CN108609971B - Cement-based tile adhesive and composition for preparing same - Google Patents

Cement-based tile adhesive and composition for preparing same Download PDF

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Publication number
CN108609971B
CN108609971B CN201810558857.3A CN201810558857A CN108609971B CN 108609971 B CN108609971 B CN 108609971B CN 201810558857 A CN201810558857 A CN 201810558857A CN 108609971 B CN108609971 B CN 108609971B
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cement
tile adhesive
composition
sand
based tile
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CN108609971A (en
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梁志豪
龚兴宇
黄莉恒
吴家伟
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Keshun Waterproof Technology Co Ltd
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Keshun Waterproof Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • C04B2111/00646Masonry mortars
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Finishing Walls (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a cement-based tile adhesive, which comprises a composition, wherein the composition comprises the following raw materials in percentage by mass: 80.00-90.00% of ordinary portland cement; 5.00-10.00% of low-alkalinity sulphoaluminate cement; 2.00-10.00% of redispersible latex powder; 1.25% -2.00% of cellulose ether; 0.25% -0.50% of guar gum powder; 1.00-6.00% of an early strength agent; the composition also comprises sand and water, wherein the mass ratio of the composition to the sand is as follows: the composition sand = 1:4, and the water accounts for 10% -15% of the total mass. Compared with the prior art, the cement-based tile adhesive provided by the invention has the advantages that the shrinkage rate of a system is well reduced by increasing the amount of aggregate (sand) in a formula to more than 65%, so that the tile adhesive can be thickly pasted, and meanwhile, the production cost is greatly reduced.

