CN108636101A - A kind of sterilizing deodoring agent and preparation method thereof and the application in aerosol - Google Patents
A kind of sterilizing deodoring agent and preparation method thereof and the application in aerosol Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
The invention belongs to eliminating smell agent preparing technical fields, and in particular to a kind of sterilizing deodoring agent and preparation method thereof and the application in aerosol.The sterilizing deodoring agent is made of the modified porous titanium dioxide of nano-silver ionic, the modified porous zirconium dioxide of nano-silver ionic, parachlorometaxylenol, zinc ricinate, small molecule water-based acrylic resin, glycerine, water, Tween 80, sodium xylene sulfonate, iso-octyl polyoxyethylene ether, triethanolamine, sodium metasilicate, sodium benzoate, calgon, sodium citrate and tasteless ethyl alcohol.Its sterilizing rate is up to 92%~99.9%, and smell-removing rate is up to 90%~100%, can solve Peculiar Smell from source, function and effect are lasting.In addition, its corresponding sterilizing deodoring aerosol application method is simple, the effect of sterilizing deodoring can reach after 20 min.
Description
Technical field
The invention belongs to eliminating smell agent preparing technical fields, and in particular to a kind of sterilizing deodoring agent and preparation method thereof in gas
Application in mist agent.
Background technology
It is toxic that the new car car just bought can have various peculiar smell, including formaldehyde, benzene, the acetone of the release of various plastic products etc.
Pernicious gas and TVOC etc..In addition, the interior being used for a long time can also have a various peculiar smell, such as smoke, vinosity, food taste and
The musty etc. generated by humidity.These peculiar smell not only influence people’s lives impression, but will generate shadow to the health of people
It rings.
Existing automobile eliminating smell agent generally uses covering type deodorizing method, is specifically covered using the essence of high concentration different
Taste, but run counter to desire sometimes, essence not only covers incessantly peculiar smell, forms a kind of more niff with peculiar smell instead.Therefore this
Mode efficiency is low, and Peculiar Smell cannot be solved on source.
Invention content
The shortcomings that overcome the prior art and deficiency, primary and foremost purpose of the invention are to provide a kind of sterilizing deodoring agent.
It is a further object of the present invention to provide a kind of preparation methods of above-mentioned sterilizing deodoring agent.
Another object of the present invention is to provide application of the above-mentioned sterilizing deodoring agent in aerosol.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of sterilizing deodoring agent is made of following raw material by mass percentage：The modified porous dioxy of nano-silver ionic
Change titanium 0.01%~5%, the modified porous zirconium dioxide 0.01%~5% of nano-silver ionic, parachlorometaxylenol 1%~
10%, zinc ricinate 1%~10%, small molecule water-based acrylic resin 1%~10%, glycerine 5%~20%, tasteless second
Alcohol 40%~80%, Tween 80 0.1%~5%, sodium xylene sulfonate 0.1%~5%, iso-octyl polyoxyethylene ether 1%~
5%, triethanolamine 0.1%~2%, sodium metasilicate 0.1%~2%, sodium benzoate 0.1%~2%, calgon 0.1%~
1%, sodium citrate 0.1%~1% and water are surplus, and above-mentioned raw materials add up to 100%.
The modified porous titanium dioxide of the nano-silver ionic and the modified porous zirconium dioxide of nano-silver ionic are with reference to patent
《A kind of zirconium dioxide photochemical catalyst of Ag doping and its preparation method and application》(application number：201410708337.8) described in
Method is prepared.
The modified porous titanium dioxide of the nano-silver ionic has multi-pore channel, can adsorb malodor molecules, and can be can
It is sterilized under the action of light-exposed, the surface of titanium dioxide has nano-silver ionic, also plays sterilization.Further, since same
Identical charges repel each other the effect of kind of charge, makes titanium dioxide not send out into aggregation, is in evenly dispersed shape.
The modified porous zirconium dioxide of the nano-silver ionic has and the modified porous titanium dioxide of above-mentioned nano-silver ionic
Identical effect.
Described is a kind of efficient fungicide to chlorine Resorcino, can kill most of bacterium.
The zinc ricinate is a kind of taste removal chemicals based on chemical reaction.
