CN108585705A - A kind of modified glass microspheres thermal insulation mortar and preparation method thereof - Google Patents

A kind of modified glass microspheres thermal insulation mortar and preparation method thereof Download PDF

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Publication number
CN108585705A
CN108585705A CN201810848019.XA CN201810848019A CN108585705A CN 108585705 A CN108585705 A CN 108585705A CN 201810848019 A CN201810848019 A CN 201810848019A CN 108585705 A CN108585705 A CN 108585705A
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China
Prior art keywords
parts
hollow glass
thermal insulation
modified
glass micropearl
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CN201810848019.XA
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Chinese (zh)
Inventor
汪琦
郭元
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Wuhu Tang Hua Building Materials Technology Co Ltd
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Wuhu Tang Hua Building Materials Technology Co Ltd
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Priority to CN201810848019.XA priority Critical patent/CN108585705A/en
Publication of CN108585705A publication Critical patent/CN108585705A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1055Coating or impregnating with inorganic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention discloses a kind of modified glass microspheres thermal insulation mortar and preparation method thereof, belongs to building material technical field, is made of following raw materials:30~50 parts of portland cement, 5~10 parts of quartz sand, 10 15 parts of kaolin, 20~30 parts of hollow glass micropearl, 2~3 parts of inorganic mineral powder, 2~3 parts of styrene-acrylic emulsion, 4~6 parts of hydroxypropyl methyl cellulose, 3~5 parts of polypropene staple, 3~5 parts of polyvinyl alcohol, 3~5 parts of potassium dihydrogen phosphate.Glass bead of the present invention is by modified; the film of higher bonding force is formed on hollow glass micropearl surface, there is iris action to hollow glass micropearl, is played the role of for the incomplete glass microballoon of closing closed; and the percentage of damage for dropping bottom glass microballoon, to reduce water absorption rate.Meanwhile the polymer film on hollow glass micropearl surface has certain intensity and toughness, plays the role of strengthening hollow glass micropearl.

