CN103183831A - Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin - Google Patents
Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin Download PDFInfo
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- CN103183831A CN103183831A CN201110447380XA CN201110447380A CN103183831A CN 103183831 A CN103183831 A CN 103183831A CN 201110447380X A CN201110447380X A CN 201110447380XA CN 201110447380 A CN201110447380 A CN 201110447380A CN 103183831 A CN103183831 A CN 103183831A
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Abstract
The invention specifically relates to a universal binder resin for a water-based plastic surface printing ink, a preparation method thereof and a printing ink using the binder resin, belonging to the field of printing inks. The binder resin provided by the invention is prepared through the following steps: subjecting a modified rosin resin and an amide oligopolymer to a condensation reaction so as to produce an intermediate product with a carboxyl group; allowing the intermediate product and a resin containing multiple carboxyl groups to undergo polymerization; and carrying out amination so as to obtain the water-soluble binder resin. Because of introduction of an acylamino group, the binder resin has good adhesion, luster and printing adaptability on a variety of plastic film substrates. According to the invention, the preparation method for the binder resin is simple; the prepared printing ink has good printing adaptability and is applicable to surface printing of a variety of plastic film substrates, and since water is used as a solvent, the printing ink has no irritant gas and is green and environment-friendly.
Description
Technical field
The present invention relates to ink area, binder of using of a kind of universal water-based plastic table printing ink and preparation method thereof specifically, and relate to a kind of printing ink that adopts this binder resin.
Background technology
In recent years, continuous lifting along with living standards of the people, the packaging industry fast development, thereby make plastics base gravure ink technology and market constantly develop, its range of application has almost comprised all packaging fields, as all types of plastic film substrate packing in industries such as food, medicine, agricultural byproducts, daily necessities.Yet the printing-ink that is used for the plastic wrapping industry at present is still traditional solvent series, contains a large amount of toxic and harmful substances more, comprises residual solvent, organic volatile and polycyclic aromatic hydrocarbons etc.Although the conventional plastic printing-ink is oiliness and pure dissolubility, dissolvent residual etc. has been done strict demand, but still can cause severe contamination to air, water source, food etc., to the people's work environment and healthy very major injury arranged.
For adapting to social development to the pursuit of " green and environmental protection ", satisfy the human consumer to the demand of environmental protection, relevant printing ink enterprise and research institution are devoted to the research and development of " green and environmental protection " printing ink always, in the hope of substituting traditional oiliness or alcohol-soluble printing ink with cleanliness without any pollution, oligosaprobic alcohol-soluble and water-soluble or water-based printing ink, thereby alleviate to the pollution of environment with to the threat of HUMAN HEALTH.Yet printing ink is by resin binder, pigment, auxiliary agent and solvent composition, and the fundamental property of printing ink mainly is to be provided by the resin binder in the component as solvent system selection, base material sticking power, compound ability etc.Therefore, for promoting the development of the water-soluble and water color ink of alcohol, improve the sticking power of printing ink on all types of plastic film substrate, satisfy the application requiring under the different condition, also obtained corresponding research as the resin binder of plastics base gravure ink core component.A kind of preparation method of polyamide resin used for alcohol-soluble ink is disclosed as number of patent application CN00126683.7, number of patent application CN200810018555.3 discloses a kind of alcohol-soluble polyurethane soluble in water and preparation method thereof, number of patent application CN200910059587.2 discloses the preparation method that a kind of single-fluid general plastic gravure alcohol-soluble and water-soluble composite China ink is used polyacrylic ester-polyurethane resin binder, number of patent application CN200910311941.6 has announced a kind of water-soluble ink connecting material resin for plastic and preparation method thereof, the ink used for plastic of these resin binders and preparation is compared with traditional oiliness or alcohol-soluble printing ink, has good environment-friendly advantage.But because the poor adhesive force of above-mentioned technical products, rate of drying is slow, can not satisfy print request, does not therefore obtain promoting.
Summary of the invention
In order to address the above problem, the invention provides a kind of alcohol water-soluble or water-soluble, without benzene, ketone equal solvent, overcome benzene, ketone equal solvent for the ink printed on surface of plastic of the pollution problem of environment binder resin.
