CN108620595B - Hard alloy screw nut mold and its manufacturing method with multilayered and graded structure - Google Patents
Hard alloy screw nut mold and its manufacturing method with multilayered and graded structure Download PDFInfo
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- CN108620595B CN108620595B CN201810741651.4A CN201810741651A CN108620595B CN 108620595 B CN108620595 B CN 108620595B CN 201810741651 A CN201810741651 A CN 201810741651A CN 108620595 B CN108620595 B CN 108620595B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/01—Selection of materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/007—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
- B22F2005/103—Cavity made by removal of insert
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
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- Manufacturing & Machinery (AREA)
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- Materials Engineering (AREA)
- Composite Materials (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses a kind of hard alloy screw nut mold and its manufacturing method with multilayered and graded structure, include toughness material matrix and the wear-resisting bed of material, the toughness material matrix has central through hole structure, the upper surface of the toughness material matrix is provided with the first wear-resisting bed of material, the central through hole structure interior surface is provided with the second wear-resisting bed of material, toughness material matrix has good impact flexibility, wear-resisting bed of material hardness is high, wearability is good, by the wear-resisting bed of material for being set to central through hole body structure surface, realize the forging function of screw nut mold, the wear-resisting bed of material for being set to toughness material body upper surface simultaneously plays a protective role to interface between layers below, high-performance carbide screw nut die life with multilayered and graded structure is long, save cemented carbide material.
Description
Technical field
The present invention relates to hard alloy technical fields, and in particular to a kind of hard alloy screw with multilayered and graded structure
Nut mold and its manufacturing method.
Background technique
Hard alloy be high rigidity, high intensity, high abrasion material, all obtained extensively in the various fields of modern industry
Using.The processing of the handwares such as screw nut carries out punching press to metal bar, obtains usually using the mold of hard alloy material
Obtain hardware.The abrasion resistance properties of sintered-carbide die working face determine the service life of entire mold.Traditional hard closes
Gold shell silk nut mold integrally uses the cemented carbide material of high-wearing feature, and after die life terminates, the material of entire mold is all
Be scrapped, but damage in fact be only mould punching face superficial layer, mold material abandoned together, caused
The waste of resource.
Using the technical solution of gradient hard alloy mold, a large amount of hard alloy resource can be saved.Only rushed in mold
The superficial layer of pressure surface uses the cemented carbide material of high-wearing feature, and mold material uses the cemented carbide material of high tenacity, mould
It is high to have stress surface hardness, wearability is good, and mold material has good impact flexibility.The wearability and toughness for making alloy obtain
Coordinate well, to improve the comprehensive performance and service life of hard alloy, preferably solves traditional homogeneous texture hard
Contradiction in alloy between wearability and toughness.But toughness mixture and two kinds of the wear-resisting mixture materials for making material base are special
Sex differernce is big, how toughness mixture and wear-resisting mixture is pressed into screw nut mold material base, need it is effective at
Type method is just able to achieve.
It includes collars outer layer and collars that Chinese patent CN103817150, which discloses a kind of gradient-structure type carbide roll ring,
Core, the configuration of collars outer layer is in the outer surface of collars core, in collars outer layer with there is mutual crucible zone between collars core, outside collars
The ingredient of forming component gradient between layer and collars core, collars outer layer and collars core is different, will mix the collars after wax is dried
Outer layer ball milling mixing material and mix wax it is dry after collars core ball milling mixing material place Min layers closed assembly powder, cold moudling is collars base
Material obtains final products through sintering.Its shortcoming is that the collars structure of the technical solution, only has ingredient terraced in the radial direction of collars
Degree, the face up cut shear when collars upper and lower surface does not have wearing layer, and collars uses, which can apply the interface of radial ingredient, to be removed
Effect, leads to collars restricted lifetime.In consideration of it, this patent proposes a kind of hard alloy screw nut with multilayered and graded structure
Mold and its manufacturing method.
Summary of the invention
The purpose of the present invention is to provide a kind of hard alloy screw nut mold and its system with multilayered and graded structure
Method is made, the specific technical proposal is:
A kind of hard alloy screw nut mold with multilayered and graded structure includes toughness material matrix, the first wear-resistant material
Layer, central through hole structure and the second wear-resisting bed of material, the toughness material matrix are cylindrical shape, the upper table of the toughness material matrix
Face is provided with the first wear-resisting bed of material, and the central through hole structure runs through toughness material matrix and the first wear-resisting bed of material, and the center is logical
The second wear-resisting bed of material is provided in pore structure.
The full-size of first wear-resisting bed of material cross section outer profile is equal to the cross-sectional diameter of toughness material matrix.
The outer profile of the second wear-resisting bed of material cross section is round perhaps polygon or is surrounded by straight line and camber line
Form perhaps straight line and curve surround perhaps multistage camber line surround perhaps camber line surrounded with curve or
Multistage curve or straight line, camber line and curve surround.
