CN107057137A - A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial - Google Patents
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial Download PDFInfo
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- CN107057137A CN107057137A CN201710409837.5A CN201710409837A CN107057137A CN 107057137 A CN107057137 A CN 107057137A CN 201710409837 A CN201710409837 A CN 201710409837A CN 107057137 A CN107057137 A CN 107057137A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/12—Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
- B29D35/122—Soles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/12—Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
- B29D35/126—Uppers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
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Abstract
The present invention provides a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, it is related to daily necessities field, the preparation method of the art and craft slippers is weighed including raw material, dispensing kneading, pulling-on piece of plasticating, is molded embryo processed, heat treatment and is punched and assemble six big steps, and the art and craft slippers are prepared from the following raw materials in parts by weight：50 70 parts of thermoplastic elastomer (TPE), 57 parts of benzyl normal-butyl phthalic acid ester, N, 13 parts of N methylene-bisacrylamides, 0.3 1 parts of fatty acid amide, 23 parts of epoxy resin, 15 parts of maleic anhydride, 12 parts of phosphorous vinegar, 25 parts of stearic acid, 13 parts of glass fibre, 12 parts of shellac, 0.2 1 parts of cellulose powder, 25 parts of silver ion class antiseptic, 0.2 0.5 parts of zinc oxide, 12 parts of ammonium dihydrogen phosphate, 5 15 parts of auxiliary agent, not only elasticity is high for the art and craft slippers, it is comfortable and easy to wear, the features such as also having sterilization, moistureproof, absorbing sweat and deodorization, the present invention is practical.
Description
Technical field
The present invention relates to daily necessities field, and in particular to a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial.
Background technology
With the raising of human living standard, the requirement of footwear also increasingly increases, meanwhile, the footwear art of the mankind is also more next
Finer, slippers are the shoes of residential use, therefore, to the comfortableness of footwear, exterior quality, it is environment-friendly in terms of propose more
There is the contradiction between resilience and hardness in high requirement, at present, common LDPE, EVA shoe bottom foamed material, usual hardness is low,
Resilience is high, or hardness is high, and resilience is low, and compression set is larger, and wearability and folding resistance be not good, wrinkle resistant and texture
It is undesirable.
The species of slipper sole material is a lot, is generally divided into natural class slipper sole material and synthesis class slipper sole material
Two kinds, natural class slipper sole material includes natural bottom leather, bamboo and wood material etc., and synthesis class slipper sole material includes rubber, PU materials
Material, PVC synthetic resin etc., the common characteristic of slipper sole material possess wear-resisting, water-fast, elastic good, easily suitable foot type, sizing
After the condition such as be unlikely to deform, synthesis class slipper sole material is most widely used class footwear material at present.
Almost also possesses the function of antibacterial without material for sole of shoe at present, because foot easily perspires, pin is easy to by bacterium
Infection, people can usually spray sterilization ointment, and sweat can substantially reduce the drug effect of sterilization ointment, therefore, and exploitation one kind has
High resiliency and composite foam material with biocidal efficacies are the targets that enterprise is pursued, and not only elasticity is high for the material, comfortable and easy to wear,
And the features such as with antibacterial, absorbing sweat, protection against the tide, deodorization, can be widely applied to manufacture beach shoes, slippers, the footwear material such as sport footwear neck
Domain.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, make
Slippers not only elasticity is high, it is comfortable and easy to wear, also with sterilization, moistureproof, deodorization and absorbing sweat the features such as.
To realize object above, the present invention is achieved by the following technical programs：
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, comprises the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：The adjacent benzene of 50-70 parts of thermoplastic elastomer (TPE), benzyl normal-butyl
5-7 parts of dicarboxylic acid esters, 1-3 parts of N,N methylene bis acrylamide, 0.3-1 parts of fatty acid amide, 2-3 parts of epoxy resin, Malaysia
1-5 parts of acid anhydrides, 1-2 parts of phosphorous vinegar, 2-5 parts of stearic acid, 1-3 parts of glass fibre, 1-2 parts of shellac, 0.2-1 parts of cellulose powder,
5-15 parts of 2-5 parts of silver ion class antiseptic, 0.2-0.5 parts of zinc oxide, 1-2 parts of ammonium dihydrogen phosphate and auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, the positive fourth of benzyl is slow added into
Base phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, mediates 45-60min
After discharge；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then piece is weighed by die cavity capacity
Material, and mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 10- is carried out at 160-170 DEG C
50 DEG C of sizing 20min are cooled to after 20min, plasticizing, then are stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：Embryo material is put into steam-heated 100-130 DEG C of drying room, taken out after 10-15min, by embryo material
It is parked in storehouse one week, then is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, and then will be dragged
Footwear sole perforating, climbs after band assembling with slippers, produces art and craft slippers.
