TW201941850A - A hard alloy screw nut mold having multi-layer gradient structure and thereof method - Google Patents
A hard alloy screw nut mold having multi-layer gradient structure and thereof method Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/01—Selection of materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
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- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/007—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
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- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
- B22F2005/103—Cavity made by removal of insert
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
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Abstract
Description
本發明涉及硬質合金技術領域,具體涉及一種具有多層梯度結構的硬質合金螺絲螺帽模具及其製造方法。The invention relates to the technical field of hard alloys, and in particular, to a hard alloy screw nut mold having a multi-layered gradient structure and a manufacturing method thereof.
硬質合金是高硬度、高強度、高耐磨的材料,在現代工業的眾多領域都得到了廣泛應用。螺絲螺帽等五金件的加工,通常使用硬質合金材質的模具,對金屬棒材進行衝壓,獲得五金製品。硬質合金模具工作面的耐磨損性能決定整個模具的使用壽命。傳統的硬質合金螺絲螺帽模具整體採用高耐磨性的硬質合金材料,模具壽命終止後,整個模具的材料都被報廢掉,但是其實發生損傷的僅是模具衝壓面的表面層,模具體材料均被一起丟棄,造成了資源的浪費。Cemented carbide is a material with high hardness, high strength, and high wear resistance, and has been widely used in many fields of modern industry. For the processing of hardware such as screws and nuts, metal molds are usually used to punch metal bars to obtain hardware products. The wear resistance of the working surface of the carbide mold determines the service life of the entire mold. Traditional hard alloy screw nut molds are made of highly wear-resistant hard alloys. After the end of the mold life, the entire mold material is scrapped, but in fact, only the surface layer of the stamping surface of the mold and the material of the mold body are damaged. All were discarded together, resulting in a waste of resources.
採用梯度硬質合金模具的技術方案,能夠節省大量的硬質合金資源。僅在模具衝壓面的表面層採用高耐磨性的硬質合金材料,模具體材料採用高韌性的硬質合金材料,模具受力面硬度高,耐磨性好,模具體材料具有良好的衝擊韌性。使合金的耐磨性和韌性得到很好的協調,從而提高硬質合金的綜合性能和使用壽命,較好的解決傳統的均勻結構硬質合金中耐磨性與韌性之間的矛盾。但是,韌性混合料和耐磨混合料兩種制作料坯的材料特性差異大,如何將韌性混合料和耐磨混合料壓制成螺絲螺帽模具料坯,需要行之有效的成型方法才能實現。Adopting the technical solution of gradient cemented carbide mold can save a lot of cemented carbide resources. Only the surface layer of the stamping surface of the mold is made of high wear-resistant hard alloy material, and the mold body material is made of high-toughness hard alloy material. The mold bearing surface has high hardness, good wear resistance, and the mold body material has good impact toughness. The wear resistance and toughness of the alloy are well coordinated, so that the comprehensive performance and service life of the cemented carbide are improved, and the contradiction between the wear resistance and toughness in the traditional uniform structure cemented carbide is better solved. However, there are large differences in the material properties of the toughness mixture and the wear-resistant mixture for making the blank. How to press the toughness mixture and the wear-resistant mixture into a screw nut mold blank requires an effective forming method.
中國專利CN103817150公開了一種梯度結構型硬質合金輥環包括輥環外層和輥環芯部,輥環外層配置在輥環芯部的外表面,在輥環外層同輥環芯部之間有互熔層,在輥環外層和輥環芯部之間形成成分梯度,輥環外層和輥環芯部的成分不同,將摻蠟乾燥後的輥環外層球磨混合料和摻蠟乾燥後的輥環芯部球磨混合料分層鋪疊裝粉,冷壓成型為輥環坯料,經燒結獲得最終產品。其缺點在於,該技術方案的輥環結構,僅在輥環的徑向有成分梯度,在輥環上下表面沒有耐磨層,輥環使用時的面上剪切力會對徑向成分的介面施加剝離作用,導致輥環壽命有限。鑒於此,本專利提出一種具有多層梯度結構的硬質合金螺絲螺帽模具及其製造方法。Chinese patent CN103817150 discloses a gradient structure type hard alloy roll ring including a roll ring outer layer and a roll ring core portion. The roll ring outer layer is arranged on the outer surface of the roll ring core portion, and there is mutual fusion between the outer layer of the roll ring and the core portion of the roll ring. Layer, forming a composition gradient between the outer layer of the roll ring and the core of the roll ring. The composition of the outer layer of the roll ring and the core of the roll ring is different. The ball milling mixture is layered and laminated powder, cold-rolled into a roll ring blank, and sintered to obtain the final product. The disadvantage is that the roller ring structure of this technical solution only has a component gradient in the radial direction of the roller ring, there is no wear layer on the upper and lower surfaces of the roller ring, and the shear force on the surface of the roller ring when it is used will affect the interface of the radial component. The application of peeling results in a limited life of the roll ring. In view of this, this patent proposes a hard alloy screw nut mold with a multi-layered gradient structure and a manufacturing method thereof.
