CN108610641A - A kind of aluminum strip based on flakey aluminium pigment - Google Patents

A kind of aluminum strip based on flakey aluminium pigment Download PDF

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Publication number
CN108610641A
CN108610641A CN201611232463.6A CN201611232463A CN108610641A CN 108610641 A CN108610641 A CN 108610641A CN 201611232463 A CN201611232463 A CN 201611232463A CN 108610641 A CN108610641 A CN 108610641A
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CN
China
Prior art keywords
parts
aluminium pigment
flakey
aluminum strip
polymer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611232463.6A
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Chinese (zh)
Inventor
刘海
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Shanghai New Materials Co Ltd Jin Ride
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Shanghai New Materials Co Ltd Jin Ride
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Priority to CN201611232463.6A priority Critical patent/CN108610641A/en
Publication of CN108610641A publication Critical patent/CN108610641A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62Metallic pigments or fillers
    • C09C1/64Aluminium
    • C09C1/648Aluminium treated with inorganic and organic, e.g. polymeric, compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • C09C3/063Coating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10Treatment with macromolecular organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment

Abstract

The invention discloses a kind of aluminum strips based on flakey aluminium pigment, are made of following parts by weight:5 99 parts of flakey aluminium pigment, 1 95 parts of wax, 15 parts of aluminium oxide, 24 parts of organic polymer, 35 parts of inorganic matter, 37 parts of polymer.The strip flakey aluminium pigment of the present invention is a kind of i.e. environmental protection (Diamond Search discharge), and the safety product (without dust pollution, no dust explosion risk) without application risk after improvement.Plastics, ink can be simply and easily widely used in, the fields such as paint solve the problems, such as that VOC emission is very high very big to environmental hazard and aluminium powder is very easy to that dust explosion occurs.