Preferably, the thermoplastic elastomer (TPE) is the BR/PVC/SBS ternary thermoplastic elastomer (TPE)s of complete dynamic vulcanization.
Preferably, the mass ratio of the benzyl normal-butyl phthalic acid ester and thermoplastic elastomer (TPE) is 1:10.
Preferably, the auxiliary agent is mixed by the raw material of following parts by weight：1-5 parts of magnesium class coupling agent, stabilized metal
4-8 parts of agent, 1-5 parts of phosphorous acid, 2-7 parts of foaming agent, 3-7 parts of deodorant.
Preferably, the fire retardant is APP, carbon black, graphite powder in mass ratio 10:1:1 mixes.
Preferably, the preparation method of the deodorant is：Folium artemisiae argyi, alum, the root of Dahurain angelica, borneol, the mixture of agalloch eaglewood and lemongrass
After being cooked by slow fire 10h, filtering, soup, which is dried, to be concentrated into thick, is produced.
The beneficial effects of the invention are as follows：
The invention provides a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, antiseptic is silver ion class antibacterial
Agent, by physical absorption ion exchange principle, has synergy, the addition of ammonium dihydrogen phosphate can improve silver ion with zinc oxide
The synergy of class antiseptic and zinc oxide so that product good anti-bacterial effect；In process of production, thermoplastic elastomer (TPE) is in two times
Add, plasticizer is slowly added to, be, in order to avoid caking after disposable input thermoplastic elastomer (TPE) and plasticizer, to cause kneader
Startup load it is excessive, thermoplastic elastomer (TPE) is added in two times, is also beneficial to be uniformly dispersed between material each component so that product bullet
Property it is high.
There is the effect for cooperateing with and promoting to imitate, metallic stabilizer can prolong to a certain extent between metallic stabilizer and phosphorous vinegar
Slow phosphorous vinegar thermal decomposition, suppresses HCl generation, significantly improves the stability and elasticity of product；Fire retardant is APP, carbon
The mixture of black and graphite powder, with cooperative flame retardant suppression cigarette effect so that product has anti-flammability；Phosphorous acid and deodorant make
With so that the features such as product has moistureproof, deodorization and absorbing sweat.
The invention provides a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, not only elasticity is high for the art and craft slippers,
It is comfortable and easy to wear, also with sterilization, moistureproof, absorbing sweat and deodorization the features such as, the present invention is practical.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1：
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, comprises the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：The BR/PVC/SBS ternary thermoplasticity of complete dynamic vulcanization
50 parts of elastomer, 5 parts of benzyl normal-butyl phthalic acid ester, 3 parts of N,N methylene bis acrylamide, 1 part of fatty acid amide, ring
2 parts of oxygen tree fat, 1 part of maleic anhydride, 2 parts of phosphorous vinegar, 5 parts of stearic acid, 1 part of glass fibre, 2 parts of shellac, cellulose powder 0.2
Part, 5 parts of silver ion class antiseptic, 0.2 part of zinc oxide, 2 parts of ammonium dihydrogen phosphate and 5 parts of auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, the positive fourth of benzyl is slow added into
Base phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, mediates after 45min
Discharging；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then piece is weighed by die cavity capacity
Material, and mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 10min, plasticizing are carried out at 170 DEG C
After be cooled to 50 DEG C of sizing 20min, then be stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：In the drying room that embryo material is put into steam-heated 100 DEG C, taken out after 15min, embryo material is parked in
One week in storehouse, then it is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, and then will be dragged
Footwear sole perforating, climbs after band assembling with slippers, produces art and craft slippers.
Wherein, auxiliary agent is mixed by the raw material of following parts by weight：1 part of magnesium class coupling agent, 4 parts of metallic stabilizer, Asia
Phosphatase 11 part, 7 parts of foaming agent, 3 parts of deodorant；Fire retardant is APP, carbon black, graphite powder in mass ratio 10:1:1 mixing and
Into；The preparation method of deodorant is：Folium artemisiae argyi, alum, the root of Dahurain angelica, borneol, agalloch eaglewood and lemongrass mixture after being cooked by slow fire 10h, mistake
Filter, soup, which is dried, to be concentrated into thick, is produced.