Description

Cement-based tile adhesive and composition for preparing same
Technical Field
The invention relates to the field of building materials, in particular to a cement-based tile adhesive and a composition for preparing the adhesive.
Background
At present, marble materials or ceramic tiles are mostly used for building floors on the market, and the marble materials or the ceramic tiles have the characteristics of easiness in cleaning, stain resistance, water resistance, corrosion resistance, wear resistance and the like, so that the building floors are widely used for floor decoration of public places such as civil buildings, large-sized markets, office buildings, hospitals and the like, and when the marble materials or the ceramic tiles are constructed, the ceramic bonding materials are used for bonding the marble materials or the ceramic tiles to the ground.
At present, the tile sticking material is mainly a cement-based tile adhesive which is popularized and used, and the adhesive is used for sticking tiles by utilizing the occlusion force and the van der Waals molecular force, thereby being very suitable for the trend of the current tiles towards low water absorption rate. However, the widespread effect of cement-based tile adhesives is not ideal at present, and the main reasons for this are: because the cement-based tile adhesive has good water-retaining property, the drying speed of the cement-based tile adhesive is slow, and the probability of shrinkage of the tile adhesive is increased along with the increase of the thickness of the tile adhesive, the interface bonding strength is low, and the brick falling phenomenon is likely to occur, so the cement-based tile adhesive needs to adopt a thin-pasting method (the pasting thickness is 3-5 mm). However, the prior domestic building wall surface is difficult to meet the requirement of a thin pasting construction method on the flatness of the wall surface (a guiding rule with the length of 2m is used for checking the flatness of a base layer, and the tolerance cannot exceed +/-3 mm). In addition, the cost of using cement-based tile adhesives is high and still unacceptable for most projects.
Disclosure of Invention
In order to solve the problem that the existing cement-based tile adhesive can not be pasted thickly, the invention provides a tile adhesive which is quick-drying and can be pasted thickly and a composition for preparing the tile adhesive.
In order to realize the purpose of the invention, the following technical scheme is adopted for realizing the purpose:
the cement-based tile adhesive comprises a composition, wherein the composition comprises the following raw materials in percentage by mass:
Figure BDA0001682570780000011
Figure BDA0001682570780000021
the composition also comprises sand, wherein the mass ratio of the composition to the sand is as follows: the composition and sand are 1: 4.
Because the proportion of the quartz sand in the invention reaches 80 percent, the anti-shrinkage capability of the system is greatly improved, the invention can be constructed for one time without shrinkage of 50mm, can achieve the integrated effect of leveling the base course and pasting the ceramic tiles, is suitable for the current situation that the base course is not flat at present, greatly reduces the application difficulty of the cement-based ceramic tile adhesive, reduces the requirement on constructors, and is very suitable for comprehensive popularization. Wherein, because the composition is added with the coagulation accelerating early strength agent, the early strength is high, and the composition can be applied to people after being pasted for 6 hours at normal temperature, and the drying speed is 50 percent faster than that of the traditional ceramic tile adhesive.
In addition, the composition in the formula can be called as concentrated tile adhesive, can be directly packaged and delivered, and can be directly used for obtaining the tile adhesive by taking medium sand and water and stirring into paste on a construction site. The formula of the composition provided by the invention only comprises the powder of the tile adhesive, does not comprise sand, and utilizes the convenience of taking quartz sand at a construction site nearby, so that the transportation cost of the traditional tile adhesive from a factory to the construction site is reduced compared with that of the traditional tile adhesive, the transportation cost of 1 ton of concentrated tile adhesive is equivalent to that of 5 tons of traditional tile adhesive, the production cost and the transportation cost from the factory to the construction site can be greatly reduced, and the cost reduction range reaches 80%.
In practical application, the composition and the medium sand on the construction site are taken, the mixing mass ratio of the composition to the medium sand is 1:4, after the mixture is uniformly mixed, water accounting for 10% -15% of the total mass is added, and the mixture is stirred into paste to be directly used. Wherein the total mass refers to the sum of the mass of the composition and the mass of the sand. For the cement-based tile adhesive obtained after water is added, the proportion of sand (aggregate) in the whole system is 70-73%, and the system has excellent shrinkage resistance, small shrinkage rate and high interface bonding strength, and is very suitable for being applied to a thick paste process.
Further, the quartz sand used by the traditional tile adhesive is selected quartz sand, the factory machine is generally adopted to select and grade standard quartz sand, the price is high (about 300 yuan/ton), the concentrated tile adhesive uses the existing concrete medium sand (the grain diameter is about 0.25-0.5 mm) of a construction site, and the price of the medium sand of the construction site is low (about 50 yuan/ton). Meanwhile, the proportion of quartz sand in the tile adhesive in the formula provided by the invention accounts for more than 65%, and according to the calculation, compared with the traditional tile adhesive, the tile adhesive obtained by mixing the concentrated tile adhesive with sand in a construction site can be reduced by about 162.5 yuan per ton of tile adhesive, so that the production cost of the invention is greatly reduced. In addition, the tile adhesive obtained by mixing the concentrated tile adhesive with the sand in a construction site has high bonding strength and good water resistance and heat resistance.
Further, the Portland cement is Portland cement No. 42.5 or Portland cement No. 52.5; the sulphoaluminate cement is No. 42.5 low-alkalinity quick-hardening sulphoaluminate cement or No. 52.5 low-alkalinity quick-hardening sulphoaluminate cement; the latex powder is one or more of vinyl acetate and ethylene copolymer rubber powder, ethylene, vinyl chloride and vinyl laurate ternary copolymer rubber powder, vinyl acetate, ethylene and higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate and higher fatty acid vinyl ester copolymer rubber powder, vinyl acetate, acrylate and higher fatty acid vinyl ester ternary copolymer rubber powder, acrylate and styrene copolymer rubber powder or acrylic acid homopolymerization rubber powder, and butadiene and styrene copolymer rubber powder; the cellulose ether is hydroxyethyl methyl cellulose ether and/or hydroxypropyl methyl cellulose ether, and the viscosity is 20000 mPa.S-50000 mPa.S; the guar gum powder is guar gum powder, and the viscosity is 60000-200000 mPa.S; the early strength agent is calcium salt series.
Compared with the prior art, the cement-based tile adhesive provided by the invention has the advantages that the amount of aggregate (sand) in the formula is increased to more than 65%, the shrinkage rate of the system is well reduced, the tile adhesive can be pasted thickly, and meanwhile, the production cost is greatly reduced. The invention also provides a composition for preparing the tile adhesive, and the composition can greatly reduce the transportation cost and the production cost of the tile adhesive and further reduce the application cost due to the full utilization of the medium sand in a construction site.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention are described in further detail below.
In the following examples, Portland cement is Portland cement No. 42.5, Portland cement No. 42.5R and Portland cement No. 52.5R, which are provided by Ender sea snail Cement Limited liability company; the low-alkalinity quick-hardening sulphoaluminate cement is No. 42.5 low-alkalinity quick-hardening sulphoaluminate cement and No. 52.5 low-alkalinity quick-hardening sulphoaluminate cement provided by Yicheng Anda special cement company Limited; the redispersible latex powder is vinyl acetate and ethylene copolymer rubber powder, ethylene, vinyl chloride and vinyl laurate ternary copolymer rubber powder, vinyl acetate, ethylene and higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate and higher fatty acid vinyl ester copolymer rubber powder, vinyl acetate and acrylic ester and higher fatty acid vinyl ester ternary copolymer rubber powder, acrylic ester and styrene copolymer rubber powder or acrylic homopolymerization rubber powder, butadiene and styrene copolymer rubber powder, which are provided by Guangzhou Kai Kaiyi chemical industry Co.Ltd; the cellulose ether is hydroxyethyl methyl cellulose ether and hydroxypropyl methyl cellulose ether provided by Guangzhou Kai polymerization chemical Co., Ltd, and the viscosity is 30000-45000 mPa.S and 20000-35000 mPa.S respectively; the guar gum powder is provided by Tao liter chemical industry Co., Ltd, Guangzhou city, and the viscosity is 60000-200000 mPa.S; the early strength agent is calcium formate provided by Kyoho chemical company Limited.
Example 1
The composition for preparing the cement-based tile adhesive comprises the following components in percentage by weight (KG):
Figure BDA0001682570780000041
and (2) taking the composition and the medium sand on the construction site, mixing the composition and the medium sand in a mass ratio of 1:4, uniformly mixing, adding water accounting for 10-15% of the total mass, and stirring into a paste to obtain the cement-based tile adhesive.
Example 2
The composition for preparing the cement-based tile adhesive comprises the following components in percentage by weight (KG):
Figure BDA0001682570780000042
and (2) taking the composition and the medium sand on the construction site, mixing the composition and the medium sand in a mass ratio of 1:4, uniformly mixing, adding water accounting for 10-15% of the total mass, and stirring into a paste to obtain the cement-based tile adhesive.
Example 3
The composition for preparing the cement-based tile adhesive comprises the following components in percentage by weight (KG):
Figure BDA0001682570780000043
Figure BDA0001682570780000051
and (2) taking the composition and the medium sand on the construction site, mixing the composition and the medium sand in a mass ratio of 1:4, uniformly mixing, adding water accounting for 10-15% of the total mass, and stirring into a paste to obtain the cement-based tile adhesive.
Example 4
The composition for preparing the cement-based tile adhesive comprises the following components in percentage by weight (KG):
Figure BDA0001682570780000052
and (2) taking the composition and the medium sand on the construction site, mixing the composition and the medium sand in a mass ratio of 1:4, uniformly mixing, adding water accounting for 10-15% of the total mass, and stirring into a paste to obtain the cement-based tile adhesive.
Example 5
The composition for preparing the cement-based tile adhesive comprises the following components in percentage by weight (KG):
Figure BDA0001682570780000053
and (2) taking the composition and the medium sand on the construction site, mixing the composition and the medium sand in a mass ratio of 1:4, uniformly mixing, adding water accounting for 10-15% of the total mass, and stirring into a paste to obtain the cement-based tile adhesive.
Performance testing
The cement-based tile adhesives provided in examples 1-5 were tested according to the relevant specifications in JC/T547-2017 ceramic tile adhesive, and the specific test results are shown in Table 1.
TABLE 1
Figure BDA0001682570780000061
As can be seen from the test data in Table 1, the tile adhesives provided in examples 1-5 all have tensile bond strength of not less than 0.5MPa and slip of less than 0.5mm (slip is 0) under various conditions, and meet the requirements of JC/T547-2017 ceramic tile adhesive on cement-based adhesives.
The above examples are merely illustrative for clearly illustrating the present invention and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the claims of the present invention.

