CN108659594A - A kind of waterproof automatically cleaning silicone resin coating and preparation method thereof - Google Patents
A kind of waterproof automatically cleaning silicone resin coating and preparation method thereof Download PDFInfo
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- CN108659594A CN108659594A CN201810486050.3A CN201810486050A CN108659594A CN 108659594 A CN108659594 A CN 108659594A CN 201810486050 A CN201810486050 A CN 201810486050A CN 108659594 A CN108659594 A CN 108659594A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of waterproof automatically cleaning silicone resin coatings, are made of the raw material of following parts by weight：20 30 parts of polymethyl-benzene base organic siliconresin, 15 18 parts of silicon fluoride, 57 parts of silane coupling agent, 27 parts of nano-titanium dioxide, 6 10 parts of palygorskite, 8 12 parts of carbon fiber, 8 12 parts of nano-calcium carbonate, 10 15 parts of kaolinite, 38 parts of carbon nanotube, 25 35 parts of softened water, 25 parts of thickener, 27 parts of dispersant, 26 parts of hydrophobing agent, 13 parts of coalescents, the present invention are good according to coating water-proof effect made from proportioning by polymethyl-benzene base organic siliconresin, silicon fluoride and silane coupling agent.It is self-cleaning that the nano-titanium dioxide of addition makes coating have effects that, while coordinating with palygorskite, carbon fiber, nano-calcium carbonate and kaolinite, and cured density is high, and surface flatness is high, so that the dust in air is not adhered on surface again, aesthetics is good.
Description
Technical field
The present invention relates to paint field, specifically a kind of waterproof automatically cleaning silicone resin coating and preparation method thereof.
Background technology
Coating is that one kind being coated on body surface and forms film under certain condition and play protection, decoration and specific
One class I liquid I of effect or fixed material, with the development of economy, coating obtains in industrial or agricultural, national defence, scientific research and people's lives
To being more and more widely used.With the development of industry, coating variety is increasing, and quality and performance are continuously improved, and apply material list
It is pure to play protection and meet requiring for people, especially in the daily life of the people, waterproof, it is moisture-proof also increasingly
It is concerned.
Water-repellent paint refers to a kind of coating that the film that coating is formed can prevent rainwater or underground water from leaking.Water-repellent paint
The waterproofing membrane formed after cured has certain extensibility, elastoplasticity, crack resistance, impermeability and weatherability, can play anti-
Water is prevented blending protective effect.Water-repellent paint has good thermal adaptability, easy to operate, for ease of maintenaince with maintenance.With the country
The use of the development of External building industry, water-repellent paint is more extensive.
Invention content
The purpose of the present invention is to provide a kind of waterproof automatically cleaning silicone resin coatings and preparation method thereof, in solution
State the problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
20-30 parts of resin, 15-18 parts of silicon fluoride, 5-7 parts of silane coupling agent, 2-7 parts of nano-titanium dioxide, 6-10 parts of palygorskite, carbon fiber
8-12 parts of dimension, 8-12 parts of nano-calcium carbonate, 10-15 parts of kaolinite, 3-8 parts of carbon nanotube, 25-35 parts of softened water, thickener 2-5
Part, 2-7 parts of dispersant, 2-6 parts of hydrophobing agent, 1-3 parts of coalescents.
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
20 parts of resin, 15 parts of silicon fluoride, 5 parts of silane coupling agent, 2 parts of nano-titanium dioxide, 6 parts of palygorskite, 8 parts of carbon fiber, nano-sized carbon
8 parts of sour calcium, 10 parts of kaolinite, 3 parts of carbon nanotube, 25 parts of softened water, 2 parts of thickener, 2 parts of dispersant, 2 parts of hydrophobing agent, film forming
1 part of auxiliary agent.
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
30 parts of resin, 18 parts of silicon fluoride, 7 parts of silane coupling agent, 7 parts of nano-titanium dioxide, 10 parts of palygorskite, carbon fiber 12 part, nanometer
12 parts of calcium carbonate, 15 parts of kaolinite, 8 parts of carbon nanotube, 35 parts of softened water, 5 parts of thickener, 7 parts of dispersant, 6 parts of hydrophobing agent, at
3 parts of film auxiliary agent.