Embodiment 2：
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, comprises the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：The BR/PVC/SBS ternary thermoplasticity of complete dynamic vulcanization
70 parts of elastomer, 7 parts of benzyl normal-butyl phthalic acid ester, 1 part of N,N methylene bis acrylamide, 0.3 part of fatty acid amide,
3 parts of epoxy resin, 5 parts of maleic anhydride, 1 part of phosphorous vinegar, 2 parts of stearic acid, 3 parts of glass fibre, 1 part of shellac, cellulose powder 1
Part, 2 parts of silver ion class antiseptic, 0.5 part of zinc oxide, 1 part of ammonium dihydrogen phosphate and 15 parts of auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, the positive fourth of benzyl is slow added into
Base phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, mediates after 60min
Discharging；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then piece is weighed by die cavity capacity
Material, and mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 20min, plasticizing are carried out at 160 DEG C
After be cooled to 50 DEG C of sizing 20min, then be stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：In the drying room that embryo material is put into steam-heated 130 DEG C, taken out after 10min, embryo material is parked in
One week in storehouse, then it is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, and then will be dragged
Footwear sole perforating, climbs after band assembling with slippers, produces art and craft slippers.
Wherein, auxiliary agent is mixed by the raw material of following parts by weight：5 parts of magnesium class coupling agent, 8 parts of metallic stabilizer, Asia
5 parts of phosphoric acid, 2 parts of foaming agent, 7 parts of deodorant；Fire retardant is APP, carbon black, graphite powder in mass ratio 10:1:1 mixing and
Into；The preparation method be the same as Example 1 of deodorant.
Embodiment 3：
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, comprises the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：The BR/PVC/SBS ternary thermoplasticity of complete dynamic vulcanization
60 parts of elastomer, 6 parts of benzyl normal-butyl phthalic acid ester, 2 parts of N,N methylene bis acrylamide, 0.4 part of fatty acid amide,
2.5 parts of epoxy resin, 3 parts of maleic anhydride, 1.5 parts of phosphorous vinegar, 4 parts of stearic acid, 2 parts of glass fibre, 1.5 parts of shellac, fiber
10 parts of plain 0.7 part of powder, 3 parts of silver ion class antiseptic, 0.4 part of zinc oxide, 1.5 parts of ammonium dihydrogen phosphate and auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, the positive fourth of benzyl is slow added into
Base phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, mediates after 50min
Discharging；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then piece is weighed by die cavity capacity
Material, and mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 15min, plasticizing are carried out at 165 DEG C
After be cooled to 50 DEG C of sizing 20min, then be stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：In the drying room that embryo material is put into steam-heated 120 DEG C, taken out after 13min, embryo material is parked in
One week in storehouse, then it is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, and then will be dragged
Footwear sole perforating, climbs after band assembling with slippers, produces art and craft slippers.
Wherein, auxiliary agent is mixed by the raw material of following parts by weight：3 parts of magnesium class coupling agent, 6 parts of metallic stabilizer, Asia
3 parts of phosphoric acid, 5 parts of foaming agent, 4 parts of deodorant；Fire retardant is APP, carbon black, graphite powder in mass ratio 10:1:1 mixing and
Into；The preparation method be the same as Example 1 of deodorant.
Embodiment 4：
A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, comprises the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：The BR/PVC/SBS ternary thermoplasticity of complete dynamic vulcanization
55 parts of elastomer, 5.5 parts of benzyl normal-butyl phthalic acid ester, 3 parts of N,N methylene bis acrylamide, fatty acid amide 0.4
Part, 2 parts of epoxy resin, 4 parts of maleic anhydride, 1.5 parts of phosphorous vinegar, 3 parts of stearic acid, 2.5 parts of glass fibre, 2 parts of shellac, fiber
15 parts of plain 0.4 part of powder, 3.5 parts of silver ion class antiseptic, 0.3 part of zinc oxide, 2 parts of ammonium dihydrogen phosphate and auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, the positive fourth of benzyl is slow added into
Base phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, mediates after 45min
Discharging；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then piece is weighed by die cavity capacity
Material, and mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 20min, plasticizing are carried out at 165 DEG C
After be cooled to 50 DEG C of sizing 20min, then be stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：In the drying room that embryo material is put into steam-heated 115 DEG C, taken out after 15min, embryo material is parked in
One week in storehouse, then it is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, and then will be dragged
Footwear sole perforating, climbs after band assembling with slippers, produces art and craft slippers.