Description

A kind of aluminum strip based on flakey aluminium pigment
Technical field
The present invention relates to aluminium pigment technical field, specially a kind of aluminum strip based on flakey aluminium pigment.
Background technology
Squamaceous aluminium pigment is typically pulpous state, and the form supply of material of paste or powdery, these pigment are frequently referred to aluminum paste Or aluminium powder.The aluminium pigment of these forms is widely used in paint, the fields such as ink and plastics, the aluminium face of forms but these are supplied Material has very big harm to environment, to health.Contain a large amount of volatile solvents inside aluminium paste, VOC emission is very high to ring Border harm is very big;These solvents are inflammable and explosive simultaneously, abnormally dangerous.Aluminium powder is very easy to that dust explosion, elder brother in 2016 occurs Mountain aluminium powder dust explosion is exactly wherein typical case;In addition the dust of aluminium powder also seriously affects the health of operating personnel.
Invention content
The purpose of the present invention is to provide a kind of aluminum strip based on flakey aluminium pigment, strip flakey aluminium face of the invention Material is a kind of i.e. environmental protection (Diamond Search discharge), and safety product (without dust pollution, no dust without application risk after improvement Risk of explosion).Plastics can be simply and easily widely used in, ink, it is very high to environment that the fields such as paint solve VOC emission The problem of harm is very big and aluminium powder is very easy to that dust explosion occurs.
To achieve the above object, the present invention provides the following technical solutions:A kind of aluminum strip based on flakey aluminium pigment, by with Lower parts by weight are constituted:5-99 parts of flakey aluminium pigment, 1-95 parts of wax, 1-5 parts of aluminium oxide, 2-4 parts of organic polymer, inorganic matter 3- 5 parts, 3-7 parts of polymer.
Preferably, the organic polymer includes one kind of acrylate copolymer, alkyd polymer and polyester resin.
Preferably, the inorganic matter includes one kind of silica, titanium oxide and zirconium oxide.
Preferably, the polymer includes polyethylene wax (PE waxes), polypropylene wax (PP waxes), ethane-acetic acid ethyenyl copolymerization Wax (EVA waxes), oxidized polyethylene wax, acrylic resin and alkyd resin are one such or a variety of.
Preferably, production method is as follows:
S1, pigment processing:Above-mentioned flakey aluminium pigment is coated into aluminium oxide, organic polymer and inorganic matter successively;
S2, mixed processing:The temperature of mixing machine is adjusted to 25-250 degrees Celsius, by wax, polymer and the squama wrapped It is mixed in sheet aluminium pigment input mixing machine, and removes solvent, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 100-250 degrees Celsius, discharge diameter It adjusting to 0.01-8 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine to 0.01-100 millimeters, from And obtain aluminum strip.
Preferably, wrappage includes following combination in the flakey aluminium pigment:Alumina layer, alumina layer+titanium dioxide Silicon layer, alumina layer+polymeric layer, alumina layer+silicon dioxide layer+polymeric layer, alumina layer+polymeric layer+titanium dioxide Silicon layer.
Preferably, the screw machine is single-screw machine or dual-screw-stem machine.
Compared with prior art, beneficial effects of the present invention are as follows:
1, by adding aluminium oxide, organic polymer, inorganic matter and polymer, when using novel pigment aluminum strip of the invention There is no dust and solvent contamination, keeps entire working environment more clean, more healthy to human body.The aluminum strip of the present invention is a kind of non- Dangerous material, client as using traditional aluminium pigment using dangerous material special transport vehicle without being transported, without with dangerous material storehouse Library stores, and production and transportation cost all greatly reduces in these.
2, the present invention allows harmful environment, traditional aluminium pigment for having risk of explosion and being detrimental to health to become a kind of Environmental-friendly novel pigment aluminum strip without risk of explosion and without health hazard.
3, novel pigment aluminum strip of the invention is applied to ink, paints and exempts from the fields such as painted plastic to make to compare conventional aluminum The better color effect of pigment, and it is more convenient to use quick.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme of the present invention is clearly and completely described, it is clear that Described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to The scope of protection of the invention.
A kind of aluminum strip based on flakey aluminium pigment, is made of following parts by weight:5-99 parts of flakey aluminium pigment, wax 1-95 Part, 1-5 parts of aluminium oxide, 2-4 parts of organic polymer, 3-5 parts of inorganic matter, 3-7 parts of polymer.
In the present invention, organic polymer includes one kind of acrylate copolymer, alkyd polymer and polyester resin.
In the present invention, inorganic matter includes one kind of silica, titanium oxide and zirconium oxide.
In the present invention, polymer includes polyethylene wax (PE waxes), polypropylene wax (PP waxes), ethane-acetic acid ethyenyl copolymerization wax (EVA waxes), oxidized polyethylene wax, acrylic resin and alkyd resin are one such or a variety of.
In the present invention, production method is as follows:
S1, pigment processing:Above-mentioned flakey aluminium pigment is coated into aluminium oxide, organic polymer and inorganic matter successively;
S2, mixed processing:The temperature of mixing machine is adjusted to 25-250 degrees Celsius, by wax, polymer and the squama wrapped It is mixed in sheet aluminium pigment input mixing machine, and removes solvent, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 100-250 degrees Celsius, discharge diameter It adjusting to 0.01-8 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine to 0.01-100 millimeters, from And obtain aluminum strip.
In the present invention, wrappage includes following combination in flakey aluminium pigment:Alumina layer, alumina layer+silica Layer, alumina layer+polymeric layer, alumina layer+silicon dioxide layer+polymeric layer, alumina layer+polymeric layer+silica Layer.
In the present invention, screw machine is single-screw machine or dual-screw-stem machine.
Embodiment 1
A kind of aluminum strip based on flakey aluminium pigment, production method are as follows:
S1, pigment processing:Above-mentioned 8 parts of flakey aluminium pigments are coated into upper 2 parts of aluminium oxide, 2 parts of organic polymers and 3 successively Part inorganic matter;
