CN108530691A - A kind of degradable biological polysaccharide lotion mulch and preparation method thereof - Google Patents

A kind of degradable biological polysaccharide lotion mulch and preparation method thereof Download PDF

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CN108530691A
CN108530691A CN201810515279.5A CN201810515279A CN108530691A CN 108530691 A CN108530691 A CN 108530691A CN 201810515279 A CN201810515279 A CN 201810515279A CN 108530691 A CN108530691 A CN 108530691A
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lotion
mulch
fungicide
mixture
water
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辛文琦
刘保健
刘国华
辛元源
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Shaanxi Golden Earth New Materials Co Ltd
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Shaanxi Golden Earth New Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • A01G13/0275Films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C08L5/08Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/52Mulches
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2248Oxides; Hydroxides of metals of copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of degradable biological polysaccharide chitosan lotion mulches and preparation method thereof, it is made of water, fungicide, biological polyoses, nonionic surface active agent, crosslinking agent and tackifier, prepare the macromolecule polysaccharide lotion that emulsion concentration is 0.5 5%, this lotion is sprayed on to the farmland surface of arid area, and the surface of desert area, existing agricultural mulching can be replaced.The advantages of this lotion mulch, is:Its raw material has used the biological polyoses that can be degraded completely, and the product of degradation is water and carbon dioxide, and totally nontoxic is harmless.It is easy for construction, as long as carrying out simple sprinkling.The problem of entropy can be protected with the water conservation of effective solution arid area.

Description

A kind of degradable biological polysaccharide lotion mulch and preparation method thereof
Technical field
The present invention relates to the preparation formulas and technique of biological polyoses lotion, and in particular to a kind of degradable biological polysaccharide-shell Glycan lotion mulch and preparation method thereof.
Background technology
It is a kind of emerging pollutant treatment technology that mulch, which is retained technology, has a vast market foreground.And biological polyoses are A kind of degradable green material, it has, and small toxicity, safe, water imbibition is strong, performance of keeping humidity is good and can be degradable etc. Feature.But its research at present and application also rarely have research in mulch field and answer mostly in medical treatment, foods and cosmetics field With.
Invention content
The object of the present invention is to provide a kind of degradable biological polysaccharide-chitosan lotion mulch and preparation method thereof, The biological polyoses lotion mulch that the technique obtains, has used the biological polyoses that can be degraded completely, the production of degradation in terms of raw material Object is water and carbon dioxide, and there are no pollution to the environment;In construction party surface construction, as long as simply spray.For solution Certainly the water conservation problem of arid area has great role.
In order to achieve the above object, the technical solution adopted by the present invention includes the following steps:
A kind of degradable biological polysaccharide-chitosan lotion mulch is lived by water, fungicide, biological polyoses, non-ionic surface Property agent, crosslinking agent and tackifier composition, wherein 0.1-2 kilograms of fungicide, 0.5-30 kilogram of raw is added in every 1000 kilograms of water Object polysaccharide, 0.2-1 kilograms of nonionic surfactant and 0.1-0.5 kilograms of crosslinking agent and tackifier.
The fungicide is sodium benzoate, hydrogen peroxide, Cosan, lime sulfur, copper sulphate, mercuric chloride, lime Bordeaux Liquid, Kocide SD, cuprous oxide, organic phosphorus type disinfectant, organo-arsenic series bactericidal agent, substituted beneze-group fungicides, azoles fungicide Or composite bactericide, stirring is to dissolving under the conditions of -10-40 DEG C.
The biological polyoses are chitin, chitosan, starch and chitin, chitosan and the water-insoluble derivative of starch It is one or more in object.
The nonionic surface active agent is polyoxyethylene-type surfactant, EPE polyol EPE and non- It is one or more in ion fluorocarbon surfactant;Polyoxyethylene-type surfactant is:Alkyl phenol polyoxyethylene ether, high-carbon Fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate or fatty acid methyl ester ethoxylate;EPE polyol EPE is Sorbitan ester or sucrose ester.
