CN107955411A - A kind of modified oxidized iron oxide red pigment - Google Patents
A kind of modified oxidized iron oxide red pigment Download PDFInfo
- Publication number
- CN107955411A CN107955411A CN201711068169.0A CN201711068169A CN107955411A CN 107955411 A CN107955411 A CN 107955411A CN 201711068169 A CN201711068169 A CN 201711068169A CN 107955411 A CN107955411 A CN 107955411A
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- CN
- China
- Prior art keywords
- parts
- iron oxide
- oxide red
- modified oxidized
- slag
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention provides a kind of modified oxidized iron oxide red pigment, includes the component of following parts by weight:Lin Suan 45 55 parts, 480 520 parts of 400 500 parts of di-iron trioxide and slag;Iron oxide content >=90, the pigment water extract pH value 37.The present invention is a kind of powdered composite inorganic iron oxide pigment of dark red palladium, iron oxide content >=90,37,600 screen residue≤1 of water extract pH value, 100 ± 5,105 DEG C of volatile matter≤1 of tinting strength, tinting power, oil absorption 20 ± 5, covering power≤10, the hydrotrope≤1.
Description
Technical field
The present invention relates to pigment technology field, and in particular to a kind of modified oxidized iron oxide red pigment.
Background technology
Iron oxide red is the traditional pigment of comparison, and application is very wide, it is common to use in works such as building, rubber, plastics, coating
Industry.It is good rust resisting pigment in coating industry iron oxide red, particularly iron oxide red primer has antirust function, can replace high price
Red lead paint, save non-ferrous metal.For anti-corrosive primer, performance requirement is higher and higher, and traditional iron oxide red exists
Application requirement in antiseptic and rustproof paint also accordingly strengthens, and in order to adapt to the development of industry, traditional iron oxide red is carried out corresponding
Modification, it is imperative to improve its comprehensive performance.
The content of the invention
(1) technical problem solved
The present invention provides a kind of modified oxidized iron oxide red pigment, the deficiencies in the prior art are overcome, are a kind of dark red palladium powder
Last shape composite inorganic iron oxide pigment, iron oxide content >=90, water extract pH value 3-7,600 screen residue≤1, tinting strength, tinting power
100 ± 5,105 DEG C of volatile matter≤1, oil absorption 20 ± 5, covering power≤10, the hydrotrope≤1.
A kind of modified oxidized iron oxide red pigment, includes the component of following parts by weight:Lin Suan 45-55 parts, di-iron trioxide
400-500 parts and 480-520 parts of slag;Iron oxide content >=90, the pigment water extract pH value 3-7.
The Lin Suan 45 parts, 480 parts of 400 parts of di-iron trioxide and slag.
The Lin Suan 55 parts, 520 parts of 500 parts of di-iron trioxide and slag.
The Lin Suan 50 parts, 500 parts of 450 parts of di-iron trioxide and slag.
A kind of preparation method of modified oxidized iron oxide red pigment, a) by above-mentioned phosphorus acid , di-iron trioxide and slag in proportion
Carry out being added to material bin startup mixing arrangement, mix 20~40 minutes;
B) slurry that weight concentration is 45~50% is made in mixed material addition deionized water, with the weight with iron oxide red
Amount is than the vinyl alkoxy phosphate and 0.2~0.3% alcamines dispersant of meter, in the slurry addition 1~3%, high speed
It is scattered it is sufficiently mixed uniformly, after the drying materials mixed, it is small that anaerobic calcining 3~3.5 is carried out at 200~100 DEG C
When, cooling crush is up to product.
(3) beneficial effect
An embodiment of the present invention provides modified oxidized iron oxide red pigment.Possesses following beneficial effect:The present invention is a kind of dark red
The powdered composite inorganic iron oxide pigment of palladium, iron oxide content >=90, water extract pH value 3-7,600 screen residue≤1,
100 ± 5,105 DEG C of volatile matter≤1 of color power, oil absorption 20 ± 5, covering power≤10, the hydrotrope≤1.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
All other embodiments obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1, a kind of modified oxidized iron oxide red pigment, includes the components of following parts by weight:The Lin Suan 45 parts, three oxygen
Change 480 parts of 400 parts of two iron and slag;Iron oxide content >=90, the pigment water extract pH value 3-7.