The longitudinal profile profile of the second wear-resisting bed of material and toughness material matrix combination interface is multistage straight line, or by straight
Perhaps perhaps multistage camber line forms perhaps camber line and curve composition or multistage for straight line and curve composition for line and camber line composition
Curve or straight line, camber line and curve form.
The full-size of first wear-resisting bed of material cross section outer profile is less than the cross-sectional diameter of toughness material matrix, described
The outer profile of first wear-resisting bed of material cross section is perhaps surrounded by straight line with camber line for round perhaps polygon or straight line
With curve surround perhaps multistage camber line surround perhaps camber line and curve surround perhaps multistage curve or
Straight line, camber line and curve surround.
The first wear-resisting bed of material is set to the top surface of toughness material matrix, or is set to the top surface and bottom of toughness material matrix simultaneously
Face.
A kind of hard alloy screw nut mould manufacturing method with multilayered and graded structure, comprising the following steps:
(1) toughness material matrix material base forms: the first die sleeve being placed into from the bottom opening of circular ring shape outer mold described
Inside circular ring shape outer mold, and guarantee that the two bottom end is concordant；First plug is inserted into the centre bore of the first die sleeve, and guarantees two
Person bottom end is concordant；Weigh Talide toughness mixture, Talide toughness mixture by WC powder, Co powder and
Cr3C2Powder is constituted and WC powder diameter is 6-16 μm, is filled into the space between circular ring shape outer mold inner wall and the first plug, is shaken
It moves so that Talide toughness mixture is uniformly filled；Second die sleeve is placed from the top opening of circular ring shape outer mold
Into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；Apply at the top of from the second die sleeve
Pressure is forced into 2Mpa and is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization to 10MPa holding 2~3 seconds, again
It unloads and is depressed into atmospheric pressure；The second die sleeve is taken out, the first plug, the first die sleeve, molding toughness material matrix material base are retained in circle
In annular outer mold.
(2) first wear-resistant material formable layers: weighing the wear-resisting mixture of Talide, and Talide is wear-resisting mixed
Conjunction material is made of WC powder, Co powder and VC powder and WC powder diameter is 0.6-6 μm, is filled into toughness material matrix material base upper surface and first
Between plug in space, shake so that the wear-resisting mixture of Talide is uniformly filled；By the second die sleeve outside circular ring shape
The top opening of mold is placed into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；
Apply pressure at the top of the second die sleeve, 4~5MPa of pressurization is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization 4~
5MPa is kept for 2~3 seconds, is then unloaded and is depressed into atmospheric pressure, and then repressurization 10MPa is kept for 5 seconds, then is unloaded and be depressed into atmospheric pressure；It takes
The first die sleeve is walked, applies pressure from the second die sleeve top, by the first plug and material base overall time from circular ring shape outer mold
First plug is extracted from the centre bore of material base, obtains the first material base after molding by ejection.
(3) second wear-resistant material stratifications enter: by the wear-resisting mixture merging molding of the Talide of the second wear-resisting bed of material
In the first material base central through hole structure afterwards, upper surface is ground smooth.
(4) sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 250 DEG C~450 DEG C of temperature range, is sintered 3~5 hours；
Sintering stage: it in 450 DEG C~1200 DEG C of temperature range, is sintered 5~8 hours；
It is sintered firm formative stage: in 1400 DEG C~1500 DEG C of temperature range, being sintered 1~2 hour.
It is further preferred that sintering includes multistage heat preservation sintering process, it is respectively as follows:
Pre-burning degreasing: it in 250 DEG C~450 DEG C of temperature range, is sintered 3~5 hours；
It is sintered the primary stage: in 450 DEG C~800 DEG C of temperature range, being sintered 3~5 hours；
Sintering shrinkage formative stage: it in 1000 DEG C~1200 DEG C of temperature range, is sintered 2~3 hours；
It is sintered firm formative stage: in 1400 DEG C~1450 DEG C of temperature range, being sintered 1~2 hour.
The preferred sintering scheme carries out the organic matter in the wear-resisting mixture of Talide in the sintering primary stage
Discharge is adequately decomposed, so that final product consistency is higher, there is higher mechanical performance.
Technical solution of the present invention has the advantages that
Toughness material matrix has good impact flexibility, and wear-resisting bed of material hardness is high, and wearability is good, logical by the center that is set to
The wear-resisting bed of material of pore structure inner surface, realizes the forging function of screw nut mold, while being set to toughness material body upper surface
The wear-resisting bed of material play a protective role to interface between layers below, with multilayered and graded structure hard alloy screw
Nut mold saves wear-resistant material layer material, and the service life is long.
Detailed description of the invention
The toughness material matrix material base shaping schematic view of Fig. 1 embodiment of the present invention one.
