CN108893029A - A kind of mosquito-proof environment-friendly materials and preparation method thereof - Google Patents
A kind of mosquito-proof environment-friendly materials and preparation method thereof Download PDFInfo
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- CN108893029A CN108893029A CN201810400691.2A CN201810400691A CN108893029A CN 108893029 A CN108893029 A CN 108893029A CN 201810400691 A CN201810400691 A CN 201810400691A CN 108893029 A CN108893029 A CN 108893029A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to environment-friendly materials technical fields, more particularly to a kind of mosquito-proof environment-friendly materials and preparation method thereof, mainly it is made of formulated, stirring of the raw materials such as 20-30 parts of novolac epoxy resin, 5-10 parts of polyvinylether, 5-7 parts of silicone oil, 3-7 parts of polyanion cellulose, 1-3 parts of double cyclopentenyl oxygen ethylmethyl acrylate, 10-15 parts of anophelifuge, 5-7 parts of dispersing agent and 3-7 parts of film forming agent etc.；Anophelifuge mainly by 10-20 parts of Pelargonium roseum extracting solution, 15-25 parts of lantana extracting solution, touch careless extracting solution 10-15 parts, the raw materials such as 10-30 parts of Mozzie buster extracting solution and 15-20 parts of mosquitoes propagation extracting solution take through ultrasonic wave soldier, filter, clarify, decolourize and ultrafiltration is made.The material film performance and good flowing properties, mosquito-proof performance is significant, effectively walks quickly and keeps away and kill mosquito, and there are also certain bactericidal effects, prolongs the service life, asepsis environment-protecting, and preparation method is simple, and production cost is low.
Description
Technical field
The present invention relates to environment-friendly materials technical fields, and in particular to a kind of mosquito-proof environment-friendly materials and preparation method thereof.
Background technique
Currently, interior wall for building is generally used paint spraying, paint finishing can be fine with basis material in body surface
Complete and tough and tensile protective film is bonded and is formed, building coating has the function of that decoration functions, defencive function and livability are improved.Respectively
Specific gravity shared by kind function is not quite similar because using purpose different.There are many mosquito in summer room, and burning mosquito-repellent incense kills mosquito
Although there is certain effect, the chloride material in mosquito-repellent incense is very big to human injury, and cannot burn mosquito-repellent incense for a long time.Mosquito repellent coating at present
It is not used widely, and mosquito-proof coating in the market is largely the mosquito-proof chemical substance of addition, not only cost improves, and
It pollutes the environment.And about mosquito-proof coating is made using anophelifuge made of plant extraction liquid, it is not obtained but more
Concern.
Summary of the invention
Goal of the invention of the invention is：In view of the above problems, a kind of mosquito-proof environment-friendly materials and its preparation are provided
Method, the material film performance and good flowing properties, mosquito-proof performance is significant, effectively walks quickly and keeps away and kill mosquito, and there are also certain sterilizations
Effect, prolongs the service life, asepsis environment-protecting, and preparation method is simple, and production cost is low.
To achieve the goals above, the technical solution adopted by the present invention is as follows：
A kind of mosquito-proof environment-friendly materials, are mainly made of following raw material：20-30 parts of novolac epoxy resin, polyethylene
It is 5-10 parts of ether, 5-7 parts of silicone oil, 3-7 parts of polyanion cellulose, 1-3 parts of double cyclopentenyl oxygen ethylmethyl acrylate, mosquito-proof
10-15 parts of agent, 5-7 parts of dispersing agent, 3-7 parts of film forming agent and 30-50 parts of water；
Wherein, the anophelifuge is mainly made of following raw material：10-20 parts of Pelargonium roseum extracting solution, Ma Ying
Red extracting solution 15-25 parts, touch careless extracting solution 10-15 parts, 10-30 parts of Mozzie buster extracting solution, 15-20 parts of mosquitoes propagation extracting solution
And 10-15 parts of lemon extract.
Preferably, it is mainly made of following raw material：25 parts of novolac epoxy resin, 7 parts of polyvinylether, 6 parts of silicone oil,
5 parts of polyanion cellulose, 2 parts of double cyclopentenyl oxygen ethylmethyl acrylate, 13 parts of anophelifuge, 6 parts of dispersing agent, film forming agent
5 parts and 40 parts of water；
Wherein, the anophelifuge is mainly made of following raw material：15 parts of Pelargonium roseum extracting solution, lantana mention
It takes 20 parts of liquid, touch 13 parts of careless extracting solution, 20 parts of Mozzie buster extracting solution, 17 parts of mosquitoes propagation extracting solution and lemon extract 13
Part.
Preferably, the dispersing agent is by one of phosphate, LBD-1 dispersing agent and perfluorocarboxylic acid ammonium salt or a variety of mixed
It closes.
