CN108642336B - Extrusion casting aluminum alloy material and preparation method thereof - Google Patents

Extrusion casting aluminum alloy material and preparation method thereof Download PDF

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CN108642336B
CN108642336B CN201810662365.9A CN201810662365A CN108642336B CN 108642336 B CN108642336 B CN 108642336B CN 201810662365 A CN201810662365 A CN 201810662365A CN 108642336 B CN108642336 B CN 108642336B
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CN108642336A (en
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王渠东
汤华平
雷川
丁文江
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Shanghai Jiaotong University
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/03—Making non-ferrous alloys by melting using master alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

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Abstract

The invention belongs to the technical field of metal materials, and particularly relates to an extrusion casting aluminum alloy material and a preparation method thereof, wherein the extrusion casting aluminum alloy material comprises the following elements in percentage by mass: 2.5-6.0%, Zn: 3.0-6.0%, Cu: 0.5-2.0%, rare earth element RE: 0.01 to 1.5%, Ti: 0.00005% -0.2%, B: 0.00001% -0.1%, Sr: 0-0.2%, Zr: 0-0.2%, the balance of Al, and less than or equal to 0.45% of impurities; the rare earth element is one or a combination of more of Ce, Y, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu. The aluminum alloy material has excellent room-temperature comprehensive mechanical property and good casting property.

Description

Extrusion casting aluminum alloy material and preparation method thereof
Technical Field
The invention belongs to the technical field of metal materials, and particularly relates to an extrusion casting aluminum alloy material and a preparation method thereof.
Background
As a traditional metal material, the cast aluminum alloy is widely applied to the fields of automobiles, aerospace and the like due to the characteristics of small density, high specific strength and the like. The cast aluminum alloy is mainly of Al-Si series, such as A356, and has the defects of low strength and low plasticity. With the development of modern industry, the demand of high-performance cast aluminum alloy is larger and larger, but the high-strength and high-toughness cast aluminum alloy in the prior art has the problems of poor castability and low mechanical property.
Chinese patent CN105603274A discloses a gravity cast high-strength high-toughness corrosion-resistant cast aluminum alloy, which comprises the following alloy components in percentage by mass: 13-15%, Zn: 3.35-4.97%, Cu: 0.8 to 1.3%, Si: 0.25-0.45%, Zr: 0.05-0.1%, Sb: 0.03-0.05%, Co: 0.01-0.03%, Mo: 0.02-0.03%, master alloy: 5.5-1.2% and the balance of Al. The yield strength at room temperature of the alloy is more than or equal to 245MPa, the tensile strength is more than or equal to 388MPa, and the elongation is more than or equal to 7.5 percent. However, the high levels of alloying elements in the cast alloy, particularly magnesium, result in poor castability of the alloy, with mold preheat temperatures as high as 320 ℃.
Chinese patent CN105154729A discloses a cast Al-Zn-Mg-Cu-Ta alloy, which comprises the following alloy components in percentage by mass: 1.5-3%, Zn: 6-10%, Cu: 1.5-2.5%, Ta: 0.02-0.51%, cerium-rich mischmetal: 0.0004-0.0102%, and the balance of Al. The tensile strength of the alloy is 287-479 MPa at room temperature. Compared with cast Al-Si alloy, the mechanical property of the alloy is obviously improved, but the tensile strength of the alloy is greatly fluctuated, and the reliability of the strength is to be improved.
Disclosure of Invention
The invention aims to provide an extrusion casting aluminum alloy material which has excellent mechanical property and casting property and widens the application field of the aluminum alloy material.
The invention also aims to provide a preparation method of the extrusion casting aluminum alloy material, which has good process stability.
The purpose of the invention can be realized by the following technical scheme:
an extrusion casting aluminum alloy material, which is characterized in that: the alloy consists of the following elements in percentage by mass, Mg: 2.5-6.0%, Zn: 3.0-6.0%, Cu: 0.5-2.0%, rare earth element RE: 0.01 to 1.5%, Ti: 0.00005% -0.2%, B: 0.00001% -0.1%, Sr: 0-0.2%, Zr: 0-0.2%, the balance of Al, and less than or equal to 0.45% of impurities;
the impurities are Fe and Si, Fe is less than or equal to 0.3 percent, and Si is less than or equal to 0.15 percent.