The molecular weight of the small molecule water-based acrylic resin is 1700, is bought from BASF JONCRYL682.By institute
When the small molecule water-based acrylic resin stated is sprayed on object, one layer of sightless film of naked eyes can be formed, object can be made
The malodor molecules on surface will not be spread out, and the sterilizing deodoring ingredient on film can remove malodor molecules with snap action.
The tasteless ethyl alcohol is for dissolving to chlorine Resorcino and zinc ricinate.
The evaporation rate of the glycerine is slower, holding sterilizing deodoring effect that can be lasting.
The Tween 80 is a kind of nonionic surfactant, can solubilising to chlorine Resorcino and zinc ricinate,
Reach the state of feed liquid stabilization.
The sodium xylene sulfonate is a kind of anion surfactant, can be solubilized to chlorine Resorcino and castor oil
Sour zinc reaches the state of feed liquid stabilization.
The iso-octyl polyoxyethylene ether is a kind of nonionic surfactant, there is very low surface tension, can be fast
Speed wetting body surface, reaches osmotic effect, the effect of feed liquid is made preferably to bring into play.
Preferably, the water is deionized water.
Preferably, the sterilizing deodoring agent is made of following raw material by mass percentage：Nano-silver ionic is modified more
The modified porous zirconium dioxide 0.5%~2.5% of porous titanium dioxide 0.5%~2.5%, nano-silver ionic, parachlorometaxylenol
1.5%~4%, zinc ricinate 1%~5%, small molecule water-based acrylic resin 3%~7%, glycerine 10%~20%,
Tasteless ethyl alcohol 45%~60%, Tween 80 0.4%~2%, sodium xylene sulfonate 0.4%~2%, iso-octyl polyoxyethylene ether
1%~3.5%, triethanolamine 0.1%~2%, sodium metasilicate 0.1%~2%, sodium benzoate 0.1%~2%, calgon
0.1%~1%, sodium citrate 0.1%~1% and water are surplus, and above-mentioned raw materials add up to 100%.
Preferably, in the sterilizing deodoring agent, the mass ratio of tasteless ethyl alcohol and deionized water is 3:2~3:1.At this point, institute
The sterilizing deodoring agent stated has preferable bactericidal effect.
It is furthermore preferred that the sterilizing deodoring agent is made of following raw material by mass percentage：Nano-silver ionic is modified
The modified porous zirconium dioxide 1.5% of poriferous titanium dioxide 1.5%, nano-silver ionic, parachlorometaxylenol 2.5%, castor oil
Sour zinc 3%, small molecule water-based acrylic resin 5%, glycerine 10%, tasteless ethyl alcohol 46%, Tween 80 1%, xylene monosulfonic acid
Sodium 1%, iso-octyl polyoxyethylene ether 2%, triethanolamine 0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, hexa metaphosphoric acid
Sodium 0.25%, sodium citrate 0.25% and water are surplus, and above-mentioned raw materials add up to 100%.
Gained scavenger is milky, has alcohol smell.
The present invention further provides a kind of preparation methods of above-mentioned sterilizing deodoring agent, include the following steps：
(1) calgon and sodium citrate are added in deionized water, stirring and dissolving obtains solution A；
(2) triethanolamine, sodium metasilicate and sodium benzoate are added in solution A, stirring and dissolving obtains solution B；
(3) small molecule water-based acrylic resin is added in solution B, stirring and dissolving obtains solution C；
(4) Tween 80, sodium xylene sulfonate are added in solution C, stirring and dissolving obtains solution D；
(5) iso-octyl polyoxyethylene ether is added in solution D, stirring and dissolving obtains solution E；
(6) tasteless ethyl alcohol and glycerine are mixed, stirs evenly, obtains solution F；
(7) by the modified porous titanium dioxide of nano-silver ionic, the modified porous zirconium dioxide of nano-silver ionic, the diformazan between chlorine
Phenol and zinc ricinate are added in solution F, and stirring and dissolving obtains solution G；
(8) solution E and solution G are mixed, is stirred evenly to get to the sterilizing deodoring agent.
Preferably, stirring and dissolving condition described in step (1) be 1500~3000r/s, temperature be 20~40 DEG C, when it is a length of
5~20min.
Preferably, stirring and dissolving condition described in step (2) be 1500~3000r/s, temperature be 20~40 DEG C, when it is a length of
5~20min.
