CN108530949A - 氧化铁绿着色粉末 - Google Patents

氧化铁绿着色粉末 Download PDF

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CN108530949A
CN108530949A CN201810368527.8A CN201810368527A CN108530949A CN 108530949 A CN108530949 A CN 108530949A CN 201810368527 A CN201810368527 A CN 201810368527A CN 108530949 A CN108530949 A CN 108530949A
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iron oxide
powder
green coloring
oxide green
coloring powder
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胡杰
徐海荣
莫炼强
计红霞
唐晓英
唐飞
沈根弟
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Deqing Zhejiang Mei Shile Pigment Science And Technology Ltd
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Deqing Zhejiang Mei Shile Pigment Science And Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/22Compounds of iron
    • C09C1/24Oxides of iron
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033Blends of pigments; Mixtured crystals; Solid solutions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08Treatment with low-molecular-weight non-polymer organic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/19Oil-absorption capacity, e.g. DBP values
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • C01P2006/82Compositional purity water content

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开的一种氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄40‑60%,碳酸钙:30‑60%,酞菁蓝:5‑10%。本发明所得到的氧化铁绿着色粉末具有以下特点:绿色粉末,粉末颗粒大小320目以上,不溶于水﹑醇,溶于酸。粉粒细腻,是晶体的氧化铁化合物,着色力、遮盖力、耐光性、耐酸性、耐碱性均佳,无毒无危害。用所述制备方法,制作所得的氧化铁绿着色粉末应用于颜料中,着色力和遮盖力都很高,耐光、耐大气性好,无水渗性和油渗性。同时这种氧化铁绿着色粉末能广泛适用于各类建筑地坪(大理石地坪、水磨石地坪)的着色,对水泥建筑和外墙涂料有着良好的改善作用,市场前景十分广阔,也可达到客户颜色多样化的需求。

Description

氧化铁绿着色粉末
技术领域
本发明涉及一种用于颜料制作的原料,特别是一种氧化铁绿着色粉末。
背景技术
氧化铁绿主要应用于颜料制作领域,氧化铁绿颜料在各类混凝土预制件和建筑制品材料中作为颜料或着色剂,直接调入水泥中应用。各种室内外的彩色混凝土表面,如墙面、地坪、天花板、支柱、门廊、路面、停车场、阶梯、车站等;各种建筑陶瓷和琉璃陶瓷,如面砖、地砖、屋瓦、嵌板、水磨石、马赛克花砖、人造大理石等。同时其也适用于各种涂料着色和保护物质,包括水性内外墙涂料、粉末涂料等;也可适用于油性漆包括还氧、醇酸、氨基等各种底漆和面漆;也可用于玩具漆、装饰漆、家具漆、电泳漆和磁漆。
现有的氧化铁绿粉末具有以下的问题:耐热性差,易褪色,尤其是在制作应用于室外彩色混凝土表面的颜料时,夏季室外温度较高,及易发生掉漆、褪色的现象。这与其中氧化铁绿粉末的组分构成、制作工艺有及其密切的关联。
发明内容
为解决上述问题,本发明提出了性能好,着色时间短,不易褪色的氧化铁绿着色粉末。
本发明设计的一种氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄40-60%,碳酸钙:30-60%,酞菁蓝:5-10%。
作为优选,氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄40%,碳酸钙:50%,酞菁蓝:10%。
作为优选,氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄60%,碳酸钙:35%,酞菁蓝:5%。
作为优选,氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄50%,碳酸钙:40%,酞菁蓝:10%。
作为优选,所述粉末呈绿色。所述的粉末颗粒大小为320目以上。其主要技术参数:水分≤1.0%,水溶物≤2.5%,筛余物≤0.5%,pH值大于6,吸油量25-35。
一种氧化铁绿着色粉末的制备方法,包括以下步骤:将氧化铁黄、碳酸钙、酞菁蓝按照氧化铁黄40-60%,碳酸钙:30-60%,酞菁蓝:5-10%的质量比例加入到高速搅拌机中;将上述材料的混合物在高速搅拌机中匀速搅拌混合1小时以上;将上述材料的混合物在粉碎机中粉碎均匀。
与现有技术相比,本发明所得到的氧化铁绿着色粉末具有以下特点:绿色粉末,粉末颗粒大小320目以上,不溶于水﹑醇,溶于酸。粉粒细腻,是晶体的氧化铁化合物,着色力、遮盖力、耐光性、耐酸性、耐碱性均佳,无毒无危害。用所述制备方法,制作所得的氧化铁绿着色粉末应用于颜料中,着色力和遮盖力都很高,耐光、耐大气性好,无水渗性和油渗性。同时这种氧化铁绿着色粉末能广泛适用于各类建筑地坪(大理石地坪、水磨石地坪)的着色,对水泥建筑和外墙涂料有着良好的改善作用,市场前景十分广阔,也可达到客户颜色多样化的需求。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述。
实施例1
本实施例描述的氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄40%,碳酸钙:50%,酞菁蓝:10%。本发明是绿色的粉末。所述的粉末颗粒大小为320目。主要技术参数为水分≤1.0%,水溶物≤2.5%,筛余物≤0.5%,pH值大于6,吸油量25-35。
一种氧化铁绿着色粉末的制备方法,包括以下步骤:(1)将氧化铁黄、碳酸钙、酞菁蓝按照氧化铁黄40%,碳酸钙:50%,酞菁蓝:10%的质量比例加入到高速搅拌机中;(2)将上述材料的混合物在高速搅拌机中匀速搅拌混合1小时以上;(3)将上述材料的混合物在粉碎机中粉碎均匀。
实施例2
与实施例1不同的是,本实施例描述的氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄60%,碳酸钙:35%,酞菁蓝:5%。其他技术参数与具体制备方法均与实施例1相同。
实施例3
与实施例1不同的是,本实施例描述的氧化铁绿着色粉末,以质量百分比计,包含如下组分:氧化铁黄50%,碳酸钙:40%,酞菁蓝:10%。其他技术参数与具体制备方法均与实施例1相同。