The rare earth element is one or a combination of more of Ce, Y, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu.
The Zn element is the total mass of the aluminum alloy: 3.0-6.0%, the Zn content should not be too high or too low, too high increases the cracking tendency of the alloy, too low reduces the precipitation strengthening effect and reduces the strength.
The Cu element is the following in total mass of the aluminum alloy: 0.5-2.0%, the Cu content is not too high or too low, when too high, an Al2CuMg phase is formed, the alloy plasticity is reduced, and when too low, the precipitation strengthening effect and the strength are reduced.
Preferably, the Ce element accounts for 0.21-1.5% of the total mass of the aluminum alloy, the Sr element accounts for 0.05-0.2% of the total mass of the aluminum alloy, and the Zr element accounts for 0.05-0.2% of the total mass of the aluminum alloy, and further preferably, the mass ratio of the Sr element to the Zr element is 1:1, because the Sr element and the Zr element are added and are added according to a specific mass ratio, the hot cracking resistance of the aluminum alloy material can be remarkably improved through solidification, the α -Al crystal grains can be refined, the hot cracking resistance of the aluminum alloy material can be remarkably improved, and Al can be precipitated in the process of solution treatment3Zr particles form precipitation strengthening, and the alloy strength is improved.
Preferably, the B element accounts for 0.002% -0.0085% of the total mass of the aluminum alloy. The addition of the B element and the Ti cooperate to refine the alloy structure, the refining effect is more excellent than that of the Ti alone, and the main reason is that the B and the Ti form TiB2Particles due to TiB2High melting point, stable existence in melt, Ti atom oriented to TiB2Migrating to form TiAl on the surface3Greatly increase the TiAl of nucleation particles3The amount of the aluminum alloy is reduced, the alloy is obviously refined, and the heat crack resistance of the aluminum alloy material is improved.
The Al, Zn and Mg are respectively selected from industrial pure aluminum, industrial pure zinc and industrial pure magnesium; the Cu and the rare earth element RE are added in an aluminum-copper intermediate alloy and an aluminum-rare earth intermediate alloy; the Ti and the B are added in an Al-Ti-B intermediate alloy; the Sr and the Zr are added by intermediate alloy of aluminum strontium and aluminum zirconium.
The preparation method of the extrusion casting aluminum alloy material comprises the following steps,
s1: smelting the alloy to prepare an aluminum alloy melt;
s2: carrying out extrusion casting on the aluminum alloy melt to prepare an aluminum alloy casting;
s3: carrying out heat treatment on the aluminum alloy casting to prepare an extrusion casting aluminum alloy material;
preferably, the step S1 includes the following steps:
(1) drying materials: respectively preheating raw materials of industrial pure aluminum, industrial pure zinc, industrial pure magnesium, aluminum-copper intermediate alloy, aluminum-rare earth intermediate alloy, aluminum-titanium-boron intermediate alloy, aluminum strontium and aluminum-zirconium intermediate alloy to 200-300 ℃, and preserving heat for 0.5-2 hours. Further preferably, the incubation time is 1 hour. Reasonable heat preservation time, shortens material drying time and saves energy under the condition of ensuring drying.
(2) Smelting: when the temperature is 200-300 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy, and stirring until the mixture is melted down; when the temperature of the melt is reduced to 680-700 ℃, adding industrial pure zinc and industrial pure magnesium for melting, and stirring until the melt is clear; heating the melt to 735-745 ℃, adding the aluminum rare earth intermediate alloy, and stirring until the melt is clear.
Further preferably, the temperature of the melt is raised to 740 ℃, the aluminum-rare earth intermediate alloy is added, and the mixture is stirred until the melt is clear. Can make the rare earth elements melt and diffuse uniformly and reduce the aggregation and precipitation of the rare earth elements.
(3) Refining: heating the melt to 735-; skimming dross and standing the melt;
preferably, the temperature of the melt is raised to 740 ℃, and a refining agent is added for refining. The time of the refining process is sufficient, and the refining effect is ensured.
(4) Degassing: adding a covering agent into the melt prepared in the step (3), and stirring for 5-10 minutes in a protective atmosphere; preferably, the protective atmosphere is N2And (4) protecting.