Preferably, stirring and dissolving condition described in step (3) be 3500~6000r/s, temperature be 20~40 DEG C, when it is a length of
10~30min.
Preferably, stirring and dissolving condition described in step (4) be 500~2000r/s, temperature be 20~40 DEG C, when it is a length of
20~40min.
Preferably, stirring and dissolving condition described in step (5) be 1500~3000r/s, temperature be 20~40 DEG C, when it is a length of
10~30min.
Preferably, stirring condition described in step (6) is 400~600r/s, and temperature is 20~40 DEG C, when it is a length of 5~
20min。
Preferably, stirring and dissolving condition described in step (7) be 500~2000r/s, temperature be 20~40 DEG C, when it is a length of
10~30min.
Preferably, stirring condition described in step (8) is 500~2000r/s, and temperature is 20~40 DEG C, when it is a length of 5~
20min。
The present invention further provides application of the sterilizing deodoring agent in sterilizing deodoring aerosol.
A kind of sterilizing deodoring aerosol, the aerosol are made of propellant and above-mentioned sterilizing deodoring agent.
Preferably, the propellant is made of propane and butane.
It is furthermore preferred that the mass ratio of the propane and butane is 2:3.
Preferably, the propellant and the mass ratio of sterilizing deodoring agent are:0.1:1~1:1.
It is furthermore preferred that the propellant and the mass ratio of sterilizing deodoring agent are:0.4:1~1:1.
Compared with prior art, the present invention having the following advantages that and advantageous effect：
(1) the sterilizing deodoring agent prepared in the present invention utilizes the modified porous titanium dioxide of nano-silver ionic and nano-silver ionic
Absorption and decomposition function of the modified porous zirconium dioxide to malodor molecules, in conjunction with the chemical taste removal of zinc ricinate and two between chlorine
The efficient sterilizing function of cresols makes the sterilizing deodoring agent of preparation have both the effect of sterilization and taste removal.Thus obtained sterilization removes
Taste agent sterilizing rate is up to 92%~99.9%, and smell-removing rate is up to 90%~100%.The sterilizing deodoring agent and traditional essence class taste removal
Agent is compared, efficient, can solve Peculiar Smell from source, function and effect are lasting.
(2) the small molecule water-based acrylic resin that the sterilizing deodoring agent for preparing uses in the present invention can on malodor molecules shape
At film, malodor molecules is made to be not easy to spread, to accelerate the effect process of sterilizing deodoring.The sterilizing deodoring agent prepared in the present invention
The glycerine and Tween 80 of use are nonionic surfactants, can solubilized parachlorometaxylenol and zinc ricinate, stablize
Feed liquid.In addition, use iso-octyl polyoxyethylene ether surface tension it is low, can quick humidification body surface, reach osmotic effect, make
The effect of sterilizing deodoring agent more preferably plays.
(3) preparation method of sterilizing deodoring agent is simple in the present invention, is conducive to industrialized production.
(4) the sterilizing deodoring aerosol application method that the present invention obtains is simple, has no toxic side effect, to using object to spray
Afterwards, it can reach the effect of sterilizing deodoring after 20 min.
Specific implementation mode
The present invention is described in further detail with reference to embodiment, embodiments of the present invention are not limited thereto.
For not specifically specified technological parameter, routine techniques progress can refer to.
Embodiment 1
The present embodiment provides a kind of sterilizing deodoring agent and preparation method thereof：
The group of sterilizing deodoring agent in the present embodiment becomes：The modified porous titanium dioxide 0.5% of nano-silver ionic, nano silver
Ion modification porous zirconium dioxide 0.5%, parachlorometaxylenol 4%, zinc ricinate 5%, small molecule water soluble acrylic acid tree
Fat 3%, glycerine 11%, Tween 80 0.4%, sodium xylene sulfonate 0.4%, iso-octyl polyoxyethylene ether 0.5%, three ethyl alcohol
Amine 0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, calgon 0.25%, sodium citrate 0.25%, tasteless ethyl alcohol
25% and deionized water be surplus, above-mentioned raw materials add up to 100%.
