CN108605940A - A kind of fluorine chlorine worm bisamide insecticide and its application - Google Patents
A kind of fluorine chlorine worm bisamide insecticide and its application Download PDFInfo
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- CN108605940A CN108605940A CN201611133912.1A CN201611133912A CN108605940A CN 108605940 A CN108605940 A CN 108605940A CN 201611133912 A CN201611133912 A CN 201611133912A CN 108605940 A CN108605940 A CN 108605940A
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- chlorine worm
- fluorine chlorine
- insecticide
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- worm bisamide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of fluorine chlorine worm bisamide insecticide of present invention offer and application, chemical constitution are as follows：
Description
Technical field
The present invention relates to agricultural technology fields, more particularly to a kind of fluorine chlorine worm bisamide insecticide and its application.
Background technology
Diseases and pests of agronomic crop is one of the Main Agricultural disaster in China, it has, and type is more, influences big and breaks out into often
The characteristics of calamity, occurrence scope and severity often result in heavy losses to Chinese national economy, particularly agricultural production.China
Crops common are the pest and disease damage of following type：Rice leaf roller, striped rice borer, beet armyworm, diamondback moth, planthopper, white powder
Disease, corn borer, bollworm, wheat rust, cotten aphid, the sheath and culm blight of rice, rice blast, wheat aphid, wheat red mite, locust, gibberella zeaze petch of wheat and barley
Deng, it has also become the great pest and disease damage for seriously affecting China's agricultural production leads to pest pair since chemical pesticide control is used for a long time
A variety of chemical insecticides such as organochlorine, organophosphor, carbamate, pyrethroid produce different degrees of drug resistance, prevent
Control significant effect decline so that peasant has to increase dosage to improve preventive effect, but reduces the safety of agricultural product again.
Invention content
In order to meet people for new insecticide demand, we have proposed a kind of fluorine chlorine worm bisamide insecticide and its use
On the way, insecticide using the present invention can achieve the effect that efficient insecticide,
The present invention is achieved by the following technical solutions：
The present invention provides a kind of fluorine chlorine worm bisamide insecticide, and chemical constitution is as follows：
Chemical name：The bromo- 1- of 3- (3- chloropyridine -2- bases)-N- [4, the 6- bis- chloro- fluoro- 2- of 3- (methylamino formamide) benzene
Base] -1H- pyrazoles -5- formamides
Empirical formula：C17H10BrCl3FN5O2
Relative molecular mass (based on international relative atomic mass in 2009)：521.56
Bioactivity：Desinsection
Fusing point (DEG C)：238-240；
A kind of noval chemical compound of the fluorine chlorine worm bisamide as my company's autonomous innovation exploitation, belongs to benzamide insecticides,
Energy efficient activation insect ryania (muscle) receptor excessively discharges the calcium ion in intracellular calcium store in turn, causes insect paralysis dead
It dies.High to the larva activity of lepidoptera pest, insecticidal spectrum is wide, and lasting effect is good.The active ingredient is shown to mammal and evil
The extremely significant selective difference of worm ryanodine receptor substantially increases the safety to mammal and other vertebrates, but
The detailed mechanism of action is still further verified up for later stage correlation test.
Present invention simultaneously provides a kind of purposes of fluorine chlorine worm bisamide insecticide, and agricultural insecticidal is being prepared as active constituent
Purposes in agent or fungicide.
Preferably, above-mentioned fluorine chlorine worm bisamide as active constituent and insecticides adjuvant, excipients be configured to pesticide field permit
Perhaps any one dosage form；Or fluorine chlorine worm bisamide is matched as active constituent and other pesticides and insecticides adjuvant, excipients
Any one dosage form of pesticide field permission is made.
Preferably, the dosage form that above-mentioned pesticide field allows is wettable powder, water dispersible granules, missible oil, aqua, suspension
Agent, microemulsion, dispersible oil-suspending agent, granule, big granula.
