CN106750606A - A kind of deodorant footwear material of Elastic - Google Patents

A kind of deodorant footwear material of Elastic Download PDF

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Publication number
CN106750606A
CN106750606A CN201710042010.5A CN201710042010A CN106750606A CN 106750606 A CN106750606 A CN 106750606A CN 201710042010 A CN201710042010 A CN 201710042010A CN 106750606 A CN106750606 A CN 106750606A
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CN
China
Prior art keywords
parts
nano
footwear material
ethanol solution
elastic
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710042010.5A
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Chinese (zh)
Inventor
梁志军
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Wenzhou Blue Ocean Shoes Co Ltd
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Wenzhou Blue Ocean Shoes Co Ltd
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Priority to CN201710042010.5A priority Critical patent/CN106750606A/en
Publication of CN106750606A publication Critical patent/CN106750606A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/10—Footwear characterised by the material made of rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention discloses a kind of deodorant footwear material of Elastic, the footwear material is formed by the Raw material processing of following weight：10 20 parts of 30 60 parts of natural rubber, 10 20 parts of PEPA, 3 10 parts of white carbon, 26 parts of sodium alginate, 6 12 parts of polyolefin elastomer, 20 40 parts of calcium carbonate, 10 20 parts of bamboo-carbon fibre, 10 20 parts of chitin fiber, 7 12 parts of antioxidant, 10 15 parts of nano silicone micro mist, 3 10 parts of nano-silver ionic powder, 14 parts of angelica essential oil and ethanol solution, footwear material prepared by the present invention has deodorizing sterilizing effect thorough, the function duration is long, human body is had no side effect, safety and sanitation, be easy to make the features such as.

