CN107285621A - A kind of water purifier glass container and preparation method thereof - Google Patents
A kind of water purifier glass container and preparation method thereof Download PDFInfo
- Publication number
- CN107285621A CN107285621A CN201710539187.6A CN201710539187A CN107285621A CN 107285621 A CN107285621 A CN 107285621A CN 201710539187 A CN201710539187 A CN 201710539187A CN 107285621 A CN107285621 A CN 107285621A
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- Prior art keywords
- parts
- glass
- oxide
- glass container
- water purifier
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
- C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
- C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of water purifier glass container and preparation method thereof, the glass container is made up of following components in parts by weight：Boron oxide is 25 parts, sodium oxide molybdena is 3 15 parts, iron oxide is 0.1 6 parts, and fluorine oxide is 0.1 1.5 parts, and magnesia is 6 21 parts, aluminum oxide is 8 35 parts, calcium oxide is 6 38 parts, and silica is 10 85 parts, and the deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then loaded material into big expects pipe or feed bin；Heat temperature raising, makes temperature reach 1,700 1800 DEG C, is kept for 1 hour 30 minutes at such a temperature, then is cooled to 1,400 1500 DEG C and obtains glass metal, then is homogenized, and clarifies, and discharges bubble, forms flowable molten mass；Forming processes, forming processes are carried out to molten mass, the glass of finished product is obtained after annealed, cooling, and the glass water absorption rate is in the range of 0.1 0.4%, and the rupture strength of the glass is up to 80 200MPa.The hard blister content that the present invention is prepared is relatively low, more environmentally-friendly energy-conservation.
Description
Technical field
The invention belongs to glass technology field, specifically a kind of water purifier glass container and preparation method thereof.
Background technology
Using for abnormity glassware be processed such as blowing, compacting or trombone slide moulding technique modern times,
Water purifier glass container, the solar energy glass pipe of solar water heater are such as applied to, it has on the formula of production technology
There is significant deficiency, there is a kind of technology prejudice, silica composition is all melted using vast scale sodium oxide molybdena or boron oxide, especially
Its alkali-free boron glass based article, but it has and not saved not environmentally, viscosity temperature property is still very high, and the great of intensity difference lacks
Fall into.How problem above, and the durability and new use that promote the energy-saving and environmental protection production of these glasswares and product had are solved
The intensity on way and lightweight, greatly save the cost of transportation, save transport energy consumption etc., be all that people thirst for solution, and do not have always
There is the technology great difficult problem succeeded.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of water purifier glass container and preparation method thereof, inside glass
Air bubble content is relatively low, and more environmentally-friendly energy-conservation, rupture strength is good.
In order to solve the above-mentioned technical problem, the present invention takes following technical scheme：
A kind of water purifier glass container, the glass container is made up of following components in parts by weight：Boron oxide is
2-5 parts, sodium oxide molybdena is 3-15 parts, and iron oxide is 0.1-6 parts, and fluorine oxide is 0.1-1.5 parts, and magnesia is 6-21 parts, aluminum oxide
For 8-35 parts, calcium oxide is 6-38 parts, and silica is 10-85 parts.
A kind of preparation method of water purifier glass container, comprises the following steps：
The deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then by material
It is fitted into big expects pipe or feed bin；
Heat temperature raising, makes temperature reach 1700-1800 DEG C, is kept for -1 hour 30 minutes at such a temperature, then be cooled to 1400-
1500 DEG C obtain glass metal, then are homogenized, clarification, discharge bubble, form flowable molten mass；
Forming processes, forming processes are carried out to molten mass, the glass of finished product, the glass water absorption rate are obtained after annealed, cooling
In the range of 0.1-0.4%, the rupture strength of the glass reaches 80-200MPa.
The forming processes include trombone slide shaping, compressing or blow molding.
During the clarification, glass fining agent is added into raw material, the amount that the glass fining agent is added is that frit is total
/ to 15th/20ths of amount, the glass fining agent is by the nitrate of 3-4 parts according to the mass fraction and 0.5-0.8 parts
Tin oxide is constituted.
The scope for 1250 DEG C -1430 DEG C is kept the temperature at during the exhaust bubble.
In the molding process, after the completion of shaping, room temperature is first cooled to, then 280-310 DEG C is increased to from room temperature, so
It is placed in 400-420 DEG C of sodium nitrate molten liquid and handles 30-50 minutes afterwards, then takes out and cool to 90-110 DEG C, place into
Handled 60-80 minutes in 400-420 DEG C of sodium nitrate molten liquid.