The crosslinking agent is one or more of ethylene glycol, polyethylene glycol, diamine compounds and glycerine Mixture.
The tackifier are the mixture of one or more of polyacrylamide, xanthans and frictioning.
A kind of preparation method of degradable biological polysaccharide-chitosan lotion mulch, includes the following steps:
Fungicide is added to the water, stirring extremely dissolving under conditions of -10-40 DEG C;Then biological polyoses are added, continue to stir It mixes;Nonionic surfactant is added, be eventually adding crosslinking agent and after tackifier stir evenly, prepares quality of the emulsion concentration For 0.5-5% macromolecule polysaccharide lotion to get to degradable biological polysaccharide-chitosan lotion mulch.
Compared with prior art, the present invention has the following advantages:
The biological polyoses lotion mulch that the present invention obtains, has used the biological polyoses that can be degraded completely in terms of raw material, The product of degradation is water and carbon dioxide, and there are no pollution to the environment;In construction party surface construction, it is as long as carrying out simple sprinkling It can.For solving the problems, such as that the water conservation of arid area has great role.This lotion is sprayed on to the farmland surface of arid area, with And the surface of desert area, existing agricultural mulching can be replaced.
The preparation method of the present invention is simple, and technique is pollution-free, and raw material has used the biological polyoses that can be degraded completely, degradation Product be water and carbon dioxide, totally nontoxic is harmless.It is easy for construction, as long as carrying out simple sprinkling.Can have Entropy is protected in the water conservation for solving the problems, such as arid area of effect.
Specific implementation mode
0.1-2 kilograms of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of -10 DEG C.Its Middle fungicide be sodium benzoate, hydrogen peroxide, Cosan, lime sulfur, copper sulphate, mercuric chloride, lime Bordeaux mixture, Kocide SD, In cuprous oxide, organic phosphates, organo-arsenic series bactericidal agent, substituted beneze-group fungicides, azoles fungicide and composite bactericide One or more mixtures.
0.5-30 kilograms of addition reaction vessel of biological polyoses is weighed, continues to stir.Wherein biological polyoses be biological polysaccharide, One or more mixtures in chitin, chitosan, starch and their water-insoluble derivatives.
0.2-1 kilograms of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is polyoxyethylene-type surfactant:Alkyl phenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid polyethenoxy Ester, fatty acid methyl ester ethoxylate etc. and EPE polyol EPE:Sorbitan ester, sucrose ester, alkylolamides Type, the mixture of one or more of non-ion fluorin carbon surface active agent etc..
Crosslinking agent and the total 0.1-0.5 kilograms of addition reaction vessel of tackifier are weighed, continues to stir.Wherein crosslinking agent is second two The mixture of one or more of the polyalcohols such as alcohol, polyethylene glycol, diamine compounds and glycerine;Tackifier are poly- third The mixture of one or more of acrylamide, xanthans and frictioning etc..
Embodiment 1:
1,0.5 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of -10 DEG C.Its Middle fungicide is sodium benzoate, hydrogen peroxide, the mixture of Cosan.
2,10 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are biological polysaccharide, first The mixture of shell element.
3,0.2 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent alkyl phenol polyoxyethylene ether, the mixture of high-carbon fatty alcohol polyoxyethylene ether.
4, crosslinking agent and tackifier totally 0.5 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is second two Alcohol;Tackifier are polyacrylamide, obtain degradable biological polysaccharide-chitosan lotion mulch.
Embodiment 2:
1,0.1 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 5 DEG C.Wherein Fungicide is copper sulphate, mercuric chloride, lime Bordeaux mixture, mixture.
2,15 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are that biological polysaccharide forms sediment The mixture of powder class and their water-insoluble derivatives.
3,0.2 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is sorbitan ester, the mixture in non-ion fluorin carbon surface active agent.