(5) Thinning: and (4) adding an aluminum-titanium-boron intermediate alloy and/or one or two of an aluminum-strontium intermediate alloy and an aluminum-zirconium intermediate alloy into the melt prepared in the step (4), refining, and skimming dross to obtain an aluminum alloy melt.
Preferably, in the step (1), the aluminum-rare earth intermediate alloy is an aluminum-cerium intermediate alloy, an aluminum-cerium-rich mischmetal, an aluminum-yttrium intermediate alloy, an aluminum-lanthanum intermediate alloy, an aluminum-praseodymium intermediate alloy, an aluminum-neodymium-rich mischmetal, an aluminum-samarium intermediate alloy, an aluminum-europium intermediate alloy, an aluminum-gadolinium intermediate alloy, an aluminum-dysprosium intermediate alloy, an aluminum-holmium intermediate alloy, an aluminum-erbium intermediate alloy, an aluminum-thulium intermediate alloy, an aluminum-ytterbium intermediate alloy, or an aluminum-lutetium intermediate alloy.
Preferably, in the step (3), the addition amount of the refining agent is 0.2-1.5% of the total mass of the melt. The refining agent is an aluminum alloy refining agent without sodium salt.
In the step (4), the addition amount of the covering agent is 0.2-1.5% of the total mass of the melt. The covering agent is MgCl with the mass ratio of 60 percent2+ 40% of KCl.
In the step S2, the aluminum alloy melt is extrusion cast at 680-700 ℃, the extrusion pressure is 50-200 MPa, the pressure holding time is 1-100 seconds, the mold temperature is 200-400 ℃, and the cooling rate is 100-.
In the step S3, the heat treatment comprises solution treatment and aging treatment;
preferably, the solution treatment is carried out for 4-48 hours at the temperature of 450-500 ℃, and water cooling is carried out, wherein the water temperature is 0-80 ℃; the aging treatment is carried out for 4-32 hours at the temperature of 100-225 ℃.
Further preferably, the solution treatment is carried out under the condition of 450-500 ℃ for 8-36 hours, and water cooling is carried out, wherein the water temperature is 0-80 ℃; the aging treatment is carried out for 4-30 hours at the temperature of 100-225 ℃.
Compared with the prior art, the invention has the beneficial effects that:
(1) the aluminum alloy material is added with rare earth elements, so that the effects of purifying melt and adsorbing impurities (Fe and Si) are achieved; Ti/B/Zr/Sr alloy elements are added compositely to play a role in refining grains; the two have combined action, thereby obviously reducing the hot cracking tendency of the alloy and improving the casting performance of the Al-Mg-Zn-Cu alloy.
(2) The aluminum alloy material has excellent room-temperature comprehensive mechanical property and good casting property, and has room-temperature tensile strength of more than or equal to 460MPa, yield strength of more than or equal to 400MPa and elongation of more than or equal to 6 percent.
(3) The preparation method is simple, the process stability is good, and the process controllability is high.
Drawings
FIG. 1 is an as-cast OM structure of the alloy of example 1 of the present invention in the form of a fine equiaxed crystal.
FIG. 2 is an as-cast SEM structure of the alloy of example 1 of the invention.
FIG. 3 is a heat treated SEM structure of the alloy of example 1 of the present invention.
Detailed Description
The invention will now be further illustrated by reference to the following examples:
example 1:
the extrusion casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 3.0%, Cu: 0.5%, Y: 0.01%, Ti: 0.01%, B: 0.002%, Sr: 0.1%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The extrusion casting method of the aluminum alloy provided by the embodiment comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt.
The smelting steps are as follows: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding an aluminum-yttrium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 36 hours at 450 ℃, cool the water and ensure the water temperature to be 25 ℃; the aging treatment is carried out under the environment of 120 ℃ for 24 hours.
In the embodiment of the invention, the hot cracking tendency of the alloy is evaluated by adopting a hot cracking rod method, the melt pouring temperature is 710 ℃, the hot cracking rod mold temperature is 200 ℃, the cracking condition of a hot cracking test rod sample is checked after pouring, the rod length generating the hot cracking, the position of the hot cracking and the size of the hot cracking are mainly considered, all influencing factors are divided into different levels, the hot cracking tendency is comprehensively considered, and the hot cracking tendency coefficient of the alloy is calculated.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 462MPa, a yield strength of 414MPa, an elongation of 8.3%, and a hot cracking tendency coefficient of 36.
