CN108641322A - A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof - Google Patents
A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof Download PDFInfo
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- CN108641322A CN108641322A CN201810534917.8A CN201810534917A CN108641322A CN 108641322 A CN108641322 A CN 108641322A CN 201810534917 A CN201810534917 A CN 201810534917A CN 108641322 A CN108641322 A CN 108641322A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of nano silver fibre, graphene composite material degerming toe-caps, are made of the material of following weight：57 parts of 20 30 parts of nano silver fibre, 26 30 parts of graphene, 28 30 parts of unsaturated polyester resin, 20 28 parts of phenolic resin, 20 26 parts of isoprene rubber, 18 20 parts of carbamate resins, 10 16 parts of ethylene propylene diene rubber, 8 10 parts of polyvinylidene chloride, 79 parts of polyethylene terephthalate, 68 parts of phthalic acid ester, 68 parts of fatty amine, 57 parts of acid anhydrides, 57 parts of epoxy resin, 57 parts of alkylene phenesic acid and alkyl phosphate；The toe-cap of preparation can be made to have the function of that deodorizing antibiotic, graphene can improve the intensity of toe-cap using nano silver fibre, while can also make toe-cap that there is good toughness, and can be bent；Acid anhydrides and epoxy resin form ester bond, improve the chemical-resistant of toe-cap；Alkyl phosphate cooperates with the service life of alkylene phenesic acid increase toe-cap.
Description
Technical field
Present invention relates particularly to a kind of nano silver fibres, graphene composite material degerming toe-cap and preparation method thereof.
Background technology
Due to the adaptation of the uprighting movement to people, the foot of the mankind is all complicated one of human height in anatomy and function
Part.Muscle or bone to foot even small mechanical influence also results in serious uncomfortable or even pain, and
The consequence that the limitation that makes one to have to is walked possibly even is generated to the physical injury of foot, to which described injury can be being cured completely
In a period of loss of athletic ability.In view of these factors, we will select suitable shoes to protect our foot, and wherein shoes
The effect of the toe-cap of son is particularly important.Additional reinforcing and anti-pierceable material are incorporated into safety shoe in many cases,
Or in the sole of safety shoe.General shoes usually have in their front to be protected made of steel, aluminium or highstrenghtpiston
Toe-cap, with protect toe be protected from fallen due to weight caused by damage.It is more also used for the composite strengthening toe-cap of shoes,
It includes the fibrous layer of multiple composite fibre enhancement layers and bigger, and the fibrous layer of the bigger is layered in multiple composite fibre enhancement layers
Between and extend out from the composite fibre enhancement layer.The composite fibre enhancement layer is by fiber reinforced plastic composite material
It is made, and is laminated on fibrous layer, to form prefabricated toe-cap.As a lot of other known toe-caps, these existing skills
The toe-cap of art cannot divulge information in its front, therefore, it is impossible to perspire or discharge moisture.This does not only result in the uncomfortable of shoe user,
Also it is disease and the ideal condition of growth creation of microorganism.
Invention content
In view of this, there is high intensity, the nanometer of high tenacity and deodorization degerming functions the object of the present invention is to provide a kind of
Silver fiber, graphene composite material degerming toe-cap.
To solve the above-mentioned problems, the technical scheme is that：
A kind of nano silver fibre, graphene composite material degerming toe-cap, are made of the material of following weight：Nanometer
20-30 parts of silver fiber, 26-30 parts of graphene, 28-30 parts of unsaturated polyester resin, 20-28 parts of phenolic resin, isoprene rubber
20-26 parts of glue, 10-16 parts of ethylene propylene diene rubber, 8-10 parts of polyvinylidene chloride, gathers to benzene 18-20 parts of carbamate resins
7-9 parts of dicarboxylate, 6-8 parts of phthalic acid ester, 6-8 parts of fatty amine, 5-7 parts of acid anhydrides, 5-7 parts of epoxy resin, alkylene
5-7 parts of 5-7 parts of phenesic acid and alkyl phosphate.
Further, a kind of nano silver fibre, graphene composite material degerming toe-cap, by following weight
Material is made：30 parts of nano silver fibre, 26 parts of graphene, 28 parts of unsaturated polyester resin, 20 parts of phenolic resin, isoprene rubber
20 parts of glue, 18 parts of carbamate resins, 10 parts of ethylene propylene diene rubber, 8 parts of polyvinylidene chloride, polyethylene terephthalate
7 parts, 6 parts of phthalic acid ester, 6 parts of fatty amine, 5 parts of acid anhydrides, 5 parts of epoxy resin, 5 parts of alkylene phenesic acid and alkyl phosphate
5 parts.