4, crosslinking agent and tackifier totally 0.3 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is second two The mixture of alcohol, diamine compounds and glycerine;Tackifier are polyacrylamide, and xanthan gum mixtures obtain degradable life Object polysaccharide-chitosan lotion mulch.
Embodiment 3:
1,2 kilograms of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 20 DEG C.Wherein Fungicide is hydrogen peroxide, lime sulfur, mercuric chloride, lime Bordeaux mixture cuprous oxide, the mixture in composite bactericide.
2,12 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are starch and its non- Mixture in soluble derivative.
3,0.5 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is polyoxyethylene-type:Alkyl phenol polyoxyethylene ether, fatty acid methyl ester ethoxylate, the mixture of sucrose ester.
4, crosslinking agent and tackifier totally 0.2 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is poly- second two Alcohol, the mixture of diamine compounds;Tackifier are polyacrylamide, obtain degradable biological polysaccharide-chitosan lotion mulch.
Embodiment 4:
1,2 kilograms of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 40 DEG C.Wherein Fungicide azoles fungicide and compound sterilizing agent composition.
2,20 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are biological polysaccharide, first Shell element, chitosan and their water-insoluble derivatives mixture.
3,0.5 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is high-carbon fatty alcohol polyoxyethylene ether, fatty acid methyl ester ethoxylate sucrose ester, alkylolamides type, non-ionic fluorocarbon table The mixture of face activating agent.
4, crosslinking agent and tackifier totally 0.5 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is poly- second two Alcohol, diamine compounds;Tackifier are polyacrylamide, xanthans, and the mixture of frictioning obtains degradable biological polysaccharide-shell Glycan lotion mulch.
Embodiment 5:
1,1 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 10 DEG C.Wherein Fungicide is sodium benzoate, hydrogen peroxide, Cosan, substituted beneze-group fungicides, the mixing of azoles fungicide and composite bactericide Object.
2,0.5-30 kilograms of addition reaction vessel of biological polyoses is weighed, continues to stir.Wherein biological polyoses are chitin, are formed sediment The mixture of powder class and their water-insoluble derivatives.
3,0.2 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is sorbitan ester, sucrose ester, alkylolamides type, the mixture of non-ion fluorin carbon surface active agent etc..
4, crosslinking agent and tackifier totally 0.2 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is second two The mixture of one or more of the polyalcohols such as alcohol, diamine compounds and glycerine;Tackifier are polyacrylamide, are obtained To degradable biological polysaccharide-chitosan lotion mulch.
Embodiment 6:
1,0.5 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 20 DEG C.Its Middle fungicide is=organic phosphates, organo-arsenic series bactericidal agent, substituted beneze-group fungicides, azoles fungicide and composite bactericide Mixture.
2,30 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are biological polysaccharide, first Shell element, chitosan, the mixture of starch.
3,0.5 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein non-ionic surface active Agent is alkyl phenol polyoxyethylene ether, fatty acid methyl ester ethoxylate etc.;Sucrose ester, alkylolamides type, non-ionic fluorocarbon table The mixture of face activating agent.
4, crosslinking agent and tackifier totally 0.1 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is poly- second two Alcohol, the mixture of diamine compounds;Tackifier are xanthans, and frictioning mixture obtains degradable biological polysaccharide lotion mulch.
Embodiment 7:
1,1.5 kilograms of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 40 DEG C.Its Middle fungicide is sodium benzoate, hydrogen peroxide, Cosan, lime Bordeaux mixture, Kocide SD, organo-arsenic series bactericidal agent, substituted benzene Series bactericidal agent, the mixture of azoles fungicide.
2,30 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses be biological polysaccharide and Mixture in its water-insoluble derivatives.
3,1 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein nonionic surfactant For alkyl phenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate Alkylolamides type, the mixture of non-ion fluorin carbon surface active agent.
4, crosslinking agent and tackifier totally 0.2 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is Diamines The mixture of the polyalcohols such as compound and glycerine;Tackifier are xanthans, and the mixture of frictioning obtains degradable biological polysaccharide Lotion mulch.
