KR102362253B1 - Cement Composition for Tile Attachment and Tile Construction Method Using The Same - Google Patents

Abstract

The present invention relates to a cement composition for pressing tiles and a tile construction method using the same. Specifically, it relates to a cement composition for compressing tiles comprising a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex, fine aggregate, and cement, and a tile construction method using the same .

Description

Cement Composition for Tile Attachment and Tile Construction Method Using The Same

The present invention relates to a cement composition for pressing tiles and a tile construction method using the same.

Tile has been widely used as a finishing material for construction from a long time ago due to its beauty in appearance, convenience of construction, sanitation, and convenience of cleaning, maintenance, and management of buildings. Tile adhesives for attaching tiles to walls or floors are classified into cement mortar-based adhesives, resin-based adhesives and emulsion-based adhesives depending on the type of main bonding material. Adhesives are the most widely used, and such cement mortar-based adhesives are commonly referred to as tile cement mortars.

Cement mortar is kneaded by mixing cement and fine aggregate, which are the main materials, with an appropriate amount of water. Among the main materials of such cement mortar, fine aggregates including sand, etc., are supplied and used from the region, but depending on the component content of fine aggregates in the region, it is difficult to work with the cement mortar used previously. .

Specifically, the main properties required for tile cement mortar include sag resistance, open time, and adhesive strength _. If it is low, it has a problem that it is impossible to work because it falls significantly.

Therefore, there is a demand for the development of a new cement composition for compressing tiles that can significantly improve sag resistance and adhesive strength and extend open time for a long time compared to conventional tile cement mortars.

Republic of Korea Patent Publication No. 10-1518251 (April 30, 2015)

It is an object of the present invention to provide a cement composition for tile pressing and a tile pressing method using the same.

Another object of the present invention is that when fine aggregate from the Middle East with a low content of silicon dioxide (silica, SiO ₂ ) is supplied and used, sag resistance, adhesive strength, fluidity and water retention are excellent, and the open time is significantly To provide an improved cement composition for pressing tiles and a tile construction method using the same.

Another object of the present invention is to provide a cement composition for tile compression with significantly improved strength and workability, and a tile construction method using the same, which can further secure working time by extending open time, improve water retention, and significantly improve strength and workability .

The present invention for achieving the above object is a cement composition for tile compression comprising a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex, fine aggregate, and cement characterized.

As an aspect of the present invention, the content of silicon dioxide contained in the fine aggregate may be 50 to 80% by weight.

As an aspect of the present invention, the water-soluble modifier may include 1 to 3% by weight, 63 to 75% by weight of fine aggregate, and 24 to 35% by weight of cement.

In an embodiment of the present invention, the content of hydroxypropyl methylcellulose and hydroxyethyl methylcellulose in the water-soluble modifier may satisfy the following formula (1).

[Equation 1]

(In Formula 1, HPMC means the weight of hydroxypropyl methylcellulose, and HEMC means the weight of hydroxyethyl methylcellulose.)

In one embodiment of the present invention, the content of starch ether in the water-soluble modifier may satisfy the following formula (2).

[Equation 2]

(In Formula 2, HPMC means the weight of hydroxypropyl methylcellulose, and SE means the weight of starch ether.)

As an aspect of the present invention, the content of the ethylene-vinyl acetate copolymer latex in the water-soluble modifier may satisfy the following formula (3).

[Equation 3]

(In Equation 3, HPMC means the weight of hydroxypropyl methylcellulose, HEMC means the weight of hydroxyethyl methylcellulose, and EVA means the content of ethylene-vinyl acetate copolymer latex.)

In one embodiment of the present invention, the water-soluble modifier is hydroxypropyl methylcellulose 20 to 30% by weight, methylhydroxyethylcellulose 15 to 20% by weight, starch ether 7 to 15% by weight, and ethylene-vinylacetate copolymer latex 40 to 55 It may include weight %.

In one embodiment of the present invention, the water-soluble modifier may further include one selected from the group consisting of lignin sulfonate and an antifoaming agent or a mixture thereof.

Another aspect of the present invention comprises the steps of preparing a cement mortar by mixing cement, fine aggregate and water; preparing a cement composition for tile pressing by mixing the cement mortar with a water-soluble modifier including hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex; applying the cement composition for tile compression to a construction surface or a tile; and compressing the tile and the construction surface.

As an aspect of the present invention, the content of silicon oxide contained in the fine aggregate may be 50 to 80% by weight.

