CN108587115A - 一种电学功能膜 - Google Patents

一种电学功能膜 Download PDF

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CN108587115A
CN108587115A CN201810440316.0A CN201810440316A CN108587115A CN 108587115 A CN108587115 A CN 108587115A CN 201810440316 A CN201810440316 A CN 201810440316A CN 108587115 A CN108587115 A CN 108587115A
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vanadium oxide
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周贤敏
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Chongqing New Kang Yi Xin Dahl New Material Co Ltd
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract

本发明公开了一种电学功能膜，包括二异氰酸酯50‑60份、氧化钒15‑22份、石墨烯1‑5份、2‑丙烯酰氨基‑2‑甲基‑1‑丙烷磺酸5‑10份、苯乙烯‑丙烯腈共聚物15‑30份、扩链剂2‑8份、催化剂3‑6份。本发明整个自组装成膜制备成本低，原料易得，制备的导电薄膜具有良好的机械和化学稳定性，薄膜的厚度和结构可控，且成膜重复性好，同时具有优良的电化学性能和稳定性，可应用于光电材料等领域。

Description

一种电学功能膜
技术领域
本发明涉及电学功能膜技术领域，具体涉及一种电学功能膜。
背景技术
由于电子器件的日趋微型化，功能薄膜材料因其独特的光学、电学、磁学以及化学特性，广泛应用于微电子器件、耐磨层等技术领域。薄膜材料种类的多样性决定了其制备方法也多种多样，在这些制备及防护涂技术中，层层自组装(LBL)技术在功能薄膜材料制备领域显示了独特的优势，许多功能薄膜材料通过此技术制备而获得。
现有的电学功能膜大多对热、化学环境、时间以及外部压力的稳定性差，同时膜的制备需要昂贵的膜槽和严格的基底，除基底外，溶液浓度、pH、清洗和吸附时间等均会影响组装质量，因而设计发明一种可定向、自组装过程简单且能形成稳定性高、重复性好、膜层可调的分子膜方法十分必要。
发明内容
本发明旨在提供了一种电学功能膜。
本发明提供如下技术方案：
一种电学功能膜及其制备方法，包括二异氰酸酯50-60份、氧化钒15-22份、石墨烯1-5份、2-丙烯酰氨基-2-甲基-1-丙烷磺酸5-10份、苯乙烯-丙烯腈共聚物15-30份、扩链剂2-8份、催化剂3-6份。
所述氧化钒为非晶态、或微晶态、纳米晶态，氧化钒的分子式表示为VOx，其中，x满足1≤x≤2.5。
所述二异氰酸酯为甲苯二异氰酸酯和1，6-已二异氰酸酯的混合物。
所述所述扩链剂为乙二醇、乙胺、1，3-丙二醇、1，4-丁二醇或1，5-戊二醇中的任意一种或至少两种的组合。
所述催化剂为辛酸亚锡、二辛酸二丁基锡或二月桂酸二丁锡中的任意一种或至少两种的组合。
与现有技术相比，本发明的有益效果是：本发明整个自组装成膜制备成本低，原料易得，制备的导电薄膜具有良好的机械和化学稳定性，薄膜的厚度和结构可控，且成膜重复性好，同时具有优良的电化学性能和稳定性，可应用于光电材料等领域。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1一种电学功能膜及其制备方法，包括二异氰酸酯50份、氧化钒15份、石墨烯1份、2-丙烯酰氨基-2-甲基-1-丙烷磺酸5份、苯乙烯-丙烯腈共聚物15份、扩链剂2份、催化剂3份。
所述氧化钒为非晶态、或微晶态、纳米晶态，氧化钒的分子式表示为VOx，其中，x满足1≤x≤2.5。
所述二异氰酸酯为甲苯二异氰酸酯和1，6-已二异氰酸酯的混合物。
所述所述扩链剂为乙二醇、乙胺、1，3-丙二醇、1，4-丁二醇或1，5-戊二醇中的任意一种或至少两种的组合。
所述催化剂为辛酸亚锡、二辛酸二丁基锡或二月桂酸二丁锡中的任意一种或至少两种的组合。
实施例2一种电学功能膜及其制备方法，包括二异氰酸酯60份、氧化钒22份、石墨烯5份、2-丙烯酰氨基-2-甲基-1-丙烷磺酸10份、苯乙烯-丙烯腈共聚物30份、扩链剂8份、催化剂6份。
所述氧化钒为非晶态、或微晶态、纳米晶态，氧化钒的分子式表示为VOx，其中，x满足1≤x≤2.5。
所述二异氰酸酯为甲苯二异氰酸酯和1，6-已二异氰酸酯的混合物。
所述所述扩链剂为乙二醇、乙胺、1，3-丙二醇、1，4-丁二醇或1，5-戊二醇中的任意一种或至少两种的组合。
所述催化剂为辛酸亚锡、二辛酸二丁基锡或二月桂酸二丁锡中的任意一种或至少两种的组合。
实施例3一种电学功能膜及其制备方法，包括二异氰酸酯55份、氧化钒18份、石墨烯3份、2-丙烯酰氨基-2-甲基-1-丙烷磺酸7份、苯乙烯-丙烯腈共聚物22份、扩链剂5份、催化剂4份。
所述氧化钒为非晶态、或微晶态、纳米晶态，氧化钒的分子式表示为VOx，其中，x满足1≤x≤2.5。
所述二异氰酸酯为甲苯二异氰酸酯和1，6-已二异氰酸酯的混合物。
所述所述扩链剂为乙二醇、乙胺、1，3-丙二醇、1，4-丁二醇或1，5-戊二醇中的任意一种或至少两种的组合。
所述催化剂为辛酸亚锡、二辛酸二丁基锡或二月桂酸二丁锡中的任意一种或至少两种的组合。
对于本领域技术人员而言，显然本发明不限于所述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是所述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。

