CN108545936A - Anti slip glass ice cup - Google Patents
Anti slip glass ice cup Download PDFInfo
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- CN108545936A CN108545936A CN201810680074.2A CN201810680074A CN108545936A CN 108545936 A CN108545936 A CN 108545936A CN 201810680074 A CN201810680074 A CN 201810680074A CN 108545936 A CN108545936 A CN 108545936A
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- glass
- cup
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- ice
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-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B15/00—Drawing glass upwardly from the melt
- C03B15/14—Drawing tubes, cylinders, or rods from the melt
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/04—Re-forming tubes or rods
- C03B23/09—Reshaping the ends, e.g. as grooves, threads or mouths
- C03B23/092—Reshaping the ends, e.g. as grooves, threads or mouths by pressing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of anti slip glass ice cups.The present invention anti slip glass ice cup certain time is being freezed in refrigerator using preposition, allow need to drink ice drink when, only need to pour the beverage into anti slip glass ice cup, beverage can fast cooling, it is ice-cold tasty and refreshing.Be not in that beverage crosses freezing situation compared to ice cube is directly added into beverage.The glass drinking cup formula of anti slip glass ice cup of the present invention is：SiO246.08~61.51 parts, Al2O315.48~26.02 parts, SrCO314.75~26.21 parts, B2O31.08~10.4 parts, Na20.68~3.42 part of O, 0.05~0.15 part of flyash, 0.5~3 part of glass fining agent.Compared with prior art, anti slip glass ice cup of the invention is for good anti-skidding, resistance to low temperature and low thermal coefficient of expansion.
Description
Technical field
The present invention relates to a kind of anti slip glass ice cups, belong to glass working arts field.
Background technology
As the improvement of people's living standards, the demand of various beverages is increasing, especially in hot summer, people
For relieve summer heat quench one's thirst, health, need the selective use of the cold drink of more designs and varieties, and existing refrigerator, refrigerator-freezer, because by when
Between limitation can't drink cold drink in time, meet the needs of people's fast pace life.It is related directly quick, easy to use thus
The patent of freezing container come into being, to solve the different demands for meeting people.
Pyrex have excellent visible light transmittance (>=90%), low-expansion coefficient, good chemical stability, freeze-resistant
The features such as ability and heat resistance, is widely used in fields such as aviation, instrument, illumination, fire prevention and tablewares.Therefore, by Pyrex
Applied to having good prospects in glass ice cup.
The present invention is by the way that on the basis of the convenient source of Pyrex, addition strontium carbonate, flyash further promote borosilicate
The mechanical resistant impact property and low temperature thermal expansivity of glass promote service life of the glass ice cup under ice-cold environmental condition with this
And ice-cold effect.The present invention anti slip glass ice cup certain time is being freezed in refrigerator using preposition, allow need to drink ice drink when,
Only need to pour the beverage into anti slip glass ice cup, beverage can fast cooling, it is ice-cold tasty and refreshing.Compared to ice is directly added into beverage
Block is not in that beverage crosses freezing situation.
Invention content
One of the objects of the present invention is to provide a kind of anti slip glass ice cups, by the convenient source basis of Pyrex
On, strontium carbonate, flyash is added and simultaneously chooses suitable glass fining agent, be prepared a kind of freeze-resistant, mechanical resistant impact it is anti-
Sliding glass ice cup.
Its technical solution includes：
A kind of anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.
Preferably, the glass drinking cup includes following raw material：SiO2、Al2O3、B2O3、Na2O, glass fining agent；Further
Preferably, the glass drinking cup includes following raw material：SiO2、Al2O3、SrCO3、B2O3、Na2O, glass fining agent；It is then preferred that
The glass drinking cup includes following raw material：SiO2、Al2O3、SrCO3、B2O3、Na2O, flyash, glass fining agent.