Wettable powder：Hygroscopicity is strong, can be dispersed or suspended in water after adding water, can spray, poison bait and soil treatment
Deng use.
Water dispersible granules are also known as dry suspending agent or grain shape wettable powder：Once into the water, can be disintegrated, divide quickly
It dissipates, forms the granular preparation of the solid-liquid dispersing system of higher suspension.
Emulsion is also known as missible oil：It is emulsion that emulsion, which adds after water, can be used for spraying, sprinkle pour, dress seed, soaking seed, pesticide-clay mixture, stem brush
Deng.
Soluble powder is also known as aqua：Can directly to water spray or sprinkle pour.
Antisettling agent refers generally to suspending agent：Suspending agent refers to uniformly dividing solid pesticide active compound with 4 microns of particles below
The preparation in water is dissipated, international code name is SC.Due to SC without as can dusting problem wet-milling (WP), it is nonflammable easy
Quick-fried, grain size is small, and bioactivity is high, and proportion is larger, and packaging volume is smaller, other opposite formulations of pesticide safety and environmental protections, therefore, SC is
As the pesticide species that water baseization pesticides new formulation tonnage is larger.
Microemulsion is made of liquid pesticide, surfactant, water, stabilizer etc., belong to thermodynamics through when the dispersion stablized
System.Its main feature is that using water as medium, organic solvent, thus non-ignitable not quick-fried, production operation, storing safety, ring are free of or contained less
Border pollution is few, saves a large amount of organic solvents；Pesticide dispersion degree is high, reaches miniaturization degree, and pesticide particle is generally 0.1~0.01
Micron, appearance are similar to transparent or sub-translucent liquid；Good dispersion in water is strong to target body permeability, adhesive force is good.
Dispersible oil-suspending agent " 0D " is the Oil- that FAO (Food and Agriculture Organization of the United Nation) (FAO) newly releases in recent years
Basedsuspensionconcentrate, the also known as code of Oildispersion dosage forms：Active ingredient (it is molten may to contain other
The active ingredient of solution) liquid preparation of the stable suspersion in organic fluid, it is used after being diluted with water.
Preferably, other above-mentioned pesticides include emamectin benzoate, avermectin, dinotefuran, clothianidin, Diacloden, Tolfenpyrad,
Pyridalyl, chlorine fluorine cyanogen insect amide, Rynaxypyr, fipronil bisamide, Biphenthrin, pyridaben, Hexythiazox, Envidor,
Methomyl, Cupric sulfate, dimehypo, cypermethrin, Fenpropathrin, chlorfenapyr, imidacloprid, Acetamiprid, Buprofezin, Bifenazate,
Hexythiazox, propargite, flubenzuron, lufenuron, diflubenzuron, triflumuron, gamma cyhalothrin, azacyclotin, clofentezine, second mite
Azoles, indoxacarb, lufenuron, metaflumizone, pleocidin, ethyl pleocidin, Amitraz, propargite, malathion, fluorine worm
Nitrile, effective cypermethrin, Fluoxastrobin, pyraclostrobin, hymexazol, Metalaxyl-M, thiophanate methyl, Tebuconazole, phenyl ether methyl cyclic
At least one of azoles and trifloxystrobin.
Preferably, above-mentioned insecticide is for preventing Lepidoptera, Homoptera and coleopteron.
Preferably, above-mentioned Lepidoptera, Homoptera and coleopteron are that diamondback moth, aleyrodid, leafhopper, beet armyworm, rice are vertical
Leaf roll snout moth's larva, bollworm, prodenia litura, aphid, acarid and flea beetle.
Compared with prior art, the beneficial effects of the present invention are：
1, insecticidal spectrum, antimicrobial spectrum are wide, and desinsection, antibacterial time are short, and the lasting period is long, learn to farm medicine phases ratio with generalization, to pest
With tag, stomach poison function, significant effect；
2, synthesis technology is simple, at low cost；
3, compounding effect is good.