Further, a kind of nano silver fibre, graphene composite material degerming toe-cap, by following weight
Material is made：20 parts of nano silver fibre, 30 parts of graphene, 30 parts of unsaturated polyester resin, 28 parts of phenolic resin, isoprene rubber
26 parts of glue, 20 parts of carbamate resins, 16 parts of ethylene propylene diene rubber, 10 parts of polyvinylidene chloride, poly terephthalic acid diethyl
9 parts of ester, 8 parts of phthalic acid ester, 8 parts of fatty amine, 7 parts of acid anhydrides, 7 parts of epoxy resin, 7 parts of alkylene phenesic acid and alkyl phosphoric acid
7 parts of ester.
Further, a kind of nano silver fibre, graphene composite material degerming toe-cap, by following weight
Material is made：25 parts of nano silver fibre, 28 parts of graphene, 29 parts of unsaturated polyester resin, 24 parts of phenolic resin, isoprene rubber
23 parts of glue, 19 parts of carbamate resins, 13 parts of ethylene propylene diene rubber, 9 parts of polyvinylidene chloride, polyethylene terephthalate
8 parts, 7 parts of phthalic acid ester, 7 parts of fatty amine, 6 parts of acid anhydrides, 6 parts of epoxy resin, 6 parts of alkylene phenesic acid and alkyl phosphate
6 parts.
Beneficial effects of the present invention:The toe-cap of preparation can be made to have the function of deodorizing antibiotic, graphite using nano silver fibre
Alkene can improve the intensity of toe-cap, while toe-cap can also be made to have good toughness, and can be bent；Acid anhydrides and epoxy resin are formed
Ester bond improves the chemical-resistant of toe-cap；It is the antioxidant of high activity with alkylene phenesic acid, alkyl phosphate is low work
The antioxidant of property, can effectively capture oxyradical or peroxylradicals, at this moment alkyl phosphorus with alkylene phenesic acid
Acid esters can supply hydrogen atom, so that same alkylene phenesic acid is regenerated, be allowed to keep permanent antioxygen efficiency, increase the use of toe-cap
Service life.
Specific implementation method
Embodiment 1
A kind of nano silver fibre, graphene composite material degerming toe-cap, are made of the material of following weight：Nanometer
30 parts of silver fiber, 26 parts of graphene, 28 parts of unsaturated polyester resin, 20 parts of phenolic resin, 20 parts of isoprene rubber, amino first
18 parts of acid ester resin, 10 parts of ethylene propylene diene rubber, 8 parts of polyvinylidene chloride, 7 parts of polyethylene terephthalate, O-phthalic
5 parts of 6 parts of acid esters, 6 parts of fatty amine, 5 parts of acid anhydrides, 5 parts of epoxy resin, 5 parts of alkylene phenesic acid and alkyl phosphate.
A kind of nano silver fibre, graphene composite material degerming toe-cap, include the following steps:
1) 30 parts of nano silver fibre, 26 parts of graphene, 28 parts of unsaturated polyester resin, 20 parts of phenolic resin, isoamyl two are taken
10 parts of 20 parts of alkene rubber, 18 parts of carbamate resins and ethylene propylene diene rubber, mixing are toasted, baking temperature 130-
150 DEG C, 10-16min, then 80-100 DEG C is cooled the temperature to, mixing baking material is made in time 10-20min, spare；
2) 5 parts of 5 parts of acid anhydrides, 5 parts of epoxy resin, 5 parts of alkylene phenesic acid and alkyl phosphate are taken, is mixed, stirring
Speed is that water-bath mixture is made using 70 DEG C of heating water bath 30min in 150rpm, time 10min, spare；
3) 6 parts of 8 parts of polyvinylidene chloride, 7 parts of polyethylene terephthalate, 6 parts of phthalic acid ester and fatty amine are taken,
The water-bath mixture prepared with step 2) in container prepared by step 2) is added to be mixed, and uses 100 DEG C of heating water bath,
Heating time is 20min, prepares the second water-bath mixture, spare；
4) putting mixing baking material prepared by step 1) into is crushed to powdered in pulverizer, put into container, add
Second water-bath mixture prepared by step 3) is mixed, mixing speed 600rpm, time 7min, and mixture is made, standby
With；
5) mixture made from step 4) is toasted, baking temperature is 170 DEG C, 16min, fast using wind turbine after baking
Speed is cooled to room temperature, and the second baking mixture is made, spare；
6) step 5) is made and puts double screw extruder plasticizing, melting, extrusion, tie rod and pelletizing into, obtain pellet, it is standby
With；
7) pellet made from step 6) is subjected to baking-curing, solidification temperature is 140 DEG C, 8min, then is down to 60 DEG C, the time
For 5min, toe-cap is made in then injection molding.