The present invention is achieved in that
A kind of water-based plastic table stamp-pad ink ink connecting material resin, described binder comprises the product that is obtained by following reaction with resin:
(1) modified rosin resin and the condensation reaction of amides oligopolymer are generated the intermediate product that has carboxyl;
(2) described intermediate product with contain the polymerization of many carboxy resins after, become water-soluble binder through amination;
Wherein the weight part of each reactant is: 17 parts of modified rosin resin 11-, amides oligopolymer 8-15 part, many carboxy resins 6-12 part, amine 8-14 part, water 52-64 part.As preferably: 14 parts of modified rosin resins, 8 parts of amides oligopolymers, 8 parts of many carboxy resins, 9 parts of amine, 61 parts in water.Because the introducing of amide group makes it have good sticking power, gloss and printing adaptability to all types of plastic film substrate.
Preferably, described modified rosin resin is the modified rosin resin that modified by polyacid rosin and polyvalent alcohol esterification addition obtain, and its acid number scope is at 130-190mgKOH/g.
Preferably, described amides oligopolymer is reactive polyamide resin.The amides oligopolymer is that molecular weight is at the polymkeric substance that is no more than 5 nanometers below 1500 with molecular length, polyamide resin can improve glossiness, sticking power, wet pigments, printability, tint retention and the stereoplasm content of this system, thereby enlarged the range of application of printing ink, its nontoxicity, free from extraneous odour.
The described resin that contains many carboxyls can list but be not limited to: toxilic acid or fumaric acid or methylene-succinic acid or acrylic resin, perhaps styrene-propene acid copolymer, perhaps vinylbenzene-a-vinyl toluene-acrylic copolymer.
Preferably, described amine is the mixture of Monoethanolamine MEA BASF and ammoniacal liquor.
Preferably, described Monoethanolamine MEA BASF: ammoniacal liquor=0 ~ 3:3 ~ 0.
Another object of the present invention provides the method for the described water-based plastic table stamp-pad ink ink connecting material resin of preparation, and described method is:
A) preparation modified rosin resin adds the amides oligopolymer then and carries out condensation reaction, constant temperature 1 ~ 2 hour under 230 ℃ of conditions of constant temperature;
B) after a step reaction finishes, add and contain carboxy resin, constant temperature is 1 ~ 1.5 hour under 230 ℃ of conditions;
C) after b step constant temperature is finished, be cooled to 150 ~ 170 ℃, in the mixed solution that the b step reaction makes, slowly add Monoethanolamine MEA BASF and carry out amination;
D) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards.
Wherein, the preparation method of described modified rosin can for:
A) rosin is put into the reactor that reflux exchanger is housed, fed nitrogen protection, be heated to 180 ℃ and make rosin melt fully, add polyprotonic acid isothermal reaction 2 hours;
B) persistently overheating to 250 ℃, add polyvalent alcohol and carry out esterification, the time kept 40-60 minute.
Described polyprotonic acid can list but be not limited to MALEIC ANHYDRIDE or FUMARIC ACID TECH GRADE acid anhydride.
Described polyvalent alcohol can list but be not limited to: glycerine, trimethylolethane, tetramethylolmethane etc.
The invention also discloses a kind of universal water-based plastic table printing ink that adopts above-mentioned binder resin, described printing ink comprises the composition of following weight part:
60 ~ 75 parts of above-mentioned binder resins, 15 ~ 25 parts of deionized waters, 10 ~ 15 parts of pigment, auxiliary agent 0.1-1 part.
Described universal water-based plastic table printing ink can adopt ordinary method, can select following technology:
With 15 ~ 25 parts of deionized waters, 60 ~ 75 parts of above-mentioned waterborne binder resins, 10 ~ 15 parts of pigment, 0.1 ~ 1 part of adding blender loader of auxiliary agent, stirred 20 minutes with high speed dispersor, it is mixed; The material that mixes is taken out, sends into sand mill and carry out sand milling, treat that fineness is lower than 15 microns after, filter, after the assay was approved packing.
Binder resin provided by the invention is that alcohol is water-soluble or water-soluble, without benzene, ketone equal solvent, overcome benzene, ketone equal solvent for the pollution problem of environment, has alleviated environment to external world to a great extent, to worker laboring environment's pollution, environmental protection; And this kind binder resin does not need with more alcohol, ester etc. to have lower irritating smell as solvent, and in use great deal of raw materials has been saved in almost zero VOC discharging; Use this binder resin and also have good adhesion, rate of drying is fast, can make printing product surface smooth, beautiful in colour, has good printing effect.And its preparation method is simple, easily control.