Preferably, the preparation method of the anophelifuge is：By Pelargonium roseum, lantana, to touch grass, Mozzie buster, mosquito net
After vanilla and lemon clean and clean up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and passes through high speed centrifugation mistake
Filter, clarification, decoloration and ultrafiltration, respectively obtain Pelargonium roseum extracting solution, lantana extracting solution, touch careless extracting solution, Mozzie buster
Extracting solution, mosquitoes propagation extracting solution and lemon extract, and after mixing by each extracting solution, obtain the anophelifuge.
The preparation method of mosquito-proof environment-friendly materials as described above, specifically includes following steps：
(1) after mixing by novolac epoxy resin, dispersing agent and water, 40-60min is stirred, mixed liquor A is obtained, it is spare；
(2) polyvinylether, silicone oil, polyanion cellulose and double cyclopentenyl oxygen ethylmethyl acrylate are added to
In the mixed liquor A, and ultrasonic disperse 30-40min, mixed liquid B is obtained, it is spare；
(3) anophelifuge and film forming agent are added in the mixed liquid B, stir 1-2h, the mosquito-proof environment-friendly materials is made.
Preferably, the temperature of stirring described in step (1) and step (3) is 80-100 DEG C, mixing speed 1500-
2000r/min。
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
Coating dispersion performance, film performance and good flowing properties of the invention have good workability, adhesion strength
Height, the anophelifuge used is the plant extraction liquid being extracted from plants, environment-protecting and non-poisonous, at low cost, has significant mosquito-proof performance,
Mosquito is effectively walked quickly and kept away and kills, effect is very significant, and there are also certain bactericidal effects, prolong the service life, asepsis environment-protecting, and it is made
Preparation Method is simple, and production cost is low.
Specific embodiment
Technical solution of the present invention will be clearly and completely described below, it is clear that described embodiment is only
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
Every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the listed item of pass.
Embodiment 1
A kind of mosquito-proof environment-friendly materials, are mainly made of following raw material：20 parts of novolac epoxy resin, polyvinylether 5
Part, 5 parts of silicone oil, 3 parts of polyanion cellulose, 1 part of double cyclopentenyl oxygen ethylmethyl acrylate, 10 parts of anophelifuge, dispersion
5 parts of agent, 3 parts of film forming agent and 30 parts of water；
Wherein, dispersing agent is phosphate；
Anophelifuge is mainly made of following raw material：10 parts of Pelargonium roseum extracting solution, 15 parts of lantana extracting solution,
Touch 10 parts of careless extracting solution, 10 parts of Mozzie buster extracting solution, mosquitoes propagation extracting solution 15 and 10 parts of lemon extract；
Preparation method is：By Pelargonium roseum, lantana, touch grass, Mozzie buster, mosquitoes propagation and lemon removal of impurities and it is clear
After wash clean, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and passes through high speed centrifugation, clarification, decoloration and ultrafiltration,
It respectively obtains Pelargonium roseum extracting solution, lantana extracting solution, touch careless extracting solution, Mozzie buster extracting solution, mosquitoes propagation extraction
Liquid and lemon extract, and after mixing by each extracting solution, obtain the anophelifuge.
The expectation of said ratio is prepared into mosquito-proof environment-friendly materials using following methods, specifically includes following steps：
It (1) after mixing by novolac epoxy resin, dispersing agent and water, is 80 DEG C in temperature, mixing speed 1500r/
40min is stirred under conditions of min, obtains mixed liquor A, it is spare；
(2) polyvinylether, silicone oil, polyanion cellulose and double cyclopentenyl oxygen ethylmethyl acrylate are added to
In the mixed liquor A, and ultrasonic disperse 30min, mixed liquid B is obtained, it is spare；
(3) anophelifuge and film forming agent are added in the mixed liquid B, they are 80 DEG C in temperature, mixing speed 1500r/
1h is stirred under conditions of min, and the mosquito-proof environment-friendly materials are made.
Embodiment 2
A kind of mosquito-proof environment-friendly materials, are mainly made of following raw material：25 parts of novolac epoxy resin, polyvinylether 7
Part, 6 parts of silicone oil, 5 parts of polyanion cellulose, 2 parts of double cyclopentenyl oxygen ethylmethyl acrylate, 13 parts of anophelifuge, dispersion
6 parts of agent, 5 parts of film forming agent and 40 parts of water；
Wherein, dispersing agent is mixed by LBD-1 dispersing agent and perfluorocarboxylic acid ammonium salt；
Anophelifuge is mainly made of following raw material：15 parts of Pelargonium roseum extracting solution, 20 parts of lantana extracting solution,
Touch 13 parts of careless extracting solution, 20 parts of Mozzie buster extracting solution, 17 parts of mosquitoes propagation extracting solution and 13 parts of lemon extract；
Preparation method is：By Pelargonium roseum, lantana, touch grass, Mozzie buster, mosquitoes propagation and lemon removal of impurities and it is clear
After wash clean, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and passes through high speed centrifugation, clarification, decoloration and ultrafiltration,
It respectively obtains Pelargonium roseum extracting solution, lantana extracting solution, touch careless extracting solution, Mozzie buster extracting solution, mosquitoes propagation extraction
Liquid and lemon extract, and after mixing by each extracting solution, obtain the anophelifuge.