First wear-resistant material formable layer schematic diagram of Fig. 2 embodiment of the present invention one.
First material base schematic diagram of Fig. 3 embodiment of the present invention one.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Fig. 4 embodiment of the present invention one
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Fig. 5 embodiment of the present invention one
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Fig. 6 embodiment of the present invention two
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Fig. 7 embodiment of the present invention two
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Fig. 8 embodiment of the present invention three
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Fig. 9 embodiment of the present invention three
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Figure 10 embodiment of the present invention four
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Figure 11 embodiment of the present invention five
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Figure 12 embodiment of the present invention five
Figure.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Figure 13 embodiment of the present invention six
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Figure 14 embodiment of the present invention six
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Figure 15 embodiment of the present invention seven
Figure.
The hard alloy screw nut mold schematic top plan view with multilayered and graded structure of Figure 16 embodiment of the present invention seven.
The hard alloy screw nut mold cross section signal with multilayered and graded structure of Figure 17 embodiment of the present invention eight
Figure.
The hard alloy screw nut mold vertical section signal with multilayered and graded structure of Figure 18 embodiment of the present invention nine
Figure.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Embodiment one
Please refer to Fig. 1 to Fig. 5, a kind of hard alloy screw nut mold with multilayered and graded structure, which is characterized in that
Include toughness material matrix 4, the first wear-resisting bed of material 91, central through hole structure 10 and the second wear-resisting bed of material 92, the toughness material matrix 4
For cylindrical shape, the upper surface of the toughness material matrix 4 is provided with the first wear-resisting bed of material 91, and the central through hole structure 10 is passed through
Toughness material matrix 4 and the first wear-resisting bed of material 91 are worn, the second wear-resisting bed of material 92 is provided in the central through hole structure 10.
The first wear-resisting bed of material 91 and the second wear-resisting bed of material 92 with a thickness of 2mm.
The outer profile of second wear-resisting 92 cross section of the bed of material is circle.The first wear-resisting 91 cross section outer profile of the bed of material
It is equal to the cross-sectional diameter of toughness material matrix 4 for round and diameter.
The longitudinal profile profile of the second wear-resisting bed of material 92 and 4 combination interface of toughness material matrix is straight line.
A kind of hard alloy screw nut mould manufacturing method with multilayered and graded structure, comprising the following steps:
(1) toughness material matrix material base forms: the first die sleeve 5 is placed into institute from the bottom opening of circular ring shape outer mold 1
It states inside circular ring shape outer mold 1, and guarantees that the two bottom end is concordant；First plug 3 is inserted into the centre bore of the first die sleeve 5, and
Guarantee that the two bottom end is concordant；Weigh Talide toughness mixture, Talide toughness mixture by WC powder,
Co powder and Cr3C2Powder is constituted and WC powder diameter is 11 μm, is filled into the space between 1 inner wall of circular ring shape outer mold and the first plug 3
It is interior, it shakes so that Talide toughness mixture is uniformly filled；By the second die sleeve 2 from the top of circular ring shape outer mold 1
Opening is placed into the circular ring shape outer mold 1, and the first plug 3 is allowed to pass through out of the second die sleeve 2 centre bore；From the second mould
2 top of set applies pressure, is forced into 2Mpa and is kept for 2 ± 1 seconds, then unload and be depressed into atmospheric pressure, then repressurization to 10MPa is kept
It 2 ± 1 seconds, unloads be depressed into atmospheric pressure again；The second die sleeve 2 is taken out, by the first plug 3, the first die sleeve 5, molding toughness material base
Body material base is retained in circular ring shape outer mold.
(2) first wear-resistant material formable layers: weighing the wear-resisting mixture of Talide, and Talide is wear-resisting mixed
Conjunction material is made of WC powder, Co powder and VC powder and WC powder diameter is 3 μm, is filled into toughness material matrix material base upper surface and the first plug
Between 3 in space, shake so that the wear-resisting mixture of Talide is uniformly filled；By the second die sleeve 2 from circular ring shape external mold
The top opening of tool 1 is placed into the circular ring shape outer mold 1, and the first plug 3 is allowed to wear out of the second die sleeve 2 centre bore
It crosses；Apply pressure at the top of the second die sleeve 2,4 ± 1MPa of pressurization is kept for 2 ± 1 seconds, then unloads and be depressed into atmospheric pressure, then added again
It presses 4 ± 1MPa to be kept for 2 ± 1 seconds, then unloads and be depressed into atmospheric pressure, then repressurization 10MPa is kept for 5 seconds, then is unloaded and be depressed into atmospheric pressure
Power；It takes the first die sleeve 5 away, applies pressure at the top of the second die sleeve 2, by the first plug 3 and material base overall time from circular ring shape
It is ejected in outer mold 1, the first plug 3 is extracted from the centre bore of material base, obtains the first material base after molding.