Example 2:
the extrusion casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 3.0%, Cu: 0.5%, Y: 0.01%, Ti: 0.01%, Sr: 0.1%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The extrusion casting method of the aluminum alloy provided by the embodiment comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding an aluminum-yttrium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy, refining, removing floating slag on the surface of the melt to obtainObtaining the aluminum alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 36 hours at 450 ℃, cool the water and ensure the water temperature to be 25 ℃; the aging treatment is carried out under the environment of 120 ℃ for 24 hours.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 452MPa, a yield strength of 401MPa, an elongation of 6.3%, and a hot cracking tendency coefficient of 160.
Example 3:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 3.0%, Cu: 0.5%, aluminum-cerium-rich mischmetal: 1.5%, Ti: 0.01%, B: 0.002%, Sr: 0.1%, Zr: 0.15 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-cerium-rich mischmetal, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: heating the melt to 730 ℃, adding a composition of 60% MgCl2+ 40% KCl as a covering agent, filling nitrogen and stirring for 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 680-700 ℃ for extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 100 seconds, the mold temperature is 200 ℃, and the cooling rate is 500K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In the embodiment, the high-toughness cast aluminum alloy has the room-temperature tensile strength of 467MPa, the yield strength of 410MPa, the elongation of 7.3 percent and the hot cracking tendency coefficient of 20.
Example 4:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 3.0%, Cu: 2.0%, La: 0.5%, Ti: 0.05%, B: 0.01%, Sr: 0.1%, Zr: 0 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-lanthanum intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for refining and finingAfter melting, removing floating slag on the surface of the melt to obtain the aluminum alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 20 seconds, the mold temperature is 250 ℃, and the cooling rate is 350K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 12 hours at the temperature of 485 ℃, and cool the water with the temperature of 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has tensile strength at room temperature of 471MPa, yield strength of 420MPa, elongation of 8.2%, and hot cracking tendency coefficient of 40.
Example 5:
the extrusion casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 6.0%, Cu: 0.5%, Er: 0.2%, Ti: 0.2%, B: 0.1%, Sr: 0.05%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
In another aspect, the present embodiment provides a method for squeeze casting of the aluminum alloy, including the steps of:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-erbium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediateRefining the gold, and then removing floating slag on the surface of the melt to obtain the aluminum alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 6 hours at 175 ℃.
In this example, the high toughness cast aluminum alloy has a room temperature tensile strength of 468MPa, a yield strength of 415MPa, an elongation of 6.5%, and a hot cracking tendency coefficient of 44.
Example 6:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 6.0%, Cu: 0.5%, Pr: 0.5%, Nd: 0.2%, Ti: 0.01%, B: 0.0023%, Sr: 0.1%, Zr: 0.2 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-praseodymium intermediate alloy and the aluminum-neodymium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thin and thinAnd (3) conversion: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 100K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 20 hours at 470 ℃, cool the solution with water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 490MPa, a yield strength of 420MPa, an elongation of 8.0%, and a hot cracking tendency coefficient of 36.
Example 7:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 2.5%, Zn: 6.0%, Cu: 2.0%, Sm: 0.8%, Ti: 0.00005%, B: 0.00001%, Sr: 0.1%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al. In another aspect, the present embodiment provides a method for squeeze casting of the aluminum alloy, including the steps of:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-samarium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning:adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature at 465 ℃ for 24 hours, cool the solution with water and keep the temperature at 25 ℃; the aging treatment is carried out for 4 hours at 225 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 470MPa, a yield strength of 420MPa, an elongation of 8.1%, and a hot cracking tendency coefficient of 42.
Example 8:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 5.0%, Zn: 3.0%, Cu: 0.5%, Eu: 0.7%, Ti: 0.05%, B: 0.01%, Sr: 0%, Zr: 0 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
In another aspect, the present embodiment provides a method for squeeze casting of the aluminum alloy, including the steps of:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-europium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10%The method comprises the following steps of (1) taking minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 8 hours at 500 ℃, cool the water and ensure the water temperature to be 25 ℃; the aging treatment is carried out by keeping the temperature for 30 hours in an environment of 100 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 450MPa, a yield strength of 401MPa, an elongation of 5.2%, and a hot cracking tendency coefficient of 32.
