation method thereof Download PDF

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CN108659642A
CN108659642A CN201810400677.2A CN201810400677A CN108659642A CN 108659642 A CN108659642 A CN 108659642A CN 201810400677 A CN201810400677 A CN 201810400677A CN 108659642 A CN108659642 A CN 108659642A
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parts
extracting solution
corrosion
mosquito
extract
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杨芳
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to environment-friendly materials technical fields, more particularly to mosquito-proof environment-friendly materials of a kind of anti-corrosion and preparation method thereof, mainly it is stirred and is made by raw materials such as 12 parts of 20 40 parts of alkoxy methyl acrylic resin, 10 15 parts of precipitated calcium carbonate, 10 20 parts of polyisocyanate, 5 10 parts of vinyltrimethoxysilane, 10 20 parts of acetone, 10 15 parts of anti-corrosion anophelifuge and other auxiliary agents;Anti-corrosion anophelifuge is mainly made of thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle extracting solution, the rich widely different raw materials such as extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, insect antibiotic property protein and boric acid that fall.The material film performance and good flowing properties, antiseptic property and mosquito-proof performance are very notable, effectively walk quickly and keep away and kill mosquito, and bactericidal and Insecticidal effect is notable, prolongs the service life, asepsis environment-protecting, and preparation method is simple, and production cost is low.

Description

A kind of mosquito-proof environment-friendly materials of anti-corrosion and preparation method thereof
Technical field
The present invention relates to environment-friendly materials technical fields, and in particular to a kind of mosquito-proof environment-friendly materials of anti-corrosion and preparation method thereof.
Background technology
Currently, interior wall for building is generally used paint spraying, paint finishing can be fine with basis material in body surface Complete and tough and tensile protective film is bonded and is formed, building coating has the function of that decoration functions, defencive function and livability are improved.Respectively Proportion shared by kind function is not quite similar because using purpose different.There are many mosquito in summer room, and burning mosquito-repellent incense kills mosquito Although there is certain effect, the chloride material in mosquito-repellent incense is very big to human injury, and cannot burn mosquito-repellent incense for a long time, and building coating is easy It is corroded in by extraneous bacterium, go mouldy, turn sour and other issues, production man adds for the mosquito-proof performance of the anti-corrosion for improving coating Add the chemical substance with anti-corrosion anti-mosquito function, not only cost improves, and pollutes the environment.And about utilizing plant extract Anti-corrosion anti-termite agent made of liquid and the mosquito-proof coating of anti-corrosion is made, but excessively do not paid close attention to and be widely used.
Invention content
The goal of the invention of the present invention is:In view of the above problems, provide a kind of mosquito-proof environment-friendly materials of anti-corrosion and its Preparation method, the material film performance and good flowing properties, antiseptic property and mosquito-proof performance are very notable, effectively walk quickly and keep away and kill Mosquito, bactericidal and Insecticidal effect is notable, prolongs the service life, asepsis environment-protecting, and preparation method is simple, and production cost is low.
To achieve the goals above, the technical solution adopted by the present invention is as follows:
A kind of mosquito-proof environment-friendly materials of anti-corrosion, are mainly made of following raw material:Alkoxy methyl acrylic resin 20- 40 parts, 10-15 parts of precipitated calcium carbonate, 10-20 parts of polyisocyanate, 5-10 parts of vinyltrimethoxysilane, acetone 10-20 Part, 10-15 parts of anti-corrosion anophelifuge, 1-3 parts of stabilizer, 1-2 parts of other auxiliary agents and 40-50 parts of water;
Wherein, the anti-corrosion anophelifuge is mainly made of following raw material:8-10 parts of thyme extracting solution, Salvia japonica It is 10-15 parts of extracting solution, 15-20 parts of Verbena officinalis extracting solution, 10-12 parts of freshwater mussel orchid extracting solution, 10-15 parts of flame nettle extracting solution, rich widely different Fall 15-20 parts of extracting solution, 10-20 parts of Folium Cephalotaxi extracting solution, 10-15 parts of gardenia extract, 10-20 parts of shikonin extract, Soviet Union 3-7 parts of wooden leaf extract 10-20 parts, 5-10 parts of insect antibiotic property protein and boric acid.