本發明的目的在於提供一種具有多層梯度結構的硬質合金螺絲螺帽模具及其製造方法,具體技術方案為:An object of the present invention is to provide a hard alloy screw nut mold with a multi-layered gradient structure and a manufacturing method thereof. The specific technical solution is:
一種具有多層梯度結構的硬質合金螺絲螺帽模具,包含韌性料基體、第一耐磨料層、中心通孔結構和第二耐磨料層,所述韌性料基體為圓柱體外形,所述韌性料基體的上表面設置有第一耐磨料層,所述中心通孔結構貫穿韌性料基體和第一耐磨料層,所述中心通孔結構內設置有第二耐磨料層。A hard alloy screw nut mold with a multi-layered gradient structure includes a tough material base, a first wear-resistant material layer, a central through-hole structure, and a second wear-resistant material layer. The tough material base has a cylindrical shape and the toughness. The upper surface of the material base is provided with a first wear-resistant material layer, the central through-hole structure penetrates the tough material base and the first wear-resistant material layer, and the central through-hole structure is provided with a second wear-resistant material layer.
所述第一耐磨料層橫截面外輪廓的最大尺寸等於韌性料基體的橫截面直徑。The maximum size of the cross-sectional outer contour of the first wear-resistant material layer is equal to the cross-sectional diameter of the tough material matrix.
所述第二耐磨料層橫截面的外輪廓為圓形,或者多邊形,或者由直線與弧線包圍而成,或者直線與曲線包圍而成,或者多段弧線包圍而成,或者弧線與曲線包圍而成,或者多段曲線,或者直線、弧線與曲線包圍而成。The outer profile of the cross section of the second wear-resistant material layer is circular, or polygonal, or surrounded by straight lines and arcs, or surrounded by straight lines and curves, or surrounded by multiple arcs, or surrounded by arcs and curves. It is composed of multiple curved lines, or straight lines, arcs, and curves.
所述第二耐磨料層與韌性料基體結合介面的縱向剖面輪廓為多段直線,或者由直線與弧線組成,或者直線與曲線組成,或者多段弧線組成,或者弧線與曲線組成,或者多段曲線,或者直線、弧線與曲線組成。The longitudinal profile of the interface between the second wear-resistant material layer and the tough material matrix is a multi-segment straight line, or a straight line and an arc line, or a straight line and a curve line, or a multi-line arc line, or an arc line and a curve line, or a multi-line curve, Or straight lines, arcs and curves.
所述第一耐磨料層橫截面外輪廓的最大尺寸小於韌性料基體的橫截面直徑,所述第一耐磨料層橫截面的外輪廓為圓形,或者多邊形,或者由直線與弧線包圍而成,或者直線與曲線包圍而成,或者多段弧線包圍而成,或者弧線與曲線包圍而成,或者多段曲線,或者直線、弧線與曲線包圍而成。The maximum size of the outer profile of the cross-section of the first wear-resistant material layer is smaller than the diameter of the cross-section of the tough material matrix. Or surrounded by straight lines and curves, or surrounded by multiple arcs, or surrounded by arcs and curves, or multiple curved lines, or surrounded by straight lines, arcs, and curves.
第一耐磨料層設置於韌性料基體的頂面,或者同時設置於韌性料基體的頂面和底面。The first wear-resistant material layer is disposed on the top surface of the tough material substrate, or on both the top surface and the bottom surface of the tough material substrate.
一種具有多層梯度結構的硬質合金螺絲螺帽模具製造方法,包括以下步驟:A manufacturing method of a hard alloy screw nut mold with a multi-layered gradient structure includes the following steps:
(1)韌性料基體料坯成型:將第一模套從圓環形外模具的底部開口放置進入所述圓環形外模具內部,並保證兩者底端平齊;將第一芯棒插入第一模套的中心孔內,並保證兩者底端平齊;稱取碳化鎢硬質合金韌性混合料,碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為6-16μm,填充進圓環形外模具內壁與第一芯棒之間的空間內,震動使得碳化鎢硬質合金韌性混合料均勻填充;將第二模套從圓環形外模具的頂部開口放置進入所述圓環形外模具,並讓第一芯棒從第二模套的中心孔內穿過;從第二模套頂部施加壓力,加壓至2Mpa保持2~3秒,然後卸壓至大氣壓力,然後再加壓至10MPa保持2~3秒,再次卸壓至大氣壓力;取出第二模套,將第一芯棒、第一模套、成型的韌性料基體料坯保留在圓環形外模具內。(1) Forming of tough material matrix and blank: Place the first mold sleeve from the bottom opening of the annular outer mold into the inside of the annular outer mold, and ensure that the bottom ends of the two are flush; insert the first core rod In the center hole of the first mold sleeve, and ensure that the bottom ends of the two are flush; weigh the tungsten carbide hard alloy toughness mixture. The tungsten carbide hard alloy toughness mixture is composed of WC powder, Co powder and Cr3C2 powder, and the particle size of WC powder 6-16μm, filled into the space between the inner wall of the outer ring mold and the first core rod, the vibration makes the tungsten carbide hard alloy toughness mixture evenly filled; the second mold sleeve is from the top of the outer ring mold The opening is placed into the circular outer mold, and the first core rod passes through the center hole of the second mold sleeve; pressure is applied from the top of the second mold sleeve, pressurized to 2Mpa for 2 to 3 seconds, and then unloaded Press to atmospheric pressure, and then pressurize to 10 MPa for 2 to 3 seconds, and then release the pressure to atmospheric pressure again; take out the second mold sleeve, and retain the first core rod, the first mold sleeve, and the formed tough material matrix blank. Inside the outer ring.