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
25 parts of resin, 16 parts of silicon fluoride, 6 parts of silane coupling agent, 4.5 parts of nano-titanium dioxide, 8 parts of palygorskite, carbon fiber 10 part, nanometer
10 parts of calcium carbonate, 13 parts of kaolinite, 5.5 parts of carbon nanotube, 30 parts of softened water, 3.5 parts of thickener, 5 parts of dispersant, hydrophobing agent 4
Part, 2 parts of coalescents.
Preferably, the palygorskite and kaolinic granularity are 500-100 mesh.
Preferably, the dispersant presses 2 by EDTA zinc and dodecafluoroheptyl methacrylate:1 mass ratio mixes.
Preferably, the coalescents are propylene glycol monomethyl ether amyl acetate.
Preferably, the hydrophobing agent is the more alkoxy ether copolymers of polysiloxanes-or organic siliconresin.
The waterproof automatically cleaning silicone resin coating, is prepared using following steps：
(1) it presses the weight proportion and measures each raw material, softened water, polymethyl-benzene Ji Youjiguishu are added in the ball mill
Fat carries out first time ball milling with 150r/min speed, and slurry is made；
(2) silicon fluoride, silane coupling agent, nano-titanium dioxide, palygorskite, carbon fiber, nano-calcium carbonate, kaolinite is added
Stone, carbon nanotube, dispersant, hydrophobing agent, coalescents keep it mixed with 400r/min high speeds ball milling 12 hours and fully dispersed
It closes uniform；
(3) thickener is added, with 50r/min stirring at low speed 4 hours, is sieved and is thickened obtained.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is applied by the way that polymethyl-benzene base organic siliconresin, silicon fluoride and silane coupling agent are obtained according to a certain ratio
The water contact angle of material can reach 120.35 °, good water-proof effect.The nano-titanium dioxide of addition has uvioresistant, antibacterial, self-cleaning
Only, anti-aging effect, thus coating have effects that it is self-cleaning, while with palygorskite, carbon fiber, nano-calcium carbonate and kaolinite
Cooperation, cured density is high, and surface flatness is high, so that the dust in air is not adhered on surface again, aesthetics is good.The present invention
Silicone resin coating, it is non-toxic and tasteless, construction and construction after film coated surface not will produce penetrating odor, do not have to the body of people
There is any influence, it is green safe；And preparation method is simple, has good elasticity, flexibility, water resistance and water proofing property.
Specific implementation mode
Embodiment 1
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
20 parts of resin, 15 parts of silicon fluoride, 5 parts of silane coupling agent, 2 parts of nano-titanium dioxide, 6 parts of palygorskite, 8 parts of carbon fiber, nano-sized carbon
8 parts of sour calcium, 10 parts of kaolinite, 3 parts of carbon nanotube, 25 parts of softened water, 2 parts of thickener, 2 parts of dispersant, 2 parts of hydrophobing agent, film forming
1 part of auxiliary agent.
The palygorskite and kaolinic granularity are 500-100 mesh.
The dispersant presses 2 by EDTA zinc and dodecafluoroheptyl methacrylate:1 mass ratio mixes.
The coalescents are propylene glycol monomethyl ether amyl acetate.
The hydrophobing agent is the more alkoxy ether copolymers of polysiloxanes-or organic siliconresin.
The waterproof automatically cleaning silicone resin coating, is prepared using following steps：
(1) it presses the weight proportion and measures each raw material, softened water, polymethyl-benzene Ji Youjiguishu are added in the ball mill
Fat carries out first time ball milling with 150r/min speed, and slurry is made；
(2) silicon fluoride, silane coupling agent, nano-titanium dioxide, palygorskite, carbon fiber, nano-calcium carbonate, kaolinite is added
Stone, carbon nanotube, dispersant, hydrophobing agent, coalescents keep it mixed with 400r/min high speeds ball milling 12 hours and fully dispersed
It closes uniform；
(3) thickener is added, with 50r/min stirring at low speed 4 hours, is sieved and is thickened obtained.
Embodiment 2
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
30 parts of resin, 18 parts of silicon fluoride, 7 parts of silane coupling agent, 7 parts of nano-titanium dioxide, 10 parts of palygorskite, carbon fiber 12 part, nanometer
12 parts of calcium carbonate, 15 parts of kaolinite, 8 parts of carbon nanotube, 35 parts of softened water, 5 parts of thickener, 7 parts of dispersant, 6 parts of hydrophobing agent, at
3 parts of film auxiliary agent.