Universal water-based plastic table printing ink provided by the invention has overcome the shortcoming of conventional plastic table printing ink, and described aqueous printing ink is as solvent, except having advantages such as nonirritant gas, environmental protection, printing adaptability is good, especially has the following advantages:
(1) strong coloring force, printing lovely luster, glossiness height;
(2) strong adhesion, wear resisting property are good;
(3) water repelling property is good, water boiling resistance;
(4) nontoxic, tasteless, meet the requirement of current food, agricultural byproducts packing.
Embodiment
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1:
The prescription of according to the form below 1 reacts:
Table 1
| Material name | Weight part |
| Gum Rosin | 11.5 |
| MALEIC ANHYDRIDE | 2.89 |
| Glycerine | 0.62 |
| Versamid 115 | 7.5 |
| 678 | 7.5 |
| Monoethanolamine MEA BASF | 3 |
| Ammoniacal liquor | 6 |
| Deionized water | 61 |
| Total amount | 100 |
Annotate: Versamid 115 is the peaceful response type polymeric amide of section
678 is village minister solid alkali soluble acrylic resin
A) rosin is put into the reactor that reflux exchanger is housed, logical nitrogen protection is heated to 180 ℃ and makes rosin melt fully, adds 180 ~ 200 ℃ of reactions of MALEIC ANHYDRIDE constant temperature 2 hours;
B) persistently overheating to 250 ℃, add the glycerine polyvalent alcohol and carry out esterification, 260 ~ 275 ℃ of constant temperature were kept 40-60 minute;
C) after step b finishes, be cooled to 230 ~ 240 ℃, add Versamid 115 isothermal reactions 1 ~ 2 hour;
D) keep 230 ~ 240 ℃, add 678, isothermal reaction 1 ~ 1.5 hour;
E) stop heating, be cooled to 150 ~ 170 ℃, slowly add Monoethanolamine MEA BASF and carry out amination;
F) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards, discharging is filtered then, obtains printing ink binder water-base resin.
The performance perameter of this resin is: outward appearance is the scarlet transparent liquid, and viscosity is 1500 ± 500mPa.s/25 ℃, pH value 8 ~ 9, and second-order transition temperature is 60 ~ 80 ℃, amount of solid content is 30 ± 2%.
Embodiment 2
The prescription of according to the form below 2 reacts:
Table 2
| Material name | Weight part |
| Gum Rosin | 12.2 |
| MALEIC ANHYDRIDE | 3 |
| Glycerine | 0.91 |
| Versamid 115 | 9.5 |
| 0663 | 6.35 |
| Monoethanolamine MEA BASF | 3 |
| Ammoniacal liquor | 8 |
| Deionized water | 57 |
| Total amount | 100 |
Annotate: Versamid 115 is the peaceful response type polymeric amide of section
0663 is self-control solid alkali soluble acrylic resin
A) rosin is put into the reactor that reflux exchanger is housed, logical nitrogen protection is heated to 180 ℃ makes rosin melt fully, adds 180 ~ 200 ℃ of reactions of MALEIC ANHYDRIDE constant temperature 2 hours;
B) persistently overheating to 250 ℃, add the glycerine polyvalent alcohol and carry out esterification, 260 ~ 275 ℃ of constant temperature were kept 40-60 minute;
C) after step b finishes, be cooled to 230 ~ 240 ℃, add Versamid 115 isothermal reactions 1 ~ 2 hour;
D) keep 230 ~ 240 ℃, add 0663, isothermal reaction 1 ~ 1.5 hour;
E) stop heating, be cooled to 150 ~ 170 ℃, slowly add Monoethanolamine MEA BASF and carry out amination;
F) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards, discharging is filtered then, obtains printing ink binder water-base resin.
The performance perameter of this binder resin is: outward appearance is the scarlet transparent liquid, and viscosity is 2000 ± 500mPa.s/25 ℃, pH value 8 ~ 9, and second-order transition temperature is 60 ~ 80 ℃, amount of solid content is 32 ± 2%.