(2)第一耐磨料層成型:稱取碳化鎢硬質合金耐磨混合料,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為0.6-6μm,填充進韌性料基體料坯上表面與第一芯棒之間空間內,震動使得碳化鎢硬質合金耐磨混合料均勻填充;將第二模套從圓環形外模具的頂部開口放置進入所述圓環形外模具,並讓第一芯棒從第二模套的中心孔內穿過;從第二模套頂部施加壓力,加壓4~5MPa保持2~3秒,然後卸壓至大氣壓力,然後再加壓4~5MPa保持2~3秒,然後卸壓至大氣壓力,然後再加壓10MPa保持5秒,再卸壓至大氣壓力;取走第一模套,從第二模套頂部施加壓力,將第一芯棒和料坯整體一次性從圓環形外模具中頂出,將第一芯棒從料坯的中心孔拔出,獲得成型後的第一料坯。(2) Forming of the first wear-resistant material layer: Weigh the tungsten carbide hard alloy wear-resistant mixture. The tungsten carbide hard alloy wear-resistant mixture is composed of WC powder, Co powder and VC powder, and the particle size of WC powder is 0.6-6 μm. Filled into the space between the upper surface of the tough material base blank and the first mandrel, the vibration makes the tungsten carbide hard alloy wear-resistant mixture uniformly filled; the second mold sleeve is placed into the top opening of the circular outer mold into the A circular outer mold, and let the first core rod pass through the center hole of the second mold sleeve; apply pressure from the top of the second mold sleeve, pressurize 4 ~ 5MPa for 2 ~ 3 seconds, and then release the pressure to atmospheric pressure , Then pressurize for 4 ~ 5MPa for 2 ~ 3 seconds, then release the pressure to atmospheric pressure, then pressurize for 10MPa for 5 seconds, then release the pressure to atmospheric pressure; remove the first mold sleeve, and from the top of the second mold sleeve Applying pressure, the entire first core rod and the blank are ejected from the circular outer mold at one time, and the first core rod is pulled out from the center hole of the blank to obtain a molded first blank.
(3)第二耐磨料層置入:將第二耐磨料層的碳化鎢硬質合金耐磨混合料置入成型後的第一料坯中心通孔結構內,將上表面研磨平整。(3) Putting the second wear-resistant material layer: The tungsten carbide hard alloy wear-resistant mixture of the second wear-resistant material layer is placed in the center through-hole structure of the first blank after molding, and the upper surface is ground and flattened.
(4)燒結包含多段保溫燒結過程,分別為:(4) Sintering involves multiple stages of thermal insulation sintering, which are:
預燒脫脂:在250℃~450℃的溫度區間,燒結3~5小時;Pre-baking and degreasing: sintering for 3 ~ 5 hours in the temperature range of 250 ℃ ~ 450 ℃;
燒結階段:在450℃~1200℃的溫度區間,燒結5~8小時;Sintering stage: sintering for 5 ~ 8 hours in the temperature range of 450 ℃ ~ 1200 ℃;
燒結穩固成型階段:在1400℃~1500℃的溫度區間,燒結1~2小時。Sintering and stable forming stage: sintering for 1 ~ 2 hours in the temperature range of 1400 ℃ ~ 1500 ℃.
進一步優選的,燒結包含多段保溫燒結過程,分別為:Further preferably, the sintering includes a plurality of stages of thermal insulation sintering processes, respectively:
預燒脫脂:在250℃~450℃的溫度區間,燒結3~5小時;Pre-baking and degreasing: sintering for 3 ~ 5 hours in the temperature range of 250 ℃ ~ 450 ℃;
燒結初級階段:在450℃~800℃的溫度區間,燒結3~5小時;Primary stage of sintering: sintering for 3 ~ 5 hours in the temperature range of 450 ℃ ~ 800 ℃;
燒結收縮成型階段:在1000℃~1200℃的溫度區間,燒結2~3小時;Sintering shrink molding stage: sintering for 2 ~ 3 hours in the temperature range of 1000 ℃ ~ 1200 ℃;
燒結穩固成型階段:在1400℃~1450℃的溫度區間,燒結1~2小時。Sintering and stable forming stage: sintering for 1 ~ 2 hours in the temperature range of 1400 ℃ ~ 1450 ℃.
該優選燒結方案,在燒結初級階段對碳化鎢硬質合金耐磨混合料內的有機物進行充分的分解排出,使得最終製品緻密度更高,有更高的機械性能。In this preferred sintering scheme, organic matter in the tungsten carbide hard alloy wear-resistant mixture is fully decomposed and discharged in the initial stage of sintering, so that the final product has higher density and higher mechanical properties.
本發明的技術方案具有如下優點:The technical solution of the present invention has the following advantages:
韌性料基體具有良好的衝擊韌性,耐磨料層硬度高,耐磨性好,借助設置于中心通孔結構內表面的耐磨料層,實現螺絲螺帽模具的鍛造功能,同時設置於韌性料基體上表面的耐磨料層對其下方的層與層之間介面起到保護作用,具有多層梯度結構的硬質合金螺絲螺帽模具節省了耐磨料層材料,壽命長。
以下實施例用於說明本發明,但不用來限制本發明的範圍。The following examples are used to illustrate the present invention, but not to limit the scope of the present invention.
實施例一Example one
請參考第1圖至第5圖,一種具有多層梯度結構的硬質合金螺絲螺帽模具,其特徵在於,包含韌性料基體4、第一耐磨料層91、中心通孔結構10和第二耐磨料層92,所述韌性料基體4為圓柱體外形,所述韌性料基體4的上表面設置有第一耐磨料層91,所述中心通孔結構10貫穿韌性料基體4和第一耐磨料層91,所述中心通孔結構10內設置有第二耐磨料層92。Please refer to FIG. 1 to FIG. 5, a hard alloy screw nut mold having a multi-layered gradient structure, which is characterized in that it includes a tough material matrix 4, a first wear-resistant material layer 91, a central through-hole structure 10 and a second resistance Abrasive layer 92. The tough material base 4 has a cylindrical shape. The upper surface of the tough material base 4 is provided with a first wear-resistant material layer 91. The central through-hole structure 10 penetrates the tough material base 4 and the first A wear-resistant material layer 91 is provided with a second wear-resistant material layer 92 in the central through-hole structure 10.