Wherein, auxiliary agent is mixed by the raw material of following parts by weight：2 parts of magnesium class coupling agent, 5 parts of metallic stabilizer, Asia
3 parts of phosphoric acid, 6 parts of foaming agent, 4 parts of deodorant；Fire retardant is APP, carbon black, graphite powder in mass ratio 10:1:1 mixing and
Into；The preparation method be the same as Example 1 of deodorant.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those
Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a kind of preparation method of the art and craft slippers of High-elasticity antimicrobial, it is characterised in that comprise the following steps：
(1) raw material is weighed：Each raw material is weighed by formula as below amount：50-70 parts of thermoplastic elastomer (TPE), benzyl normal-butyl O-phthalic
5-7 parts of acid esters, 1-3 parts of N,N methylene bis acrylamide, 0.3-1 parts of fatty acid amide, 2-3 parts of epoxy resin, maleic anhydride
1-5 parts, 1-2 parts of phosphorous vinegar, 2-5 parts of stearic acid, 1-3 parts of glass fibre, 1-2 parts of shellac, 0.2-1 parts of cellulose powder, silver from
5-15 parts of 2-5 parts of subclass antiseptic, 0.2-0.5 parts of zinc oxide, 1-2 parts of ammonium dihydrogen phosphate and auxiliary agent, it is standby；
(2) dispensing is mediated：The thermoplastic elastomer (TPE) of formula ratio half is added into kneader, benzyl normal-butyl is slow added into adjacent
Phthalic acid ester, is subsequently added into surplus stock, carries out heating kneading in the case where steam pressure is 0.3MPa, goes out after mediating 45-60min
Material；
(3) plasticate pulling-on piece：Compound after kneading is put into twin-roll plastic mixing mill, pulling-on piece of plasticating is carried out at 135 DEG C；
(4) it is molded embryo processed：The piece for post-tensioning of plasticating is subjected to punching by model and obtains sheet stock, then sheet stock is weighed by die cavity capacity, and
Mould is put into, then the mould equipped with sheet stock is put into hot press, heating plasticizing 10-20min, modeling are carried out at 160-170 DEG C
50 DEG C of sizing 20min are cooled to after change, then are stripped taking-up, the embryo material as plastified；
(5) it is heat-treated：Embryo material is put into steam-heated 100-130 DEG C of drying room, is taken out after 10-15min, embryo material is parked
One week in storehouse, then it is punched；
(6) punching assembling：The specification requirement that embryo material is climbed into band by slipper sole and slippers is punched, then by slipper
Bottom perforating, climbs after band assembling with slippers, produces art and craft slippers.
2. the preparation method of the art and craft slippers of High-elasticity antimicrobial as claimed in claim 1, it is characterised in that the thermoplastic elastomehc
Property body be complete dynamic vulcanization BR/PVC/SBS ternary thermoplastic elastomer (TPE)s.
3. the preparation method of the art and craft slippers of High-elasticity antimicrobial as claimed in claim 1, it is characterised in that the positive fourth of benzyl
The mass ratio of base phthalic acid ester and thermoplastic elastomer (TPE) is 1:10.
4. the preparation method of the art and craft slippers of High-elasticity antimicrobial as claimed in claim 1, it is characterised in that the auxiliary agent by with
The raw material of lower parts by weight is mixed：1-5 parts of magnesium class coupling agent, 4-8 parts of metallic stabilizer, 1-5 parts of phosphorous acid, fire retardant 2-
7 parts, 3-7 parts of deodorant.
5. the preparation method of the art and craft slippers of High-elasticity antimicrobial as claimed in claim 4, it is characterised in that the fire retardant is
APP, carbon black, graphite powder in mass ratio 10:1:1 mixes.
6. the preparation method of the art and craft slippers of High-elasticity antimicrobial as claimed in claim 4, it is characterised in that the deodorant
Preparation method is：Folium artemisiae argyi, alum, the root of Dahurain angelica, borneol, agalloch eaglewood and lemongrass mixture after being cooked by slow fire 10h, filtering, soup is dried
It is concentrated into thick, produces.
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| CN201710409837.5A CN107057137A (en) | 2017-06-02 | 2017-06-02 | A kind of preparation method of the art and craft slippers of High-elasticity antimicrobial |
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| CN110423399A (en) * | 2019-07-25 | 2019-11-08 | 福建省莆田市双源鞋业有限公司 | A kind of deodorizing sole and its processing method |
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