The expectation of said ratio is prepared into mosquito-proof environment-friendly materials using following methods, specifically includes following steps：
It (1) after mixing by novolac epoxy resin, dispersing agent and water, is 90 DEG C in temperature, mixing speed 1700r/
50min is stirred under conditions of min, obtains mixed liquor A, it is spare；
(2) polyvinylether, silicone oil, polyanion cellulose and double cyclopentenyl oxygen ethylmethyl acrylate are added to
In the mixed liquor A, and ultrasonic disperse 35min, mixed liquid B is obtained, it is spare；
(3) anophelifuge and film forming agent are added in the mixed liquid B, they are 90 DEG C in temperature, mixing speed 1700r/
1.5h is stirred under conditions of min, and the mosquito-proof environment-friendly materials are made.
Embodiment 3
A kind of mosquito-proof environment-friendly materials, are mainly made of following raw material：30 parts of novolac epoxy resin, polyvinylether 10
Part, 7 parts of silicone oil, 7 parts of polyanion cellulose, 3 parts of double cyclopentenyl oxygen ethylmethyl acrylate, 15 parts of anophelifuge, dispersion
7 parts of agent, 7 parts of film forming agent and 50 parts of water；
Wherein, dispersing agent is mixed by phosphate, LBD-1 dispersing agent and perfluorocarboxylic acid ammonium salt；
Anophelifuge is mainly made of following raw material：20 parts of Pelargonium roseum extracting solution, 25 parts of lantana extracting solution,
Touch 15 parts of careless extracting solution, 30 parts of Mozzie buster extracting solution, 20 parts of mosquitoes propagation extracting solution and 15 parts of lemon extract；
Preparation method is：By Pelargonium roseum, lantana, touch grass, Mozzie buster, mosquitoes propagation and lemon removal of impurities and it is clear
After wash clean, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and passes through high speed centrifugation, clarification, decoloration and ultrafiltration,
It respectively obtains Pelargonium roseum extracting solution, lantana extracting solution, touch careless extracting solution, Mozzie buster extracting solution, mosquitoes propagation extraction
Liquid and lemon extract, and after mixing by each extracting solution, obtain the anophelifuge.
The expectation of said ratio is prepared into mosquito-proof environment-friendly materials using following methods, specifically includes following steps：
It (1) after mixing by novolac epoxy resin, dispersing agent and water, is 100 DEG C in temperature, mixing speed 2000r/
60min is stirred under conditions of min, obtains mixed liquor A, it is spare；
(2) polyvinylether, silicone oil, polyanion cellulose and double cyclopentenyl oxygen ethylmethyl acrylate are added to
In the mixed liquor A, and ultrasonic disperse 40min, mixed liquid B is obtained, it is spare；
(3) anophelifuge and film forming agent are added in the mixed liquid B, they are 100 DEG C in temperature, mixing speed 2000r/
2h is stirred under conditions of min, and the mosquito-proof environment-friendly materials are made.
Applicant carried out comparative experimentss once, and carry out correlated performance test, and test method is as follows：Selection 7 is identical
Coating made from comparative example 1-4 and embodiment 1-3 is modified the experiment bin inner wall of 7 same sizes by the experiment bin of specification,
Identical mosquito populations, the mosquito populations after 2h in statistical experiment storehouse are put into, and calculate mosquito to reduce percentage, as a result such as table 1
It is shown.
Comparative example 1：Decorate common coating.
Comparative example 2：The raw material of decorative paint is novolac epoxy resin, polyvinylether, silicone oil, polyanion cellulose, double
Cyclopentenyl oxygen ethylmethyl acrylate, dispersing agent, film forming agent and water are other identical as the embodiment of the present invention 1.
Comparative example 3：The raw material of decorative paint is novolac epoxy resin, polyvinylether, silicone oil, polyanion cellulose, double
Cyclopentenyl oxygen ethylmethyl acrylate, dispersing agent, film forming agent, anophelifuge and water, the raw material of anophelifuge are Pelargonium roseum
Extracting solution, lantana extracting solution touch careless extracting solution, other identical as the embodiment of the present invention 1.