The cement composition for tile compression according to the present invention has excellent sag resistance and adhesive strength, and can have the effect of significantly improving open time, and particularly, sand having a low silicon dioxide (silica, SiO ₂ ) content. Even when used, it has excellent sag resistance, adhesive strength, water retention, fluidity and long open time without deterioration of physical properties, and thus can have excellent workability.

Hereinafter, the present invention will be described in more detail through the accompanying embodiments or examples. However, the following specific examples or examples are only a reference for describing the present invention in detail, and the present invention is not limited thereto, and may be implemented in various forms.

Also, unless defined otherwise, all technical and scientific terms have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description herein is for the purpose of effectively describing particular embodiments only and is not intended to limit the invention.

Also, the singular forms used in the specification and appended claims may also be intended to include the plural forms unless the context specifically dictates otherwise.

Also, when a part "includes" a certain component, it means that other components may be further included, rather than excluding other components, unless otherwise stated.

In the present invention, the term 'cement composition for tile compression' refers to tile cement mortar.

The present invention for achieving the above object provides a cement composition for tile compression and a tile construction method using the same.

Hereinafter, the cement composition for tile compression according to the present invention will be described in detail.

A first aspect of the cement composition for tile compression according to the present invention includes a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex, fine aggregate, and cement.

A second aspect of the cement composition for tile compression according to the present invention is a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether, ethylene-vinyl acetate copolymer latex and lignin sulfonate, fine aggregate and cement. will include

A third aspect of the cement composition for tile compression according to the present invention is a water-soluble modifier including hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether, ethylene-vinyl acetate copolymer latex and an antifoaming agent, fine aggregate and cement. will be.

A fourth aspect of the cement composition for tile compression according to the present invention is a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether, ethylene-vinyl acetate copolymer latex, lignin sulfonate and an antifoaming agent, fine aggregate and It contains cement.

Conventional cement composition for tile compression is manufactured to meet domestic conditions, and when used in the Middle East, etc., due to the difference in the silicon dioxide content of fine aggregates, etc. used by supplying local materials, the physical properties are reduced to the extent that work cannot be performed. There was a problem being In order to solve this problem, the inventors of the present invention used a water-soluble modifier including hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex together with cement and fine aggregate, depending on the composition of the fine aggregate. The problem of deterioration of physical properties was solved. Specifically, it has solved the deterioration of physical properties due to the components of fine aggregates supplied and used at the construction site. In particular, even when supplying and using fine aggregates from the Middle East with low silicon dioxide content, excellent sagging resistance, adhesive strength and long open time The remarkably improved effect with

Hereinafter, each configuration of the cement composition for tile compression of the present invention will be described in more detail.

In one embodiment of the present invention, the water-soluble modifier may include hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether, and ethylene-vinylacetate copolymer latex.

The hydroxypropyl methyl cellulose (Hydroxypropyl methyl cellulose, HPMC) may have a viscosity of 10,000 to 30,000 mPa·s at 20 rpm, 20° C., and 2 wt% aqueous solution conditions with a Brookfield viscometer, specifically, a viscosity of 17,000 to It may be 24,000 mPa·s. By including hydroxypropyl methylcellulose satisfying the above viscosity range, it is possible to improve the strength and water retention of the cement composition for tile compression of the present invention to be manufactured later, and to improve resistance to the underlayer.

In the present invention, water retention means the water retention capacity of the adhesive for tiles to be manufactured, and as a result, there is an advantage in that construction convenience can be remarkably improved by maintaining a similar viscosity during the open time as a result of such a remarkable improvement in water retention.

The hydroxypropyl methylcellulose may be included in an amount of 15 to 35 wt%, preferably 20 to 30 wt%, based on the total weight of the water-soluble modifier. In the above range, it is possible to improve the strength and water retention of the cement composition for tile compression of the present invention to be manufactured later.

The hydroxyethyl methyl cellulose (Hydroxyethyl methyl cellulose, HEMC) may have a viscosity of 30,000 to 50,000 mPa·s at 20 rpm, 20° C., and 2% by weight with a Brookfield viscometer, and specifically 37,000 to 43,000 mPa·s may be s. By including hydroxyethyl methylcellulose satisfying the above viscosity range, it is possible to improve the water retention and workability of the cement composition for compressing tiles of the present invention to be manufactured later.

The hydroxyethyl methylcellulose may be included in an amount of 15 to 25 wt%, preferably 15 to 20 wt%, based on the total weight of the water-soluble modifier. In the above range, it is possible to improve the water retention and workability of the cement composition for tile compression of the present invention to be manufactured later.