Description

A kind of modified glass microspheres thermal insulation mortar and preparation method thereof
Technical field
The present invention relates to building material technical field, more particularly to a kind of modified glass microspheres thermal insulation mortar and its preparation side Method.
Background technology
Building heat-insulating mortar reduces building energy consumption by improving the thermal and insulating performance of building, is to realize building energy conservation Most basic approach.Thermal insulation mortar is, using cement as gelating material, to admix some property-modifying additives using various light materials as aggregate, It is stirred and a kind of manufactured premixed dry mortar through manufacturing enterprise, the one kind for being mainly used for constructing building insulating layer is built Material is built, there are the excellent properties such as heat-insulating and fire-proof, water resistance and weatherability, there is the extensive market demand.
Kervit microbead insulated sand slurry is compared with organic wall heat insulation material, good, the ageing-resistant, deformation coefficient with fire protecting performance , there are extensive research and application prospect in the advantages that small, high with surface material adhesion strength in terms of outer wall heat insulating.
Due to the difference of manufacturing condition and raw material, glass bead can cause closing incomplete in process of production, Be also easy to produce along with the fragility of glass bead itself, during production, transport and use it is broken, cause actual use glass Changing bead surface has more open pore, increases so as to cause water absorption rate and intrinsic strength declines, influence vitrification micropearl morttar Thermal and insulating performance and intensity.
Invention content
The present invention provides a kind of modified glass microspheres thermal insulation mortars and preparation method thereof, solve in existing thermal insulation mortar The breakable problem of glass bead.
In order to solve the above technical problems, the technical scheme is that:
A kind of modified glass microspheres thermal insulation mortar, is made of following weight parts raw material:30~50 parts of portland cement, stone 5~10 parts of sand, 10~15 parts of kaolin, 20~30 parts of hollow glass micropearl, 2~3 parts of inorganic mineral powder, styrene-acrylic emulsion 2~3 Part, 4~6 parts of hydroxypropyl methyl cellulose, 3~5 parts of polypropene staple, 3~5 parts of polyvinyl alcohol, 3~5 parts of potassium dihydrogen phosphate.
Wherein it is preferred to which the inorganic mineral powder is blast furnace granulated slag or phosphorus slag.
Wherein it is preferred to which the polypropene staple is pencil monofilament, length is 3~5mm.
Wherein it is preferred to which the average molecular weight of the polyvinyl alcohol is 11~130,000.
A kind of preparation method of modified glass microspheres thermal insulation mortar, includes the following steps:
(1) inorganic mineral powder is taken, 100~200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, be then added It is equivalent to the water of inorganic mineral powder and styrene-acrylic emulsion weight, 30~40min is stirred with 6000~8000r/min, obtains mixture, It is sprayed on hollow glass micropearl surface using hot atomized spray processes, obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 300~400r/min is stirred 10~ 15min to get.
Beneficial effects of the present invention:
The present invention, by after inorganic mineral powder and mixed with polymers, is sprayed at hollow glass micropearl table using hot atomized spray processes Face forms the film of higher bonding force on hollow glass micropearl surface, has iris action to hollow glass micropearl, for closing not Complete glass microballoon plays the role of percentage of damage that is closed, and dropping bottom glass microballoon, to reduce water absorption rate.Meanwhile it is empty The polymer film on heart glass microballoon surface has certain intensity and toughness, plays the role of strengthening hollow glass micropearl.It should Technique is apparent to the water imbibition and raising intensity effect that reduce hollow glass micropearl.
After mixed polymer is added in the thermal insulation mortar of the present invention, thermal insulation mortar obtains thermal property and mechanical property Optimum balance, property indices are above the requirement of national standard, and thermal coefficient is less than 0.10W/ (mK), especially draws It stretches adhesion strength and reaches 0.65MPa, be suitable for the market demand of architectural exterior insulation bonding applique surface brick, while thermal insulation mortar is with good Good water-retaining property and workability.
Specific implementation mode
Below in conjunction with the specific embodiment of the invention, technical scheme of the present invention is clearly and completely described, is shown So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
In following embodiments, for the polypropene staple used for pencil monofilament, length is 3~5mm;Polyvinyl alcohol is averaged Molecular weight is 11~130,000.
Embodiment 1
The present embodiment provides a kind of modified glass microspheres thermal insulation mortars, are made of following weight parts raw material:Silicate cement 40 parts of mud, 8 parts of quartz sand, 12 parts of kaolin, 25 parts of hollow glass micropearl, 2.5 parts of blast furnace granulated slag, 2.5 parts of styrene-acrylic emulsion, hydroxypropyl 5 parts of ylmethyl cellulose, 4 parts of polypropene staple, 4 parts of polyvinyl alcohol, 4 parts of potassium dihydrogen phosphate.
The preparation method of the present embodiment modified glass microspheres thermal insulation mortar, includes the following steps:
(1) blast furnace granulated slag is taken, 200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, be then added and be equivalent to The water of inorganic mineral powder and styrene-acrylic emulsion weight is stirred 35min with 7000r/min, obtains mixture, using hot atomized spray processes It is sprayed on hollow glass micropearl surface, obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 350r/min are stirred 12min, i.e., .
Embodiment 2
The present embodiment provides a kind of modified glass microspheres thermal insulation mortars, are made of following weight parts raw material:Silicate cement 30 parts of mud, 10 parts of quartz sand, 10 parts of kaolin, 30 parts of hollow glass micropearl, 2 parts of blast furnace granulated slag, 3 parts of styrene-acrylic emulsion, hydroxypropyl 4 parts of methylcellulose, 5 parts of polypropene staple, 3 parts of polyvinyl alcohol, 5 parts of potassium dihydrogen phosphate.
The preparation method of the present embodiment modified glass microspheres thermal insulation mortar, includes the following steps:
(1) blast furnace granulated slag is taken, 100 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, be then added and be equivalent to The water of inorganic mineral powder and styrene-acrylic emulsion weight is stirred 30min with 8000r/min, obtains mixture, using hot atomized spray processes It is sprayed on hollow glass micropearl surface, obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 300r/min are stirred 15min, i.e., .
Embodiment 3
The present embodiment provides a kind of modified glass microspheres thermal insulation mortars, are made of following weight parts raw material:Silicate cement 50 parts of mud, 5 parts of quartz sand, 15 parts of kaolin, 20 parts of hollow glass micropearl, 3 parts of phosphorus slag, 2 parts of styrene-acrylic emulsion, hydroxypropyl methyl are fine 6 parts of dimension element, 3 parts of polypropene staple, 5 parts of polyvinyl alcohol, 3 parts of potassium dihydrogen phosphate.
The preparation method of the present embodiment modified glass microspheres thermal insulation mortar, includes the following steps:
(1) phosphorus slag is taken, 200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, then addition is equivalent to inorganic The water of miberal powder and styrene-acrylic emulsion weight is stirred 40min with 6000r/min, obtains mixture, is sprayed on using hot atomized spray processes Hollow glass micropearl surface obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 400r/min are stirred 10min, i.e., .
Embodiment 4
The present embodiment provides a kind of modified glass microspheres thermal insulation mortars, are made of following weight parts raw material:Silicate cement 32 parts of mud, 8 parts of quartz sand, 12 parts of kaolin, 28 parts of hollow glass micropearl, 2.6 parts of phosphorus slag, 2.8 parts of styrene-acrylic emulsion, hydroxypropyl first 5 parts of base cellulose, 4 parts of polypropene staple, 4 parts of polyvinyl alcohol, 4 parts of potassium dihydrogen phosphate.
The preparation method of the present embodiment modified glass microspheres thermal insulation mortar, includes the following steps:
(1) phosphorus slag is taken, 200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, then addition is equivalent to inorganic The water of miberal powder and styrene-acrylic emulsion weight is stirred 35min with 6000~8000r/min, obtains mixture, using hot atomizing spraying Method is sprayed on hollow glass micropearl surface, obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 350r/min are stirred 12min, i.e., .
Embodiment 5
The present embodiment provides a kind of modified glass microspheres thermal insulation mortars, are made of following weight parts raw material:Silicate cement 45 parts of mud, 8 parts of quartz sand, 12 parts of kaolin, 28 parts of hollow glass micropearl, 2.5 parts of blast furnace granulated slag, 2.5 parts of styrene-acrylic emulsion, hydroxypropyl 5 parts of ylmethyl cellulose, 4 parts of polypropene staple, 4 parts of polyvinyl alcohol, 4 parts of potassium dihydrogen phosphate.
The preparation method of the present embodiment modified glass microspheres thermal insulation mortar, includes the following steps:
(1) blast furnace granulated slag is taken, 200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, be then added and be equivalent to The water of inorganic mineral powder and styrene-acrylic emulsion weight is stirred 38min with 7000r/min, obtains mixture, using hot atomized spray processes It is sprayed on hollow glass micropearl surface, obtains modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added into batch mixer Modified hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 400r/min are stirred 12min, i.e., .
Performance detection
According to national standard GB/T-20473-2006《Building heat-insulating mortar》To the modified expanded perlite thermal insulation mortar of the present invention Progressive detects, as a result such as table 1:
1 thermal insulation mortar performance test results of the present invention of table
Index Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Thermal coefficient W/ (m.k) 0.062 0.058 0.060 0.061 0.063
Compression strength MPa 2.18 2.12 2.11 2.16 2.15
Adhesive strength MPa 0.65 0.63 0.62 0.61 0.59
Dry density kg/m3 425 419 426 417 419
Backfin ratio 1.75 1.69 1.72 1.70 1.72
As it can be seen from table 1 the adhesion strength of the thermal insulation mortar reaches 0.65MPa, meet JGJ 110-97《Architectural engineering Cohesive strength of decorative tile test stone》Adhesion strength is no less than the requirement of 0.4MPa, and thermal coefficient is less than 0.10W/ (mK).
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (5)