Preferably, it is mainly made of following raw material:30 parts of alkoxy methyl acrylic resin, precipitated calcium carbonate 13 Part, 15 parts of polyisocyanate, 7 parts of vinyltrimethoxysilane, 15 parts of acetone, 13 parts of anti-corrosion anophelifuge, 2 parts of stabilizer, its 45 parts of his 1.5 parts of auxiliary agent and water;
Wherein, the anti-corrosion anophelifuge is mainly made of following raw material:9 parts of thyme extracting solution, Salvia japonica carry It takes 13 parts of liquid, 17 parts of Verbena officinalis extracting solution, 11 parts of freshwater mussel orchid extracting solution, 13 parts of flame nettle extracting solution, rich widely different fall 17 parts of extracting solution, three 15 parts of sharp China fir leaf extract, 13 parts of gardenia extract, 15 parts of shikonin extract, 15 parts of bush leaf extract, insect antibiotic property egg 5 parts of 7 parts of white matter and boric acid.
Preferably, the preparation method of the anti-corrosion anophelifuge is:
S1:By thyme, Salvia japonica, Verbena officinalis, freshwater mussel orchid, flame nettle, it is rich it is widely different fall, Folium Cephalotaxi, cape jasmine, Asian puccoon and bush After leaf cleans and cleans up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification, Decoloration and ultrafiltration, respectively obtain thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle and carry Take liquid, it is rich it is widely different fall extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, and mix equal After even, mixed extract is obtained, it is spare;
S2:Insect antibiotic property protein and boric acid are added in above-mentioned mixed extract and are uniformly mixed, institute is made State anti-corrosion anophelifuge.
Preferably, other described auxiliary agents are by one or more in coalescents, antifoaming agent, thickener and high temperature resistant agent Composition.
Preferably, the stabilizer is made of one or more in fluorocarbons, potassium stearate and phosphorous vinegar.
The preparation method of the mosquito-proof environment-friendly materials of anti-corrosion as described above, specifically includes following steps:
(1) after mixing alkoxy methyl acrylic resin, acetone and water, 30- is stirred at being 40-60 DEG C in temperature 50min obtains mixed liquor A, spare;
(2) by precipitated calcium carbonate, polyisocyanate, vinyltrimethoxysilane, anti-corrosion anophelifuge, stabilizer and other After auxiliary agent mixing, ultrasonic disperse 20-30min obtains mixed liquid B, spare;
(3) after mixing mixed liquor A and mixed liquid B, 40-60min is stirred at being 40-60 DEG C in temperature, is made described anti- Rotten mosquito-proof environment-friendly materials.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
The material film performance and good flowing properties of the present invention, stability is excellent, and performance is stablized, and has good construction Performance, adhesion strength is high, and the anti-corrosion anophelifuge used is the plant extraction liquid extracted from plant, environment-protecting and non-poisonous, at low cost, prevents Rotten performance and mosquito-proof performance are very notable, effectively walk quickly and keep away and kill mosquito, and bactericidal and Insecticidal effect is notable, prolongs the service life, nothing Poison ring is protected, and preparation method is simple, and production cost is low.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is only A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art The every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases Any and all combinations of the Listed Items of pass.
Embodiment 1
A kind of mosquito-proof environment-friendly materials of anti-corrosion, are mainly made of following raw material:Alkoxy methyl acrylic resin 20 Part, 10 parts of precipitated calcium carbonate, 10 parts of polyisocyanate, 5 parts of vinyltrimethoxysilane, 10 parts of acetone, anti-corrosion anophelifuge 10 Part, 1 part of stabilizer, 1 part of other auxiliary agents and 40 parts of water;
Wherein, stabilizer is by fluorocarbons;Other auxiliary agents are made of coalescents and antifoaming agent;
Anti-corrosion anophelifuge is mainly made of following raw material:8 parts of thyme extracting solution, 10 parts of Salvia japonica extracting solution, 15 parts of Verbena officinalis extracting solution, 10 parts of freshwater mussel orchid extracting solution, 10 parts of flame nettle extracting solution, it is rich it is widely different fall 15 parts of extracting solution, Folium Cephalotaxi carries Take 10 parts of liquid, 10 parts of gardenia extract, 10 parts of shikonin extract, 10 parts of bush leaf extract, 5 parts of insect antibiotic property protein and 3 parts of boric acid;Preparation method is:
S1:By thyme, Salvia japonica, Verbena officinalis, freshwater mussel orchid, flame nettle, it is rich it is widely different fall, Folium Cephalotaxi, cape jasmine, Asian puccoon and bush After leaf cleans and cleans up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification, Decoloration and ultrafiltration, respectively obtain thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle and carry Take liquid, it is rich it is widely different fall extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, and mix equal After even, mixed extract is obtained, it is spare;
S2:Insect antibiotic property protein and boric acid are added in above-mentioned mixed extract and are uniformly mixed, institute is made State anti-corrosion anophelifuge.
