CN108641468A - A kind of formula of alcohol aqueous composite ink - Google Patents

A kind of formula of alcohol aqueous composite ink Download PDF

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Publication number
CN108641468A
CN108641468A CN201810811652.1A CN201810811652A CN108641468A CN 108641468 A CN108641468 A CN 108641468A CN 201810811652 A CN201810811652 A CN 201810811652A CN 108641468 A CN108641468 A CN 108641468A
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CN
China
Prior art keywords
parts
aqueous composite
formula
pigment
composite ink
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810811652.1A
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Chinese (zh)
Inventor
陆伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhangjiagang City Department Of Dingxin Mstar Technology Ltd
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Zhangjiagang City Department Of Dingxin Mstar Technology Ltd
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Priority to CN201810811652.1A priority Critical patent/CN108641468A/en
Publication of CN108641468A publication Critical patent/CN108641468A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of formulas of alcohol aqueous composite ink, become according to parts by weight group:50~80 parts of acrylic vinegar resin, 20~30 parts of urethane acrylate, 15~25 parts of ethyl alcohol, 15~25 parts of isopropanol, 10~20 parts of pigment, 0.3~1 part of levelling agent, 0.5~1.5 part of antioxidant, 3~5 parts of dispersant, 0.5~1.5 part of antifoaming agent, 0.2~0.8 part of adhesion promoter, 10~20 parts of deionized water.Alcohol aqueous composite ink in the present invention using ethyl alcohol and isopropanol make solvent have the advantages that it is safe and environment-friendly, and by adding adhesion promoter, with preferable adhesive force.