Example 9:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 6.0%, Zn: 3.0%, Cu: 0.5%, Gd: 1.5%, Ti: 0.012%, B: 0.0025%, Sr: 0.2%, Zr: 0.2 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-gadolinium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a refining agent for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutesA clock; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 12 hours at 4850 ℃, cool the water and heat the water to 25 ℃; the aging treatment is carried out for 20 hours at the temperature of 120 ℃.
In this example, the high toughness cast aluminum alloy has a room temperature tensile strength of 463MPa, a yield strength of 405MPa, an elongation of 6.2%, and a hot cracking tendency coefficient of 64.
Example 10:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 5.0%, Zn: 3.0%, Cu: 2.0%, Yb: 0.2%, Ti: 0.015%, B: 0.0031%, Sr: 0.2%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
In another aspect, the present embodiment provides a method for squeeze casting of the aluminum alloy, including the steps of:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-ytterbium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2+ 40% KCl composition as covering agent, nitrogen fillingStirring for 5-10 min; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 36 hours at 450 ℃, cool the water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 466MPa, a yield strength of 413MPa, an elongation of 6.8%, and a hot cracking tendency coefficient of 32.
Example 11:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 4.5%, Zn: 6.0%, Cu: 0.7%, Ho: 0.10%, Ti: 0.025%, B: 0.005%, Sr: 0.1%, Zr: 0.2 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-holmium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2+ 40% KCl composition as coatingCovering with a covering agent, filling nitrogen and stirring for 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 12 hours at the temperature of 485 ℃, and cool the water with the temperature of 25 ℃; the aging treatment is carried out for 6 hours at 175 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 490MPa, a yield strength of 420MPa, an elongation of 6.1%, and a hot cracking tendency coefficient of 68.
Example 12:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 6.0%, Zn: 6.0%, Cu: 0.5%, Pr: 0.6%, Er: 0.9%, Ti: 0.045%, B: 0.0085%, Sr: 0%, Zr: 0 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-praseodymium intermediate alloy and the aluminum-erbium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: adding 60 percent of the mixture when the temperature of the melt is raised to 730 DEG CMgCl2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has a tensile strength at room temperature of 488MPa, a yield strength of 423MPa, an elongation of 6.2%, and a hot cracking tendency coefficient of 40.
Example 13:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 6.0%, Zn: 5.2%, Cu: 1.5%, Dy: 0.3%, Ti: 0.015%, B: 0.003%, Sr: 0.1%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-dysprosium soil intermediate alloy, and uniformly stirring until the melt is molten; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt rises to 730Adding 60% MgCl at DEG C2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 20 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 15 hours at 480 ℃, cool the water and ensure that the water temperature is 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 491MPa, a yield strength of 421MPa, an elongation of 6.1%, and a hot cracking tendency coefficient of 52.
Example 14:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 4.5%, Zn: 4.3%, Cu: 1.2%, Tm: 0.2%, Ti: 0.04%, B: 0.0082%, Sr: 0.05%, Zr: 0.05 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-thulium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) degassing: to be meltedThe temperature of the mixture is raised to 730 ℃, and 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 5 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 30 hours at the temperature of 460 ℃, and cool the water with the temperature of 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has tensile strength at room temperature of 503MPa, yield strength of 443MPa, elongation of 10.6%, and hot cracking tendency coefficient of 0.
Example 15:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 4.3%, Zn: 4.8%, Cu: 1.0%, Lu: 0.2%, Ti: 0.016%, B: 0.0032%, Sr: 0.1%, Zr: 0.2 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-lutetium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing floating slag on the surface after refining, and standing the melt; (4) removing deviceGas: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high-toughness cast aluminum alloy has a room-temperature tensile strength of 494MPa, a yield strength of 450MPa, an elongation of 8.1%, and a hot-cracking tendency coefficient of 12.
Example 16:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 3.8%, Zn: 4.5%, Cu: 1.2%, Y: 0.15%, Ti: 0.009%, B: 0.002%, Sr: 0.2%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding an aluminum-yttrium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, continuing for 10-20 minutes, removing surface scum after refining, and standing and meltingA body; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours under the environment of 150 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 480MPa, a yield strength of 443MPa, an elongation of 8.5%, and a hot cracking tendency coefficient of 16.