The bubble contained by inside glass that the present invention is prepared is less, and more environmentally-friendly energy-conservation, rupture strength is good, effectively carries
High-quality, is especially suitable for manufacturing the glass container of water purifier.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to the invention will be further described.
Present invention is disclosed a kind of water purifier glass container, the glass container is by parts by weight with the following group
It is grouped into：Boron oxide is 2-5 parts, and sodium oxide molybdena is 3-15 parts, and iron oxide is 0.1-6 parts, and fluorine oxide is 0.1-1.5 parts, magnesia
For 6-21 parts, aluminum oxide is 8-35 parts, and calcium oxide is 6-38 parts, and silica is 10-85 parts.According to above setting weight number
Than can flexibly adjust the consumption of each component, preferably be matched so as to reach, lift product quality.
Embodiment one
A kind of preparation method of water purifier glass container, comprises the following steps：
The deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then by material
It is fitted into big expects pipe or feed bin.It is 2 parts to choose boron oxide, and sodium oxide molybdena is 3 parts, and iron oxide is 5 parts, and fluorine oxide is 1 part, magnesia
For 6 parts, aluminum oxide is 8 parts, and calcium oxide is 6 parts, and silica is 80 parts.
Heat temperature raising, makes temperature reach 1700 DEG C, is kept for 30 minutes at such a temperature, then be cooled to 1400 DEG C and obtain glass
Liquid, then be homogenized, clarify, discharge bubble, form flowable molten mass, the model for 1250 DEG C is kept the temperature at during exhaust bubble
Enclose.
Using trombone slide forming processes, forming processes are carried out to molten mass, the glass of finished product is obtained after annealed, cooling,
The glass water absorption rate is in the range of 0.1%, and the rupture strength of the glass reaches 80MPa.
During the clarification, glass fining agent is added into raw material, the amount that the glass fining agent is added is that frit is total
/ the 20 of amount, the glass fining agent is made up of 3 parts of nitrate and 0.5 part of tin oxide according to the mass fraction.
In molding process, after the completion of shaping, room temperature is first cooled to, then 280 DEG C are increased to from room temperature, is then placed within
Handled 50 minutes in 400 DEG C of sodium nitrate molten liquid, then take out and cool to 90 DEG C, place into 400 DEG C of sodium nitrate molten liquid
Middle processing 80 minutes.
Embodiment two
A kind of preparation method of water purifier glass container, comprises the following steps：
The deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then by material
It is fitted into big expects pipe or feed bin.Boron oxide is 4 parts, and sodium oxide molybdena is 10 parts, and iron oxide is 3 parts, and fluorine oxide is 0.5 part, magnesia
For 13 parts, aluminum oxide is 20 parts, and calcium oxide is 30 parts, and silica is 15 parts.
Heat temperature raising, makes temperature reach 1750 DEG C, is kept for 50 minutes at such a temperature, then be cooled to 1450 DEG C and obtain glass
Liquid, then be homogenized, clarify, discharge bubble, form flowable molten mass, the model for 1300 DEG C is kept the temperature at during exhaust bubble
Enclose.
Handled using blow molding, forming processes carried out to molten mass, the glass of finished product is obtained after annealed, cooling,
The glass water absorption rate is in the range of 0.3%, and the rupture strength of the glass reaches 140MPa.
During the clarification, glass fining agent is added into raw material, the amount that the glass fining agent is added is that frit is total
/ the 18 of amount, the glass fining agent is made up of 4 parts of nitrate and 0.6 part of tin oxide according to the mass fraction.
In molding process, after the completion of shaping, room temperature is first cooled to, then 290 DEG C are increased to from room temperature, is then placed within
Handled 40 minutes in 410 DEG C of sodium nitrate molten liquid, then take out and cool to 100 DEG C, place into 410 DEG C of sodium nitrate molten liquid
Middle processing 70 minutes.
Embodiment three
A kind of preparation method of water purifier glass container, comprises the following steps：
The deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then by material
It is fitted into big expects pipe or feed bin.It is 5 parts to choose boron oxide, and sodium oxide molybdena is 15 parts, and iron oxide is 6 parts, and fluorine oxide is 1.5 parts, oxygen
It is 21 parts to change magnesium, and aluminum oxide is 35 parts, and calcium oxide is 38 parts, and silica is 70 parts
Heat temperature raising, makes temperature reach 1800 DEG C, is kept for 1 hour at such a temperature, then is cooled to 1500 DEG C and obtains glass metal, then
Bubble is discharged in homogenizing, clarification, forms flowable molten mass.The scope for 1430 DEG C is kept the temperature at during exhaust bubble.