Embodiment 3
The prescription of according to the form below 3 reacts:
Table 3
| Material name | Weight part |
| Gum Rosin | 13.4 |
| MALEIC ANHYDRIDE | 3.37 |
| Glycerine | 0.72 |
| Macromelt 6239 | 8.75 |
| 678 | 8.75 |
| Monoethanolamine MEA BASF | 3.5 |
| Ammoniacal liquor | 7 |
| Deionized water | 54.5 |
| Total amount | 100 |
Annotate: Macromelt 6239 is Henkel polyamide oligomer as well as
678 is village minister solid alkali soluble acrylic resin
A) rosin is put into the reactor that reflux exchanger is housed, logical nitrogen protection is heated to 180 ℃ makes rosin melt fully, adds 180 ~ 200 ℃ of reactions of MALEIC ANHYDRIDE constant temperature 2 hours;
B) persistently overheating to 250 ℃, add the glycerine polyvalent alcohol and carry out esterification, 260 ~ 275 ℃ of constant temperature were kept 40-60 minute;
C) after step b finishes, be cooled to 230 ~ 240 ℃, add Macromelt 6239 isothermal reactions 1 ~ 2 hour;
D) keep 230 ~ 240 ℃, add 678, isothermal reaction 1 ~ 1.5 hour;
E) stop heating, be cooled to 150 ~ 170 ℃, slowly add Monoethanolamine MEA BASF and carry out amination;
F) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards, discharging is filtered then, obtains printing ink binder water-base resin.
The performance perameter of this binder resin is: outward appearance is the scarlet transparent liquid, and viscosity is 2000 ± 500mPa.s/25 ℃, pH value 8 ~ 9, and second-order transition temperature is 60 ~ 80 ℃, amount of solid content is 35 ± 2%.
Embodiment 4
The prescription of according to the form below 4 reacts:
Table 4
| Material name | Weight percent |
| Gum Rosin | 10.7 |
| MALEIC ANHYDRIDE | 2.7 |
| Tetramethylolmethane | 0.58 |
| Macromelt 6239 | 8.4 |
| 678 | 5.6 |
| Monoethanolamine MEA BASF | 2.8 |
| Ammoniacal liquor | 5.6 |
| Deionized water | 63.6 |
| ? | 100 |
Annotate: Macromelt 6239 is Henkel polyamide oligomer as well as
678 is village minister solid alkali soluble acrylic resin
A) rosin is put into the reactor that reflux exchanger is housed, logical nitrogen protection is heated to 180 ℃ makes rosin melt fully, adds 180 ~ 200 ℃ of reactions of MALEIC ANHYDRIDE constant temperature 2 hours;
B) persistently overheating to 250 ℃, add the tetramethylolmethane polyvalent alcohol and carry out esterification, 260 ~ 275 ℃ of constant temperature were kept 40-60 minute;
C) after step b finishes, be cooled to 230 ~ 240 ℃, add Macromelt 6239 isothermal reactions 1 ~ 2 hour;
D) keep 230 ~ 240 ℃, add 678, isothermal reaction 1 ~ 1.5 hour;
E) stop heating, be cooled to 150 ~ 170 ℃, slowly add Monoethanolamine MEA BASF and carry out amination;
F) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards, discharging is filtered then, obtains printing ink binder water-base resin.
The performance perameter of this binder resin is: outward appearance is the scarlet transparent liquid, and viscosity is 1500 ± 500mPa.s/25 ℃, pH value 8 ~ 9, and second-order transition temperature is 60 ~ 80 ℃, amount of solid content is 28 ± 2%.
Embodiment 5
With 25 parts of deionized waters, water-based plastic table printing ink with 60 parts of binder water-base resins, pigment too 10 parts of golden red, 0.2 part of silicone antifoam agent, 0.1 part in tensio-active agent, 1 part of adding blender loader of wax emulsion, stirred 20 minutes with high speed dispersor, it is mixed; The material that mixes is taken out, sends into sand mill and carry out sand milling, treat that fineness is lower than 15 microns after, filter; Through after the assay was approved, packing namely makes universal water-based plastic table printing ink.
Its key technical indexes sees Table 5:
Table 5
| Project | Technical indicator |
| Color | Approximate standard specimen |
| Fineness (μ m) | ≤15 |
| Tinting strength (%) | 95~110 |
| Viscosity (coating 4# cup, second, 25 ℃) | 50±5 |
| First dryness (mm/30 second) | 20~50 |
| Water tolerance | 48 hours |
| Rub resistance | Rubbing 10 times does not fade |
Embodiment 6
With 18 parts of deionized waters, 70 parts of binder water-base resins of water-based plastic table printing ink, blue 12 parts of monastral blue, 0.2 part of silicone antifoam agent, 0.1 part in tensio-active agent, 1 part of adding blender loader of wax emulsion, stirred 20 minutes with high speed dispersor, it is mixed; The material that mixes is taken out, sends into sand mill and carry out sand milling, treat that fineness is lower than 15 microns after, filter; Through after the assay was approved, packing namely makes universal water-based plastic table printing ink.