Claims (8)

1. The cement-based tile adhesive capable of being thickly pasted is characterized by comprising a composition, sand and water, wherein the composition comprises the following raw materials in percentage by mass:
Figure FDA0003202166830000011
wherein the mass ratio of the composition to the sand is as follows: sand 1: 4;
water accounts for 10-15% of the total mass;
the sand is the existing medium sand for concrete in a construction site;
when in use, the composition is mixed with the existing concrete medium sand and water in a construction site and stirred into paste to obtain the tile adhesive.
2. The cement-based tile adhesive of claim 1, wherein the Portland cement is Portland cement number 42.5 or Portland cement number 52.5.
3. The cement-based tile adhesive of claim 1, wherein the low alkalinity sulphoaluminate cement is No. 42.5 low alkalinity fast hardening sulphoaluminate cement or No. 52.5 low alkalinity fast hardening sulphoaluminate cement.
4. The cement-based tile adhesive as claimed in claim 1, wherein the latex powder is one or more of vinyl acetate-ethylene copolymer rubber powder, ethylene-vinyl chloride-vinyl laurate ternary copolymer rubber powder, vinyl acetate-ethylene-higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate-higher fatty acid vinyl ester copolymer rubber powder, vinyl acetate-acrylate-higher fatty acid vinyl ester ternary copolymer rubber powder, acrylate-styrene copolymer rubber powder or acrylic acid homopolymerization rubber powder, and butadiene-styrene copolymer rubber powder.
5. The cement-based tile adhesive according to claim 1, wherein the cellulose ether is hydroxyethyl methyl cellulose ether and/or hydroxypropyl methyl cellulose ether having a viscosity of between 20000 to 50000 mPa-s.
6. The cement-based tile adhesive according to claim 1, wherein the guar gum powder is guar gum powder, and the viscosity is 60000-200000 mPa-s.
7. The cement-based tile adhesive of claim 1, wherein the early strength agent is a calcium salt series.
8. A composition for preparing the cement-based tile adhesive according to any one of claims 1 to 7, which is characterized by comprising the following raw materials in percentage by mass:
Figure FDA0003202166830000021
1.00-6.00% of early strength agent.
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CN109516740A (en) * 2018-12-24 2019-03-26 广州协堡建材有限公司 The dedicated clay of the levelling integrated construction of floor tile paving and its construction method
CN110183191A (en) * 2019-05-22 2019-08-30 北京工业大学 A kind of ceramic tile bond and preparation method with low temperature resistance
CN113603434A (en) * 2021-09-10 2021-11-05 四川蜀羊防水材料有限公司 Waterproof tile glue and preparation method thereof
CN117210166B (en) * 2023-09-21 2024-03-12 科顺民用建材有限公司 Composition for preparing adhesive, preparation method and application thereof
CN117447169B (en) * 2023-12-26 2024-04-12 唐山盾石干粉建材有限责任公司 Ceramic large plate bonding mortar and preparation method thereof

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