Example 17:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 3.5%, Zn: 4.0%, Cu: 1.2%, Nd: 0.15%, Ti: 0.015%, B: 0.003%, Sr: 0.15%, Zr: 0.15 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
In another aspect, the present embodiment provides a method for squeeze casting of the aluminum alloy, including the steps of:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-neodymium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining for 10-20 minutes when the temperature of the melt reaches 740 ℃, and refiningSkimming the surface scum, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 1 second, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours at the temperature of 120 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 486MPa, a yield strength of 439MPa, an elongation of 7.5%, and a hot cracking tendency coefficient of 20.
Example 18:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 4.1%, Zn: 4.5%, Cu: 0.8%, Sm: 0.15%, Ti: 0.016%, B: 0.0032%, Sr: 0%, Zr: 0.1 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-samarium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, namely adding a powder injection refining agent (Dingchen) for refining when the temperature of the melt reaches 740 ℃, and continuing for 10-20 minutesSkimming floating slag on the surface after refining, and standing the melt; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours at the temperature of 120 ℃.
In this example, the high toughness cast aluminum alloy has a room temperature tensile strength of 478MPa, a yield strength of 423MPa, an elongation of 9.0%, and a hot cracking tendency coefficient of 24.
Example 19:
the squeeze casting aluminum alloy material provided by the embodiment comprises the following elements in percentage by mass: 4.0%, Zn: 3.4%, Cu: 0.9%, Ce: 0.2%, Er: 0.1%, Ti: 0.03%, B: 0.006%, Sr: 0.1%, Zr: 0 percent, unavoidable impurities Fe less than or equal to 0.3 percent, Si less than or equal to 0.15 percent and the balance of Al.
The embodiment provides an extrusion casting method of the aluminum alloy, which comprises the following steps:
a. and smelting the alloy to obtain an aluminum alloy melt. A smelting step: (1) drying the materials, and preheating the raw materials at 250 ℃ for 2 hours; (2) smelting, setting the smelting temperature of a melting furnace to be 710 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy when the furnace temperature is increased to 300 ℃ until the materials are molten, and uniformly stirring; when the temperature of the melt is reduced to 690 ℃, adding industrial pure zinc and industrial pure magnesium, melting, and uniformly stirring until the melt is melted down; heating the melt to 740 ℃, adding the aluminum-cerium intermediate alloy and the aluminum-erbium intermediate alloy, and uniformly stirring until the melt is clear; (3) refining, adding powder spraying for refining when the temperature of the melt reaches 740 DEG CRefining the mixture for 10-20 minutes, removing floating slag on the surface of the refined mixture, and standing the refined mixture; (4) degassing: when the temperature of the melt is raised to 730 ℃, 60 percent MgCl is added2The composition of + 40% KCl is used as a covering agent, nitrogen is filled, stirring is carried out, and the duration is 5-10 minutes; (5) thinning: adding Al-Ti-B, Al-Sr and Al-Zr intermediate alloy for fining, and removing dross on the surface of the melt to obtain the Al-alloy melt.
b. And carrying out extrusion casting on the melt to obtain the aluminum alloy. Casting: and pouring the aluminum melt into an extrusion casting machine at 690 ℃, and carrying out extrusion casting, wherein the extrusion pressure is 100MPa, the pressure maintaining time is 10 seconds, the mold temperature is 300 ℃, and the cooling rate is 200K/s.
c. And sequentially carrying out solid solution treatment and aging treatment on the aluminum alloy to obtain the high-strength and high-toughness cast aluminum alloy. The solution treatment is to keep the temperature for 24 hours at 470 ℃, cool the solution by water and ensure the water temperature to be 25 ℃; the aging treatment is carried out for 16 hours at the temperature of 120 ℃.
In this example, the high strength and toughness cast aluminum alloy has a room temperature tensile strength of 480MPa, a yield strength of 432MPa, an elongation of 8.8%, and a hot cracking tendency coefficient of 36.
Tables 1 and 2 give statistics on the alloy composition, mechanical properties and coefficient of hot cracking tendency of the examples.
Table 1 example alloy compositions (mass fraction,%)
Figure BDA0001707054240000201
Figure BDA0001707054240000211
TABLE 2 tensile properties and coefficients of hot cracking tendency of the alloys
Figure BDA0001707054240000212
Figure BDA0001707054240000221
As can be seen from the test data of the above examples, the mechanical properties and casting properties of the aluminum alloy, especially example 14, are excellent with the addition of equal volumes of Sr and Zr.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention, and the present invention should not be limited by the disclosure of the preferred embodiments. Therefore, it is intended that all equivalents and modifications which do not depart from the spirit of the invention disclosed herein are deemed to be within the scope of the invention.