所述第一耐磨料層91和第二耐磨料層92的厚度為2mm。The thickness of the first abrasion-resistant material layer 91 and the second abrasion-resistant material layer 92 is 2 mm.
所述第二耐磨料層92橫截面的外輪廓為圓形。所述第一耐磨料層91橫截面外輪廓為圓形且直徑等於韌性料基體4的橫截面直徑。The cross-section of the second wear-resistant material layer 92 has a circular outer shape. The cross-sectional outer contour of the first wear-resistant material layer 91 is circular and has a diameter equal to the cross-sectional diameter of the tough material base 4.
所述第二耐磨料層92與韌性料基體4結合介面的縱向剖面輪廓為直線。A longitudinal cross-sectional profile of a bonding interface between the second wear-resistant material layer 92 and the tough material base 4 is a straight line.
一種具有多層梯度結構的硬質合金螺絲螺帽模具製造方法,包括以下步驟:A manufacturing method of a hard alloy screw nut mold with a multi-layered gradient structure includes the following steps:
(1)韌性料基體料坯成型:將第一模套5從圓環形外模具1的底部開口放置進入所述圓環形外模具1內部,並保證兩者底端平齊;將第一芯棒3插入第一模套5的中心孔內,並保證兩者底端平齊;稱取碳化鎢硬質合金韌性混合料,碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為11μm,填充進圓環形外模具1內壁與第一芯棒3之間的空間內,震動使得碳化鎢硬質合金韌性混合料均勻填充;將第二模套2從圓環形外模具1的頂部開口放置進入所述圓環形外模具1,並讓第一芯棒3從第二模套2的中心孔內穿過;從第二模套2頂部施加壓力,加壓至2Mpa保持2±1秒,然後卸壓至大氣壓力,然後再加壓至10MPa保持2±1秒,再次卸壓至大氣壓力;取出第二模套2,將第一芯棒3、第一模套5、成型的韌性料基體料坯保留在圓環形外模具內。(1) Forming of tough material matrix and blank: Place the first mold sleeve 5 from the bottom opening of the annular outer mold 1 into the annular outer mold 1 and ensure that the bottom ends of the two are flush; The core rod 3 is inserted into the center hole of the first mold sleeve 5 and the bottom ends of the two are flush; the tungsten carbide hard alloy toughness mixture is weighed. The tungsten carbide hard alloy toughness mixture is composed of WC powder, Co powder and Cr3C2 powder. The WC powder has a particle size of 11 μm, and is filled into the space between the inner wall of the circular outer mold 1 and the first core rod 3, and the vibration causes the tungsten carbide hard alloy toughness mixture to be uniformly filled; the second mold sleeve 2 is removed from the circle. The top opening of the ring-shaped outer mold 1 is placed into the ring-shaped outer mold 1, and the first core rod 3 is passed through the center hole of the second mold sleeve 2; pressure is applied from the top of the second mold sleeve 2, and Press to 2Mpa for 2 ± 1 seconds, then release the pressure to atmospheric pressure, and then pressurize to 10MPa for 2 ± 1 seconds, then release the pressure to atmospheric pressure again; take out the second mold sleeve 2 and place the first core rod 3, the first A mold sleeve 5. The formed tough material matrix blank is retained in a circular outer mold.
(2)第一耐磨料層成型:稱取碳化鎢硬質合金耐磨混合料,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為3μm,填充進韌性料基體料坯上表面與第一芯棒3之間空間內,震動使得碳化鎢硬質合金耐磨混合料均勻填充;將第二模套2從圓環形外模具1的頂部開口放置進入所述圓環形外模具1,並讓第一芯棒3從第二模套2的中心孔內穿過;從第二模套2頂部施加壓力,加壓4±1MPa保持2±1秒,然後卸壓至大氣壓力,然後再加壓4±1MPa保持2±1秒,然後卸壓至大氣壓力,然後再加壓10MPa保持5秒,再卸壓至大氣壓力;取走第一模套5,從第二模套2頂部施加壓力,將第一芯棒3和料坯整體一次性從圓環形外模具1中頂出,將第一芯棒3從料坯的中心孔拔出,獲得成型後的第一料坯。(2) Forming of the first wear-resistant material layer: Weigh the tungsten carbide hard alloy wear-resistant mixture. The tungsten carbide hard alloy wear-resistant mixture is composed of WC powder, Co powder, and VC powder, and the particle size of the WC powder is 3 μm. In the space between the upper surface of the tough material base blank and the first core rod 3, the vibration causes the tungsten carbide hard alloy wear-resistant mixture to be evenly filled; the second mold sleeve 2 is placed into the space from the top opening of the outer annular mold 1 The circular outer mold 1 is described, and the first core rod 3 is passed through the center hole of the second mold sleeve 2; pressure is applied from the top of the second mold sleeve 2, and the pressure is maintained at 4 ± 1 MPa for 2 ± 1 seconds, and then Relieve pressure to atmospheric pressure, and then pressurize 4 ± 1MPa for 2 ± 1 seconds, then release pressure to atmospheric pressure, and then pressurize 10MPa for 5 seconds, and then release pressure to atmospheric pressure; remove the first mold sleeve 5, Apply pressure from the top of the second mold sleeve 2 to eject the first core rod 3 and the blank from the circular outer mold 1 at a time, and pull the first core rod 3 out of the center hole of the blank to obtain the molding. After the first blank.