Preparation process is as follows：
(1) calgon and sodium citrate are added in deionized water, 5min is stirred under the conditions of 2000r/s and 30 DEG C
Make dissolving, obtains solution A；
(2) triethanolamine, sodium metasilicate and sodium benzoate are added in solution A, are stirred under the conditions of 2000r/s and 30 DEG C
5min makes dissolving, obtains solution B；
(3) small molecule water-based acrylic resin is added in solution B, 15min is stirred under the conditions of 4000r/s and 30 DEG C to be made
Dissolving, obtains solution C；
(4) Tween 80, sodium xylene sulfonate are added in solution C, 30min is stirred under the conditions of 1000r/s and 30 DEG C to be made
Dissolving, obtains solution D；
(5) iso-octyl polyoxyethylene ether is added in solution D, stirring 15min makes molten under the conditions of 2000r/s and 30 DEG C
Solution, obtains solution E；
(6) tasteless ethyl alcohol and glycerine are mixed, stirs evenly, obtains solution F；
(7) by the modified porous titanium dioxide of nano-silver ionic, the modified porous zirconium dioxide of nano-silver ionic, the diformazan between chlorine
Phenol and zinc ricinate are added in solution F, and 15min is stirred under the conditions of 1000r/s and 30 DEG C makes dissolving, obtains solution G；
(8) solution E and solution G are mixed, 10min is stirred under the conditions of 1000r/s and 30 DEG C makes dissolving to get to described
Sterilizing deodoring agent.
Gained scavenger is milky, has alcohol smell, proportion 0.923g/m3, viscosity 52mPa.s.
Embodiment 2
The present embodiment provides a kind of sterilizing deodoring agent and preparation method thereof：
The group of sterilizing deodoring agent in the present embodiment becomes：The modified porous titanium dioxide 1% of nano-silver ionic, nano silver from
The modified porous zirconium dioxide 1% of son, parachlorometaxylenol 3%, zinc ricinate 4%, small molecule water-based acrylic resin
4%, glycerine 15%, Tween 80 0.8%, sodium xylene sulfonate 0.8%, iso-octyl polyoxyethylene ether 1%, triethanolamine
0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, calgon 0.25%, sodium citrate 0.25%, tasteless ethyl alcohol
35% and deionized water be surplus, above-mentioned raw materials add up to 100%.
Preparation process is the same as embodiment 1.
Gained scavenger is milky, has alcohol smell, proportion 0.914g/m3, viscosity 64mPa.s.
Embodiment 3
The present embodiment provides a kind of sterilizing deodoring agent and preparation method thereof：
The group of sterilizing deodoring agent in the present embodiment becomes：The modified porous titanium dioxide 1.5% of nano-silver ionic, nano silver
Ion modification porous zirconium dioxide 1.5%, parachlorometaxylenol 2.5%, zinc ricinate 3%, small molecule water soluble acrylic acid
Resin 5%, glycerine 10%, Tween 80 1%, sodium xylene sulfonate 1%, iso-octyl polyoxyethylene ether 2%, triethanolamine
0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, calgon 0.25%, sodium citrate 0.25%, tasteless ethyl alcohol
45% and deionized water be surplus, above-mentioned raw materials add up to 100%.
Preparation process is the same as embodiment 1.
Gained scavenger is milky, has alcohol smell, proportion 0.875g/m3, viscosity 72mPa.s.
Embodiment 4
The present embodiment provides a kind of sterilizing deodoring agent and preparation method thereof：
The group of sterilizing deodoring agent in the present embodiment becomes：The modified porous titanium dioxide 2% of nano-silver ionic, nano silver from
The modified porous zirconium dioxide 2% of son, parachlorometaxylenol 2%, zinc ricinate 2%, small molecule water-based acrylic resin
6%, glycerine 20%, Tween 80 1.5%, sodium xylene sulfonate 1.2%, iso-octyl polyoxyethylene ether 2.5%, triethanolamine
0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, calgon 0.25%, sodium citrate 0.25%, tasteless ethyl alcohol
55% and deionized water be surplus, above-mentioned raw materials add up to 100%.
Preparation process is the same as embodiment 1.
Gained scavenger is milky, has alcohol smell, proportion 0.867g/m3, viscosity 95mPa.s.