Embodiment 8:
1,1 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 30 DEG C.Wherein Fungicide is sodium benzoate, copper sulphate, mercuric chloride, lime Bordeaux mixture, Kocide SD, cuprous oxide, organic phosphates, organo-arsenic class Fungicide, the mixture of composite bactericide.
2,0.5-30 kilograms of addition reaction vessel of biological polyoses is weighed, continues to stir.Wherein biological polyoses are biological polyoses The mixture of class, starch and their water-insoluble derivatives.
3,1 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein nonionic surfactant Sorbitan ester, sucrose ester, alkylolamides type, the mixture of non-ion fluorin carbon surface active agent.
4, crosslinking agent and tackifier totally 0.3 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is poly- second two Alcohol, the mixture of one or more of diamine compounds;Tackifier are xanthan gum mixtures, and it is more to obtain degradable biological Sugar-chitosan lotion mulch.
Embodiment 9:
1,0.5 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 25 DEG C.Its Middle fungicide is copper sulphate, mercuric chloride, lime Bordeaux mixture, Kocide SD, cuprous oxide, organic phosphates, organo-arsenic series bactericidal agent And the mixture of composite bactericide.
2,5 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are biological polysaccharide, first Shell element, chitosan, the mixture of starch.
3,1 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein nonionic surfactant Polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate, sorbitan ester, non-ion fluorin carbon surface active agent, sucrose The mixture of ester.
4, crosslinking agent and tackifier totally 0.5 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is glycerine etc. A variety of mixture in polyalcohol;Tackifier are polyacrylamide, xanthans, and it is more to obtain degradable biological for the mixture of frictioning Sugared lotion mulch.
Embodiment 10:
1,0.1 kilogram of fungicide is weighed, and 1000 kilograms of water are added, high-speed stirred extremely dissolves under conditions of 20 DEG C.Its Middle fungicide is sodium benzoate, mercuric chloride, lime Bordeaux mixture, Kocide SD, cuprous oxide, organic phosphates, the sterilization of organo-arsenic class Agent, the mixture of substituted beneze-group fungicides.
2,15 kilograms of addition reaction vessels of biological polyoses are weighed, continue to stir.Wherein biological polyoses are biological polysaccharide, first Shell is plain, the mixture in starch and their water-insoluble derivatives.
3,1 kilogram of addition reaction vessel of nonionic surfactant is weighed, continues to stir.Wherein nonionic surfactant For high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, the sucrose esters such as fatty acid methyl ester ethoxylate, non-ion fluorin The mixture of carbon surface active agent.
4, crosslinking agent and tackifier totally 0.5 kilogram of addition reaction vessel are weighed, continues to stir.Wherein crosslinking agent is Diamines The mixture of one or more of the polyalcohols such as compound and glycerine;Tackifier are xanthans, and the mixture of frictioning obtains To degradable biological polysaccharide-chitosan lotion mulch.
Emulsion concentration prepared by the present invention is the macromolecule polysaccharide lotion of 0.5-5%, this lotion is sprayed on punja The farmland surface in area and the surface of desert area, can replace existing agricultural mulching.The advantages of this lotion mulch, is: Its raw material has used the biological polyoses that can be degraded completely, and the product of degradation is water and carbon dioxide, and totally nontoxic is harmless.Construction It is convenient, as long as carrying out simple sprinkling.The problem of entropy can be protected with the water conservation of effective solution arid area.
By laboratory preliminary test, the degradation cycle in farmland is about 40-140 days, and the degradation cycle in deserted mountain is about 180 days, moistening effect was substantially suitable with existing mulch.But it has advantage of low cost, easy for construction, degradable.
Protection scope of the present invention is not limited to the above embodiments, for those of ordinary skill in the art, if If the various changes and deformations that carried out to the present invention belong within the scope of the claims in the present invention and equivalent technologies, the meaning of the present invention Including figure also includes these changes and deforms.