The content of hydroxypropyl methylcellulose and hydroxyethyl methylcellulose may satisfy Formula 1 below.

[Equation 1]

(In Formula 1, HPMC means the weight of hydroxypropyl methylcellulose, and HEMC means the weight of hydroxyethyl methylcellulose.)

When the content of hydroxypropyl methylcellulose and hydroxyethyl methylcellulose of the water-soluble modifier of the present invention satisfies Equation 1, it is more preferable in terms of improving the initial adhesion of the cement composition for tile compression to be produced later.

In the present invention, the initial adhesiveness refers to the adhesive strength when 1 day has elapsed after curing the cement composition for tile compression.

This is because the modifier used in the conventional cement mortar has a problem in that the open time (working time) is extended by the addition of the modifier, the fluidity of the cement composition for tile compression is improved, and the adhesion of the tile is lowered. When the adhesion is lowered by adding the conventional modifier, it is difficult to fix the tile at a desired position, and problems such as the tile falling off before curing may occur. However, the water-soluble modifier of the present invention contains hydroxypropyl methylcellulose and hydroxyethyl methylcellulose that satisfy the above-mentioned content ratio and Formula 1, so that it is easy to fix the tile during construction by securing adhesion even when the open time is extended. In addition, it is possible to prevent problems such as falling off of the tile before curing.

The starch ether refers to a compound that has undergone a reforming reaction through an etherification reaction of starch. The starch ether is not limited thereto, but may be selected from, for example, carboxymethyl starch and hydroxyalkyl starch. The starch ether may have a viscosity of 1,000 to 10,000 mPa·s, preferably 2,000 to 5,000 mPa·s, in a Brookfield viscometer at 20 rpm and 20° C. in a 4 wt% aqueous solution. When mixed cellulose satisfying the above viscosity range and starch ether satisfying the above viscosity range are mixed, the adhesiveness of the cement composition for tile compression to be produced later is further improved, so that the tile can be stably installed even on a rough or smooth construction surface. It has the advantage of being able to attach it. Due to these advantages, it is possible to directly install the tile on various construction surfaces without a separate post-treatment, thereby reducing the construction cost.

The starch ether may be included in an amount of 5 to 20 wt%, preferably 7 to 15 wt%, based on the total weight of the water-soluble modifier, and may satisfy Equation 2 below.

[Equation 2]

(In Formula 2, HPMC means the weight of hydroxypropyl methylcellulose, and SE means the weight of starch ether.)

The starch ether is preferable because it can significantly improve water retention in the content range satisfying Equation 2 above.

In the present invention, water retention means the water retention capacity of the adhesive for tiles to be manufactured, and as a result, there is an advantage in that construction convenience can be remarkably improved by maintaining a similar viscosity during the open time as a result of such a remarkable improvement in water retention. This improvement in construction convenience enables uniform construction of tiles, thereby remarkably improving the quality of the manufactured tile surface.

The water-soluble modifier can improve the adhesion of the cement composition for tile compression by including the mixed cellulose and starch ether in which the hydroxypropyl methylcellulose and hydroxyethyl methylcellulose are mixed, while significantly extending the open time Thus, there is an advantage that can make construction easier. Specifically, the cement composition for tile compression of the present invention has the advantage that the open time can be improved by at least 1.3 times and up to 2.4 times compared to the conventional cement mortar by including the mixed cellulose and starch ether at the same time.

The ethylene-vinyl acetate copolymer latex (Ethylene-Vinyl Acetate copolymer latex) is re-dispersible in water and may be in the form of a powder, commercialized examples include Daemyung Chemical's KE-00037 and Wacker's Vinapas 5044N, RE5012T, etc. it may be The ethylene-vinyl acetate copolymer latex can further improve the overall bonding strength, adhesive strength and workability of the cement composition for tile compression of the present invention, and maintain excellent adhesive strength and abrasion resistance even after curing of the cement composition for tile compression. It is desirable to be able to provide

The ethylene-vinyl acetate copolymer latex may be included in an amount of 35 to 60% by weight, preferably 40 to 55% by weight, based on the total weight of the water-soluble modifier.

In addition, the ethylene-vinyl acetate copolymer latex may satisfy the following formula (3).

[Equation 3]

(In Equation 3, HPMC means the weight of hydroxypropyl methylcellulose, HEMC means the weight of hydroxyethyl methylcellulose, and EVA means the content of ethylene-vinyl acetate copolymer latex.)