Embodiment 2
A kind of nano silver fibre, graphene composite material degerming toe-cap, are made of the material of following weight：Nanometer
20 parts of silver fiber, 30 parts of graphene, 30 parts of unsaturated polyester resin, 28 parts of phenolic resin, 26 parts of isoprene rubber, amino first
20 parts of acid ester resin, 16 parts of ethylene propylene diene rubber, 10 parts of polyvinylidene chloride, 9 parts of polyethylene terephthalate, O-phthalic
7 parts of 8 parts of acid esters, 8 parts of fatty amine, 7 parts of acid anhydrides, 7 parts of epoxy resin, 7 parts of alkylene phenesic acid and alkyl phosphate.
A kind of nano silver fibre, graphene composite material degerming toe-cap, include the following steps:
1) 20 parts of nano silver fibre, 30 parts of graphene, 30 parts of unsaturated polyester resin, 28 parts of phenolic resin, isoamyl two are taken
16 parts of 26 parts of alkene rubber, 20 parts of carbamate resins and ethylene propylene diene rubber, mixing are toasted, and baking temperature is 130 DEG C,
10min, then 80 DEG C are cooled the temperature to, mixing baking material is made in time 10min, spare；
2) 7 parts of 7 parts of acid anhydrides, 7 parts of epoxy resin, 7 parts of alkylene phenesic acid and alkyl phosphate are taken, is mixed, stirring
Speed is that water-bath mixture is made using 50 DEG C of heating water bath 20min in 100rpm, time 6min, spare；
3) 10 parts of polyvinylidene chloride, 9 parts of polyethylene terephthalate, 8 parts of phthalic acid ester and fatty amine 8 are taken
Part, the water-bath mixture prepared with step 2) in container prepared by step 2) is added and is mixed, and is added using 90 DEG C of water-bath
Heat, heating time 10min prepare the second water-bath mixture, spare；
4) putting mixing baking material prepared by step 1) into is crushed to powdered in pulverizer, put into container, add
Second water-bath mixture prepared by step 3) is mixed, mixing speed 500rpm, time 5min, and mixture is made, standby
With；
5) mixture made from step 4) is toasted, baking temperature is 160 DEG C, 10min, fast using wind turbine after baking
Speed is cooled to room temperature, and the second baking mixture is made, spare；
6) step 5) is made and puts double screw extruder plasticizing, melting, extrusion, tie rod and pelletizing into, obtain pellet, it is standby
With；
7) pellet made from step 6) is subjected to baking-curing, solidification temperature is 120 DEG C, 6min, then is down to 50 DEG C, the time
For 3min, toe-cap is made in then injection molding.
Embodiment 3
A kind of nano silver fibre, graphene composite material degerming toe-cap, are made of the material of following weight：Nanometer
25 parts of silver fiber, 28 parts of graphene, 29 parts of unsaturated polyester resin, 24 parts of phenolic resin, 23 parts of isoprene rubber, amino first
19 parts of acid ester resin, 13 parts of ethylene propylene diene rubber, 9 parts of polyvinylidene chloride, 8 parts of polyethylene terephthalate, O-phthalic
6 parts of 7 parts of acid esters, 7 parts of fatty amine, 6 parts of acid anhydrides, 6 parts of epoxy resin, 6 parts of alkylene phenesic acid and alkyl phosphate.
A kind of nano silver fibre, graphene composite material degerming toe-cap, include the following steps:
1) 25 parts of nano silver fibre, 28 parts of graphene, 29 parts of unsaturated polyester resin, 24 parts of phenolic resin, isoamyl two are taken
13 parts of 23 parts of alkene rubber, 19 parts of carbamate resins and ethylene propylene diene rubber, mixing are toasted, and baking temperature is 140 DEG C,
13min, then 90 DEG C are cooled the temperature to, mixing baking material is made in time 15min, spare；
2) 6 parts of 6 parts of acid anhydrides, 6 parts of epoxy resin, 6 parts of alkylene phenesic acid and alkyl phosphate are taken, is mixed, stirring
Speed is that water-bath mixture is made using 60 DEG C of heating water bath 25min in 125rpm, time 8min, spare；
3) 7 parts of 9 parts of polyvinylidene chloride, 8 parts of polyethylene terephthalate, 7 parts of phthalic acid ester and fatty amine are taken,
The water-bath mixture prepared with step 2) in container prepared by step 2) is added to be mixed, and uses 95 DEG C of heating water bath,
Heating time is 15min, prepares the second water-bath mixture, spare；
4) putting mixing baking material prepared by step 1) into is crushed to powdered in pulverizer, put into container, add
Second water-bath mixture prepared by step 3) is mixed, mixing speed 550rpm, time 6min, and mixture is made, standby
With；
5) mixture made from step 4) is toasted, baking temperature is 165 DEG C, 13min, fast using wind turbine after baking
Speed is cooled to room temperature, and the second baking mixture is made, spare；
6) step 5) is made and puts double screw extruder plasticizing, melting, extrusion, tie rod and pelletizing into, obtain pellet, it is standby
With；
7) pellet made from step 6) is subjected to baking-curing, solidification temperature is 130 DEG C, 7min, then is down to 55 DEG C, the time
For 4min, toe-cap is made in then injection molding.