Its key technical indexes sees Table 6:
Table 6
| Project | Technical indicator |
| Color | Approximate standard specimen |
| Fineness (μ m) | ≤15 |
| Tinting strength (%) | 95~110 |
| Viscosity (coating 4# cup, second, 25 ℃) | 45±10 |
| First dryness (mm/30 second) | 20~50 |
| Water tolerance | 48 hours |
| Rub resistance | Rubbing 10 times does not fade |
Embodiment 7
With 25 parts of deionized waters, 75 parts of binder water-base resins of water-based plastic table printing ink, blue 15 parts of monastral blue, 0.2 part of silicone antifoam agent, 0.1 part in tensio-active agent, 1 part of adding blender loader of wax emulsion, stirred 20 minutes with high speed dispersor, it is mixed; The material that mixes is taken out, sends into sand mill and carry out sand milling, treat that fineness is lower than 15 microns after, filter; Through after the assay was approved, packing namely makes universal water-based plastic table printing ink.
Its key technical indexes sees Table 7:
Table 7
| Project | Technical indicator |
| Color | Approximate standard specimen |
| Fineness (μ m) | ≤15 |
| Tinting strength (%) | 95~110 |
| Viscosity (coating 4# cup, second, 25 ℃) | 45±10 |
| First dryness (mm/30 second) | 20~50 |
| Water tolerance | 48 hours |
| Rub resistance | Rubbing 10 times does not fade |
As can be seen, printing ink tinting strength provided by the invention, water tolerance, wear resistance all are significantly improved from table 5-7.
More than technical scheme that the embodiment of the invention is provided be described in detail, used specific case herein principle and the embodiment of the embodiment of the invention are set forth, the explanation of above embodiment only is applicable to the principle that helps to understand the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, the part that on embodiment and range of application, all can change, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1. water-based plastic table stamp-pad ink ink connecting material resin, it is characterized in that: described binder comprises the product that is obtained by following reaction with resin:
(1) modified rosin resin and the condensation reaction of amides oligopolymer are generated the intermediate product that has carboxyl;
(2) described intermediate product with contain the polymerization of many carboxy resins after, become water-soluble binder through amination;
Wherein the weight part of each reactant is: 17 parts of modified rosin resin 11-, amides oligopolymer 8-15 part, many carboxy resins 6-12 part, amine 8-14 part, water 52-64 part.
2. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 1, it is characterized in that: described modified rosin resin is the modified rosin resin that modified by polyacid rosin and polyvalent alcohol esterification addition obtain, and its acid number scope is at 130-190mgKOH/g.
3. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 1, it is characterized in that: described amides oligopolymer is reactive polyamide resin.
4. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 1, it is characterized in that: the described resin that contains many carboxyls is toxilic acid or fumaric acid or methylene-succinic acid or acrylic resin, perhaps styrene-propene acid copolymer, perhaps vinylbenzene-a-vinyl toluene-acrylic copolymer.
5. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 1, it is characterized in that: described amine is the mixture of Monoethanolamine MEA BASF and ammoniacal liquor, described Monoethanolamine MEA BASF: ammoniacal liquor=0 ~ 3:3 ~ 0.
6. method for preparing the described water-based plastic table of one of claim 1 ~ 5 stamp-pad ink ink connecting material resin, it is characterized in that: described method is:
A) preparation modified rosin resin adds the amides oligopolymer then and carries out condensation reaction, constant temperature 1 ~ 2 hour under 230 ℃ of conditions of constant temperature;
B) after a step reaction finishes, add and contain carboxy resin, constant temperature is 1 ~ 1.5 hour under 230 ℃ of conditions;
C) after b step constant temperature is finished, be cooled to 150 ~ 170 ℃, in the mixed solution that the b step reaction makes, slowly add Monoethanolamine MEA BASF and carry out amination;
D) continue to be cooled to below 100 ℃, slowly add ammoniacal liquor and carry out amination reaction, add the required water yield afterwards.