The ethylene-vinyl acetate copolymer latex does not significantly affect the fluidity of the cement composition for tile compression of the present invention in the range satisfying the above content range and Equation 3, and is more effective in improving overall adhesion and workability. may be desirable.

In particular, the water-soluble modifier is used together with ethylene-vinyl acetate copolymer latex satisfying Formula 3, mixed cellulose satisfying Formula 1, and starch ether satisfying Formula 2, for tile compression of the present invention produced later The strength of the cement composition can be further improved. This is different from the conventional cement mortar using fine aggregates having a low silicon dioxide content, the adhesive strength was low and work was impossible even with known modifiers or additives, whereas the cement composition for tile bonding of the present invention has the silicon dioxide of fine aggregate. It has excellent adhesive strength, substrate resistance and water retention regardless of the content, and thus workability is remarkably improved.

The cement composition for tile compression according to an aspect of the present invention contains a water-soluble modifier comprising mixed cellulose, starch ether, and ethylene-vinyl acetate copolymer latex satisfying Equations 1 to 3 above, so that the same as sand in the Middle East region It is preferable because excellent physical properties can be realized even when a cement composition for tile compression is formed by mixing it with a cement mortar using fine aggregate with a low silicon (SiO ₂ ) content. Specifically, the cement composition for tile compression of the present invention comprising the water-soluble modifier has high sag resistance, excellent adhesive strength, and significantly improved open time, even when fine aggregate with a low silicon dioxide (SiO ₂ ) content is used. It is preferable because the cement composition for tile compression of the present invention with significantly improved workability can be prepared.

The average particle diameter of the ethylene-vinyl acetate copolymer latex is not limited, but may be, for example, 1 to 200 μm, specifically 1 to 100 μm, and can be excellently dispersed in water within the particle diameter range. , it is preferable because the adhesiveness can be further improved.

In one aspect of the present invention, the water-soluble modifier may further include one or two selected from the group consisting of lignin sulfonate and an antifoaming agent, wherein the lignin sulfonate is calcium lignosulfonate, It may be one comprising one or two or more selected from sodium lignosulfonate and the like. The lignin sulfonate may be included in an amount of 0.1 to 10% by weight, specifically 0.1 to 5% by weight, based on the total weight of the water-soluble modifier, and in the above range, adhesion during tile construction of the cement composition for tile compression of the present invention It is possible to further improve the wetting properties and fluidity of the cotton.

The antifoaming agent can be used without limitation if it is a material commonly used in cement, specifically, one or more selected from polyhydric alcohols and fatty acid esters may be supported on a carrier, and more specifically, the carrier is amorphous silica can be The cement composition for tile compression according to an aspect of the present invention includes an antifoaming agent in which a polyhydric alcohol or fatty acid ester is supported on the amorphous silica carrier, thereby improving the work convenience as well as the defoaming action, and the above-mentioned lignin sulfonate There is an advantage in that it is possible to prevent a decrease in adhesive strength that may be caused by this.

Each of the antifoaming agents may be included in an amount of 0.01 to 10% by weight, specifically 0.1 to 5% by weight, based on the total weight of the water-soluble modifier.

The water-soluble modifier may be included in an amount of 0.1 to 10% by weight, preferably 0.5 to 8% by weight, and more preferably 1 to 3% by weight based on the total weight of the composition for compressing tiles of the present invention. When the cement composition for tile compression of the present invention is prepared by mixing with fine aggregate and cement to be described later in the above range, the adhesive strength is excellent, the sagging resistance strength is excellent, and the open time is maintained for a long time, which further improves workability. may have an effect.

In one aspect of the present invention, the fine aggregate may include one or two or more of sand, pearlite, etc., such as sand, river sand, mountain sand, and silica sand, and specifically means containing a low content of silicon dioxide do. The content of silicon dioxide contained in the fine aggregate is 90% by weight or less, and specifically may be 50 to 80% by weight.

The cement composition for tile compression of the present invention has a problem in that it cannot be used for tile adhesion when the conventional tile cement mortar uses fine aggregate having a low silicon dioxide content of 90% by weight or less, whereas the silicon dioxide content Even when the fine aggregate having a low value of 50 to 80% by weight is used, there is an advantage in that excellent adhesive strength, sagging resistance, etc. can be exhibited.

The fine aggregate may be included in an amount of 55 to 80% by weight, preferably 63 to 75% by weight, based on the total weight of the tile pressing agent composition of the present invention. By being included in the above content range, it is more preferable to implement excellent adhesive strength and workability.