Description

A kind of formula of alcohol aqueous composite ink
Technical field
The present invention relates to field of ink manufacture, more particularly to a kind of formula of alcohol aqueous composite ink.
Background technology
In recent years, with the rapid development of packaging industry, plastic gravure ink market is also constantly expanding.Intaglio printing oil Ink is very extensive in plastics package sector application, such as food, medicine, feed, agricultural product, articles for daily use packaging field.
Traditional gravure ink depends on the molten type chlorination polypropylene resin of benzene for a long time, and benzene and ketone must be used as solvent, Due to largely using benzene and ketone as solvent, food, the compound packet of medical plastics in the Flexible-Packaging Industry printed using this ink The contained printing ink solvent residual quantity long-term existence of dress is benzene, ketone by the release rate and release characteristics standard testing result of pollutant It is exceeded, and the residues such as benzene, ketone, dimethylbenzene are very big to human injury, therefore cause food, pharmaceuticals industry long-term existence hidden safely Suffer from.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of formula of alcohol aqueous composite ink, existing skill can be solved The problem of art.
Invention content
The purpose of the present invention is to provide a kind of formulas of alcohol aqueous composite ink, to overcome deficiency in the prior art.
To achieve the above object, the present invention provides the following technical solutions:
A kind of formula of alcohol aqueous composite ink, becomes according to parts by weight group:50~80 parts of acrylic vinegar resin, polyurethane 20~30 parts of acrylate, 15~25 parts of ethyl alcohol, 15~25 parts of isopropanol, 10~20 parts of pigment, 0.3~1 part of levelling agent, antioxygen 0.5~1.5 part of agent, 3~5 parts of dispersant, 0.5~1.5 part of antifoaming agent, 0.2~0.8 part of adhesion promoter, deionized water 10~20 parts.
Preferably, become according to parts by weight group:60~80 parts of acrylic vinegar resin, 24~30 parts of urethane acrylate, 18~25 parts of ethyl alcohol, 18~25 parts of isopropanol, 13~20 parts of pigment, 0.5~1 part of levelling agent, 0.75~1.5 part of antioxidant, 3.75~5 parts of dispersant, 0.8~1.5 part of antifoaming agent, 0.4~0.8 part of adhesion promoter, 12~20 parts of deionized water.
Preferably, become according to parts by weight group:70~80 parts of acrylic vinegar resin, 28~30 parts of urethane acrylate, 22~25 parts of ethyl alcohol, 22~25 parts of isopropanol, 16~20 parts of pigment, 0.8~1 part of levelling agent, 1.25~1.5 parts of antioxidant, 4.5~5 parts of dispersant, 1.1~1.5 parts of antifoaming agent, 0.6~0.8 part of adhesion promoter, 16~20 parts of deionized water.
Preferably, the pigment is using yellow uitramarine, red pigment, blue pigment, viridine green, black pigment, white One kind in pigment.
Preferably, the levelling agent uses SR3088.
Preferably, the dispersant uses BYK-191.
Preferably, the antifoaming agent uses butylphosphoric acid ester.
Preferably, the adhesion promoter is using sour modified chlorinated polyolefin.
Compared with the prior art, the advantages of the present invention are as follows:Alcohol aqueous composite ink in the present invention is using ethyl alcohol and different Propyl alcohol make solvent have the advantages that it is safe and environment-friendly, and by add adhesion promoter, have preferable adhesive force.
Specific implementation mode
The present invention is described further by the following example:According to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of formula of alcohol aqueous composite ink, becomes according to parts by weight group:Acrylic vinegar resin 50~ 80 parts, 20~30 parts of urethane acrylate, 15~25 parts of ethyl alcohol, 15~25 parts of isopropanol, 10~20 parts of pigment, levelling agent 0.3~1 part, 0.5~1.5 part of antioxidant, 3~5 parts of dispersant, 0.5~1.5 part of antifoaming agent, adhesion promoter 0.2~ 0.8 part, 10~20 parts of deionized water.
Wherein, the pigment is using yellow uitramarine, red pigment, blue pigment, viridine green, black pigment, white face One kind in material.
Wherein, the levelling agent uses SR3088.
Wherein, the dispersant uses BYK-191.
Wherein, the antifoaming agent uses butylphosphoric acid ester.
Wherein, the adhesion promoter is using sour modified chlorinated polyolefin.
Following formulas that the alcohol aqueous composite ink in the present invention is illustrated with specifically embodiment.
Embodiment 1
Become according to parts by weight group:50 parts of acrylic vinegar resin, 20 parts of urethane acrylate, 15 parts of ethyl alcohol, isopropanol 15 parts, 10 parts of pigment, 0.3 part of levelling agent, 0.5 part of antioxidant, 3 parts of dispersant, 0.5 part of antifoaming agent, adhesion promoter 0.2 Part, 10 parts of deionized water.
Embodiment 2
Become according to parts by weight group:60 parts of acrylic vinegar resin, 24 parts of urethane acrylate, 18 parts of ethyl alcohol, isopropanol 18 parts, 13 parts of pigment, 0.5 part of levelling agent, 0.75 part of antioxidant, 3.75 parts of dispersant, 0.8 part of antifoaming agent, adhesive force promotion 0.4 part of agent, 12 parts of deionized water.
Embodiment 3
Become according to parts by weight group:70 parts of acrylic vinegar resin, 28 parts of urethane acrylate, 22 parts of ethyl alcohol, isopropanol 22 parts, 16 parts of pigment, 0.8 part of levelling agent, 1.25 parts of antioxidant, 4.5 parts of dispersant, 1.1 parts of antifoaming agent, adhesion promoter 0.6 part, 16 parts of deionized water.
Embodiment 4
Become according to parts by weight group:80 parts of acrylic vinegar resin, 30 parts of urethane acrylate, 25 parts of ethyl alcohol, isopropanol 25 parts, 20 parts of pigment, 1 part of levelling agent, 1.5 parts of antioxidant, 5 parts of dispersant, 1.5 parts of antifoaming agent, adhesion promoter 0.8 Part, 20 parts of deionized water.
Alcohol aqueous composite ink in the present invention using ethyl alcohol and isopropanol make solvent have the advantages that it is safe and environment-friendly.It is logical It crosses and the adhesive force of alcohol aqueous composite ink in the present invention is tested, the results showed that, according to the formula in the various embodiments described above The adhesive force of obtained alcohol aqueous composite ink is preferable, has broad application prospects.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that including a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (8)