7. the method for preparing water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 6, it is characterized in that: the preparation method of described modified rosin is:
A) rosin is put into the reactor that reflux exchanger is housed, fed nitrogen protection, be heated to 180 ℃ and make rosin melt fully, add polyprotonic acid isothermal reaction 2 hours;
B) persistently overheating to 250 ℃, add polyvalent alcohol and carry out esterification, the time kept 40-60 minute.
8. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 7, it is characterized in that: described polyprotonic acid is MALEIC ANHYDRIDE or FUMARIC ACID TECH GRADE acid anhydride.
9. water-based plastic table stamp-pad ink ink connecting material resin as claimed in claim 7, it is characterized in that: described polyvalent alcohol is glycerine, tetramethylolmethane.
10. universal water-based plastic table printing ink, it is characterized in that: described printing ink comprises the composition of following weight part:
60 ~ 75 parts of the described binder resins of one of claim 1 ~ 5,15 ~ 25 parts of deionized waters, 10 ~ 15 parts of pigment, auxiliary agent 0.1-1 part.
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| CN201110447380.XA CN103183831B (en) | 2011-12-28 | 2011-12-28 | Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263076A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly coca-red double-PE ink and preparation method thereof |
| CN106244235A (en) * | 2016-08-10 | 2016-12-21 | 昆明理工大学 | A kind of Preparation method and use of lignite wax resin modified thing |
| CN107964278A (en) * | 2017-12-22 | 2018-04-27 | 澧县津溥包装制品有限责任公司 | One kind printing ink and preparation method |
| CN109321031A (en) * | 2018-05-23 | 2019-02-12 | 江苏唐彩油墨科技股份有限公司 | Heat shrink films aqueous intaglio printing ink and preparation method thereof |
| CN110643219A (en) * | 2019-11-14 | 2020-01-03 | 云南开放大学 | Gravure ink for printing PET aluminum-plated film |
| CN112795021A (en) * | 2020-12-31 | 2021-05-14 | 广东银洋环保新材料有限公司 | Degradable water-based plastic ink binder resin and preparation method thereof |
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| CN108410254B (en) * | 2018-01-31 | 2021-03-19 | 广东英科集团股份有限公司 | Water-based binder and food-contactable water-based ink prepared from same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973617A (en) * | 1988-08-15 | 1990-11-27 | Basf Corporation | Water-borne surface printing inks containing acrylic resin and carboxylated rosin modified polyamide |
| CN101649161A (en) * | 2009-07-31 | 2010-02-17 | 张家港市阳光化工有限公司 | Preparation method of high-viscosity rosin resin |
-
2011
- 2011-12-28 CN CN201110447380.XA patent/CN103183831B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973617A (en) * | 1988-08-15 | 1990-11-27 | Basf Corporation | Water-borne surface printing inks containing acrylic resin and carboxylated rosin modified polyamide |
| CN101649161A (en) * | 2009-07-31 | 2010-02-17 | 张家港市阳光化工有限公司 | Preparation method of high-viscosity rosin resin |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263076A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly coca-red double-PE ink and preparation method thereof |
| CN104263076B (en) * | 2014-10-24 | 2015-12-30 | 成都普瑞斯特新材料有限公司 | Laughable red pair of PE ink of environment-friendly type and preparation method thereof |
| CN106244235A (en) * | 2016-08-10 | 2016-12-21 | 昆明理工大学 | A kind of Preparation method and use of lignite wax resin modified thing |
| CN107964278A (en) * | 2017-12-22 | 2018-04-27 | 澧县津溥包装制品有限责任公司 | One kind printing ink and preparation method |
| CN109321031A (en) * | 2018-05-23 | 2019-02-12 | 江苏唐彩油墨科技股份有限公司 | Heat shrink films aqueous intaglio printing ink and preparation method thereof |
| CN109321031B (en) * | 2018-05-23 | 2021-12-07 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure printing ink for heat shrinkable film and preparation method thereof |
| CN110643219A (en) * | 2019-11-14 | 2020-01-03 | 云南开放大学 | Gravure ink for printing PET aluminum-plated film |
| CN112795021A (en) * | 2020-12-31 | 2021-05-14 | 广东银洋环保新材料有限公司 | Degradable water-based plastic ink binder resin and preparation method thereof |
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