Claims (9)

1. An extrusion casting aluminum alloy material, which is characterized in that: the alloy consists of the following elements in percentage by mass, Mg: 2.5-6.0%, Zn: 3.0-6.0%, Cu: 0.5-2.0%, rare earth element RE: 0.01 to 1.5%, Ti: 0.00005% -0.2%, B: 0.002% -0.0085%, Sr: 0.05-0.2%, Zr: 0.05-0.2%, the balance of Al, and less than or equal to 0.45% of impurities;
the mass ratio of the Sr element to the Zr element is 1: 1;
the rare earth element is one or a combination of more of Ce, Y, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu.
2. The squeeze cast aluminum alloy material according to claim 1, wherein: the Al, Zn and Mg are respectively selected from industrial pure aluminum, industrial pure zinc and industrial pure magnesium; the Cu and the rare earth element RE are added in an aluminum-copper intermediate alloy and an aluminum-rare earth intermediate alloy; the Ti and the B are added in an Al-Ti-B intermediate alloy; the Sr and the Zr are added by intermediate alloy of aluminum strontium and aluminum zirconium.
3. The production method of an extrusion-cast aluminum alloy material as set forth in claim 1, comprising the step of,
s1: smelting the alloy to prepare an aluminum alloy melt;
s2: carrying out extrusion casting on the aluminum alloy melt to prepare an aluminum alloy casting;
s3: and carrying out heat treatment on the aluminum alloy casting to prepare the extrusion casting aluminum alloy material.
4. The production method of an extrusion casting aluminum alloy material according to claim 3, characterized in that: in the step S1, the following processes are included:
(1) drying materials: respectively preheating raw materials of industrial pure aluminum, industrial pure zinc, industrial pure magnesium, aluminum-copper intermediate alloy, aluminum-rare earth intermediate alloy, aluminum-titanium-boron intermediate alloy, aluminum strontium and aluminum-zirconium intermediate alloy to 200-300 ℃, and preserving heat for 0.5-2 hours;
(2) smelting: when the temperature is 200-300 ℃, adding industrial pure aluminum and aluminum-copper intermediate alloy, and stirring until the mixture is melted down; when the temperature of the melt is reduced to 680-700 ℃, adding industrial pure zinc and industrial pure magnesium for melting, and stirring until the melt is clear; heating the melt to 735-;
(3) refining: heating the melt to 735-; skimming dross and standing the melt;
(4) degassing: adding a covering agent into the melt prepared in the step (3), and stirring for 5-10 minutes in a protective atmosphere;
(5) thinning: and (4) adding an aluminum-titanium-boron intermediate alloy and/or one or two of an aluminum-strontium intermediate alloy and an aluminum-zirconium intermediate alloy into the melt prepared in the step (4), refining, and skimming dross to obtain an aluminum alloy melt.
5. The production method of an extrusion casting aluminum alloy material according to claim 4, characterized in that: in the step (3), the addition amount of the refining agent is 0.2-1.5% of the total mass of the melt.
6. The production method of an extrusion casting aluminum alloy material according to claim 4, characterized in that: in the step (4), the addition amount of the covering agent is 0.2-1.5% of the total mass of the melt.
7. The production method of an extrusion casting aluminum alloy material according to claim 4, characterized in that: in the step S2, the aluminum alloy melt is extrusion cast at 680-700 ℃, the extrusion pressure is 50-200 MPa, the pressure maintaining time is 1-100 seconds, the mold temperature is 200-400 ℃, and the cooling rate is 100-500K/S.
8. The production method of an extrusion casting aluminum alloy material according to claim 4, characterized in that: in step S3, the heat treatment includes solution treatment and aging treatment.
9. The preparation method of the squeeze casting aluminum alloy material as claimed in claim 8, wherein the solution treatment is heat preservation for 4-48 hours at 450-500 ℃, water cooling is carried out, and the water temperature is 0-80 ℃; the aging treatment is carried out for 4-32 hours at the temperature of 100-225 ℃.
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