(3)第二耐磨料層置入:將預製成型的同心圓柱狀第二耐磨料層的碳化鎢硬質合金耐磨混合料坯體,塞入成型後的第一料坯的中心通孔結構內,將上表面研磨平整。(3) Inserting the second wear-resistant material layer: The tungsten carbide hard alloy wear-resistant material mixture body of the preformed concentric cylindrical second wear-resistant material layer is inserted into the center through hole of the first material blank after molding. Within the structure, the upper surface is ground and flattened.
(4)燒結包含多段保溫燒結過程,分別為:(4) Sintering involves multiple stages of thermal insulation sintering, which are:
預燒脫脂:在250℃的溫度,燒結5小時;Calcination and degreasing: sintering at 250 ° C for 5 hours;
燒結階段:在1200℃的溫度,燒結8小時;Sintering stage: sintering for 8 hours at 1200 ° C;
燒結穩固成型階段:在1500℃的溫度,燒結2小時。Sintering and solid forming stage: sintering for 2 hours at 1500 ° C.
實施例二Example two
請參考第6圖至第7圖,本實施例與實施例一的差別在於,所述第一耐磨料層91和第二耐磨料層92的最大厚度為8mm,所述第二耐磨料層92橫截面的外輪廓為多邊形,所述第二耐磨料層92與韌性料基體4結合介面的縱向剖面輪廓為多段線,第二耐磨料層92置入採用將碳化鎢硬質合金耐磨混合料預製成型的帶有中心通孔的第二耐磨料層插入第一料坯內。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為6μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為0.6μm。Please refer to FIG. 6 to FIG. 7. The difference between this embodiment and the first embodiment is that the maximum thickness of the first wear-resistant material layer 91 and the second wear-resistant material layer 92 is 8 mm, and the second wear-resistant material layer is 8 mm. The outer profile of the cross-section of the material layer 92 is polygonal. The longitudinal profile of the interface between the second wear-resistant material layer 92 and the tough material base 4 is a polyline. The second wear-resistant material layer 92 is placed with tungsten carbide The second wear-resistant material layer with a central through hole prefabricated by the wear-resistant mixture is inserted into the first blank. Tungsten carbide cemented carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder and the particle size of WC powder is 6 μm. Tungsten carbide cemented carbide wear-resistant mixture is composed of WC powder, Co powder and VC powder and WC powder particle size is 0.6 μm.
燒結包含多段保溫燒結過程,分別為:Sintering consists of multiple thermal insulation sintering processes, which are:
預燒脫脂:在450℃的溫度,燒結3小時;Calcination and degreasing: sintering at 450 ° C for 3 hours;
燒結階段:在1200℃的溫度,燒結5小時;Sintering stage: sintering for 5 hours at 1200 ° C;
燒結穩固成型階段:在1400℃的溫度,燒結1小時。Sintering and stable forming stage: sintering for 1 hour at a temperature of 1400 ° C.
其餘相同。The rest is the same.
實施例三Example three
請參考第8圖至第9圖,本實施例與實施例一的差別在於,所述第一耐磨料層91和第二耐磨料層92的最大厚度為5mm,所述第二耐磨料層92橫截面的外輪廓由直線與弧線包圍而成,所述第二耐磨料層92與韌性料基體4結合介面的縱向剖面輪廓由直線與弧線組成,第二耐磨料層92的置入過程為:將第二芯棒插入第一料坯中心通孔內並保證其中心對稱線與第一料坯中心通孔內重合,將第二耐磨料層碳化鎢硬質合金耐磨混合料粉體填入第一料坯中心通孔與第二芯棒之間並壓實,然後拔出第二芯棒。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為16μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為6μm。Please refer to FIG. 8 to FIG. 9. The difference between this embodiment and the first embodiment is that the maximum thickness of the first wear-resistant material layer 91 and the second wear-resistant material layer 92 is 5 mm, and the second wear-resistant material layer is 5 mm. The outer profile of the cross section of the material layer 92 is surrounded by straight lines and arcs. The longitudinal profile of the interface between the second wear-resistant material layer 92 and the tough material base 4 is composed of straight lines and arcs. The insertion process is: insert the second core rod into the central through hole of the first blank and ensure that the center symmetry line coincides with the central through hole of the first blank, and mix the second wear-resistant tungsten carbide hard alloy layer with wear resistance The powder is filled between the central through hole of the first blank and the second core rod and compacted, and then the second core rod is pulled out. Tungsten carbide cemented carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder and the particle size of WC powder is 16 μm. Tungsten carbide cemented carbide wear-resistant mixture is composed of WC powder, Co powder and VC powder and WC powder particle size is 6 μm .
燒結包含多段保溫燒結過程,分別為:Sintering consists of multiple thermal insulation sintering processes, which are:
預燒脫脂:在250℃的溫度,燒結5小時;Calcination and degreasing: sintering at 250 ° C for 5 hours;
燒結初級階段:在800℃的溫度,燒結5小時;Primary sintering stage: sintering at 800 ° C for 5 hours;
燒結收縮成型階段:在1000℃的溫度,燒結3小時;Sintering shrink molding stage: sintering for 3 hours at 1000 ° C;
燒結穩固成型階段:在1450℃的溫度,燒結2小時。Sintering and stable forming stage: Sintering for 2 hours at 1450 ° C.
其餘相同。The rest is the same.