The expectation of said ratio is prepared into the mosquito-proof environment-friendly materials of anti-corrosion using following methods, specifically includes following steps:
(1) after mixing alkoxy methyl acrylic resin, acetone and water, 30min is stirred at being 40 DEG C in temperature, is obtained Mixed liquor A, it is spare;
(2) by precipitated calcium carbonate, polyisocyanate, vinyltrimethoxysilane, anti-corrosion anophelifuge, stabilizer and other After auxiliary agent mixing, ultrasonic disperse 20min obtains mixed liquid B, spare;
(3) after mixing mixed liquor A and mixed liquid B, 40min is stirred at being 40 DEG C in temperature, it is mosquito-proof that the anti-corrosion is made Environment-friendly materials.
Embodiment 2
A kind of mosquito-proof environment-friendly materials of anti-corrosion, are mainly made of following raw material:Alkoxy methyl acrylic resin 30 Part, 13 parts of precipitated calcium carbonate, 15 parts of polyisocyanate, 7 parts of vinyltrimethoxysilane, 15 parts of acetone, anti-corrosion anophelifuge 13 Part, 2 parts of stabilizer, 1.5 parts of other auxiliary agents and 45 parts of water;
Wherein, stabilizer is made of potassium stearate and phosphorous vinegar;
Other auxiliary agents are made of coalescents, antifoaming agent and thickener;
Anti-corrosion anophelifuge is mainly made of following raw material:9 parts of thyme extracting solution, 13 parts of Salvia japonica extracting solution, 17 parts of Verbena officinalis extracting solution, 11 parts of freshwater mussel orchid extracting solution, 13 parts of flame nettle extracting solution, it is rich it is widely different fall 17 parts of extracting solution, Folium Cephalotaxi carries Take 15 parts of liquid, 13 parts of gardenia extract, 15 parts of shikonin extract, 15 parts of bush leaf extract, 7 parts of insect antibiotic property protein and 5 parts of boric acid;Preparation method is:
S1:By thyme, Salvia japonica, Verbena officinalis, freshwater mussel orchid, flame nettle, it is rich it is widely different fall, Folium Cephalotaxi, cape jasmine, Asian puccoon and bush After leaf cleans and cleans up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification, Decoloration and ultrafiltration, respectively obtain thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle and carry Take liquid, it is rich it is widely different fall extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, and mix equal After even, mixed extract is obtained, it is spare;
S2:Insect antibiotic property protein and boric acid are added in above-mentioned mixed extract and are uniformly mixed, institute is made State anti-corrosion anophelifuge.
The expectation of said ratio is prepared into the mosquito-proof environment-friendly materials of anti-corrosion using following methods, specifically includes following steps:
(1) after mixing alkoxy methyl acrylic resin, acetone and water, 40min is stirred at being 50 DEG C in temperature, is obtained Mixed liquor A, it is spare;
(2) by precipitated calcium carbonate, polyisocyanate, vinyltrimethoxysilane, anti-corrosion anophelifuge, stabilizer and other After auxiliary agent mixing, ultrasonic disperse 25min obtains mixed liquid B, spare;
(3) after mixing mixed liquor A and mixed liquid B, 50min is stirred at being 50 DEG C in temperature, it is mosquito-proof that the anti-corrosion is made Environment-friendly materials.
Embodiment 3
A kind of mosquito-proof environment-friendly materials of anti-corrosion, are mainly made of following raw material:Alkoxy methyl acrylic resin 40 Part, 15 parts of precipitated calcium carbonate, 20 parts of polyisocyanate, 10 parts of vinyltrimethoxysilane, 20 parts of acetone, anti-corrosion anophelifuge 15 Part, 3 parts of stabilizer, 2 parts of other auxiliary agents and 50 parts of water;
Wherein, stabilizer is made of fluorocarbons, potassium stearate and phosphorous vinegar;
Other auxiliary agents are made of coalescents, antifoaming agent, thickener and high temperature resistant agent;
Anti-corrosion anophelifuge is mainly made of following raw material:10 parts of thyme extracting solution, 15 parts of Salvia japonica extracting solution, 20 parts of Verbena officinalis extracting solution, 12 parts of freshwater mussel orchid extracting solution, 15 parts of flame nettle extracting solution, it is rich it is widely different fall 20 parts of extracting solution, Folium Cephalotaxi carries Take 20 parts of liquid, 15 parts of gardenia extract, 20 parts of shikonin extract, 20 parts of bush leaf extract, 10 parts of insect antibiotic property protein And 7 parts of boric acid;Preparation method is:
S1:By thyme, Salvia japonica, Verbena officinalis, freshwater mussel orchid, flame nettle, it is rich it is widely different fall, Folium Cephalotaxi, cape jasmine, Asian puccoon and bush After leaf cleans and cleans up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification, Decoloration and ultrafiltration, respectively obtain thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle and carry Take liquid, it is rich it is widely different fall extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, and mix equal After even, mixed extract is obtained, it is spare;
S2:Insect antibiotic property protein and boric acid are added in above-mentioned mixed extract and are uniformly mixed, institute is made State anti-corrosion anophelifuge.