Specific implementation mode
With reference to embodiment, present disclosure is further illustrated.It should be appreciated that the implementation of the present invention is not limited to
In the following examples, the accommodation in any form or change made to the present invention both fall within the scope of the present invention；Under and
The method in embodiment is stated, is the conventional method of this field unless otherwise instructed.
Embodiment 1：
Fluorine chlorine worm bisamide (content 95%) toxicity measures：
1, test medicine：Take 95% fluorine chlorine worm bisamide active compound, 95% Rynaxypyr TC, 95% Buprofezin TC,
95.60% pyridaben TC.
2, test worm target：Diamondback moth Plutella xylostella (L.) 3 age mid-term larva of indoor raising, beet night
Moth Spodoptera exigua H ü bner3 latter stage in age larvas, planthopper Nilaparvata lugens4 age nymphs, cinnabar leaf
Mite Tetranychus cinnabarinus deutonymphs and at mite.
3, using solvent：Compound is configured to 2.5% preparation with DMF, is then diluted to 100ppm with 1 ‰ tween water.
4, test period：2015.10.
Remarks：Every test worm growing way is small and weak in test result observation, be slow in action, feeding is obviously less is determined as
Polypide is dead.
Test result is as shown in table 1：
Table 1：Fluorine chlorine worm bisamide (content 95%) toxicity measures
As shown in Table 1, the compound of the present invention is in the killing effect of diamondback moth and beet armyworm, when high concentration
(100ppm) can reach 100% killing pest, but in low concentration, effect is not notable, there is part insecticidal effect.To rice
In the experiment of the killing effect of plant hopper and Tetranychus cinnabarinus, it can be seen that in high concentration and low concentration, have good insecticidal effect, far
Far more than common insecticide pyridaben TC and Buprofezin TC.
Embodiment 2：
30% fluorine chlorine worm bisamide SC determinations of activity：
1, test medicine：30% fluorine chlorine worm bisamide SC, 25% diafenthiuron EC (card card), 2.5% imidacloprid DMF solution,
95.60% pyridaben TC.
2, test worm target：Diamondback moth Plutella xylostella (L.) 3 age mid-term larva of indoor raising, striped rice borer
Chilo suppressalis (Walker) four ages mid-term larva, Tetranychus cinnabarinus Tetranychus cinnabarinus deutonymphs and
At mite, aphis craccivora AphiscraccivoraKoch.
3, using solvent：Compound is configured to 2.5% preparation with DMF, is then diluted to 100ppm with 1 ‰ tween water.
4, test period：2015.10.
Remarks：Every test worm growing way is small and weak in test result observation, be slow in action, feeding is obviously less is determined as
Polypide is dead.
Test result is as shown in table 2：
Table 2：30% fluorine chlorine worm bisamide SC determinations of activity
As seen from the above table, in testing the killing of diamondback moth, fluorine chlorine worm bisamide of the invention can in high concentration and
Low concentration all has good killing effect to diamondback moth, considerably beyond 25% diafenthiuron EC of common insecticide (card card)；Right
In the killing experiment of striped rice borer, fluorine chlorine worm bisamide of the invention and 25% diafenthiuron EC (card blocks) equally, can not play killing
Effect；In testing the killing of aphis craccivora, fluorine chlorine worm bisamide of the invention and 2.5% imidacloprid of common efficient pesticides
DMF solution reaches essentially identical killing effect；In testing the killing of Tetranychus cinnabarinus, the double acyls of 20% fluorine chlorine worm of the invention
Amine is unable to reach the effect of 95.60% pyridaben TC, but combines table 1, and the fluorine chlorine worm bisamide of high concentration is to Tetranychus cinnabarinus
Killing effect is significantly larger than pyridaben.