實施例四Embodiment 4
請參考第10圖,本實施例與實施例一的差別在於,所述第一耐磨料層91和第二耐磨料層92的最大厚度為4mm,所述第二耐磨料層92橫截面的外輪廓為直線與曲線包圍而成。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為14μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為1μm。Please refer to FIG. 10. The difference between this embodiment and the first embodiment is that the maximum thickness of the first wear-resistant material layer 91 and the second wear-resistant material layer 92 is 4 mm, and the second wear-resistant material layer 92 is horizontal. The outer contour of the section is surrounded by straight lines and curves. Tungsten carbide carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder and the particle size of WC powder is 14 μm. .
燒結包含多段保溫燒結過程,分別為:Sintering consists of multiple thermal insulation sintering processes, which are:
預燒脫脂:在350℃的溫度,燒結4小時;Calcination and degreasing: sintering for 4 hours at 350 ° C;
燒結階段:在750℃的溫度,燒結7小時;Sintering stage: 7 hours at 750 ° C;
燒結穩固成型階段:在1450℃的溫度,燒結1.5小時。Sintering and stable forming stage: sintering at a temperature of 1450 ° C for 1.5 hours.
其餘相同。The rest is the same.
實施例五Example 5
請參考第11圖至第12圖,本實施例與實施例一的差別在於,所述第一耐磨料層91和第二耐磨料層92的最大厚度為5mm,所述第二耐磨料層92橫截面的外輪廓由多段弧線包圍而成,所述第二耐磨料層92與韌性料基體4結合介面的縱向剖面輪廓由直線與曲線組成,第二耐磨料層92的置入過程為:將第二芯棒插入第一料坯中心通孔內並保證其中心對稱線與第一料坯中心通孔內重合,將第二耐磨料層碳化鎢硬質合金耐磨混合料粉體填入第一料坯中心通孔與第二芯棒之間並壓實,然後拔出第二芯棒。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為7μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為5μm。Please refer to FIG. 11 to FIG. 12. The difference between this embodiment and the first embodiment is that the maximum thickness of the first wear-resistant material layer 91 and the second wear-resistant material layer 92 is 5 mm, and the second wear-resistant material layer is 5 mm. The outer profile of the cross-section of the material layer 92 is surrounded by multiple arcs. The longitudinal profile of the interface between the second wear-resistant material layer 92 and the tough material base 4 is composed of straight lines and curves. The input process is: insert the second core rod into the central through hole of the first blank and ensure that the central symmetry line coincides with the central through hole of the first blank, and the second wear-resistant layer of tungsten carbide hard alloy wear-resistant mixture The powder is filled between the central through hole of the first blank and the second core rod and compacted, and then the second core rod is pulled out. Tungsten carbide cemented carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder, and the particle size of WC powder is 7 μm. Tungsten carbide cemented carbide wear-resistant mixture is composed of WC powder, Co powder and VC powder, and WC powder particle size is 5 μm. .
燒結包含多段保溫燒結過程,分別為:Sintering consists of multiple thermal insulation sintering processes, which are:
預燒脫脂:在450℃的溫度,燒結3小時;Calcination and degreasing: sintering at 450 ° C for 3 hours;
燒結初級階段:在600℃的溫度,燒結3小時;Primary stage of sintering: sintering at 600 ℃ for 3 hours;
燒結收縮成型階段:在1200℃的溫度,燒結2小時;Sintering shrink molding stage: sintering for 2 hours at 1200 ° C;
燒結穩固成型階段:在1400℃的溫度,燒結1小時。Sintering and stable forming stage: sintering for 1 hour at a temperature of 1400 ° C.
其餘相同。The rest is the same.
實施例六Example Six
請參考第13圖至第14圖,本實施例與實施例一的差別在於,所述第一耐磨料層91和第二耐磨料層92的最大厚度為5mm,所述第二耐磨料層92橫截面的外輪廓由直線、弧線與曲線包圍而成,所述第二耐磨料層92與韌性料基體4結合介面的縱向剖面輪廓由直線、弧線與曲線組成,第一耐磨料層91設置於韌性料基體4的上表面和下表面,第二耐磨料層92的置入過程為:將第二芯棒插入第一料坯中心通孔內並保證其中心對稱線與第一料坯中心通孔內重合,將第二耐磨料層碳化鎢硬質合金耐磨混合料粉體填入第一料坯中心通孔與第二芯棒之間並壓實,然後拔出第二芯棒。。Please refer to FIG. 13 to FIG. 14. The difference between this embodiment and the first embodiment is that the maximum thickness of the first wear-resistant material layer 91 and the second wear-resistant material layer 92 is 5 mm, and the second wear-resistant material layer is 5 mm. The outer contour of the cross section of the material layer 92 is surrounded by straight lines, arcs and curves. The longitudinal profile of the interface of the second wear-resistant material layer 92 and the tough material base 4 is composed of straight lines, arcs and curves. The material layer 91 is disposed on the upper surface and the lower surface of the tough material base 4. The second wear-resistant material layer 92 is inserted as follows: the second core rod is inserted into the central through hole of the first material blank and the central symmetry line and The center through hole of the first blank is overlapped, and the tungsten carbide hard alloy wear-resistant mixture powder of the second wear layer is filled between the center through hole of the first blank and the second core rod and compacted, and then pulled out. Second mandrel. .
其餘相同。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為15μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為2μm。The rest is the same. Tungsten carbide carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder and the particle size of WC powder is 15 μm. Tungsten carbide hard alloy wear-resistant mixture is composed of WC powder, Co powder and VC powder and WC powder particle size is 2 μm. .