A kind of preparation method of modified oxidized iron oxide red pigment, a) by above-mentioned phosphorus acid , di-iron trioxide and slag in proportion
Carry out being added to material bin startup mixing arrangement, mix 20~40 minutes;
B) slurry that weight concentration is 45~50% is made in mixed material addition deionized water, with the weight with iron oxide red
Amount is than the vinyl alkoxy phosphate and 0.2~0.3% alcamines dispersant of meter, in the slurry addition 1~3%, high speed
It is scattered it is sufficiently mixed uniformly, after the drying materials mixed, it is small that anaerobic calcining 3~3.5 is carried out at 200~100 DEG C
When, cooling crush is up to product.
Embodiment 2, a kind of modified oxidized iron oxide red pigment, includes the components of following parts by weight:The Lin Suan 55 parts, three oxygen
Change 520 parts of 500 parts of two iron and slag;Iron oxide content >=90, the pigment water extract pH value 3-7.
A kind of preparation method of modified oxidized iron oxide red pigment, a) by above-mentioned phosphorus acid , di-iron trioxide and slag in proportion
Carry out being added to material bin startup mixing arrangement, mix 20~40 minutes;
B) slurry that weight concentration is 45~50% is made in mixed material addition deionized water, with the weight with iron oxide red
Amount is than the vinyl alkoxy phosphate and 0.2~0.3% alcamines dispersant of meter, in the slurry addition 1~3%, high speed
It is scattered it is sufficiently mixed uniformly, after the drying materials mixed, it is small that anaerobic calcining 3~3.5 is carried out at 200~100 DEG C
When, cooling crush is up to product.
Embodiment 3, a kind of modified oxidized iron oxide red pigment, includes the components of following parts by weight:The Lin Suan 50 parts, three oxygen
Change 500 parts of 450 parts of two iron and slag;Iron oxide content >=90, the pigment water extract pH value 3-7.
A kind of preparation method of modified oxidized iron oxide red pigment, a) by above-mentioned phosphorus acid , di-iron trioxide and slag in proportion
Carry out being added to material bin startup mixing arrangement, mix 20~40 minutes;
B) slurry that weight concentration is 45~50% is made in mixed material addition deionized water, with the weight with iron oxide red
Amount is than the vinyl alkoxy phosphate and 0.2~0.3% alcamines dispersant of meter, in the slurry addition 1~3%, high speed
It is scattered it is sufficiently mixed uniformly, after the drying materials mixed, it is small that anaerobic calcining 3~3.5 is carried out at 200~100 DEG C
When, cooling crush is up to product.
The present invention is a kind of powdered composite inorganic iron oxide pigment of dark red palladium, iron oxide content >=90, water extract
PH value 3-7,600 screen residue≤1,100 ± 5,105 DEG C of volatile matter≤1 of tinting strength, tinting power, oil absorption 20 ± 5, covering power≤10, water
Molten thing≤1.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Non-exclusive inclusion, so that process, method, article or equipment including a series of elements not only will including those
Element, but also including other elements that are not explicitly listed, or further include as this process, method, article or equipment
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Also there are other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those of ordinary skill in the art that:It still can be to foregoing each implementation
Technical solution described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention skill scheme.
Claims (5)
- A kind of 1. modified oxidized iron oxide red pigment, it is characterised in that:Include the component of following parts by weight:Lin Suan 45-55 parts, three oxygen Change 480-520 parts of 400-500 parts of two iron and slag;Iron oxide content >=90, the pigment water extract pH value 3-7.
- A kind of 2. modified oxidized iron oxide red pigment according to claim 1, it is characterised in that:The Lin Suan 45 parts, three oxygen Change 480 parts of 400 parts of two iron and slag.
- A kind of 3. modified oxidized iron oxide red pigment according to claim 1, it is characterised in that:The Lin Suan 55 parts, three oxygen Change 520 parts of 500 parts of two iron and slag.