According to an aspect of the present invention, the cement may be used without limitation when it is conventionally used for tiles, but may be specifically hydraulically hardenable cement, and more specifically, Portland cement, fly ash cement ), may be one or two or more selected from aluminum-containing cement (aluminous cement). In addition, color cement may be used, and if necessary, at least one selected from hemihydrate gypsum, slaked lime, calcium carbonate and clay may be used together with the cement in the cement composition for tile compression.

The cement may be included in an amount of 15 to 40% by weight, preferably from 24 to 35% by weight, based on the total weight of the tile pressing agent composition of the present invention. In the above content range, it is more preferable because it can have excellent adhesive strength and durability.

Hereinafter, a tile construction method according to the present invention will be described in detail.

The tile construction method of the present invention comprises the steps of preparing a cement mortar by mixing cement, fine aggregate, and water;

preparing a cement composition for tile pressing by mixing the cement mortar with a water-soluble modifier including hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex;

applying the cement composition for tile compression to a construction surface or a tile; and

Compressing the tile and the construction surface; may include

The cement, fine aggregate, and water-soluble modifier may be the same as those described in the cement composition for tile compression described above.

Although the type of water is not limited in the present invention, it is preferable to use clean purified water without impurities. In addition, the ratio (W/B) of water and binder (a mixture of cement and fine aggregate) is not limited, but may be 0.18 to 0.4, specifically 0.2 to 0.35. In the above range, drying shrinkage, material separation, etc. are more preferable as conditions that do not occur.

When a tile is installed by the tile construction method according to the present invention, the construction is convenient due to the extension of the open time, and the occurrence of problems such as the tile falling off in the future can be prevented by improving the adhesive strength.

The manufacturing step of cement for tile compression may include 1 to 3% by weight of the above-described water-soluble modifier based on the solid content from the viewpoint of simultaneously securing fluidity and adhesiveness. In this case, the step of preparing the cement composition for tile compression may further include the step of aging after mixing the water-soluble modifier with the cement mortar, and this aging may be performed for 5 to 30 minutes, but the construction surface, type of tile Of course, it may vary depending on the type of cement and the like.

In the step of applying the cement composition for tile compression to the construction surface or tile, the application of the cement composition for tile compression may be preferably made to the construction surface for uniform construction and convenience of construction, but is not limited thereto. .

Furthermore, the thickness of the adhesive for tiles to be applied may be performed in a conventional range, but the adhesive layer is thin and the adhesion is not sufficient, or the thickness of the adhesive layer is thick to prevent the sagging of the tile from occurring. It can be applied to a thickness of 2 to 20 mm.

In the step of bonding the tile and the construction surface, the tile is not limited if it is commonly used, but specifically, it may include a porcelain tile, a ceramic tile, a stone tile, a marble tile, a metal tile, or a glass tile. .

The first to fourth aspects of the present invention described above are only examples for describing an aspect according to the present invention in detail, and the present invention is not limited by the above aspects.

Hereinafter, the present invention will be specifically described by way of Examples. The examples described below are only for helping the understanding of the present invention, and the present invention is not limited thereto.

Hereinafter, the present invention will be described in more detail based on Examples and Comparative Examples. However, the following examples and comparative examples are merely examples for explaining the present invention in more detail, and the present invention is not limited by the following examples and comparative examples.

[Experiment method]

1. Adhesive strength and open time measurement

The measurement of adhesive strength and open time was based on KS L 1593, and the adhesive strength was measured based on the time when 1 day had elapsed after curing, and when 7 days had elapsed after curing, the bonding strength was measured after 7 days. Adhesive strength was measured.

2. Evaluation of sag resistance

Sagging resistance was measured according to ISO 13007 (EN 12004), Ceramic tiles-Grouts and adhesives.

3. Workability evaluation

A sensory test was conducted on 20 incumbent tile builders. The sensory test items are the smoothness of the sample, the adhesion of the tile, and the overall preference. According to the five-point scale method, 5 points for excellent workability and 1 point for poor workability are evaluated, and the average value of each item is obtained it was At this time, the object and tiles were evaluated according to ISO 13007, and the appearance after construction was evaluated based on the time when 7 days had elapsed after construction.

4. Check Deviation of Adhesive Strength

Have three incumbent tile builders attach 30 tiles each using cement for tile compression, and then harden them at room temperature for 7 days. Among the 30 tiles, the 1st, 5th, 10th, 15th, 20th, 25th, and 30th tiles adhered by each tile compression cement composition were tested for adhesive strength in accordance with KS L 1593 standards. was calculated, and the standard deviation was calculated and expressed.