1. a kind of formula of alcohol aqueous composite ink, which is characterized in that become according to parts by weight group:Acrylic vinegar resin 50~80 Part, 20~30 parts of urethane acrylate, 15~25 parts of ethyl alcohol, 15~25 parts of isopropanol, 10~20 parts of pigment, levelling agent 0.3 ~1 part, 0.5~1.5 part of antioxidant, 3~5 parts of dispersant, 0.5~1.5 part of antifoaming agent, adhesion promoter 0.2~0.8 Part, 10~20 parts of deionized water.
2. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that become according to parts by weight group:Third 60~80 parts of olefin(e) acid vinegar resin, 24~30 parts of urethane acrylate, 18~25 parts of ethyl alcohol, 18~25 parts of isopropanol, pigment 13 ~20 parts, 0.5~1 part of levelling agent, 0.75~1.5 part of antioxidant, 3.75~5 parts of dispersant, 0.8~1.5 part of antifoaming agent is attached 0.4~0.8 part of adhesion promoter, 12~20 parts of deionized water.
3. the formula of alcohol aqueous composite ink according to claim 2, which is characterized in that become according to parts by weight group:Third 70~80 parts of olefin(e) acid vinegar resin, 28~30 parts of urethane acrylate, 22~25 parts of ethyl alcohol, 22~25 parts of isopropanol, pigment 16 ~20 parts, 0.8~1 part of levelling agent, 1.25~1.5 parts of antioxidant, 4.5~5 parts of dispersant, 1.1~1.5 parts of antifoaming agent is attached 0.6~0.8 part of adhesion promoter, 16~20 parts of deionized water.
4. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that the pigment uses yellow face One kind in material, red pigment, blue pigment, viridine green, black pigment, white pigment.
5. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that the levelling agent uses SR3088。
6. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that the dispersant uses BYK- 191。
7. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that the antifoaming agent uses phosphoric acid fourth Ester.
8. the formula of alcohol aqueous composite ink according to claim 1, which is characterized in that the adhesion promoter uses Sour modified chlorinated polyolefin.
CN201810811652.1A 2018-07-23 2018-07-23 A kind of formula of alcohol aqueous composite ink Withdrawn CN108641468A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111019432A (en) * 2019-12-05 2020-04-17 曾令涛 Printing ink for 3D composite board mobile phone shell and preparation method thereof
CN113861755A (en) * 2021-10-08 2021-12-31 苏州中亚油墨有限公司 Environment-friendly printing ink and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010631A (en) * 2009-10-29 2011-04-13 成都市新津托展油墨有限公司 Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof
CN104804531A (en) * 2015-04-23 2015-07-29 黎司华 Environmental-friendly water-soluble composite printing ink and preparation method thereof
CN107760095A (en) * 2017-12-01 2018-03-06 云南红塔油墨有限公司 Water-based gravure gold ink and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010631A (en) * 2009-10-29 2011-04-13 成都市新津托展油墨有限公司 Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof
CN104804531A (en) * 2015-04-23 2015-07-29 黎司华 Environmental-friendly water-soluble composite printing ink and preparation method thereof
CN107760095A (en) * 2017-12-01 2018-03-06 云南红塔油墨有限公司 Water-based gravure gold ink and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111019432A (en) * 2019-12-05 2020-04-17 曾令涛 Printing ink for 3D composite board mobile phone shell and preparation method thereof
CN113861755A (en) * 2021-10-08 2021-12-31 苏州中亚油墨有限公司 Environment-friendly printing ink and preparation method thereof
CN113861755B (en) * 2021-10-08 2022-06-21 苏州中亚油墨有限公司 Environment-friendly printing ink and preparation method thereof

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Application publication date: 20181012

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