The expectation of said ratio is prepared into the mosquito-proof environment-friendly materials of anti-corrosion using following methods, specifically includes following steps:
(1) after mixing alkoxy methyl acrylic resin, acetone and water, 50min is stirred at being 60 DEG C in temperature, is obtained Mixed liquor A, it is spare;
(2) by precipitated calcium carbonate, polyisocyanate, vinyltrimethoxysilane, anti-corrosion anophelifuge, stabilizer and other After auxiliary agent mixing, ultrasonic disperse 30min obtains mixed liquid B, spare;
(3) after mixing mixed liquor A and mixed liquid B, 60min is stirred at being 60 DEG C in temperature, it is mosquito-proof that the anti-corrosion is made Environment-friendly materials.
Applicant carried out contrast experiments once, and carry out correlated performance test, and test method is as follows:Selection 7 is identical Coating made from comparative example 1-5 and embodiment 1-3 is modified the experiment bin inner wall of 8 same sizes by the experiment bin of specification, It is put into identical mosquito populations, the mosquito populations after 2h in statistical experiment storehouse, and calculate mosquito and reduce percentage, it is detected after 2 years Coating goes bad corrosion condition, and calculates the corrosion percentage that goes bad, and the results are shown in Table 1.
Comparative example 1:Decorate common coating.
Comparative example 2:The raw material of decorative paint is alkoxy methyl acrylic resin, acetone, precipitated calcium carbonate, polyisocyanate Ester, vinyltrimethoxysilane, stabilizer, other auxiliary agents and water are other identical as the embodiment of the present invention 1.
Comparative example 3:The raw material of decorative paint is alkoxy methyl acrylic resin, acetone, precipitated calcium carbonate, polyisocyanate The raw material of ester, vinyltrimethoxysilane, stabilizer, anti-corrosion anophelifuge, other auxiliary agents and water, anti-corrosion anophelifuge is thyme Extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution and flame nettle extracting solution, it is other to implement with the present invention Example 1 is identical.
Comparative example 4:The raw material of decorative paint is novolac epoxy resin, polyvinylether, silicone oil, polyanion cellulose, double Cyclopentenyl oxygen ethylmethyl acrylate, dispersant, film forming agent, anophelifuge and water, the raw material of anophelifuge are rich widely different to fall extraction Liquid, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, others and 1 phase of the embodiment of the present invention Together.
Comparative example 5:The raw material of decorative paint is novolac epoxy resin, polyvinylether, silicone oil, polyanion cellulose, double The raw material of cyclopentenyl oxygen ethylmethyl acrylate, dispersant, film forming agent, anophelifuge and water, anophelifuge is insect antibiotic property Protein and boric acid are other identical as the embodiment of the present invention 1.
1 coating test result of table
Such as table 1 the results show that the rotten corrosion percentage of coating obtained by 1-3 of the embodiment of the present invention reduces, performance maintains Well, service life significantly extends, and mosquito reduces percentage and improves.Illustrate the present invention material have significant antiseptic property and Mosquito is effectively walked quickly and kept away and kill to mosquito-proof performance, and bactericidal and Insecticidal effect is notable, prolongs the service life, asepsis environment-protecting, and preparation method Simply, production cost is low.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to In the covered the scope of the claims of the present invention.