Forming processes, forming processes are carried out to molten mass, the glass of finished product is obtained after annealed, cooling, the glass is inhaled
Water rate is in the range of 0.4%, and the rupture strength of the glass reaches 80-200MPa.
The forming processes include trombone slide shaping, compressing or blow molding.
During the clarification, glass fining agent is added into raw material, the amount that the glass fining agent is added is that frit is total
/ the 15 of amount, the glass fining agent is made up of 4 parts of nitrate and 0.8 part of tin oxide according to the mass fraction.
In the molding process, after the completion of shaping, room temperature is first cooled to, then 310 DEG C, Ran Houfang are increased to from room temperature
Put and handled 30 minutes in 420 DEG C of sodium nitrate molten liquid, then take out and cool to 110 DEG C, place into 420 DEG C of nitric acid sodium fusion
Melt in liquid and handle 60 minutes.
It should be noted that described above is not the restriction to technical solution of the present invention, the wound of the present invention is not being departed from
On the premise of making design, any obvious replacement is within protection scope of the present invention.
Claims (6)
1. a kind of water purifier glass container, it is characterised in that the glass container is by following components in parts by weight
Composition：Boron oxide is 2-5 parts, and sodium oxide molybdena is 3-15 parts, and iron oxide is 0.1-6 parts, and fluorine oxide is 0.1-1.5 parts, and magnesia is
6-21 parts, aluminum oxide is 8-35 parts, and calcium oxide is 6-38 parts, and silica is 10-85 parts.
2. a kind of preparation method of water purifier glass container according to claim 1, comprises the following steps：
The deal of each raw material is prepared according to setting ratio, then all raw materials are mixed and stirred, then by material
It is fitted into big expects pipe or feed bin；
Heat temperature raising, makes temperature reach 1700-1800 DEG C, is kept for -1 hour 30 minutes at such a temperature, then be cooled to 1400-
1500 DEG C obtain glass metal, then are homogenized, clarification, discharge bubble, form flowable molten mass；
Forming processes, forming processes are carried out to molten mass, the glass of finished product, the glass water absorption rate are obtained after annealed, cooling
In the range of 0.1-0.4%, the rupture strength of the glass reaches 80-200MPa.
3. the preparation method of water purifier glass container according to claim 2, it is characterised in that the forming processes bag
Include trombone slide shaping, compressing or blow molding.
4. the preparation method of water purifier glass container according to claim 3, it is characterised in that past during the clarification
Glass fining agent is added in raw material, the amount that the glass fining agent is added for frit total amount 1 to 15/20ths/
One, the glass fining agent is made up of the nitrate and 0.5-0.8 parts of tin oxide of 3-4 parts according to the mass fraction.
5. the preparation method of water purifier glass container according to claim 4, it is characterised in that will during the exhaust bubble
Temperature is maintained at the scope for 1250 DEG C -1430 DEG C.
6. the preparation method of water purifier glass container according to claim 5, it is characterised in that the forming processes mistake
Cheng Zhong, after the completion of shaping, is first cooled to room temperature, then is increased to 280-310 DEG C from room temperature, is then placed within 400-420 DEG C of nitre
Handled 30-50 minutes in sour sodium fused solution, then take out and cool to 90-110 DEG C, place into 400-420 DEG C of sodium nitrate molten
Handled 60-80 minutes in liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710539187.6A CN107285621A (en) | 2017-07-04 | 2017-07-04 | A kind of water purifier glass container and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710539187.6A CN107285621A (en) | 2017-07-04 | 2017-07-04 | A kind of water purifier glass container and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107285621A true CN107285621A (en) | 2017-10-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710539187.6A Pending CN107285621A (en) | 2017-07-04 | 2017-07-04 | A kind of water purifier glass container and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108545936A (en) * | 2018-06-27 | 2018-09-18 | 淄博泰康轻工制品有限公司 | Anti slip glass ice cup |
-
2017
- 2017-07-04 CN CN201710539187.6A patent/CN107285621A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108545936A (en) * | 2018-06-27 | 2018-09-18 | 淄博泰康轻工制品有限公司 | Anti slip glass ice cup |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171024 |
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| RJ01 | Rejection of invention patent application after publication |