During glass metal is clear, the effect Main physical dissolving between gas and glass metal and chemolysis.It is clarifying
When, the gas of glass metal dissolving, equilibrium relation is point by this kind of gas in each phase between the gas and kiln gas in bubble
Pressure is determined.Gas enters the lower phase of partial pressure by dividing higher phase.The partial pressure for being such as dissolved in gas in glass metal is more than gas
Bubble in gas of the same race partial pressure, then bubble will from surrounding glass metal draw gas.The saturation journey of dissolved gas in glass metal
Degree is bigger, and the partial pressure of gas is lower in bubble in glass metal, then the speed that gas increases is also bigger, and bubble is made to increase and rise.
Conversely, as the partial pressure of gas in bubble is more than the partial pressure of the gas dissolved in glass metal, then the gas in bubble will be dissolved and
So that bubble is become smaller, or even is completely dissolved and disappears.
The glass fining agent that the present invention adds can generate a large amount of dissolving and the gas in glass, in satiety in glass metal
And state, the partial pressure in their glass metal is improved, and to the gas evolution remained in glass metal, reduce existing in bubble
The partial pressure of other bubbles.Again the ability that it draws this gas from glass metal is strengthened, the gas generated due to fining agent
The gas having with bubble Central Plains is precipitated jointly, will increase the diameter of bubble, accelerates the rising of bubble.These bubbles are in uphill process
In the minute bubbles on periphery can be received to rise together with minute bubbles again, and an a part of minute bubbles are taken out of, glass metal are made to be clarified.
The glass fining agent toxicity of common white arsenic, antimony oxide compared with prior art, addition of the invention is smaller, while with the present invention's
SiO2、Al2O3、SrCO3、B2O3、Na2O, fly vitreous system good combination and notable clarification is played.
Preferably, the glass drinking cup is prepared by following raw material by weight：SiO246.08~61.51
Part, Al2O315.48~26.02 parts, SrCO314.75~26.21 parts, B2O31.08~10.4 parts, Na2O 0.68~3.42
Part, 0.05~0.15 part of flyash, 0.5~3 part of glass fining agent.
Preferably, the glass fining agent be potassium nitrate, ceria, prodan, any one in stannic oxide or
The a variety of mixing of person；It is further preferred that the glass fining agent is potassium nitrate, ceria, prodan, stannic oxide are pressed
Mass ratio 1:(1~3):(0.1~0.8):(0.5~1.5) mixes.
The preparation method of the anti slip glass ice cup, includes the following steps：
S1 weighs raw material by weight, and ball grinds obtain mixed powder；
Mixture powder is melted, heat preservation, clarification, is homogenized by S2, and obtained glass metal is drawn into glass tube by daraf(reciprocal of farad) of hanging down；
Glass tube is made annealing treatment rapidly；
The glass tube of annealing is cut into short glass tube and heats back cover by S3, profit after then heating short glass tube oral area
Upper screw thread is rolled with threaded mold pushing, is cooled to room temperature, obtains glass drinking cup；
S4 covers upper silica gel sheath to get anti slip glass ice cup in bath of glass wall of cup side.
It is further preferred that the preparation method of the anti slip glass ice cup, includes the following steps：
S1 weighs raw material by weight, and ball grinds, it is 5~20 μm of mixed powders to obtain granularity；
Mixed powder is heated to 1450~1550 DEG C of meltings by S2, and speed of agitator is 100~300 revs/min, temperature is
1.5~3h is kept the temperature at 1450~1550 DEG C, then 15~30min of clarification at 1400~1500 DEG C, then 1400~1500 DEG C
Lower standing is homogenized 15~30min, and obtained glass metal is drawn into glass tube by daraf(reciprocal of farad) of hanging down；Glass tube is placed in 500 rapidly~
1.5~3.0h is kept the temperature at 600 DEG C, then cools to 15~30 DEG C with the furnace, the glass tube made annealing treatment；
Back cover after the glass tube of annealing is cut into short glass tube and is heated to 500~600 DEG C by S3；Then glass is short
Spout part is heated to 500~600 DEG C, then rolls upper screw thread using the pushing of upper threaded mold, is cooled to 15~30 DEG C, obtains glass
Glass cup；
S4 covers upper silica gel sheath to get anti slip glass ice cup in bath of glass wall of cup side.
The technique effect that the present invention is brought has：
(1) anti slip glass ice cup of the invention can extend glass to a certain extent for excellent mechanical resistant impact property
The service life of glass cup.