Claims (5)

1.一种电学功能膜，其特征在于，包括二异氰酸酯50-60份、氧化钒15-22份、石墨烯1-5份、2-丙烯酰氨基-2-甲基-1-丙烷磺酸5-10份、苯乙烯-丙烯腈共聚物15-30份、扩链剂2-8份、催化剂3-6份。
2.根据权利要求1所述的一种电学功能膜，其特征在于：所述氧化钒为非晶态、或微晶态、纳米晶态，氧化钒的分子式表示为VOx，其中，x满足1≤x≤2.5。
3.根据权利要求1所述的一种电学功能膜，其特征在于：所述二异氰酸酯为甲苯二异氰酸酯和1，6-已二异氰酸酯的混合物。
4.根据权利要求1所述的一种电学功能膜，其特征在于：所述所述扩链剂为乙二醇、乙胺、1，3-丙二醇、1，4-丁二醇或1，5-戊二醇中的任意一种或至少两种的组合。
5.根据权利要求1所述的一种电学功能膜，其特征在于：所述催化剂为辛酸亚锡、二辛酸二丁基锡或二月桂酸二丁锡中的任意一种或至少两种的组合。
CN201810440316.0A 2018-05-10 2018-05-10 一种电学功能膜 Pending CN108587115A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792591A (zh) * 2009-12-30 2010-08-04 中国科学院广州化学研究所 一种全生物降解塑料薄膜及其制备方法
CN101915620A (zh) * 2010-08-20 2010-12-15 电子科技大学 一种用于微测辐射热计的氧化钒薄膜及其制作方法
CN104226127A (zh) * 2014-09-10 2014-12-24 浙江工商大学 一种石墨烯/聚氨酯杂化气体分离膜的制备方法及其产品
CN106947239A (zh) * 2017-03-15 2017-07-14 东莞市雄林新材料科技股份有限公司 一种具有自动修复功能的tpu薄膜及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792591A (zh) * 2009-12-30 2010-08-04 中国科学院广州化学研究所 一种全生物降解塑料薄膜及其制备方法
CN101915620A (zh) * 2010-08-20 2010-12-15 电子科技大学 一种用于微测辐射热计的氧化钒薄膜及其制作方法
CN104226127A (zh) * 2014-09-10 2014-12-24 浙江工商大学 一种石墨烯/聚氨酯杂化气体分离膜的制备方法及其产品
CN106947239A (zh) * 2017-03-15 2017-07-14 东莞市雄林新材料科技股份有限公司 一种具有自动修复功能的tpu薄膜及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
罗河胜编: "《塑料材料手册》", 31 March 2010, 广东科技出版社 *
黄可龙主编: "《精细化学品技术手册》", 30 June 1994, 中南工业大学出版社 *

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