Claims (7)

1.一种氧化铁绿着色粉末,其特征在于:以质量百分比计,包含如下组分:氧化铁黄40-60%,碳酸钙:30-60%,酞菁蓝:5-10%。
2.根据权利要求1所述的氧化铁绿着色粉末,其特征在于:以质量百分比计,包含如下组分:氧化铁黄40%,碳酸钙:50%,酞菁蓝:10%。
3.根据权利要求1所述的氧化铁绿着色粉末,其特征在于:以质量百分比计,包含如下组分:氧化铁黄60%,碳酸钙:35%,酞菁蓝:5%。
4.根据权利要求1所述的氧化铁绿着色粉末,其特征在于:以质量百分比计,包含如下组分:氧化铁黄50%,碳酸钙:40%,酞菁蓝:10%。
5.根据权利要求1所述的氧化铁绿着色粉末,其特征在于:上述粉末呈绿色。
6.根据权利要求1所述的氧化铁绿着色粉末,其特征在于:所述的粉末颗粒大小为320目以上。
7.一种如权利要求1所述的氧化铁绿着色粉末的制备方法,其特征在于包括以下步骤:
(1)将氧化铁黄、碳酸钙、酞菁蓝按照如权利要求1所述的质量比例加入到高速搅拌机中;
(2)将上述材料的混合物在高速搅拌机中匀速搅拌混合1小时以上;
(3)将上述材料的混合物在粉碎机中粉碎均匀。
CN201810368527.8A 2018-04-23 2018-04-23 氧化铁绿着色粉末 Pending CN108530949A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643203A (zh) * 2019-10-15 2020-01-03 湖州师范学院 一种易分散型氧化铁绿颜料及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
全国新型建材情报信息网编: "《现代与未来的国内外新型建筑材料》", 30 September 1995, 中国建材工业出版社 *
荆晓莹: "《五光十色的化学世界》", 30 June 2014, 北京工业大学出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643203A (zh) * 2019-10-15 2020-01-03 湖州师范学院 一种易分散型氧化铁绿颜料及其制备方法

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Application publication date: 20180914