(3) second wear-resistant material stratifications enter: the tungsten carbide hard of the wear-resisting bed of material of prefabricated profiled concentric cylindrical second is closed
The wear-resisting mixture green body of gold, fills in the central through hole structure of the first material base after molding, upper surface is ground smooth.
(4) sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 250 DEG C of temperature, is sintered 5 hours；
Sintering stage: it in 1200 DEG C of temperature, is sintered 8 hours；
It is sintered firm formative stage: in 1500 DEG C of temperature, being sintered 2 hours.
Embodiment two
Please refer to Fig. 6 to Fig. 7, the present embodiment and embodiment one the difference is that, the first wear-resisting bed of material 91 and second
The maximum gauge of the wear-resisting bed of material 92 is 8mm, and the outer profile of second wear-resisting 92 cross section of the bed of material is polygon, and described second is resistance to
The longitudinal profile profile of abrasive material 92 and 4 combination interface of toughness material matrix is multi-section-line, and the second wear-resisting merging of the bed of material 92 uses will
The prefabricated profiled second wear-resisting bed of material with central through hole of the wear-resisting mixture of Talide is inserted into the first material base.Carbon
Change tungsten hard alloy toughness mixture by WC powder, Co powder and Cr3C2Powder is constituted and WC powder diameter is 6 μm, and Talide is resistance to
Mill mixture is made of WC powder, Co powder and VC powder and WC powder diameter is 0.6 μm.
Sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 450 DEG C of temperature, is sintered 3 hours；
Sintering stage: it in 1200 DEG C of temperature, is sintered 5 hours；
It is sintered firm formative stage: in 1400 DEG C DEG C of temperature, being sintered 1 hour.
Remaining is identical.
Embodiment three
Please refer to Fig. 8 to Fig. 9, the present embodiment and embodiment one the difference is that, the first wear-resisting bed of material 91 and second
The maximum gauge of the wear-resisting bed of material 92 is 5mm, the outer profile of second wear-resisting 92 cross section of the bed of material surrounded by straight line and camber line and
At, the longitudinal profile profile of the second wear-resisting bed of material 92 and 4 combination interface of toughness material matrix is made of straight line and camber line, and second
The merging process of the wear-resisting bed of material 92 are as follows: the second plug is inserted into the first material base central through hole and guarantees its centre symmetry line and the
It is overlapped in one material base central through hole, the second wear-resisting wear-resisting mixture powder of bed of material Talide is inserted in the first material base
It between heart through-hole and the second plug and is compacted, then extracts the second plug.Talide toughness mixture is by WC powder, Co
Powder and Cr3C2Powder is constituted and WC powder diameter is 16 μm, and the wear-resisting mixture of Talide is made of WC powder, Co powder and VC powder
And WC powder diameter is 6 μm.
Sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 250 DEG C of temperature, is sintered 5 hours；
It is sintered the primary stage: in 800 DEG C of temperature, being sintered 5 hours；
Sintering shrinkage formative stage: it in 1000 DEG C of temperature, is sintered 3 hours；
It is sintered firm formative stage: in 1450 DEG C of temperature, being sintered 2 hours.
Remaining is identical.
Example IV
Referring to FIG. 10, the present embodiment and embodiment one the difference is that, the first wear-resisting bed of material 91 and second is wear-resisting
The maximum gauge of the bed of material 92 is 4mm, and the outer profile of second wear-resisting 92 cross section of the bed of material is that straight line is surrounded with curve.Carbon
Change tungsten hard alloy toughness mixture by WC powder, Co powder and Cr3C2Powder is constituted and WC powder diameter is 14 μm, Talide
Wear-resisting mixture is made of WC powder, Co powder and VC powder and WC powder diameter is 1 μm.
Sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 350 DEG C of temperature, is sintered 4 hours；
Sintering stage: it in 750 DEG C of temperature, is sintered 7 hours；
It is sintered firm formative stage: in 1450 DEG C of temperature, being sintered 1.5 hours.
Remaining is identical.
Embodiment five
Please refer to Figure 11 to Figure 12, the present embodiment and embodiment one the difference is that, the first wear-resisting bed of material 91 and the
The maximum gauge of the two wear-resisting bed of materials 92 is 5mm, the outer profile of second wear-resisting 92 cross section of the bed of material surrounded by multistage camber line and
At, the longitudinal profile profile of the second wear-resisting bed of material 92 and 4 combination interface of toughness material matrix is made of straight line and curve, and second
The merging process of the wear-resisting bed of material 92 are as follows: the second plug is inserted into the first material base central through hole and guarantees its centre symmetry line and the
It is overlapped in one material base central through hole, the second wear-resisting wear-resisting mixture powder of bed of material Talide is inserted in the first material base
It between heart through-hole and the second plug and is compacted, then extracts the second plug.Talide toughness mixture is by WC powder, Co
Powder and Cr3C2Powder constitute and WC powder diameter be 7 μm, the wear-resisting mixture of Talide be made of WC powder, Co powder and VC powder and
WC powder diameter is 5 μm.
Sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 450 DEG C of temperature, is sintered 3 hours；
It is sintered the primary stage: in 600 DEG C of temperature, being sintered 3 hours；
Sintering shrinkage formative stage: it in 1200 DEG C of temperature, is sintered 2 hours；
It is sintered firm formative stage: in 1400 DEG C of temperature, being sintered 1 hour.
Remaining is identical.
Embodiment six
Please refer to Figure 13 to Figure 14, the present embodiment and embodiment one the difference is that, the first wear-resisting bed of material 91 and the
The maximum gauge of the two wear-resisting bed of materials 92 is 5mm, and the outer profile of second wear-resisting 92 cross section of the bed of material is by straight line, camber line and curve
It surrounds, the longitudinal profile profile of the second wear-resisting bed of material 92 and 4 combination interface of toughness material matrix is by straight line, camber line and song
Line composition, the first wear-resisting bed of material 91 are set to the upper and lower surfaces of toughness material matrix 4, the merging of the second wear-resisting bed of material 92
Journey are as follows: the second plug is inserted into the first material base central through hole and is guaranteed weight in its centre symmetry line and the first material base central through hole
Close, by the wear-resisting mixture powder of the second wear-resisting bed of material Talide insert the first material base central through hole and the second plug it
Between and be compacted, then extract the second plug.
Remaining is identical.Talide toughness mixture is by WC powder, Co powder and Cr3C2Powder is constituted and WC powder diameter is
15 μm, the wear-resisting mixture of Talide is made of WC powder, Co powder and VC powder and WC powder diameter is 2 μm.
Sintering includes multistage heat preservation sintering process, is respectively as follows:
Pre-burning degreasing: it in 350 DEG C of temperature range, is sintered 4 hours；
It is sintered the primary stage: in 700 DEG C of temperature, being sintered 4 hours；
Sintering shrinkage formative stage: it in 1150 DEG C of temperature, is sintered 2.5 hours；
It is sintered firm formative stage: in 1400 DEG C of temperature, being sintered 1.5 hours.
Embodiment seven
Please refer to Figure 15 to 16, the present embodiment and embodiment one the difference is that, first wear-resisting 91 cross section of the bed of material
The full-size of outer profile is less than the outer diameter of toughness material matrix 4, and the outer profile of first wear-resisting 91 cross section of the bed of material is polygon
Shape.Talide toughness mixture is by WC powder, Co powder and Cr3C2Powder is constituted and WC powder diameter is 9 μm, tungsten carbide hard
Alloy wear-resisting mixture is made of WC powder, Co powder and VC powder and WC powder diameter is 1 μm.
Remaining is identical.
Embodiment eight
Please refer to Figure 17, the present embodiment and embodiment one the difference is that, second wear-resisting 92 cross section of the bed of material it is interior
Surface profile is polygon.Remaining is identical.
Embodiment nine
Please refer to Figure 18, the present embodiment and embodiment one the difference is that, the hard conjunction with multilayered and graded structure
Gold shell silk nut mold outer profile is frustum cone structure, the outer profile of longitudinal section be it is trapezoidal, the first wear-resisting bed of material 91 is set to
The top surface of rotary table.Remaining is identical.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (7)
1. a kind of hard alloy screw nut mold with multilayered and graded structure, which is characterized in that include toughness material matrix, the
The one wear-resisting bed of material, central through hole structure and the second wear-resisting bed of material, the toughness material matrix are cylindrical shape, the toughness material base
The upper surface of body is provided with the first wear-resisting bed of material, and the central through hole structure runs through toughness material matrix and the first wear-resisting bed of material, institute
It states central through hole inner structural wall and is provided with the second wear-resisting bed of material；
The manufacturing method of the hard alloy screw nut mold with multilayered and graded structure the following steps are included:
(1) toughness material matrix material base forms: the first die sleeve is placed into the annulus from the bottom opening of circular ring shape outer mold
Inside shape outer mold, and guarantee that the two bottom end is concordant；First plug is inserted into the centre bore of the first die sleeve, and guarantees the two bottom
Hold level with both hands neat；Weigh Talide toughness mixture, Talide toughness mixture by WC powder, Co powder and