Description

A kind of deodorant footwear material of Elastic
Technical field
The present invention relates to footwear manufacture material field, specially a kind of deodorant footwear material of Elastic.
Background technology
It is well known that the peculiar smell and harmful mushroom in footwear are the problems for perplexing people all the time.Tinea pedis（Foot odour）Be by Vigorous in the eccrine secretion of body, sweat gland secretion produces dirty smelly in the case where bacterium, mould are decomposed.Perspiration promotes bacterium easily numerous Grow, therefore foot odour often occurs together with ephidrosis.Tinea pedis not only has a strong impact on the daily work and life of patient, but also easily infects To other people.To prevent tinea pedis, people come up with many methods, wherein just having using the good cotton-padded shoes pad of absorbing sweat effect, or use Chinese medicine The shoe-pad crossed etc. drug-treated improves in-shoe environment, the effect in a short time having is preferable, but is perspiring many or for a long time using In the case of be extremely difficult to ideal effect.
The content of the invention
It is an object of the invention to provide a kind of deodorant footwear material of Elastic, with asking for solving to propose in above-mentioned background technology Topic.
To achieve the above object, the present invention provides following technical scheme：A kind of deodorant footwear material of Elastic, the footwear material is Formed by the Raw material processing of following weight：Natural rubber 30-60 parts, PEPA 10-20 parts, white carbon 3-10 Part, sodium alginate 2-6 parts, polyolefin elastomer 6-12 parts, calcium carbonate 20-40 parts, bamboo-carbon fibre 10-20 parts, chitin fiber 10-20 parts, antioxidant 7-12 parts, 10-15 parts of nano silicone micro mist, 3-10 parts, angelica essential oil 1-4 parts of nano-silver ionic powder and Ethanol solution 10-20 parts.
Preferably, the preferred composition proportion of the footwear material includes：45 parts of natural rubber, 15 parts of PEPA, white carbon 7 Part, 4 parts of sodium alginate, 9 parts of polyolefin elastomer, 30 parts of calcium carbonate, 15 parts of bamboo-carbon fibre, 15 parts of chitin fiber, antioxidant 15 parts of 10 parts, 12 parts of nano silicone micro mist, 7 parts of nano-silver ionic powder, 3 parts of angelica essential oil and ethanol solution.
Preferably, its preparation method is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1000-2000 revs/min, and mixing time is 20min-30min, it Stand afterwards and obtain mixture A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 180 DEG C -220 DEG C, and the reaction time is 10min-20min, is slowly cooled to afterwards Room temperature, obtains mixture B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 30min- at normal temperatures After 40min, 1h is stood, that is, obtain Elastic deodoring materials.
Compared with prior art, the beneficial effects of the invention are as follows：Footwear material prepared by the present invention has deodorizing sterilizing effect thorough Bottom, the function duration is long, and human body is had no side effect, safety and sanitation, be easy to make the features such as；In addition, being added with the present invention Nano silicone micro mist, nano-silver ionic powder, can extend antibacterial time, further increase antibacterial and deodouring effect of footwear material；And And the polyolefin elastomer for using is at normal temperatures into caoutchouc elasticity, with density it is small, bending is big, low-temperature impact resistance is high, easy Processing, it is reusable the features such as, the service life of footwear material can be extended.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
The present invention provides a kind of technical scheme：A kind of deodorant footwear material of Elastic, footwear material is by following weight Raw material processing is formed：Natural rubber 30-60 parts, PEPA 10-20 parts, white carbon 3-10 parts, sodium alginate 2-6 parts, it is poly- Olefin elastomer 6-12 parts, calcium carbonate 20-40 parts, bamboo-carbon fibre 10-20 parts, chitin fiber 10-20 parts, antioxidant 7-12 Part, 10-15 parts of nano silicone micro mist, 3-10 parts, angelica essential oil 1-4 parts and ethanol solution 10-20 parts of nano-silver ionic powder.
Embodiment one：
Footwear material is formed by the Raw material processing of following weight：30 parts of natural rubber, 10 parts of PEPA, white carbon 3 Part, 2 parts of sodium alginate, 6 parts of polyolefin elastomer, 20 parts of calcium carbonate, 10 parts of bamboo-carbon fibre, 10 parts of chitin fiber, antioxidant 7 Part, 10 parts of nano silicone micro mist, 3 parts of nano-silver ionic powder, 1 part of angelica essential oil and 10 parts of ethanol solution.
The preparation method of the present embodiment is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1000 revs/min, and mixing time is 20min, stands mixed afterwards Compound A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 180 DEG C, and the reaction time is 10min, is slowly cooled to room temperature afterwards, is mixed Compound B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 30min at normal temperatures Afterwards, 1h is stood, that is, obtains Elastic deodoring materials.
Embodiment two：
Footwear material is formed by the Raw material processing of following weight：60 parts of natural rubber, 20 parts of PEPA, white carbon 10 Part, 6 parts of sodium alginate, 12 parts of polyolefin elastomer, 40 parts of calcium carbonate, 20 parts of bamboo-carbon fibre, 20 parts of chitin fiber, antioxidant 20 parts of 12 parts, 15 parts of nano silicone micro mist, 10 parts of nano-silver ionic powder, 4 parts of angelica essential oil and ethanol solution.
The preparation method of the present embodiment is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 2000 revs/min, and mixing time is 30min, stands mixed afterwards Compound A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 220 DEG C, and the reaction time is 20min, is slowly cooled to room temperature afterwards, is mixed Compound B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 40min at normal temperatures Afterwards, 1h is stood, that is, obtains Elastic deodoring materials.
Embodiment three：
Footwear material is formed by the Raw material processing of following weight：40 parts of natural rubber, 12 parts of PEPA, white carbon 5 Part, 3 parts of sodium alginate, 7 parts of polyolefin elastomer, 25 parts of calcium carbonate, 12 parts of bamboo-carbon fibre, 12 parts of chitin fiber, antioxidant 8 Part, 11 parts of nano silicone micro mist, 4 parts of nano-silver ionic powder, 2 parts of angelica essential oil and 12 parts of ethanol solution.
The preparation method of the present embodiment is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1200 revs/min, and mixing time is 22min, stands mixed afterwards Compound A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 190 DEG C, and the reaction time is 12min, is slowly cooled to room temperature afterwards, is mixed Compound B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 32min at normal temperatures Afterwards, 1h is stood, that is, obtains Elastic deodoring materials.
Example IV：
Footwear material is formed by the Raw material processing of following weight：50 parts of natural rubber, 18 parts of PEPA, white carbon 8 Part, 5 parts of sodium alginate, 11 parts of polyolefin elastomer, 35 parts of calcium carbonate, 18 parts of bamboo-carbon fibre, 18 parts of chitin fiber, antioxidant 18 parts of 11 parts, 14 parts of nano silicone micro mist, 9 parts of nano-silver ionic powder, 3 parts of angelica essential oil and ethanol solution.
The preparation method of the present embodiment is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1800 revs/min, and mixing time is 28min, stands mixed afterwards Compound A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 210 DEG C, and the reaction time is 18min, is slowly cooled to room temperature afterwards, is mixed Compound B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 38min at normal temperatures Afterwards, 1h is stood, that is, obtains Elastic deodoring materials.
Embodiment five：
Footwear material is formed by the Raw material processing of following weight：45 parts of natural rubber, 15 parts of PEPA, white carbon 7 Part, 4 parts of sodium alginate, 9 parts of polyolefin elastomer, 30 parts of calcium carbonate, 15 parts of bamboo-carbon fibre, 15 parts of chitin fiber, antioxidant 15 parts of 10 parts, 12 parts of nano silicone micro mist, 7 parts of nano-silver ionic powder, 3 parts of angelica essential oil and ethanol solution.
The preparation method of the present embodiment is comprised the following steps：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1500 revs/min, and mixing time is 25min, stands mixed afterwards Compound A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 200 DEG C, and the reaction time is 15min, is slowly cooled to room temperature afterwards, is mixed Compound B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 35min at normal temperatures Afterwards, 1h is stood, that is, obtains Elastic deodoring materials.
Footwear material prepared by the present invention has deodorizing sterilizing effect thoroughly, and the function duration is long, and human body is had no side effect, peace Full health, it is easy to the features such as making；In addition, being added with nano silicone micro mist, nano-silver ionic powder in the present invention, can extend anti- The bacterium time, further increase antibacterial and deodouring effect of footwear material；And the polyolefin elastomer for using is at normal temperatures into rubber bullet Property, with density is small, bending big, low-temperature impact resistance high, easy processing, it is reusable the features such as, footwear material can be extended Service life.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (3)