Claims (7)

1. a kind of degradable biological polysaccharide sugar lotion mulch, which is characterized in that by water, fungicide, biological polyoses, nonionic table Face activating agent, crosslinking agent and tackifier composition, wherein 0.1-2 kilograms of fungicide, 0.5-30 thousand is added in every 1000 kilograms of water Gram biological polyoses, 0.2-1 kilograms of nonionic surfactant and 0.1-0.5 kilograms of crosslinking agent and tackifier.
2. a kind of degradable biological polysaccharide lotion mulch according to claim 1, which is characterized in that the fungicide is Sodium benzoate, Cosan, lime sulfur, copper sulphate, mercuric chloride, lime Bordeaux mixture, Kocide SD, cuprous oxide, has hydrogen peroxide The Phosphorus fungicide of machine, organo-arsenic series bactericidal agent, substituted beneze-group fungicides, azoles fungicide or composite bactericide.
3. a kind of degradable biological polysaccharide lotion mulch according to claim 1, which is characterized in that the biological polyoses It is one or more in chitin, chitosan, starch and chitin, chitosan and starch water-insoluble derivatives.
4. a kind of degradable biological polysaccharide sugar lotion mulch according to claim 1, which is characterized in that the nonionic Type surfactant is in polyoxyethylene-type surfactant, EPE polyol EPE and non-ion fluorin carbon surface active agent It is one or more;Polyoxyethylene-type surfactant is:Alkyl phenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, fat Fat acid polyoxyethylene ester or fatty acid methyl ester ethoxylate;EPE polyol EPE is sorbitan ester or sucrose Ester.
5. a kind of degradable biological polysaccharide sugar lotion mulch according to claim 1, which is characterized in that the crosslinking agent For the mixture of one or more of ethylene glycol, polyethylene glycol, diamine compounds and glycerine.
6. a kind of degradable biological polysaccharide lotion mulch according to claim 1, which is characterized in that the tackifier are The mixture of one or more of polyacrylamide, xanthans and frictioning.
7. a kind of preparation method of degradable biological polysaccharide lotion mulch as described in claim 1 to 6 any one, feature It is, includes the following steps:
Fungicide is added to the water, stirring extremely dissolving under conditions of -10-40 DEG C;Then biological polyoses are added, continue to stir; Nonionic surfactant is added, be eventually adding crosslinking agent and after tackifier stir evenly, it is a concentration of to prepare quality of the emulsion The macromolecule polysaccharide lotion of 0.5-5% is to get to degradable biological polysaccharide lotion mulch.
CN201810515279.5A 2018-05-25 2018-05-25 A kind of degradable biological polysaccharide lotion mulch and preparation method thereof Pending CN108530691A (en)

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CN110352758A (en) * 2019-07-19 2019-10-22 陕西科技大学 A kind of covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
CN110354906A (en) * 2019-08-27 2019-10-22 合肥学院 A kind of Cu2O/ chitin composite membrane and preparation method thereof
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CN110387246A (en) * 2019-07-19 2019-10-29 陕西科技大学 A kind of polylactic resin covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
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CN110240523A (en) * 2019-07-19 2019-09-17 陕西科技大学 A kind of degradable water polo of N P and K liquid fertilizer and its application method for Arid&semi-arid area tree planting
CN110249875A (en) * 2019-07-19 2019-09-20 陕西科技大学 A kind of environment-friendly type covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
CN110256160A (en) * 2019-07-19 2019-09-20 陕西科技大学 A kind of complexing agent and its application method of agricultural land soil hardening resisting agent and fertilizer
CN110352758A (en) * 2019-07-19 2019-10-22 陕西科技大学 A kind of covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
CN110373098A (en) * 2019-07-19 2019-10-25 陕西科技大学 A kind of green covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
CN110387246A (en) * 2019-07-19 2019-10-29 陕西科技大学 A kind of polylactic resin covering material and its application method for inhibiting moisture evaporation for Arid&semi-arid area
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