(2) anti slip glass ice cup of the invention is after experience freezes for a long time, and because being provided with silica gel sheath, comfortable feel is prevented
Sliding effect is good.
(3) the low temperature coefficient of thermal expansion of anti slip glass ice cup of the invention is small, has good freexing tolerance energy, is suitble in ice
It is used in cold environment.
Specific implementation mode
Each raw material sources in embodiment：
It is analytically pure commercial goods if not refering in particular to, heretofore described chemical substance.
SiO2：That is quartz sand, 20~40 mesh of grain size, SiO2Content >=99%, ten thousand river quartz Development Co., Ltd of Heyuan City.
Al2O3：20~40 mesh of grain size, Zhengzhou Yi Wang chemical products Co., Ltd.
SrCO3：No. CAS：1633-05-2,20~40 mesh of grain size, purity 98%, Zhengzhou Tuo Yuan chemical products Co., Ltd.
B2O3：No. CAS：1303-86-2,20~40 mesh of grain size, purity 98%, Zhengzhou Han Shuo industrial chemicals Co., Ltd.
Na2O：No. CAS：1313-59-3,10~20 mesh of grain size, purity 98%, Zhengzhou Han Shuo industrial chemicals Co., Ltd.
Flyash：Model：Hy-0005, grain size are 0.5~200 μm, meet I specified in GBT1596-2005 grades of mark
Standard, Lingshou County Hua Yao mineral products processings factory.
Potassium nitrate：No. CAS：7757-79-1.
Ceria：No. CAS：1306-38-3.
Prodan：No. CAS：16893-85-9.
Stannic oxide：No. CAS：18282-10-5.
Embodiment 1
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, B2O38.24 parts, Na21.37 parts of O, 1.35 parts of glass fining agent.The glass fining agent is
Potassium nitrate, ceria in mass ratio 1:4.2 mixing.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, B2O38.24 parts, Na21.37 parts of O,
1.35 parts of glass fining agent；It is 5~20 μm to be all added in planetary ball mill and be milled to granularity, obtained mixed powder；It is described
Glass fining agent is potassium nitrate, ceria in mass ratio 1:4.2 mixing.
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 2
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 1.35 parts of glass fining agent.Institute
It is potassium nitrate, ceria in mass ratio 1 to state glass fining agent:4.2 mixing.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 1.35 parts of glass fining agent；It is 5~20 μm to be all added in planetary ball mill and be milled to granularity, is obtained
Mixed powder；The glass fining agent is potassium nitrate, ceria in mass ratio 1:4.2 mixing.
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 3
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 0.12 part of flyash, glass are clear
Clear 1.35 parts of agent.The glass fining agent is potassium nitrate, ceria in mass ratio 1:4.2 mixing.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 0.12 part of flyash, 1.35 parts of glass fining agent；All being milled to granularity in addition planetary ball mill is
5~20 μm, obtained mixed powder；The glass fining agent is potassium nitrate, ceria in mass ratio 1:4.2 mixing.
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 4
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 0.12 part of flyash, glass are clear
Clear 1.35 parts of agent.The glass fining agent is potassium nitrate, ceria, prodan in mass ratio 1:3.7:0.5 mixes.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 0.12 part of flyash, 1.35 parts of glass fining agent；All being milled to granularity in addition planetary ball mill is
5~20 μm, obtained mixed powder；The glass fining agent is potassium nitrate, ceria, prodan in mass ratio 1:3.7:
0.5 mixes；
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 5
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 0.12 part of flyash, glass are clear
Clear 1.35 parts of agent.The glass fining agent is potassium nitrate, ceria, stannic oxide in mass ratio 1:3.3:0.9 mixes.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 0.12 part of flyash, 1.35 parts of glass fining agent；All being milled to granularity in addition planetary ball mill is
5~20 μm, obtained mixed powder；The glass fining agent is potassium nitrate, ceria, stannic oxide in mass ratio 1:3.3:
0.9 mixes.