Experimental example：
It is control group one to choose toe-cap prepared by latex material, and toe-cap prepared by the embodiment of the present invention three is experimental group.
Experimental subjects, toe-cap prepared by toe-cap and the embodiment of the present invention three prepared by synthetic rubber.
Requirement of experiment, toe-cap prepared by the toe-cap and the embodiment of the present invention three standby to synthesis rubber system are tested for the property.
Table 1 is to experimental subjects performance test acquired results
Table 1
In conjunction with table 1, the toe-cap of toe-cap and the preparation of the embodiment of the present invention three prepared by comparison synthetic rubber, it can be seen that this
A kind of nano silver fibre, graphene composite material degerming toe-cap are invented, stretching, the bending of the toe-cap not only prepared than synthetic rubber
It is good with wear-resisting property, also there is good antibacterial property energy.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work should all be covered within the scope of the present invention.
Claims (4)
1. a kind of nano silver fibre, graphene composite material degerming toe-cap, it is characterised in that：By the material of following weight
It is made：It is 20-30 parts of nano silver fibre, 26-30 parts of graphene, 28-30 parts of unsaturated polyester resin, 20-28 parts of phenolic resin, different
20-26 parts of pentadiene rubber, 18-20 parts of carbamate resins, 10-16 parts of ethylene propylene diene rubber, polyvinylidene chloride 8-10
Part, 7-9 parts of polyethylene terephthalate, 6-8 parts of phthalic acid ester, 6-8 parts of fatty amine, 5-7 parts of acid anhydrides, epoxy resin 5-
5-7 parts of 7 parts, 5-7 parts of alkylene phenesic acid and alkyl phosphate.
2. a kind of nano silver fibre, graphene composite material degerming toe-cap as described in claim 1, it is characterised in that：By following
The material of weight is made：30 parts of nano silver fibre, 26 parts of graphene, 28 parts of unsaturated polyester resin, phenolic resin 20
Part, 20 parts of isoprene rubber, 18 parts of carbamate resins, 10 parts of ethylene propylene diene rubber, 8 parts of polyvinylidene chloride, poly- pair
7 parts of diethyl phthalate, 6 parts of phthalic acid ester, 6 parts of fatty amine, 5 parts of acid anhydrides, 5 parts of epoxy resin, alkylene phenesic acid 5
5 parts of part and alkyl phosphate.
3. a kind of nano silver fibre, graphene composite material degerming toe-cap as described in claim 1, it is characterised in that：By following
The material of weight is made：20 parts of nano silver fibre, 30 parts of graphene, 30 parts of unsaturated polyester resin, phenolic resin 28
Part, 26 parts of isoprene rubber, 20 parts of carbamate resins, 16 parts of ethylene propylene diene rubber, 10 parts of polyvinylidene chloride, poly- pair
9 parts of diethyl phthalate, 8 parts of phthalic acid ester, 8 parts of fatty amine, 7 parts of acid anhydrides, 7 parts of epoxy resin, alkylene phenesic acid 7
7 parts of part and alkyl phosphate.
4. a kind of nano silver fibre, graphene composite material degerming toe-cap as described in claim 1, it is characterised in that：By following
The material of weight is made：25 parts of nano silver fibre, 28 parts of graphene, 29 parts of unsaturated polyester resin, phenolic resin 24
Part, 23 parts of isoprene rubber, 19 parts of carbamate resins, 13 parts of ethylene propylene diene rubber, 9 parts of polyvinylidene chloride, poly- pair
8 parts of diethyl phthalate, 7 parts of phthalic acid ester, 7 parts of fatty amine, 6 parts of acid anhydrides, 6 parts of epoxy resin, alkylene phenesic acid 6
6 parts of part and alkyl phosphate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810534917.8A CN108641322A (en) | 2018-05-29 | 2018-05-29 | A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810534917.8A CN108641322A (en) | 2018-05-29 | 2018-05-29 | A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof |
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| CN108641322A true CN108641322A (en) | 2018-10-12 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115354258A (en) * | 2022-08-23 | 2022-11-18 | 徐州淮声电力工程有限公司 | High-entropy alloy polymer composite paving material and manufacturing method thereof |
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Application publication date: 20181012 |