1. the deodorant footwear material of a kind of Elastic, it is characterised in that：The footwear material is by the Raw material processing of following weight Into：Natural rubber 30-60 parts, PEPA 10-20 parts, white carbon 3-10 parts, sodium alginate 2-6 parts, polyolefin elastomer 6-12 parts, calcium carbonate 20-40 parts, bamboo-carbon fibre 10-20 parts, chitin fiber 10-20 parts, antioxidant 7-12 parts, nano silicone Micro mist 10-15 parts, 3-10 parts, angelica essential oil 1-4 parts and ethanol solution 10-20 parts of nano-silver ionic powder.
2. the deodorant footwear material of a kind of Elastic according to claim 1, it is characterised in that：The preferred composition of footwear material is matched somebody with somebody Than including：45 parts of natural rubber, 15 parts of PEPA, 7 parts of white carbon, 4 parts of sodium alginate, 9 parts of polyolefin elastomer, carbonic acid 30 parts of calcium, 15 parts of bamboo-carbon fibre, 15 parts of chitin fiber, 10 parts of antioxidant, 12 parts of nano silicone micro mist, nano-silver ionic powder 7 15 parts of part, 3 parts of angelica essential oil and ethanol solution.
3. the deodorant footwear material of a kind of Elastic according to claim 1, it is characterised in that：Its preparation method includes following step Suddenly：
A, PEPA, white carbon, sodium alginate, polyolefin elastomer, calcium carbonate, bamboo-carbon fibre, chitin fiber are mixed It is stirred in addition mixer after conjunction, mixer rotating speed is 1000-2000 revs/min, and mixing time is 20min-30min, it Stand afterwards and obtain mixture A；
B, addition natural rubber, antioxidant, nano silicone micro mist and 1/2 ethanol solution in mixture A, add high after mixing Reacted in pressure reactor, reaction temperature is 180 DEG C -220 DEG C, and the reaction time is 10min-20min, is slowly cooled to afterwards Room temperature, obtains mixture B；
C, addition nano-silver ionic powder, angelica essential oil and 1/2 ethanol solution in mixture B, react 30min- at normal temperatures After 40min, 1h is stood, that is, obtain Elastic deodoring materials.
CN201710042010.5A 2017-01-20 2017-01-20 A kind of deodorant footwear material of Elastic Pending CN106750606A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107411218A (en) * 2017-06-02 2017-12-01 安徽爱舍家居制品有限公司 One kind has high tenacity and sterilizing function slippers and its manufacture method
CN108641322A (en) * 2018-05-29 2018-10-12 赛纳（苏州）安防用品有限公司 A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof
CN110511452A (en) * 2019-10-14 2019-11-29 福建五持恒科技发展有限公司 Graphene natural rubber macromolecule control bacterium mixed foaming material and preparation method thereof
CN112746335A (en) * 2020-12-25 2021-05-04 云南汉盟制药有限公司 Preparation method of industrial hemp fiber powder and composite foam material and antibacterial composite insole
CN113502005A (en) * 2021-07-30 2021-10-15 苏州远浩新纺织科技有限公司 Antibacterial and deodorant lining material for shoes and preparation method thereof

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CN103694501A (en) * 2013-11-25 2014-04-02 安徽淮化股份有限公司 Elastic antimicrobial deodorizing sole material
CN106189191A (en) * 2016-07-14 2016-12-07 安徽亳州喜宝鞋服有限公司 A kind of polyurethane material of high-strength high-elasticity for footwear material and preparation method thereof

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CN103694501A (en) * 2013-11-25 2014-04-02 安徽淮化股份有限公司 Elastic antimicrobial deodorizing sole material
CN106189191A (en) * 2016-07-14 2016-12-07 安徽亳州喜宝鞋服有限公司 A kind of polyurethane material of high-strength high-elasticity for footwear material and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107411218A (en) * 2017-06-02 2017-12-01 安徽爱舍家居制品有限公司 One kind has high tenacity and sterilizing function slippers and its manufacture method
CN108641322A (en) * 2018-05-29 2018-10-12 赛纳（苏州）安防用品有限公司 A kind of nano silver fibre, graphene composite material degerming toe-cap and preparation method thereof
CN110511452A (en) * 2019-10-14 2019-11-29 福建五持恒科技发展有限公司 Graphene natural rubber macromolecule control bacterium mixed foaming material and preparation method thereof
CN112746335A (en) * 2020-12-25 2021-05-04 云南汉盟制药有限公司 Preparation method of industrial hemp fiber powder and composite foam material and antibacterial composite insole
CN113502005A (en) * 2021-07-30 2021-10-15 苏州远浩新纺织科技有限公司 Antibacterial and deodorant lining material for shoes and preparation method thereof

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