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 6
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 0.12 part of flyash, glass are clear
Clear 1.35 parts of agent.The glass fining agent is potassium nitrate, prodan, stannic oxide in mass ratio 1:1.4:2.8 mixing.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 0.12 part of flyash, 1.35 parts of glass fining agent；All being milled to granularity in addition planetary ball mill is
5~20 μm, obtained mixed powder；The glass fining agent is potassium nitrate, prodan, stannic oxide in mass ratio 1:1.4:
2.8 mixing；
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Embodiment 7
Anti slip glass ice cup, is made of glass drinking cup and silica gel sheath.The glass drinking cup raw material (parts by weight)：SiO2
53.79 part, Al2O319.75 part, SrCO315.38 part, B2O38.24 parts, Na21.37 parts of O, 0.12 part of flyash, glass are clear
Clear 1.35 parts of agent.The glass fining agent is potassium nitrate, ceria, prodan, stannic oxide in mass ratio 1:3:0.4:
0.8 mixes.
The preparation method of anti slip glass ice cup：
S1 weighs raw material by weight：SiO253.79 part, Al2O319.75 part, SrCO315.38 part, B2O3 8.24
Part, Na21.37 parts of O, 0.12 part of flyash, 1.35 parts of glass fining agent；All being milled to granularity in addition planetary ball mill is
5~20 μm, obtained mixed powder；The glass fining agent is potassium nitrate, ceria, prodan, stannic oxide by matter
Measure ratio 1:3:0.4:0.8 mixes；
S2 mixture powder is added in graphite crucible is heated to 1530 DEG C melting, and speed of agitator be 200 turns/
Point, temperature be 1530 DEG C at keep the temperature 2h, make fully to carry out high-temperature chemical reaction between each component, then be clarified at 1450 DEG C
20min is discharged the air swept along in melt and the bubble of raw material decomposes generation, homogenizing 20min is then stood at 1450 DEG C, is obtained
Glass metal the glass tube of diameter 70mm, wall thickness 10mm, length 500mm is drawn by daraf(reciprocal of farad) of hanging down；Glass tube is placed in rapidly
2h is kept the temperature at 550 DEG C, then cools to room temperature (25 DEG C), the glass tube made annealing treatment with the furnace；
The glass tube of annealing is cut into length as the short glass tube of 120mm by production requirement and is heated to 550 DEG C by S3
Graphite knife back cover is used afterwards；Then short glass tube oral area is heated to 550 DEG C, then rolls upper spiral shell using the pushing of upper threaded mold
Line is cooled to room temperature (25 DEG C), obtains glass drinking cup；
S4 covers upper silica gel sheath to get the anti slip glass ice of diameter 70mm, wall thickness 10mm, high 120mm in bath of glass wall of cup side
Cup.
Test case 1
Mechanical resistant impact test：
Glass drinking cup rim of a cup prepared by embodiment is placed on platform downward, the steel ball of 35g is individually placed to away from product bottom
Portion 500mm, 505mm, 510mm, 515mm, 520mm, 525mm, 530mm, 535mm, 540mm, 545mm, 550mm, 555mm,
On the position of 560mm, 565mm, 570mm, 575mm, 580mm, make whether ball free-falling, observation glass drinking cup are crushed；Every group
Test takes 10 samples, and distance of the steel ball away from product bottom when every group of sample more than half quantity is broken at this time is denoted as broken height
Degree；Statistical result is shown in Table 1.
1 mechanical resistant impact test of table
| Embodiment | Break height |
| Embodiment 1 | 520mm |
| Embodiment 2 | 540mm |
| Embodiment 3 | 560mm |
| Embodiment 4 | 565mm |
| Embodiment 5 | 565mm |
| Embodiment 6 | 565mm |
| Embodiment 7 | 575mm |
The present invention is added to SrCO3, the mechanical resistant impact property of glass drinking cup is significantly enhanced after the substances such as flyash.
Test case 2
Coefficient of thermal expansion：DIL0806A proximate matters material thermal dilatometer coefficient tester carries out heat to the glass drinking cup in embodiment
Expansion test, test result are shown in Table 2.