1. a kind of modified glass microspheres thermal insulation mortar, it is characterised in that be made of following weight parts raw material:Portland cement 30 ~50 parts, 5~10 parts of quartz sand, 10-15 parts of kaolin, 20~30 parts of hollow glass micropearl, 2~3 parts of inorganic mineral powder, phenylpropyl alcohol breast 2~3 parts of liquid, 4~6 parts of hydroxypropyl methyl cellulose, 3~5 parts of polypropene staple, 3~5 parts of polyvinyl alcohol, potassium dihydrogen phosphate 3 ~5 parts.
2. a kind of modified glass microspheres thermal insulation mortar according to claim 1, it is characterised in that:The inorganic mineral powder is height Stove grain slag or phosphorus slag.
3. a kind of modified glass microspheres thermal insulation mortar according to claim 1, it is characterised in that:The polypropene staple For pencil monofilament, length is 3~5mm.
4. a kind of modified glass microspheres thermal insulation mortar according to claim 1, it is characterised in that:The polyvinyl alcohol is put down Average molecular weight is 11~130,000.
5. a kind of preparation method of Claims 1 to 5 any one of them modified glass microspheres thermal insulation mortar, it is characterised in that packet Include following steps:
(1) inorganic mineral powder is taken, 100~200 mesh fine powders is worn into and styrene-acrylic emulsion is added in high-speed shearing machine, be then added suitable In the water of inorganic mineral powder and styrene-acrylic emulsion weight, 30~40min is stirred with 6000~8000r/min, obtains mixture, is used Hot atomized spray processes are sprayed on hollow glass micropearl surface, obtain modified hollow glass micropearl;
(2) it takes portland cement, quartz sand, kaolin to be added in batch mixer after mixing, then is added and is modified into batch mixer Hollow glass micropearl, polypropene staple, polyvinyl alcohol and potassium dihydrogen phosphate, 300~400r/min is stirred 10~ 15min to get.
CN201810848019.XA 2018-07-27 2018-07-27 A kind of modified glass microspheres thermal insulation mortar and preparation method thereof Pending CN108585705A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115259709A (en) * 2022-09-26 2022-11-01 石家庄市长安育才建材有限公司 Modified glass bead and preparation method thereof, coagulation-accelerating early strength agent and preparation method thereof