S2, mixed processing:The temperature of mixing machine is adjusted to 190 degrees Celsius, by 6 parts of waxes, 3 polymer and wrap 8 It is mixed in part flakey aluminium pigment input mixing machine, and removes solvent, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 190 degrees Celsius, discharging diameter adjustment To 3 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine, to 30 millimeters to obtain aluminum strip.
Embodiment 2
A kind of aluminum strip based on flakey aluminium pigment, production method are as follows:
S1, pigment processing:By above-mentioned 10 parts of flakey aluminium pigments coat successively upper 3 parts of aluminium oxide, 3 parts of organic polymers and 4 parts of inorganic matters;
S2, mixed processing:The temperature of mixing machine adjusted to 210 degrees Celsius, by 7 parts of waxes, 4 parts of polymer and is wrapped It is mixed in 10 parts of flakey aluminium pigment input mixing machines, and removes solvent, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 210 degrees Celsius, discharging diameter adjustment To 5 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine, to 40 millimeters to obtain aluminum strip.
Embodiment 3
A kind of aluminum strip based on flakey aluminium pigment, production method are as follows:
S1, pigment processing:By above-mentioned 12 parts of flakey aluminium pigments coat successively upper 5 parts of aluminium oxide, 4 parts of organic polymers and 5 parts of inorganic matters;
S2, mixed processing:The temperature of mixing machine is adjusted to 220 degrees Celsius, by 10 parts of waxes, 7 parts of polymer and is wrapped 12 parts of flakey aluminium pigments input mixing machine in mixed, and solvent is removed, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 220 degrees Celsius, discharging diameter adjustment To 6 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine, to 50 millimeters to obtain aluminum strip.
Embodiment 4
4 parts of 6 parts of the flakey aluminium paste and polyethylene chloroflo of aluminium oxide will be coated, mixing machine has been added to, at 180 degrees Celsius Under conditions of mix 30 minutes, and under conditions of 200 degrees Celsius solvent volatilize remove.Then it is squeezed using single-screw machine Go out aluminum strip granulation, the bore of single-screw machine is 4 millimeters.
Embodiment 5
5 parts of 5 parts of the flakey aluminium paste and polyethylene chloroflo of aluminium oxide will be coated, mixing machine has been added to, at 180 degrees Celsius Under conditions of mix 30 minutes, and under conditions of 200 degrees Celsius solvent volatilize remove.Then it is squeezed using single-screw machine Go out aluminum strip granulation, the bore of single-screw machine is 5 millimeters.
Embodiment 6
6 parts of 4 parts of the flakey aluminium paste and acrylic resin of aluminium oxide will be coated, mixing machine has been added to, at 200 degrees Celsius Under conditions of mix 30 minutes, and under conditions of 200 degrees Celsius solvent volatilize remove.Then it is squeezed using single-screw machine Go out aluminum strip granulation, the bore of single-screw machine is 4 millimeters.
Embodiment 7
3 parts of 7 parts of the flakey aluminium paste and ethane-acetic acid ethyenyl copolymerization wax (EVA waxes) of aluminium oxide will be coated, has been added to mixed Conjunction machine mixes 30 minutes under conditions of 200 degrees Celsius, and solvent is volatilized under conditions of 200 degrees Celsius and is removed.Then make It is carried out squeezing out aluminum strip granulation with single-screw machine, the bore of single-screw machine is 4 millimeters.
Concrete case
One client of somewhere wants to do the silver-like effect plastic products of Gao Bailiang always, attempts many traditional aluminium pastes and aluminium powder, But because these aluminium pigment pieces are easy to be destroyed by machine, it is unable to reach the metal sense and white luminance of customer requirement. After product of the present invention, it is found that the metal sense of silver color and white luminance are obviously improved, and the requirement of client can be reached.Finally Client is obtained to approve and smoothly take order.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of aluminum strip based on flakey aluminium pigment, which is characterized in that be made of following parts by weight:Flakey aluminium pigment 5-99 Part, 1-95 parts of wax, 1-5 parts of aluminium oxide, 2-4 parts of organic polymer, 3-5 parts of inorganic matter, 3-7 parts of polymer.
2. a kind of aluminum strip based on flakey aluminium pigment according to claim 1, it is characterised in that:The organic polymer Include one kind of acrylate copolymer, alkyd polymer and polyester resin.
3. a kind of aluminum strip based on flakey aluminium pigment according to claim 1, it is characterised in that:The inorganic matter includes One kind of silica, titanium oxide and zirconium oxide.
4. a kind of aluminum strip based on flakey aluminium pigment according to claim 1, it is characterised in that:The polymer includes Polyethylene wax (PE waxes), polypropylene wax (PP waxes), ethane-acetic acid ethyenyl copolymerization wax (EVA waxes), oxidized polyethylene wax, acrylic acid Resin and alkyd resin are one such or a variety of.
5. a kind of aluminum strip based on flakey aluminium pigment according to claim 1, which is characterized in that its production method is such as Under:
S1, pigment processing:Above-mentioned flakey aluminium pigment is coated into aluminium oxide, organic polymer and inorganic matter successively;
S2, mixed processing:The temperature of mixing machine is adjusted to 25-250 degrees Celsius, by wax, polymer and the flakey wrapped It is mixed in aluminium pigment input mixing machine, and removes solvent, to obtain mixture;
S3, extruding and discharging:Screw machine is chosen, the temperature of screw machine is then adjusted to 100-250 degrees Celsius, discharging diameter adjustment To 0.01-8 millimeters, then discharging length adjustment the mixture in S2 is added in screw machine to 0.01-100 millimeters, to Go out aluminum strip.
6. a kind of aluminum strip based on flakey aluminium pigment according to claim 1,2,3 or 5, it is characterised in that:The squama Wrappage includes following combination in sheet aluminium pigment:Alumina layer, alumina layer+silicon dioxide layer, alumina layer+polymer Layer, alumina layer+silicon dioxide layer+polymeric layer, alumina layer+polymeric layer+silicon dioxide layer.
7. a kind of aluminum strip based on flakey aluminium pigment according to claim 5, it is characterised in that:The screw machine is single Screw machine or dual-screw-stem machine.
CN201611232463.6A 2016-12-28 2016-12-28 A kind of aluminum strip based on flakey aluminium pigment Pending CN108610641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611232463.6A CN108610641A (en) 2016-12-28 2016-12-28 A kind of aluminum strip based on flakey aluminium pigment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611232463.6A CN108610641A (en) 2016-12-28 2016-12-28 A kind of aluminum strip based on flakey aluminium pigment