2 coefficient of thermal expansion of table
The present invention is described in detail above, specific case used herein is to the principle of the present invention and embodiment party
Formula is expounded, and the explanation of above example is only intended to facilitate the understanding of the method and its core concept of the invention；Meanwhile it is right
In those of ordinary skill in the art, according to the thought of the present invention, change is had in specific embodiments and applications
Place, in conclusion the content of the present specification should not be construed as limiting the invention.
Claims (9)
1. a kind of anti slip glass ice cup, it is characterised in that：It is made of glass drinking cup and silica gel sheath.
2. anti slip glass ice cup as described in claim 1, which is characterized in that the glass drinking cup includes following raw material：SiO2、
Al2O3、B2O3、Na2O, glass fining agent.
3. anti slip glass ice cup as described in claim 1, which is characterized in that the glass drinking cup includes following raw material：SiO2、
Al2O3、SrCO3、B2O3、Na2O, glass fining agent.
4. anti slip glass ice cup as described in claim 1, which is characterized in that the glass drinking cup includes following raw material：SiO2、
Al2O3、SrCO3、B2O3、Na2O, flyash, glass fining agent.
5. anti slip glass ice cup as described in claim 1, which is characterized in that the glass drinking cup by it is following by weight
Raw material is prepared：SiO246.08~61.51 parts, Al2O315.48~26.02 parts, SrCO314.75~26.21 parts, B2O3
1.08~10.4 parts, Na2O0.68~3.42 part, 0.05~0.15 part of flyash, 0.5~3 part of glass fining agent.
6. anti slip glass ice cup as claimed in claim 5, it is characterised in that：The glass fining agent is potassium nitrate, titanium dioxide
Any one in cerium, prodan, stannic oxide or a variety of mixing.
7. anti slip glass ice cup as claimed in claim 6, it is characterised in that：The glass fining agent is potassium nitrate, titanium dioxide
Cerium, prodan, stannic oxide in mass ratio 1:(1~3):(0.1~0.8):(0.5~1.5) mixes.
8. such as the preparation method of claim 1~7 any one of them anti slip glass ice cup, which is characterized in that including following steps
Suddenly：
S1 weighs raw material by weight, and ball grinds obtain mixed powder；
Mixture powder is melted, heat preservation, clarification, is homogenized by S2, and obtained glass metal is drawn into glass tube by daraf(reciprocal of farad) of hanging down；Rapidly
Glass tube is made annealing treatment；
The glass tube of annealing is cut into short glass tube and heats back cover by S3, using upper after then heating short glass tube oral area
Threaded mold pushing rolls screw thread, is cooled to room temperature, obtains glass drinking cup；
S4 covers upper silica gel sheath to get anti slip glass ice cup in bath of glass wall of cup side.
9. the preparation method of anti slip glass ice cup as claimed in claim 8, which is characterized in that include the following steps：
S1 weighs raw material by weight, and ball grinds, it is 5~20 μm of mixed powders to obtain granularity；
S2 by mixed powder be heated to 1450~1550 DEG C melting, and speed of agitator be 100~300 revs/min, temperature 1450
1.5~3h is kept the temperature at~1550 DEG C, 15~30min is then clarified at 1400~1500 DEG C, is then stood for 1400~1500 DEG C
Change 15~30min, obtained glass metal is drawn into glass tube by daraf(reciprocal of farad) of hanging down；Glass tube is placed at 500~600 DEG C rapidly and is protected
1.5~3.0h of temperature, then cools to 15~30 DEG C with the furnace, the glass tube made annealing treatment；
Back cover after the glass tube of annealing is cut into short glass tube and is heated to 500~600 DEG C by S3；Then by short glass tube mouth
Portion is heated to 500~600 DEG C, then rolls upper screw thread using the pushing of upper threaded mold, is cooled to 15~30 DEG C, obtains bath of glass
Cup；
S4 covers upper silica gel sheath to get anti slip glass ice cup in bath of glass wall of cup side.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810680074.2A CN108545936A (en) | 2018-06-27 | 2018-06-27 | Anti slip glass ice cup |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810680074.2A CN108545936A (en) | 2018-06-27 | 2018-06-27 | Anti slip glass ice cup |
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| CN108545936A true CN108545936A (en) | 2018-09-18 |
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Application publication date: 20180918 |