Cr3C2 powder is constituted and WC powder diameter is 6-16 μm, is filled into the space between circular ring shape outer mold inner wall and the first plug, is shaken
It moves so that Talide toughness mixture is uniformly filled；Second die sleeve is placed from the top opening of circular ring shape outer mold
Into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；Apply at the top of from the second die sleeve
Pressure is forced into 2Mpa and is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization to 10MPa holding 2~3 seconds, again
It unloads and is depressed into atmospheric pressure；The second die sleeve is taken out, the first plug, the first die sleeve, molding toughness material matrix material base are retained in circle
In annular outer mold；
(2) first wear-resistant material formable layers: the wear-resisting mixture of Talide, the wear-resisting mixture of Talide are weighed
It is made of WC powder, Co powder and VC powder and WC powder diameter is 0.6-6 μm, be filled into toughness material matrix material base upper surface and the first plug
Between in space, shake so that the wear-resisting mixture of Talide is uniformly filled；By the second die sleeve from circular ring shape outer mold
Top opening be placed into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；From
Apply pressure at the top of two die sleeves, 4~5MPa of pressurization is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then 4~5MPa of repressurization
It is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization 10MPa is kept for 5 seconds, then is unloaded and be depressed into atmospheric pressure；Take away
One die sleeve applies pressure from the second die sleeve top, the first plug and material base overall time is ejected from circular ring shape outer mold,
First plug is extracted from the centre bore of material base, obtains the first material base after molding；
(3) second wear-resistant material stratifications enter: the wear-resisting mixture merging of the Talide of the second wear-resisting bed of material is after molding
In the central through hole structure of first material base, upper surface is ground smooth；
(4) it is sintered: in 250 DEG C~450 DEG C of temperature range, being sintered 3~5 hours；It is warming up to 450 DEG C~1200 DEG C of temperature again
Section is sintered 5~8 hours；It then proceedes to be warming up to 1400 DEG C~1500 DEG C of temperature range, is sintered 1~2 hour.
2. as described in claim 1 with the hard alloy screw nut mold of multilayered and graded structure, which is characterized in that described the
The full-size of one wear-resisting bed of material cross section outer profile is equal to the cross-sectional diameter of toughness material matrix.
3. as described in claim 1 with the hard alloy screw nut mold of multilayered and graded structure, which is characterized in that described the
The outer profile of two wear-resisting bed of material cross sections be round perhaps polygon perhaps surrounded by straight line with camber line or straight line and
Curve surrounds perhaps multistage camber line and surrounds perhaps camber line to be surrounded or multistage curve with curve, Huo Zhezhi
Line, camber line and curve surround.
4. as described in claim 1 with the hard alloy screw nut mold of multilayered and graded structure, which is characterized in that described the
The longitudinal profile profile of the two wear-resisting bed of materials and toughness material matrix combination interface is multistage straight line, or is made of straight line and camber line,
Perhaps straight line and curve form perhaps multistage camber line composition perhaps camber line and curve form perhaps multistage curve or straight line,
Camber line and curve form.
5. as described in claim 1 with the hard alloy screw nut mold of multilayered and graded structure, which is characterized in that described the
The full-size of one wear-resisting bed of material cross section outer profile is less than the cross-sectional diameter of toughness material matrix, and the first wear-resisting bed of material is horizontal
The outer profile in section be round perhaps polygon perhaps surrounded by straight line with camber line or straight line and curve encirclement and
Perhaps camber line and curve, which are surrounded, at perhaps multistage camber line surrounds perhaps multistage curve or straight line, camber line and bent
Line surrounds.
6. the hard alloy screw nut mold according to any one of claims 1 to 5 with multilayered and graded structure,
It is characterized in that, the first wear-resisting bed of material is set to the upper surface of toughness material matrix, or it is set to the upper of toughness material matrix simultaneously
Surface and bottom surface.