Embodiment 5
The present embodiment provides a kind of sterilizing deodoring agent and preparation method thereof：
The group of sterilizing deodoring agent in the present embodiment becomes：The modified porous titanium dioxide 2.5% of nano-silver ionic, nano silver
Ion modification porous zirconium dioxide 2.5%, parachlorometaxylenol 1.5%, zinc ricinate 1%, small molecule water soluble acrylic acid
Resin 7%, glycerine 15%, Tween 80 2%, sodium xylene sulfonate 2%, iso-octyl polyoxyethylene ether 3.5%, triethanolamine
0.5%, sodium metasilicate 0.25%, sodium benzoate 0.25%, calgon 0.25%, sodium citrate 0.25%, tasteless ethyl alcohol
60% and deionized water be surplus, above-mentioned raw materials add up to 100%.
Preparation process is the same as embodiment 1.
Gained scavenger is milky, has alcohol smell, proportion 0.845g/m3, viscosity 103mPa.s.
Embodiment 6
The present embodiment provides the application effects of the sterilizing deodoring aerosol obtained by Examples 1 to 5：
Sterilizing deodoring agent obtained by Examples 1 to 5 is mixed in proportion with propellant shown in table 1, sterilizing deodoring is prepared
Then aerosol tests it to Escherichia coli, Staphylococcus aureus according to GB 27948-2011 (air sanitizer hygienic requirements)
The removal rate of bacterium detects its smell-removing rate according to GB/T 14675-1993 (measurement of air quality stench), and acquired results are shown in Table 1.
The air freshener used in comparative example is provided by Guangdong free energy Science and Technology Co., Ltd..
The application effect of the sterilizing deodoring aerosol obtained by Examples 1 to 5 of table 1
Raw material composition in 2 Examples 1 to 5 of table
The raw material of sterilizing deodoring agent in 3 present invention of table forms and effect
Above-described embodiment is preferrred embodiment of the present invention, but embodiments of the present invention are not limited to above-mentioned implementation
Example, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications,
Equivalent substitute mode is answered, is included within the scope of the present invention.
Claims (10)
1. a kind of sterilizing deodoring agent, which is characterized in that be made of following raw material by mass percentage：Nano-silver ionic is modified
The modified porous zirconium dioxide 0.01%~5% of poriferous titanium dioxide 0.01%~5%, nano-silver ionic, parachlorometaxylenol
1%~10%, zinc ricinate 1%~10%, small molecule water-based acrylic resin 1%~10%, glycerine 5%~20%,
Tasteless ethyl alcohol 40%~80%, Tween 80 0.1%~5%, sodium xylene sulfonate 0.1%~5%, iso-octyl polyoxyethylene ether
1%~5%, triethanolamine 0.1%~2%, sodium metasilicate 0.1%~2%, sodium benzoate 0.1%~2%, calgon
0.1%~1%, sodium citrate 0.1%~1% and water are surplus, and above-mentioned raw materials add up to 100%.
2. sterilizing deodoring agent according to claim 1, which is characterized in that be made of following raw material by mass percentage：
The modified porous zirconium dioxide of the modified porous titanium dioxide 0.5%~2.5% of nano-silver ionic, nano-silver ionic 0.5%~
2.5%, parachlorometaxylenol 1.5%~4%, zinc ricinate 1%~5%, small molecule water-based acrylic resin 3%~
7%, glycerine 10%~20%, tasteless ethyl alcohol 45%~60%, Tween 80 0.4%~2%, sodium xylene sulfonate 0.4%~
2%, iso-octyl polyoxyethylene ether 1%~3.5%, triethanolamine 0.1%~2%, sodium metasilicate 0.1%~2%, sodium benzoate
0.1%~2%, calgon 0.1%~1%, sodium citrate 0.1%~1% and water are surplus, and above-mentioned raw materials add up to
100%.
3. sterilizing deodoring agent according to claim 1 or claim 2, it is characterised in that：The mass ratio of tasteless ethyl alcohol and water is 3:2~3:
1。
4. sterilizing deodoring agent according to claim 3, which is characterized in that be made of following raw material by mass percentage：
The modified porous titanium dioxide 1.5% of nano-silver ionic, the modified porous zirconium dioxide 1.5% of nano-silver ionic, to chloro-m-xylene
Phenol 2.5%, zinc ricinate 3%, small molecule water-based acrylic resin 5%, glycerine 10%, tasteless ethyl alcohol 46%, Tween 80
1%, sodium xylene sulfonate 1%, iso-octyl polyoxyethylene ether 2%, triethanolamine 0.5%, sodium metasilicate 0.25%, sodium benzoate
0.25%, calgon 0.25%, sodium citrate 0.25% and water are surplus, and above-mentioned raw materials add up to 100%.