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EP2404885A2 (en) * 2010-07-06 2012-01-11 Quick-Mix Gruppe Gmbh & Co. Kg New construction material mixtures
CN103193420A (en) * 2012-01-10 2013-07-10 平湖市法而特建筑保温科技有限公司 Nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick
CN105050981A (en) * 2013-04-04 2015-11-11 圣戈班韦伯公司 Insulating mortar composition
CN107814547A (en) * 2017-11-07 2018-03-20 滕艳 A kind of thermal insulation mortar

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Publication number Priority date Publication date Assignee Title
EP2404885A2 (en) * 2010-07-06 2012-01-11 Quick-Mix Gruppe Gmbh & Co. Kg New construction material mixtures
CN103193420A (en) * 2012-01-10 2013-07-10 平湖市法而特建筑保温科技有限公司 Nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick
CN105050981A (en) * 2013-04-04 2015-11-11 圣戈班韦伯公司 Insulating mortar composition
CN107814547A (en) * 2017-11-07 2018-03-20 滕艳 A kind of thermal insulation mortar

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115259709A (en) * 2022-09-26 2022-11-01 石家庄市长安育才建材有限公司 Modified glass bead and preparation method thereof, coagulation-accelerating early strength agent and preparation method thereof
CN115259709B (en) * 2022-09-26 2023-01-06 石家庄市长安育才建材有限公司 Modified glass bead and preparation method thereof, coagulation-accelerating early strength agent and preparation method thereof

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