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110172252A (en) * 2019-03-20 2019-08-27 杭州伊斯特塑料制品有限公司 A kind of high temperature hot investment casting wax
CN110172253A (en) * 2019-03-20 2019-08-27 杭州伊斯特塑料制品有限公司 A kind of high temperature precision casting wax

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0374472A (en) * 1989-08-17 1991-03-29 Asahi Kasei Metals Kk Aluminum pigment, its production and metallic coating material containing the same
JP2001031909A (en) * 1999-07-21 2001-02-06 Nippon Paint Co Ltd Bright coating composition, coating film forming method and laminated coating film
CN101445675A (en) * 2008-12-12 2009-06-03 温州亦柏化工有限公司 Colored aluminum pigment with high color depth and preparation method thereof
CN101805457A (en) * 2010-04-23 2010-08-18 长沙族兴金属颜料有限公司 Special aluminium pigment for plastics and preparation method thereof
CN105566726A (en) * 2016-02-02 2016-05-11 合肥旭阳铝颜料有限公司 Strip aluminum pigment and preparation method thereof
CN106147028A (en) * 2016-07-27 2016-11-23 合肥旭阳铝颜料有限公司 A kind of modified water magnesite strengthens the aluminum pigment of resistance to UV aging

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0374472A (en) * 1989-08-17 1991-03-29 Asahi Kasei Metals Kk Aluminum pigment, its production and metallic coating material containing the same
JP2001031909A (en) * 1999-07-21 2001-02-06 Nippon Paint Co Ltd Bright coating composition, coating film forming method and laminated coating film
CN101445675A (en) * 2008-12-12 2009-06-03 温州亦柏化工有限公司 Colored aluminum pigment with high color depth and preparation method thereof
CN101805457A (en) * 2010-04-23 2010-08-18 长沙族兴金属颜料有限公司 Special aluminium pigment for plastics and preparation method thereof
CN105566726A (en) * 2016-02-02 2016-05-11 合肥旭阳铝颜料有限公司 Strip aluminum pigment and preparation method thereof
CN106147028A (en) * 2016-07-27 2016-11-23 合肥旭阳铝颜料有限公司 A kind of modified water magnesite strengthens the aluminum pigment of resistance to UV aging

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110172252A (en) * 2019-03-20 2019-08-27 杭州伊斯特塑料制品有限公司 A kind of high temperature hot investment casting wax
CN110172253A (en) * 2019-03-20 2019-08-27 杭州伊斯特塑料制品有限公司 A kind of high temperature precision casting wax

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