[Example 1]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 2]

2.6 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, hydroxyethyl methylcellulose 2.0 having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.5 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 3.9 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 3]

2.1 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.9 kg of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, 0.9 kg of starch ether (Casucol 301, AVEBE), and 5.1 kg of ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 4]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Then, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.54 kg of sand having a SiO ₂ content of 65%. Here, 94 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for pressing tiles.

[Example 5]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.5 kg of cement (one type of Hanil cement), and 3.56 kg of sand having a SiO ₂ content of 65%. Here, 150 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 6]

1.8 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s at 20 rpm and 2 wt% aqueous solution at 20 °C, 1.3 hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.4 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 5.5 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.52 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 100 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for compressing tiles.

[Example 7]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.6 kg, defoaming agent 0.03 kg, and calcium lignosulfonate 0.07 kg were mixed to prepare a water-soluble modifier .

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 8]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 50%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Example 9]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having an SiO ₂ content of 80%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Comparative Example 1]

4.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 4.4 kg of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, and 1.2 kg of starch ether (Casucol 301, AVEBE) was mixed to prepare a cement additive composition for tiles.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

[Comparative Example 2]

2.4 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 1.8 of hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 1.1 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 4.7 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.62 kg of sand having a SiO ₂ content of 65%. Here, 26 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for pressing tiles.

[Comparative Example 3]

2.0 kg of hydroxypropyl methylcellulose having a viscosity of 15,000 mPa·s under the conditions of 20 rpm and 2 wt% aqueous solution at 20 °C, 2.5 hydroxyethyl methylcellulose having a viscosity of 15,000 mPa·s at 20 rpm and 2 wt% of aqueous solution at 20 °C kg, 3.0 kg of methyl cellulose having a methyl group substitution rate of 30% by weight, and a viscosity of 2% by weight aqueous solution of 15,000 CPS, and 2.5 kg of hydroxypropyl starch having a viscosity of 6,000 cps in 10% by weight aqueous solution were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.82 kg of cement (one type of Hanil cement), and 3.38 kg of sand having a SiO ₂ content of 65%. Here, 0.26 kg of the ethylene vinyl acetate-based resin (manufactured by Wacker, RE5012T) and 27.6 g of the water-soluble modifier were mixed and aged for 20 minutes to prepare a cement composition for pressing tiles.

[Comparative Example 4]

2.2 kg of hydroxypropyl methylcellulose having a viscosity of 20,000 mPa·s at 20 rpm, 20 °C 2 wt% aqueous solution, 1.9 hydroxyethyl methylcellulose having a viscosity of 40,000 mPa·s at 20 rpm, 2 wt% aqueous solution at 20 °C kg, starch ether (Casucol 301, AVEBE) 2.2 kg, and ethylene-vinyl acetate copolymer latex (KE-00037, Daemyung Chemical) 3.9 kg were mixed to prepare a water-soluble modifier.

Thereafter, a cement mortar was prepared by slowly mixing 1.8 kg of water, 1.56 kg of cement (one type of Hanil cement), and 3.58 kg of sand having a SiO ₂ content of 65%. Here, 62 g of the water-soluble modifier was mixed and aged for 20 minutes to prepare a cement composition for tile compression.

The composition ratios of the water-soluble modifiers of Examples 1 to 9 and Comparative Examples 1 to 4 are shown in Table 1 below.

Water-soluble modifier (unit: kg) expression 1 value expression 2 value expression 3 value HPMC HEMC SE EVA

Example 1 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Example 2 2.6 2.0 1.5 3.9 1.3 0.58 0.85 Example 3 2.2 1.9 0.9 5.1 1.1 0.43 1.3 Example 4 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Example 5 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Example 6 1.8 1.3 1.4 5.5 1.4 0.8 1.8 Example 7 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Example 8 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Example 9 2.4 1.8 1.1 4.6 1.3 0.46 1.1 Comparative Example 1 4.4 4.4 1.2 0 1.0 0.14 - Comparative Example 2 2.4 1.8 1.1 4.7 1.3 0.46 1.1 Comparative Example 3 2.0 2.5 2.5 0.26 0.8 1.5 0.06 Comparative Example 4 2.2 1.9 2.2 3.9 1.2 1.0 0.95
In Table 1, HPMC is the weight of hydroxypropyl methylcellulose, HEMC is the weight of hydroxyethyl methylcellulose, SE is the weight of starch ether, EVA is the content of ethylene-vinyl acetate copolymer latex.