7. a kind of hard alloy screw nut mould manufacturing method with multilayered and graded structure, which is characterized in that including following
Step:
(1) toughness material matrix material base forms: the first die sleeve is placed into the annulus from the bottom opening of circular ring shape outer mold
Inside shape outer mold, and guarantee that the two bottom end is concordant；First plug is inserted into the centre bore of the first die sleeve, and guarantees the two bottom
Hold level with both hands neat；Weigh Talide toughness mixture, Talide toughness mixture by WC powder, Co powder and
Cr3C2 powder is constituted and WC powder diameter is 6-16 μm, is filled into the space between circular ring shape outer mold inner wall and the first plug, is shaken
It moves so that Talide toughness mixture is uniformly filled；Second die sleeve is placed from the top opening of circular ring shape outer mold
Into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；Apply at the top of from the second die sleeve
Pressure is forced into 2Mpa and is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization to 10MPa holding 2~3 seconds, again
It unloads and is depressed into atmospheric pressure；The second die sleeve is taken out, the first plug, the first die sleeve, molding toughness material matrix material base are retained in circle
In annular outer mold；
(2) first wear-resistant material formable layers: the wear-resisting mixture of Talide, the wear-resisting mixture of Talide are weighed
It is made of WC powder, Co powder and VC powder and WC powder diameter is 0.6-6 μm, be filled into toughness material matrix material base upper surface and the first plug
Between in space, shake so that the wear-resisting mixture of Talide is uniformly filled；By the second die sleeve from circular ring shape outer mold
Top opening be placed into the circular ring shape outer mold, and the first plug is allowed to pass through out of the second die sleeve centre bore；From
Apply pressure at the top of two die sleeves, 4~5MPa of pressurization is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then 4~5MPa of repressurization
It is kept for 2~3 seconds, then unloads and be depressed into atmospheric pressure, then repressurization 10MPa is kept for 5 seconds, then is unloaded and be depressed into atmospheric pressure；Take away
One die sleeve applies pressure from the second die sleeve top, the first plug and material base overall time is ejected from circular ring shape outer mold,
First plug is extracted from the centre bore of material base, obtains the first material base after molding；
(3) second wear-resistant material stratifications enter: the wear-resisting mixture merging of the Talide of the second wear-resisting bed of material is after molding
In the central through hole structure of first material base, upper surface is ground smooth；
(4) it is sintered: in 250 DEG C~450 DEG C of temperature range, being sintered 3~5 hours；It is warming up to 450 DEG C~1200 DEG C of temperature again
Section is sintered 5~8 hours；It then proceedes to be warming up to 1400 DEG C~1500 DEG C of temperature range, is sintered 1~2 hour.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2018/099317 WO2019192114A1 (en) | 2018-04-03 | 2018-08-08 | Cemented carbide screw nut mold having multi-layer graded structure and manufacturing method therefor |
| EP18913306.9A EP3650136A4 (en) | 2018-04-03 | 2018-08-08 | Cemented carbide screw nut mold having multi-layer graded structure and manufacturing method therefor |
| TW107136011A TWI669175B (en) | 2018-04-03 | 2018-10-12 | A hard alloy screw nut mold having multi-layer gradient structure and thereof method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2018103036484 | 2018-04-03 | ||
| CN201810303648 | 2018-04-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108620595A CN108620595A (en) | 2018-10-09 |
| CN108620595B true CN108620595B (en) | 2019-06-04 |
Family
ID=63688774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810741651.4A Active CN108620595B (en) | 2018-04-03 | 2018-07-09 | Hard alloy screw nut mold and its manufacturing method with multilayered and graded structure |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP3650136A4 (en) |
| CN (1) | CN108620595B (en) |
| TW (1) | TWI669175B (en) |
| WO (1) | WO2019192114A1 (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06136409A (en) * | 1992-10-28 | 1994-05-17 | Kobe Steel Ltd | Production of composite cylinder |
| CN1526488A (en) * | 2003-09-24 | 2004-09-08 | 自贡硬质合金有限责任公司 | Production process of wire drawing hard alloy die with gradient varying performance |
| JP2006118033A (en) * | 2004-10-25 | 2006-05-11 | Hokkaido | Method for producing compositionally gradient cemented carbide |
| EP2093301A1 (en) * | 2006-11-20 | 2009-08-26 | Kabushiki Kaisha Miyanaga | Superhard tip and process for producing the same |
| CN102168195A (en) * | 2011-04-13 | 2011-08-31 | 南京航空航天大学 | Method for preparing gradient porous Ti-Mg-based composite material |