Claims (6)

1. a kind of mosquito-proof environment-friendly materials of anti-corrosion, which is characterized in that be mainly made of following raw material:Alkoxy methyl propylene 20-40 parts of acid resin, 10-15 parts of precipitated calcium carbonate, 10-20 parts of polyisocyanate, 5-10 parts of vinyltrimethoxysilane, third 40-50 parts of 10-20 parts of ketone, 10-15 parts of anti-corrosion anophelifuge, 1-3 parts of stabilizer, 1-2 parts of other auxiliary agents and water;
Wherein, the anti-corrosion anophelifuge is mainly made of following raw material:8-10 parts of thyme extracting solution, Salvia japonica extraction 10-15 parts of liquid, 15-20 parts of Verbena officinalis extracting solution, 10-12 parts of freshwater mussel orchid extracting solution, 10-15 parts of flame nettle extracting solution, rich widely different fall carry Take 15-20 parts of liquid, 10-20 parts of Folium Cephalotaxi extracting solution, 10-15 parts of gardenia extract, 10-20 parts of shikonin extract, bush leaf 3-7 parts of 10-20 parts of extracting solution, 5-10 parts of insect antibiotic property protein and boric acid.
2. the mosquito-proof environment-friendly materials of anti-corrosion according to claim 1, which is characterized in that mainly by following raw material system At:30 parts of alkoxy methyl acrylic resin, 13 parts of precipitated calcium carbonate, 15 parts of polyisocyanate, vinyltrimethoxysilane 7 Part, 15 parts of acetone, 13 parts of anti-corrosion anophelifuge, 2 parts of stabilizer, 1.5 parts of other auxiliary agents and 45 parts of water;
Wherein, the anti-corrosion anophelifuge is mainly made of following raw material:9 parts of thyme extracting solution, Salvia japonica extracting solution 13 parts, 17 parts of Verbena officinalis extracting solution, 11 parts of freshwater mussel orchid extracting solution, 13 parts of flame nettle extracting solution, rich widely different fall 17 parts of extracting solution, cepehalotaxus fortunei 15 parts of leaf extract, 13 parts of gardenia extract, 15 parts of shikonin extract, 15 parts of bush leaf extract, insect antibiotic property protein 7 5 parts of part and boric acid.
3. the mosquito-proof environment-friendly materials of anti-corrosion according to claim 1 or 2, which is characterized in that the preparation of the anti-corrosion anophelifuge Method is:
S1:By thyme, Salvia japonica, Verbena officinalis, freshwater mussel orchid, flame nettle, it is rich it is widely different fall, Folium Cephalotaxi, cape jasmine, Asian puccoon and bush leaf remove It is miscellaneous and after cleaning up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification, decoloration And ultrafiltration, respectively obtain thyme extracting solution, Salvia japonica extracting solution, Verbena officinalis extracting solution, freshwater mussel orchid extracting solution, flame nettle extraction Liquid, it is rich it is widely different fall extracting solution, Folium Cephalotaxi extracting solution, gardenia extract, shikonin extract, bush leaf extract, and be uniformly mixed Afterwards, mixed extract is obtained, it is spare;
S2:Insect antibiotic property protein and boric acid are added in above-mentioned mixed extract and are uniformly mixed, is made described anti- Rotten anophelifuge.
4. the mosquito-proof environment-friendly materials of anti-corrosion according to claim 1 or 2, it is characterised in that:Other described auxiliary agents are by forming a film One or more compositions in auxiliary agent, antifoaming agent, thickener and high temperature resistant agent.
5. the mosquito-proof environment-friendly materials of anti-corrosion according to claim 1 or 2, it is characterised in that:The stabilizer is carbonized by fluorine Close one or more compositions in object, potassium stearate and phosphorous vinegar.
6. the preparation method of the mosquito-proof environment-friendly materials of anti-corrosion according to any one of claims 1-5, which is characterized in that specific Include the following steps:
(1) after mixing alkoxy methyl acrylic resin, acetone and water, 30-50min is stirred at being 40-60 DEG C in temperature, is obtained It is spare to mixed liquor A;
(2) by precipitated calcium carbonate, polyisocyanate, vinyltrimethoxysilane, anti-corrosion anophelifuge, stabilizer and other auxiliary agents After mixing, ultrasonic disperse 20-30min obtains mixed liquid B, spare;
(3) after mixing mixed liquor A and mixed liquid B, 40-60min is stirred at being 40-60 DEG C in temperature, it is anti-that the anti-corrosion is made Mosquito environment-friendly materials.
CN201810400677.2A 2018-04-28 2018-04-28 A kind of mosquito-proof environment-friendly materials of anti-corrosion and preparation method thereof Pending CN108659642A (en)

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CN115197612A (en) * 2022-08-10 2022-10-18 中冶武汉冶金建筑研究院有限公司 Environment-friendly anti-mosquito coating for interior wall and preparation method thereof
CN116716045A (en) * 2023-08-04 2023-09-08 鑫鹏源(聊城)智能科技有限公司 Corrosion-resistant seamless line pipe and manufacturing method thereof

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