The palygorskite and kaolinic granularity are 500-100 mesh.
The dispersant presses 2 by EDTA zinc and dodecafluoroheptyl methacrylate:1 mass ratio mixes.
The coalescents are propylene glycol monomethyl ether amyl acetate.
The hydrophobing agent is the more alkoxy ether copolymers of polysiloxanes-or organic siliconresin.
The waterproof automatically cleaning silicone resin coating, is prepared using following steps：
(1) it presses the weight proportion and measures each raw material, softened water, polymethyl-benzene Ji Youjiguishu are added in the ball mill
Fat carries out first time ball milling with 150r/min speed, and slurry is made；
(2) silicon fluoride, silane coupling agent, nano-titanium dioxide, palygorskite, carbon fiber, nano-calcium carbonate, kaolinite is added
Stone, carbon nanotube, dispersant, hydrophobing agent, coalescents keep it mixed with 400r/min high speeds ball milling 12 hours and fully dispersed
It closes uniform；
(3) thickener is added, with 50r/min stirring at low speed 4 hours, is sieved and is thickened obtained.
Embodiment 3
A kind of waterproof automatically cleaning silicone resin coating, is made of the raw material of following parts by weight：Polymethyl-benzene base organosilicon
25 parts of resin, 16 parts of silicon fluoride, 6 parts of silane coupling agent, 4.5 parts of nano-titanium dioxide, 8 parts of palygorskite, carbon fiber 10 part, nanometer
10 parts of calcium carbonate, 13 parts of kaolinite, 5.5 parts of carbon nanotube, 30 parts of softened water, 3.5 parts of thickener, 5 parts of dispersant, hydrophobing agent 4
Part, 2 parts of coalescents.
The palygorskite and kaolinic granularity are 500-100 mesh.
The dispersant presses 2 by EDTA zinc and dodecafluoroheptyl methacrylate:1 mass ratio mixes.
The coalescents are propylene glycol monomethyl ether amyl acetate.
The hydrophobing agent is the more alkoxy ether copolymers of polysiloxanes-or organic siliconresin.
The waterproof automatically cleaning silicone resin coating, is prepared using following steps：
(1) it presses the weight proportion and measures each raw material, softened water, polymethyl-benzene Ji Youjiguishu are added in the ball mill
Fat carries out first time ball milling with 150r/min speed, and slurry is made；
(2) silicon fluoride, silane coupling agent, nano-titanium dioxide, palygorskite, carbon fiber, nano-calcium carbonate, kaolinite is added
Stone, carbon nanotube, dispersant, hydrophobing agent, coalescents keep it mixed with 400r/min high speeds ball milling 12 hours and fully dispersed
It closes uniform；
(3) thickener is added, with 50r/min stirring at low speed 4 hours, is sieved and is thickened obtained.
Claims (9)
1. a kind of waterproof automatically cleaning silicone resin coating, which is characterized in that be made of the raw material of following parts by weight：Polymethyl-benzene
20-30 parts of base organic siliconresin, 15-18 parts of silicon fluoride, 5-7 parts of silane coupling agent, 2-7 parts of nano-titanium dioxide, palygorskite 6-
10 parts, 8-12 parts of carbon fiber, 8-12 parts of nano-calcium carbonate, 10-15 parts of kaolinite, 3-8 parts of carbon nanotube, 25-35 parts of softened water,
2-5 parts of thickener, 2-7 parts of dispersant, 2-6 parts of hydrophobing agent, 1-3 parts of coalescents.
2. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that by the original of following parts by weight
Material is made：20 parts of polymethyl-benzene base organic siliconresin, 15 parts of silicon fluoride, 5 parts of silane coupling agent, 2 parts of nano-titanium dioxide, slope thread
6 parts of stone, 8 parts of carbon fiber, 8 parts of nano-calcium carbonate, 10 parts of kaolinite, 3 parts of carbon nanotube, 25 parts of softened water, thickener 2 part, point
2 parts of powder, 2 parts of hydrophobing agent, 1 part of coalescents.
3. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that by the original of following parts by weight
Material is made：30 parts of polymethyl-benzene base organic siliconresin, 18 parts of silicon fluoride, 7 parts of silane coupling agent, 7 parts of nano-titanium dioxide, slope thread
10 parts of stone, 12 parts of carbon fiber, 12 parts of nano-calcium carbonate, 15 parts of kaolinite, 8 parts of carbon nanotube, 35 parts of softened water, 5 parts of thickener,
7 parts of dispersant, 6 parts of hydrophobing agent, 3 parts of coalescents.
4. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that by the original of following parts by weight
Material is made：25 parts of polymethyl-benzene base organic siliconresin, 16 parts of silicon fluoride, 6 parts of silane coupling agent, 4.5 parts of nano-titanium dioxide, slope
8 parts of thread stone, 10 parts of carbon fiber, 10 parts of nano-calcium carbonate, 13 parts of kaolinite, 5.5 parts of carbon nanotube, 30 parts of softened water, thickener
3.5 parts, 5 parts of dispersant, 4 parts of hydrophobing agent, 2 parts of coalescents.
5. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that the palygorskite and kaolinite
The granularity of stone is 500-100 mesh.
6. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that the dispersant is by EDTA
Zinc and dodecafluoroheptyl methacrylate press 2:1 mass ratio mixes.
7. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that the coalescents are third
Glycol methyl ether amyl acetate.
8. waterproof automatically cleaning silicone resin coating according to claim 1, which is characterized in that the hydrophobing agent is poly- silicon
Oxygen alkane-more alkoxies ether copolymer or organic siliconresin.
9. a kind of preparation method of waterproof automatically cleaning silicone resin coating, which is characterized in that include the following steps：
(1) it presses the weight proportion and measures each raw material, softened water, polymethyl-benzene base organic siliconresin are added in the ball mill, with
150r/mi n speed carries out first time ball milling, and slurry is made；
(2) silicon fluoride, silane coupling agent, nano-titanium dioxide, palygorskite, carbon fiber, nano-calcium carbonate, kaolinite, carbon is added
Nanotube, dispersant, hydrophobing agent, coalescents keep its mixing equal with 400r/mi n high speeds ball milling 12 hours and fully dispersed
It is even；
(3) thickener is added, with 50r/mi n stirring at low speed 4 hours, is sieved and is thickened obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810486050.3A CN108659594A (en) | 2018-05-21 | 2018-05-21 | A kind of waterproof automatically cleaning silicone resin coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810486050.3A CN108659594A (en) | 2018-05-21 | 2018-05-21 | A kind of waterproof automatically cleaning silicone resin coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN108659594A true CN108659594A (en) | 2018-10-16 |
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| CN201810486050.3A Withdrawn CN108659594A (en) | 2018-05-21 | 2018-05-21 | A kind of waterproof automatically cleaning silicone resin coating and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229369A (en) * | 2019-06-11 | 2019-09-13 | 义乌海源塑料制品有限公司 | A kind of antistatic PVC laminated film of hydrophobic oleophobic and preparation method thereof |
| CN110951394A (en) * | 2019-12-10 | 2020-04-03 | 江西高鑫电瓷电器有限公司 | Anti-icing insulator coating and preparation method thereof |
| CN113904044A (en) * | 2021-09-30 | 2022-01-07 | 珠海冠宇电池股份有限公司 | Battery and electronic device |
| CN114806400A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Waterproof protective material for deep well and preparation method thereof |
| CN116120835A (en) * | 2023-02-23 | 2023-05-16 | 广西南宁维一防腐科技有限公司 | Wall coating and preparation method thereof |
-
2018
- 2018-05-21 CN CN201810486050.3A patent/CN108659594A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229369A (en) * | 2019-06-11 | 2019-09-13 | 义乌海源塑料制品有限公司 | A kind of antistatic PVC laminated film of hydrophobic oleophobic and preparation method thereof |
| CN110951394A (en) * | 2019-12-10 | 2020-04-03 | 江西高鑫电瓷电器有限公司 | Anti-icing insulator coating and preparation method thereof |
| CN113904044A (en) * | 2021-09-30 | 2022-01-07 | 珠海冠宇电池股份有限公司 | Battery and electronic device |
| CN114806400A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Waterproof protective material for deep well and preparation method thereof |
| CN116120835A (en) * | 2023-02-23 | 2023-05-16 | 广西南宁维一防腐科技有限公司 | Wall coating and preparation method thereof |
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Application publication date: 20181016 |
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