The compositions of the cement compositions for tile compression of Examples 1 to 9 and Comparative Examples 1 to 4 are shown in Table 2 below.

water soluble modifier
(Unit: kg) cement
(Unit: kg) sand Content (kg) SiO ₂ content (unit: %) Example 1 0.062 3.58 1.56 65 Example 2 0.062 3.58 1.56 65 Example 3 0.062 3.58 1.56 65 Example 4 0.094 3.54 1.56 65 Example 5 0.15 3.56 1.5 65 Example 6 0.062 3.58 1.56 65 Example 7 0.062 3.58 1.56 65 Example 8 0.062 3.58 1.56 50 Example 9 0.062 3.58 1.56 80 Comparative Example 1 0.062 3.58 1.56 65 Comparative Example 2 0.026 3.62 1.56 65 Comparative Example 3 0.027 3.4 1.8 65 Comparative Example 4 0.062 3.58 1.56 65

The adhesive strength, open time, and sag resistance of the cement compositions for tile compression of Examples 1 to 9 and Comparative Examples 1 and 2 were measured and shown in Table 3 below.

Adhesive strength (kgf/cm ² ) Open time (minutes) Deflection resistance (%) Early after 7 days Example 1 6.5 9.7 45 3.5 Example 2 6.1 9.5 43 3.3 Example 3 6.4 9.6 41 3.3 Example 4 6.2 9.5 40 3.4 Example 5 6.3 9.6 40 3.4 Example 6 6.5 9.4 41 3.3 Example 7 6.5 9.7 44 3.5 Example 8 6.4 9.6 44 3.4 Example 9 6.9 9.8 47 3.9 Comparative Example 1 2.1 7.2 17 0.5 Comparative Example 2 3.0 7.3 28 1.2 Comparative Example 3 2.5 7.3 19 1.1 Comparative Example 4 2.8 7.7 29 1.8

As shown in Table 3, in the case of the cement composition for compressing tiles according to an embodiment of the present invention, it can be confirmed that the adhesive strength is high, and the off-time is secured at a certain level or more, while exhibiting a degree of sagging resistance that is easy for construction. can

Specifically, in the case of the examples satisfying Equations 1 to 3, it was found that they had excellent initial adhesive strength, and in particular, as in Examples 1 to 9, tile compression containing the water-soluble modifier of the present invention In the case of cement for use, it can be seen that even when sand having a low SiO ₂ content is used, it has excellent adhesive strength, open time, and sag resistance. Specifically, it can be seen that even when sand with a low SiO ₂ content of 80% or less is used, it has similar adhesive strength, open time, and sag resistance as using sand with a SiO ₂ content of 95% or more used in Korea. have.

On the other hand, it can be seen that Comparative Examples 1 to 4 have poor adhesive strength, open time, and sagging resistance compared to Examples of the present invention. When sand with a high SiO ₂ content is used, it has adequate adhesive strength, open time, and sag resistance even at a typical blending ratio of a water-soluble modifier. However, when sand with an SiO ₂ content of 80% or less is used, the physical properties are poor as a conventional water-soluble modifier. It can be seen that indicates

The differences in workability and adhesive strength of the cement compositions for tile compression of Examples 1 to 9 and Comparative Examples 1 to 4 were measured and shown in Table 4 below.

correctness adherence overall preference Deviation of adhesive strength (kgf/cm ² ) Example 1 4.8 4.6 4.7 0.63 Example 2 4.3 4.3 4.3 0.65 Example 3 4.4 4.2 4.3 0.62 Example 4 4.7 4.5 4.6 0.65 Example 5 4.6 4.5 4.6 0.63 Example 6 4.6 4.8 4.5 0.62 Example 7 4.8 4.7 4.8 0.62 Example 8 4.8 4.6 4.7 0.65 Example 9 4.9 4.9 4.9 0.61 Comparative Example 1 2.1 2.0 2.0 2.38 Comparative Example 2 4.2 3.8 4.0 2.30 Comparative Example 3 4.1 2.8 3.5 2.34 Comparative Example 4 4.2 3.9 4.1 2.28

As shown in Table 4, it can be seen that the cement composition for compressing tiles according to an embodiment of the present invention is excellent in flatness and adhesion as well as overall preference. On the other hand, in the case of Comparative Examples 1 to 4, it can be seen that the flatness, adhesion, and overall preference are lowered, and in particular, it can be seen that the adhesion is significantly lowered.