5. a kind of preparation method of any one of Claims 1 to 4 sterilizing deodoring agent, which is characterized in that include the following steps：
(1) calgon and sodium citrate are added in deionized water, stirring and dissolving obtains solution A；
(2) triethanolamine, sodium metasilicate and sodium benzoate are added in solution A, stirring and dissolving obtains solution B；
(3) small molecule water-based acrylic resin is added in solution B, stirring and dissolving obtains solution C；
(4) Tween 80, sodium xylene sulfonate are added in solution C, stirring and dissolving obtains solution D；
(5) iso-octyl polyoxyethylene ether is added in solution D, stirring and dissolving obtains solution E；
(6) tasteless ethyl alcohol and glycerine are mixed, stirs evenly, obtains solution F；
(7) by the modified porous titanium dioxide of nano-silver ionic, the modified porous zirconium dioxide of nano-silver ionic, parachlorometaxylenol
It is added in solution F with zinc ricinate, stirring and dissolving obtains solution G；
(8) solution E and solution G are mixed, is stirred evenly to get to the sterilizing deodoring agent.
6. the application of any one of Claims 1 to 4 sterilizing deodoring agent, it is characterised in that：The sterilizing deodoring agent is used for
Sterilizing deodoring aerosol.
7. a kind of sterilizing deodoring aerosol, it is characterised in that：The aerosol is by any one of propellant and Claims 1 to 4 institute
State sterilizing deodoring agent composition.
8. sterilizing deodoring aerosol according to claim 7, it is characterised in that：The propellant presses quality by propane and butane
Than being 2:3 compositions.
9. according to the sterilizing deodoring aerosol of claim 7 or 8, it is characterised in that：The propellant and sterilizing deodoring agent
Mass ratio is:0.1:1~1:1.
10. sterilizing deodoring aerosol according to claim 9, it is characterised in that：The matter of the propellant and sterilizing deodoring agent
Measuring ratio is:0.4:1~1:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN109777647A (en) * | 2019-03-04 | 2019-05-21 | 广东欧蝶兰高新科技日用品有限公司 | A kind of clothing removes peculiar smell composition |
| CN109794134A (en) * | 2019-03-18 | 2019-05-24 | 中山爱居环保科技有限公司 | A kind of high temperature resistant photocatalysis sustained releasing type is except aldehyde ordor removing lotion and preparation method thereof |
| CN111036066A (en) * | 2019-12-30 | 2020-04-21 | 中新合创建设集团有限公司 | Indoor/in-vehicle formaldehyde-removing air purification treatment construction process |
| CN111493094A (en) * | 2020-04-24 | 2020-08-07 | 杨小垒 | Air disinfectant and spreading method thereof |
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| CN113457416A (en) * | 2021-07-05 | 2021-10-01 | 生态环境部华南环境科学研究所 | Broad-spectrum efficient peculiar smell purifying agent and preparation method and application thereof |
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| CN114225619A (en) * | 2021-12-24 | 2022-03-25 | 汉宁化学(上海)有限公司 | Long-acting deodorant |
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| CN109364679A (en) * | 2018-11-07 | 2019-02-22 | 广东信鹏化工实业有限公司 | A kind of peculiar smell formaldehyde eliminating agent and its preparation method and application |
| CN109777647A (en) * | 2019-03-04 | 2019-05-21 | 广东欧蝶兰高新科技日用品有限公司 | A kind of clothing removes peculiar smell composition |
| CN109794134A (en) * | 2019-03-18 | 2019-05-24 | 中山爱居环保科技有限公司 | A kind of high temperature resistant photocatalysis sustained releasing type is except aldehyde ordor removing lotion and preparation method thereof |
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| CN114225619A (en) * | 2021-12-24 | 2022-03-25 | 汉宁化学(上海)有限公司 | Long-acting deodorant |
| WO2023170404A1 (en) * | 2022-03-07 | 2023-09-14 | X Mist Limited | Aerosol sanitiser |
| CN115068651A (en) * | 2022-06-09 | 2022-09-20 | 深圳乙奇生物科技有限公司 | Nanometer photolysis degerming odor-removing spray and preparation method thereof |
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