Claims (7)
1. a kind of fluorine chlorine worm bisamide insecticide and its application, which is characterized in that chemical constitution is as follows：
Chemical name：The bromo- 1- of 3- (3- chloropyridine -2- bases)-N- [4, the 6- bis- chloro- fluoro- 2- of 3- (methylamino formamide) phenyl] -
1H- pyrazoles -5- formamides
Empirical formula：C17H10BrCl3FN5O2
Relative molecular mass (based on international relative atomic mass in 2009)：521.56
Bioactivity：Desinsection
Fusing point (DEG C)：238-240.
2. a kind of application of fluorine chlorine worm bisamide insecticide, which is characterized in that fluorine chlorine worm bisamide is being prepared as active constituent
Purposes in agricultural fungicides.
3. a kind of application of fluorine chlorine worm bisamide insecticide as claimed in claim 2, which is characterized in that the double acyls of the fluorine chlorine worm
Amine is configured to any one dosage form of pesticide field permission as active constituent and insecticides adjuvant, excipients；Or fluorine chlorine worm is double
Amide is configured to any one agent of pesticide field permission as active constituent and other pesticides and insecticides adjuvant, excipients
Type.
4. a kind of application of fluorine chlorine worm bisamide insecticide as claimed in claim 3, which is characterized in that the pesticide field is permitted
Perhaps dosage form is wettable powder, water dispersible granules, missible oil, aqua, suspending agent, microemulsion, dispersible oil-suspending agent, particle
Agent, big granula.
5. a kind of application of fluorine chlorine worm bisamide insecticide as claimed in claim 2, which is characterized in that other described pesticide packets
Include emamectin benzoate, avermectin, dinotefuran, clothianidin, Diacloden, Tolfenpyrad, pyridalyl, chlorine fluorine cyanogen insect amide, chlorine worm benzene
Formamide, fipronil bisamide, Biphenthrin, pyridaben, Hexythiazox, Envidor, Methomyl, Cupric sulfate, dimehypo, chlorine cyanogen chrysanthemum
Ester, Fenpropathrin, chlorfenapyr, imidacloprid, Acetamiprid, Buprofezin, Bifenazate, hexythiazox, propargite, flubenzuron, lufenuron,
Diflubenzuron, gamma cyhalothrin, azacyclotin, clofentezine, etoxazole, indoxacarb, lufenuron, metaflumizone, kills at triflumuron more
Rhzomorph, ethyl pleocidin, Amitraz, propargite, malathion, ethiprole, effective cypermethrin, Fluoxastrobin, pyrazoles ether bacterium
At least one of ester, hymexazol, Metalaxyl-M, thiophanate methyl, Tebuconazole, difenoconazole and trifloxystrobin.
6. a kind of application of fluorine chlorine worm bisamide insecticide as claimed in claim 2, which is characterized in that the insecticide is used for
Prevent Lepidoptera, Homoptera and coleopteron.
7. a kind of application of fluorine chlorine worm bisamide insecticide as claimed in claim 6, which is characterized in that the Lepidoptera, same
Wing mesh and coleopteron be diamondback moth, aleyrodid, leafhopper, beet armyworm, rice leaf roller, bollworm, prodenia litura, aphid,
Acarid and flea beetle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611133912.1A CN108605940A (en) | 2016-12-10 | 2016-12-10 | A kind of fluorine chlorine worm bisamide insecticide and its application |
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|---|---|---|---|
| CN201611133912.1A CN108605940A (en) | 2016-12-10 | 2016-12-10 | A kind of fluorine chlorine worm bisamide insecticide and its application |
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| CN109845745A (en) * | 2019-01-19 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of composition containing fluorine chlorine worm bisamide and process for preparation of benzoylurea compounds |
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| CN109845746A (en) * | 2019-01-25 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination of fluorine-containing chlorine worm bisamide and biological source insecticide |
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2016
- 2016-12-10 CN CN201611133912.1A patent/CN108605940A/en not_active Withdrawn
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| CN115886003A (en) * | 2022-12-09 | 2023-04-04 | 湖南化研院检测技术有限公司 | Insecticidal composition containing bromofenoxaprop-benzene bisamide and chlorofluoromethane and application thereof |
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