Comparative example 4：The raw material of decorative paint is novolac epoxy resin, polyvinylether, silicone oil, polyanion cellulose, double
Cyclopentenyl oxygen ethylmethyl acrylate, dispersing agent, film forming agent, anophelifuge and water, the raw material of anophelifuge are Mozzie buster extraction
Liquid, mosquitoes propagation extracting solution and lemon extract are other identical as the embodiment of the present invention 1.
1 coating test result of table
| Group | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Mosquito reduces percentage % | 17.5 | 15.5 | 48.7 | 49.2 | 72.2 | 77.5 | 81.5 |
Such as table 1 the results show that material film performance and good flowing properties, anti-mosquito property obtained by 1-3 of the embodiment of the present invention
Mosquito effectively significantly can be walked quickly and kept away and kill, it is 3 times of comparative example 1 or so that mosquito, which reduces percentage, asepsis environment-protecting, and it is prepared
Method is simple, and production cost is low.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the patents of the present invention.
Claims (6)
1. a kind of mosquito-proof environment-friendly materials, which is characterized in that be mainly made of following raw material：Novolac epoxy resin 20-30
Part, 5-10 parts of polyvinylether, 5-7 parts of silicone oil, 3-7 parts of polyanion cellulose, double cyclopentenyl oxygen ethylmethyl acrylate
1-3 parts, 10-15 parts of anophelifuge, 5-7 parts of dispersing agent, 3-7 parts of film forming agent and 30-50 parts of water；
Wherein, the anophelifuge is mainly made of following raw material：10-20 parts of Pelargonium roseum extracting solution, lantana mention
It takes 15-25 parts of liquid, touch careless extracting solution 10-15 parts, 10-30 parts of Mozzie buster extracting solution, 15-20 parts of mosquitoes propagation extracting solution and lemon
10-15 parts of lemon extracting solution.
2. mosquito-proof environment-friendly materials according to claim 1, which is characterized in that be mainly made of following raw material：Phenol
25 parts of formaldehyde epoxy resin, 7 parts of polyvinylether, 6 parts of silicone oil, 5 parts of polyanion cellulose, double cyclopentenyl oxygen ethyl-methyl propylene
2 parts of acid esters, 13 parts of anophelifuge, 6 parts of dispersing agent, 5 parts of film forming agent and 40 parts of water；
Wherein, the anophelifuge is mainly made of following raw material：15 parts of Pelargonium roseum extracting solution, lantana extracting solution
20 parts, touch 13 parts of careless extracting solution, 20 parts of Mozzie buster extracting solution, 17 parts of mosquitoes propagation extracting solution and 13 parts of lemon extract.
3. mosquito-proof environment-friendly materials according to claim 1 or 2, it is characterised in that：The dispersing agent is by phosphate, LBD-
One of 1 dispersing agent and perfluorocarboxylic acid ammonium salt or a variety of mixing.
4. mosquito-proof environment-friendly materials according to claim 1 or 2, which is characterized in that the preparation method of the anophelifuge is：It will
Pelargonium roseum, lantana touch after grass, Mozzie buster, mosquitoes propagation and lemon clean and clean up, and carry out after rubbing respectively
Organic solvent ultrasonic wave soldier takes, and by high speed centrifugation, clarification, decoloration and ultrafiltration, respectively obtains Pelargonium roseum extraction
Liquid, lantana extracting solution touch careless extracting solution, Mozzie buster extracting solution, mosquitoes propagation extracting solution and lemon extract, and will respectively mention
It takes liquid after mixing, obtains the anophelifuge.
5. the preparation method of mosquito-proof environment-friendly materials described in any one of -4 according to claim 1, which is characterized in that specifically include
Following steps：
(1) after mixing by novolac epoxy resin, dispersing agent and water, 40-60min is stirred, mixed liquor A is obtained, it is spare；
(2) polyvinylether, silicone oil, polyanion cellulose and double cyclopentenyl oxygen ethylmethyl acrylate are added to described
In mixed liquor A, and ultrasonic disperse 30-40min, mixed liquid B is obtained, it is spare；
(3) anophelifuge and film forming agent are added in the mixed liquid B, stir 1-2h, the mosquito-proof environment-friendly materials is made.
6. the preparation method of mosquito-proof environment-friendly materials according to claim 5, it is characterised in that：In step (1) and step (3)
The temperature of the stirring is 80-100 DEG C, mixing speed 1500-2000r/min.
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| CN115197612A (en) * | 2022-08-10 | 2022-10-18 | 中冶武汉冶金建筑研究院有限公司 | Environment-friendly anti-mosquito coating for interior wall and preparation method thereof |
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Application publication date: 20181127 |