燒結包含多段保溫燒結過程,分別為:Sintering consists of multiple thermal insulation sintering processes, which are:
預燒脫脂:在350℃的溫度區間,燒結4小時;Calcination and degreasing: sintering for 4 hours at 350 ° C;
燒結初級階段:在700℃的溫度,燒結4小時;Primary stage of sintering: sintering at 700 ℃ for 4 hours;
燒結收縮成型階段:在1150℃的溫度,燒結2.5小時;Sintering shrink molding stage: sintering for 2.5 hours at 1150 ° C;
燒結穩固成型階段:在1400℃的溫度,燒結1.5小時。Sintering and solid forming stage: sintering at a temperature of 1400 ° C for 1.5 hours.
實施例七Example Seven
請參考第15圖至16,本實施例與實施例一的差別在於,所述第一耐磨料層91橫截面外輪廓的最大尺寸小於韌性料基體4的外徑,所述第一耐磨料層91橫截面的外輪廓為多邊形。碳化鎢硬質合金韌性混合料由WC粉、Co粉和Cr3C2粉構成且WC粉粒徑為9μm,碳化鎢硬質合金耐磨混合料由WC粉、Co粉和VC粉構成且WC粉粒徑為1μm。Please refer to FIGS. 15 to 16. The difference between this embodiment and the first embodiment is that the maximum size of the cross-sectional outer contour of the first wear-resistant material layer 91 is smaller than the outer diameter of the tough material base 4. The outer contour of the cross section of the material layer 91 is polygonal. Tungsten carbide carbide toughness mixture is composed of WC powder, Co powder and Cr3C2 powder and the particle size of WC powder is 9 μm, tungsten carbide hard alloy wear-resistant mixture is composed of WC powder, Co powder and VC powder and WC powder particle size is 1 μm .
其餘相同。The rest is the same.
實施例八Example eight
請參考第17圖,本實施例與實施例一的差別在於,所述第二耐磨料層92橫截面的內表面輪廓為多邊形。其餘相同。Please refer to FIG. 17. The difference between this embodiment and the first embodiment is that the inner surface profile of the cross section of the second wear-resistant material layer 92 is polygonal. The rest is the same.
實施例九Example Nine
請參考第18圖,本實施例與實施例一的差別在於,所述具有多層梯度結構的硬質合金螺絲螺帽模具外輪廓為圓臺結構,縱截面的外輪廓為梯形,所述第一耐磨料層91設置於圓臺的頂部表面。其餘相同。Please refer to FIG. 18. The difference between this embodiment and the first embodiment is that the outer contour of the hard alloy screw nut mold with a multi-layered gradient structure is a round table structure, and the outer contour of the longitudinal section is trapezoidal. The abrasive layer 91 is provided on the top surface of the circular table. The rest is the same.
雖然,上文中已經用一般性說明及具體實施例對本發明作了詳盡的描述,但在本發明基礎上,可以對之作一些修改或改進,這對本領域技術人員而言是顯而易見的。因此,在不偏離本發明精神的基礎上所做的這些修改或改進,均屬於本發明要求保護的範圍。Although the present invention has been described in detail with the general description and specific embodiments, it is obvious to those skilled in the art that some modifications or improvements can be made based on the present invention. Therefore, these modifications or improvements made without departing from the spirit of the present invention belong to the scope of protection of the present invention.
1‧‧‧外模具1‧‧‧ Outer Mould
2‧‧‧第二模套2‧‧‧Second mold set
3‧‧‧第一芯棒3‧‧‧ first mandrel
4‧‧‧韌性料基體4‧‧‧ ductile material matrix
5‧‧‧第一模套5‧‧‧The first mold sleeve
91‧‧‧第一耐磨料層91‧‧‧The first wear-resistant material layer
10‧‧‧中心通孔結構10‧‧‧ Center Through Hole Structure
92‧‧‧第一耐磨料層92‧‧‧The first wear-resistant material layer
第1圖本發明實施例一的韌性料基體料坯成型示意圖。 第2圖本發明實施例一的第一耐磨料層成型示意圖。 第3圖本發明實施例一的第一料坯示意圖。 第4圖本發明實施例一的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第5圖本發明實施例一的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第6圖本發明實施例二的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第7圖本發明實施例二的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第8圖本發明實施例三的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第9圖本發明實施例三的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第10圖本發明實施例四的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第11圖本發明實施例五的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第12圖本發明實施例五的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第13圖本發明實施例六的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第14圖本發明實施例六的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第15圖本發明實施例七的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。 第16圖本發明實施例七的具有多層梯度結構的硬質合金螺絲螺帽模具俯視示意圖。 第17圖本發明實施例八的具有多層梯度結構的硬質合金螺絲螺帽模具橫截面示意圖。 第18圖本發明實施例九的具有多層梯度結構的硬質合金螺絲螺帽模具縱剖面示意圖。FIG. 1 is a schematic diagram of forming a tough material matrix preform according to the first embodiment of the present invention. FIG. 2 is a schematic diagram of forming a first wear-resistant material layer according to the first embodiment of the present invention. FIG. 3 is a schematic view of a first billet according to the first embodiment of the present invention. FIG. 4 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to the first embodiment of the present invention. FIG. 5 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to the first embodiment of the present invention. FIG. 6 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to the second embodiment of the present invention. FIG. 7 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to the second embodiment of the present invention. FIG. 8 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 3 of the present invention. FIG. 9 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 3 of the present invention. FIG. 10 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 4 of the present invention. FIG. 11 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to Embodiment 5 of the present invention. FIG. 12 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 5 of the present invention. FIG. 13 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 6 of the present invention. FIG. 14 is a schematic longitudinal sectional view of a hard alloy screw nut mold having a multi-layered gradient structure in Embodiment 6 of the present invention. FIG. 15 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 7 of the present invention. FIG. 16 is a schematic top view of a hard alloy screw nut mold with a multi-layered gradient structure according to the seventh embodiment of the present invention. FIG. 17 is a schematic cross-sectional view of a hard alloy screw nut mold with a multi-layered gradient structure in Embodiment 8 of the present invention. FIG. 18 is a schematic longitudinal sectional view of a hard alloy screw nut mold with a multi-layered gradient structure according to Embodiment 9 of the present invention.