- A kind of 4. modified oxidized iron oxide red pigment according to claim 1, it is characterised in that:The Lin Suan 50 parts, three oxygen Change 500 parts of 450 parts of two iron and slag.
- A kind of 5. preparation method of modified oxidized iron oxide red pigment according to claim 1, it is characterised in that:A) by above-mentioned phosphorus Suan , di-iron trioxide and slag carry out being added to material bin in proportion and start mixing arrangement, mix 20~40 minutes;B) slurry that weight concentration is 45~50% is made in mixed material addition deionized water, with the weight ratio with iron oxide red Meter, adds 1~3% vinyl alkoxy phosphate and 0.2~0.3% alcamines dispersant, high speed dispersion in the slurry It is set to be sufficiently mixed uniformly, it is cold when progress anaerobic calcining 3~3.5 is small at 200~100 DEG C after the drying materials mixed But crush up to product.
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CN201711068169.0A CN107955411A (en) | 2017-11-03 | 2017-11-03 | A kind of modified oxidized iron oxide red pigment |
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CN201711068169.0A CN107955411A (en) | 2017-11-03 | 2017-11-03 | A kind of modified oxidized iron oxide red pigment |
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CN201711068169.0A Pending CN107955411A (en) | 2017-11-03 | 2017-11-03 | A kind of modified oxidized iron oxide red pigment |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109897399A (en) * | 2019-03-04 | 2019-06-18 | 吉林大学 | A kind of modified iron oxide red and the preparation method and application thereof |
CN111154292B (en) * | 2020-01-22 | 2021-08-03 | 湘潭湘钢瑞兴公司 | Method for preparing low-cost iron oxide black pigment from steel plant converter iron slag |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86100780A (en) * | 1986-01-28 | 1987-10-07 | 淄博钴厂 | A kind of manufacture method of ferric oxide red colorant |
CN1057277A (en) * | 1990-06-11 | 1991-12-25 | 宣化县氧化铁颜料厂 | A kind of production method of ferric oxide red colorant |
CN104004396A (en) * | 2014-06-03 | 2014-08-27 | 上海宝冶钢渣综合开发实业有限公司 | Anti-rust and extender integrated pigment and preparation method thereof |
CN104073050A (en) * | 2014-06-15 | 2014-10-01 | 安徽奥邦新材料有限公司 | Modified iron oxide red pigment and preparation method thereof |
CN104212222A (en) * | 2014-09-24 | 2014-12-17 | 广西新晶科技有限公司 | Application, composite anti-rusting pigment and parathion method of calcium phosphate aluminum silicate |
-
2017
- 2017-11-03 CN CN201711068169.0A patent/CN107955411A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86100780A (en) * | 1986-01-28 | 1987-10-07 | 淄博钴厂 | A kind of manufacture method of ferric oxide red colorant |
CN1057277A (en) * | 1990-06-11 | 1991-12-25 | 宣化县氧化铁颜料厂 | A kind of production method of ferric oxide red colorant |
CN104004396A (en) * | 2014-06-03 | 2014-08-27 | 上海宝冶钢渣综合开发实业有限公司 | Anti-rust and extender integrated pigment and preparation method thereof |
CN104073050A (en) * | 2014-06-15 | 2014-10-01 | 安徽奥邦新材料有限公司 | Modified iron oxide red pigment and preparation method thereof |
CN104212222A (en) * | 2014-09-24 | 2014-12-17 | 广西新晶科技有限公司 | Application, composite anti-rusting pigment and parathion method of calcium phosphate aluminum silicate |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109897399A (en) * | 2019-03-04 | 2019-06-18 | 吉林大学 | A kind of modified iron oxide red and the preparation method and application thereof |
CN111154292B (en) * | 2020-01-22 | 2021-08-03 | 湘潭湘钢瑞兴公司 | Method for preparing low-cost iron oxide black pigment from steel plant converter iron slag |
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PB01 | Publication | ||
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Application publication date: 20180424 |