| CN102434665A (en) * | 2011-09-15 | 2012-05-02 | 上海高更高实业有限公司 | Light gradient hard-alloy sealing ring and manufacture method thereof |
| CN204449293U (en) * | 2015-03-12 | 2015-07-08 | 成都工业学院 | A kind of sintered-carbide die |
| CN105644026A (en) * | 2015-12-25 | 2016-06-08 | 洛阳金鹭硬质合金工具有限公司 | Composite sheet substrate product with ternary composite gradient structure |
| TWM549123U (en) * | 2017-06-27 | 2017-09-21 | Sinjingrui Tungsten Steel (Siamen) Co Ltd | High performance hard alloy screw/nut mold with multi-layer gradient structure |
| CN206838934U (en) * | 2017-06-20 | 2018-01-05 | 鑫京瑞钨钢（厦门）有限公司 | High-performance carbide screw nut mould with multilayered and graded structure |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5656735A (en) * | 1979-10-17 | 1981-05-18 | Inoue Japax Res Inc | Improved die |
| CN1218814C (en) * | 2003-12-15 | 2005-09-14 | 高峻峰 | Method for manufacturing metal or ceramic bond superhard grinding tool |
| JP2005342744A (en) * | 2004-06-01 | 2005-12-15 | Sanalloy Industry Co Ltd | Wear resistant sintered tool, and its manufacturing method |
| CN102773371A (en) * | 2011-05-09 | 2012-11-14 | 智品精密机械有限公司 | Method for forming gasket or nut without scraps |
| CN202877359U (en) * | 2012-09-26 | 2013-04-17 | 蚌埠凤凰滤清器有限责任公司 | Reinforced concave-convex mold core for thick plate mold of filter cleaner |
| MX365368B (en) * | 2012-09-27 | 2019-05-30 | Allomet Corp | Methods of forming a metallic or ceramic article having a novel composition of functionally graded material and articles containing the same. |
| CN103418788B (en) * | 2013-07-23 | 2015-05-20 | 浙江大学 | Device and method for thermoforming gradient materials |
| CN103817150B (en) | 2014-02-26 | 2015-07-01 | 湖南天益高技术材料制造有限公司 | Gradient-structure hard alloy roll collar and manufacturing process thereof |
| CN104057271B (en) * | 2014-07-04 | 2016-05-18 | 福建金鑫钨业股份有限公司 | A kind of preparation method of carbide alloy tool and mould |
| CN104588500A (en) * | 2014-12-31 | 2015-05-06 | 苏州欧美克合金工具有限公司 | Nut producing mould |
| CN205110786U (en) * | 2015-11-20 | 2016-03-30 | 碧梦技(上海）复合材料有限公司 | Powder metallurgy die |
| CN205927107U (en) * | 2016-08-16 | 2017-02-08 | 合肥波林新材料股份有限公司 | Take mixture forming die of inclined plane product |
| CN106735167B (en) * | 2016-12-15 | 2018-05-25 | 鑫京瑞钨钢（厦门）有限公司 | A kind of preparation method of extra-coarse grained carbide alloy gradient DRILL POINT DIES |
| TWM557151U (en) * | 2017-11-06 | 2018-03-21 | 承昌鎢鋼製品有限公司 | Multilayer-layer screws and nuts die |
| CN107775006A (en) * | 2017-12-12 | 2018-03-09 | 鑫京瑞钨钢（厦门）有限公司 | A kind of gradient hard alloy DRILL POINT DIES |
-
2018
- 2018-07-09 CN CN201810741651.4A patent/CN108620595B/en active Active
- 2018-08-08 WO PCT/CN2018/099317 patent/WO2019192114A1/en unknown
- 2018-08-08 EP EP18913306.9A patent/EP3650136A4/en not_active Withdrawn
- 2018-10-12 TW TW107136011A patent/TWI669175B/en active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06136409A (en) * | 1992-10-28 | 1994-05-17 | Kobe Steel Ltd | Production of composite cylinder |
| CN1526488A (en) * | 2003-09-24 | 2004-09-08 | 自贡硬质合金有限责任公司 | Production process of wire drawing hard alloy die with gradient varying performance |
| JP2006118033A (en) * | 2004-10-25 | 2006-05-11 | Hokkaido | Method for producing compositionally gradient cemented carbide |
| EP2093301A1 (en) * | 2006-11-20 | 2009-08-26 | Kabushiki Kaisha Miyanaga | Superhard tip and process for producing the same |
| CN102168195A (en) * | 2011-04-13 | 2011-08-31 | 南京航空航天大学 | Method for preparing gradient porous Ti-Mg-based composite material |
| CN102434665A (en) * | 2011-09-15 | 2012-05-02 | 上海高更高实业有限公司 | Light gradient hard-alloy sealing ring and manufacture method thereof |
| CN204449293U (en) * | 2015-03-12 | 2015-07-08 | 成都工业学院 | A kind of sintered-carbide die |
| CN105644026A (en) * | 2015-12-25 | 2016-06-08 | 洛阳金鹭硬质合金工具有限公司 | Composite sheet substrate product with ternary composite gradient structure |
| CN206838934U (en) * | 2017-06-20 | 2018-01-05 | 鑫京瑞钨钢（厦门）有限公司 | High-performance carbide screw nut mould with multilayered and graded structure |
| TWM549123U (en) * | 2017-06-27 | 2017-09-21 | Sinjingrui Tungsten Steel (Siamen) Co Ltd | High performance hard alloy screw/nut mold with multi-layer gradient structure |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201941850A (en) | 2019-11-01 |
| EP3650136A1 (en) | 2020-05-13 |
| TWI669175B (en) | 2019-08-21 |
| CN108620595A (en) | 2018-10-09 |
| EP3650136A4 (en) | 2020-07-08 |
| WO2019192114A1 (en) | 2019-10-10 |
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Address after: 361000 6th floor of plant 1, No. 21, Ma Luan Road, Jimei District, Xiamen City, Fujian Province Patentee after: Xinjingrui tungsten steel (Fujian) Co.,Ltd. Address before: 361000 6th floor of plant 1, No. 21, Ma Luan Road, Jimei District, Xiamen City, Fujian Province Patentee before: XINJINGRUI TUNGSTEN STEEL (XIAMEN) Co.,Ltd. |