Claims (7)
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CN201810303648 | 2018-04-03 | ||
??CN201810303648.4 | 2018-04-03 | ||
CNCN201810303648.4 | 2018-04-03 | ||
CNCN201810741651.4 | 2018-07-09 | ||
CN201810741651.4A CN108620595B (en) | 2018-04-03 | 2018-07-09 | Hard alloy screw nut mold and its manufacturing method with multilayered and graded structure |
??CN201810741651.4 | 2018-07-09 |
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TWI669175B TWI669175B (en) | 2019-08-21 |
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TW107136011A TWI669175B (en) | 2018-04-03 | 2018-10-12 | A hard alloy screw nut mold having multi-layer gradient structure and thereof method |
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EP (1) | EP3650136A4 (en) |
CN (1) | CN108620595B (en) |
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JPS5656735A (en) * | 1979-10-17 | 1981-05-18 | Inoue Japax Res Inc | Improved die |
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CN100341647C (en) * | 2003-09-24 | 2007-10-10 | 自贡硬质合金有限责任公司 | Production process of wire drawing hard alloy die with gradient varying performance |
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JP2005342744A (en) * | 2004-06-01 | 2005-12-15 | Sanalloy Industry Co Ltd | Wear resistant sintered tool, and its manufacturing method |
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ES2720062T3 (en) * | 2006-11-20 | 2019-07-17 | Kk Miyanaga | Super hard tip and process to produce the same |
CN102168195A (en) * | 2011-04-13 | 2011-08-31 | 南京航空航天大学 | Method for preparing gradient porous Ti-Mg-based composite material |
CN102773371A (en) * | 2011-05-09 | 2012-11-14 | 智品精密机械有限公司 | Method for forming gasket or nut without scraps |
CN102434665B (en) * | 2011-09-15 | 2015-01-28 | 上海高更高实业有限公司 | Light gradient hard-alloy sealing ring and manufacture method thereof |
CN202877359U (en) * | 2012-09-26 | 2013-04-17 | 蚌埠凤凰滤清器有限责任公司 | Reinforced concave-convex mold core for thick plate mold of filter cleaner |
MX365368B (en) * | 2012-09-27 | 2019-05-30 | Allomet Corp | Methods of forming a metallic or ceramic article having a novel composition of functionally graded material and articles containing the same. |
CN103418788B (en) * | 2013-07-23 | 2015-05-20 | 浙江大学 | Device and method for thermoforming gradient materials |
CN103817150B (en) | 2014-02-26 | 2015-07-01 | 湖南天益高技术材料制造有限公司 | Gradient-structure hard alloy roll collar and manufacturing process thereof |
CN104057271B (en) * | 2014-07-04 | 2016-05-18 | 福建金鑫钨业股份有限公司 | A kind of preparation method of carbide alloy tool and mould |
CN104588500A (en) * | 2014-12-31 | 2015-05-06 | 苏州欧美克合金工具有限公司 | Nut producing mould |
CN204449293U (en) * | 2015-03-12 | 2015-07-08 | 成都工业学院 | A kind of sintered-carbide die |
CN205110786U (en) * | 2015-11-20 | 2016-03-30 | 碧梦技(上海)复合材料有限公司 | Powder metallurgy die |
CN105644026B (en) * | 2015-12-25 | 2018-08-03 | 洛阳金鹭硬质合金工具有限公司 | A kind of composite sheet matrix product with tri compound gradient-structure |
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CN206838934U (en) * | 2017-06-20 | 2018-01-05 | 鑫京瑞钨钢(厦门)有限公司 | High-performance carbide screw nut mould with multilayered and graded structure |
TWM549123U (en) * | 2017-06-27 | 2017-09-21 | Sinjingrui Tungsten Steel (Siamen) Co Ltd | High performance hard alloy screw/nut mold with multi-layer gradient structure |
TWM557151U (en) * | 2017-11-06 | 2018-03-21 | 承昌鎢鋼製品有限公司 | Multilayer-layer screws and nuts die |
CN107775006A (en) * | 2017-12-12 | 2018-03-09 | 鑫京瑞钨钢(厦门)有限公司 | A kind of gradient hard alloy DRILL POINT DIES |
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2018
- 2018-07-09 CN CN201810741651.4A patent/CN108620595B/en active Active
- 2018-08-08 WO PCT/CN2018/099317 patent/WO2019192114A1/en unknown
- 2018-08-08 EP EP18913306.9A patent/EP3650136A4/en not_active Withdrawn
- 2018-10-12 TW TW107136011A patent/TWI669175B/en active
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EP3650136A1 (en) | 2020-05-13 |
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EP3650136A4 (en) | 2020-07-08 |
WO2019192114A1 (en) | 2019-10-10 |
CN108620595B (en) | 2019-06-04 |
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