Moreover, in the case of Examples 1 to 9, using a water-soluble modifier containing mixed cellulose, starch ether, and ethylene-vinyl acetate copolymer latex that satisfies Formulas 1 to 3 described above, the variation in adhesive strength was very It can be seen that a tile surface of uniform quality can be constructed even after construction, and problems such as falling off of the tile after construction can be significantly reduced.

On the other hand, Comparative Example 1 which does not contain ethylene-vinyl acetate copolymer latex and Comparative Example 2 in which the content of the water-soluble modifier is 0.5%, Comparative Example 4 which does not satisfy Equation 2, and Comparative Examples which do not satisfy Equations 1 to 3 In 3, it can be seen that the deviation of adhesive strength is large, and even after construction, the tile surface has a non-uniform quality, and problems such as tile fall-off appear.

Examples 1 to 8 according to an aspect of the present invention, as salpin in Tables 3 and 4, by using a water-soluble modifier satisfying Formulas 1 to 3 as shown in Table 1, the content of SiO ₂ It can be seen that even when using a fine aggregate as low as 65%, it has excellent physical properties such as excellent adhesive strength, water retention, sagging resistance, and workability. That is, the cement composition for tile compression of the present invention can realize excellent adhesive strength, water retention, sagging resistance, workability, etc. can be implemented

As described above, the present invention has been described by specific matters and limited examples, but these are provided to help a more general understanding of the present invention, and the present invention is not limited to the above examples, and the field to which the present invention belongs Various modifications and variations are possible from these descriptions by those of ordinary skill in the art.

Therefore, the spirit of the present invention should not be limited to the described embodiments, and not only the claims to be described later, but also all those with equivalent or equivalent modifications to the claims will be said to belong to the scope of the spirit of the present invention. .

Claims (10)

water-soluble modifiers including hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinylacetate copolymer latex, fine aggregate and cement;
The content of hydroxypropyl methylcellulose and hydroxyethyl methylcellulose in the water-soluble modifier is a cement composition for tile compression that satisfies Equation 1 below.
[Equation 1]

(In Formula 1, HPMC means the weight of hydroxypropyl methylcellulose, and HEMC means the weight of hydroxyethyl methylcellulose.) According to claim 1,
The content of silicon dioxide contained in the fine aggregate is 50 to 80% by weight of the cement composition for pressing tiles. According to claim 1,
A cement composition for tile compression comprising 1 to 3% by weight of the water-soluble modifier, 63 to 75% by weight of fine aggregate, and 24 to 35% by weight of cement. delete According to claim 1,
The content of starch ether in the water-soluble modifier is a cement composition for tile compression that satisfies Equation 2 below.
[Equation 2]

(In Formula 2, HPMC means the weight of hydroxypropyl methylcellulose, and SE means the weight of starch ether.) According to claim 1,
The content of the ethylene-vinyl acetate copolymer latex in the water-soluble modifier is a cement composition for tile compression that satisfies the following Equation 3.
[Equation 3]

(In Equation 3, HPMC means the weight of hydroxypropyl methylcellulose, HEMC means the weight of hydroxyethyl methylcellulose, and EVA means the content of ethylene-vinyl acetate copolymer latex.) According to claim 1,
The water-soluble modifier comprises 20 to 30% by weight of hydroxypropyl methylcellulose, 15 to 20% by weight of methylhydroxyethylcellulose, 7 to 15% by weight of starch ether, and 40 to 55% by weight of ethylene-vinylacetate copolymer latex A cement composition for pressing in tiles. According to claim 1,
The water-soluble modifier is a cement composition for tile compression further comprising one or a mixture thereof selected from the group consisting of lignin sulfonate and an antifoaming agent. preparing a cement mortar by mixing cement, fine aggregate, and water;
preparing a cement composition for tile pressing by mixing the cement mortar with a water-soluble modifier comprising hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, starch ether and ethylene-vinyl acetate copolymer latex;
applying the cement composition for tile compression to a construction surface or a tile; and
Including; compressing the tile and the construction surface;
The content of hydroxypropyl methylcellulose and hydroxyethyl methylcellulose in the water-soluble modifier is a tile construction method that satisfies the following formula 1.
[Equation 1]

(In Formula 1, HPMC means the weight of hydroxypropyl methylcellulose, and HEMC means the weight of hydroxyethyl methylcellulose.) 10. The method of claim 9,
The content of silicon oxide contained in the fine aggregate is 50 to 80% by weight of the tile construction method.