CN108504433A - 抗氧化防锈润滑切削液及其制备方法 - Google Patents

抗氧化防锈润滑切削液及其制备方法 Download PDF

Info

Publication number
CN108504433A
CN108504433A CN201810294939.1A CN201810294939A CN108504433A CN 108504433 A CN108504433 A CN 108504433A CN 201810294939 A CN201810294939 A CN 201810294939A CN 108504433 A CN108504433 A CN 108504433A
Authority
CN
China
Prior art keywords
rust
auxiliary agent
cutting fluid
stirred
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810294939.1A
Other languages
English (en)
Inventor
赵文兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810294939.1A priority Critical patent/CN108504433A/zh
Publication of CN108504433A publication Critical patent/CN108504433A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02—Natural products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/064—Thiourea type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2221/041—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明属于金属切削加工技术领域。本发明的技术方案为：抗氧化防锈润滑切削液，由以下质量份的原料组成：乙二醇3～5，妥尔油酸钠盐4～5，聚山梨酯‑80 2～3，二壬基萘磺酸锌2～3，三乙醇胺油酸皂1～2，二硬酯胺2～3，二甲基硅油0.6～1.2，双十四碳醇酯3～4，月桂酸2～3，助剂4～6以及水150～180。本发明的有益效果是，抗氧化效果好，不易变质，贮存时间长，防锈效果好，使工件和刀具不易生锈，延长了使用时间。

Description

抗氧化防锈润滑切削液及其制备方法
技术领域
本发明属于金属切削加工技术领域，特别涉及抗氧化防锈润滑切削液及其制备方法。
背景技术
金属切削加工时，通常采用切削液来冷却和润滑刀具。传统切削液产品存在以下缺陷：一是由于含有亚硝酸盐不利于环境保护和人体健康；二是传统的切削液产品抗氧化效果差、易变质、贮存时间短，防锈效果差，致使工件和刀具易生锈，降低了工件和刀具使用时间。
发明内容
本发明目的在于提供一种抗氧化防锈润滑切削液，该切削液不仅抗氧化效果好、不易变质、贮存时间长、防锈效果好，从而使工件和刀具不易生锈，延长了刀具使用时间，而且无毒无味，对人体无害。
为实现上述目的，本发明采用如下技术方案：
本发明抗氧化防锈润滑切削液，由以下质量份的原料组成：乙二醇3～5，妥尔油酸钠盐4～5，聚山梨酯-80 2～3，二壬基萘磺酸锌2～3，三乙醇胺油酸皂1～2，二硬酯胺2～3，二甲基硅油0.6～1.2，双十四碳醇酯3～4，月桂酸2～3，助剂4～6以及水150～180；助剂由以下质量份的原料组成：分散剂NNO 1～2，聚甘油脂肪酸0.4～0.6，松焦油3～4，2-氨基-2-甲基-1-丙醇1～2，高耐磨炭黑2～4，硅油4～6，植酸2～3，乙酰丙酮2～3，山梨糖醇1～2，硫脲2～3，二异丙醇胺0.4～0.7，消泡剂0.2～0.4以及水40～50。
本发明同时提供一种抗氧化防锈润滑切削液的生产工艺：包括如下步骤：
(1)助剂的制备
步骤一、将分散剂NNO、聚甘油脂肪酸、山梨糖醇加到水中，加热至50～60℃，搅拌均匀后加入消泡剂备用；
步骤二、将松焦油、硅油、植酸、高耐磨炭黑、乙酰丙酮混合加热至40～50℃，搅拌均匀后将步骤一中的产物缓慢加入，以300～400r/min的转速搅拌，加料结束后加热至70～80℃，并在1800～2000r/min下高速搅拌10～15min，再加入2-氨基-2-甲基-1-丙醇，硫脲以及二异丙醇胺，继续搅拌5～10min即可；
(2)抗氧化防锈润滑切削液的制备
步骤三、将妥尔油酸钠盐、三乙醇胺油酸皂、聚山梨酯-80和双十四碳醇酯混合，加热至30～50℃，搅拌反应20～40min后得到混合物A；
步骤四、将水煮沸后迅速冷却至70～80℃，再加入二硬酯胺和月桂酸搅拌均匀，然后加入助剂在800～900r/min下搅拌反应40～60min，得到混合物B；
步骤五、将步骤四中的混合物B边搅拌边缓慢加入至步骤三种的混合物A中，将温度控制在40～55℃，搅拌均匀后加入乙二醇，二壬基萘磺酸锌，二甲基硅油以及助剂，在1400～1600r/min下高速搅拌20～30min后过滤即可。
本发明的有益效果是：本品抗氧化效果好，不易变质，贮存时间长，防锈效果好，使工件和刀具不易生锈，延长了使用时间，此外，还具有优良的润滑性能，减少工件之间的摩擦，保护刀具。
具体实施方式
实施例1，本发明抗氧化防锈润滑切削液，由以下质量份的原料组成：乙二醇3～5，妥尔油酸钠盐4～5，聚山梨酯-80 2～3，二壬基萘磺酸锌2～3，三乙醇胺油酸皂1～2，二硬酯胺2～3，二甲基硅油0.6～1.2，双十四碳醇酯3～4，月桂酸2～3，助剂4～6以及水150～180；助剂由以下质量份的原料组成：分散剂NNO 1～2，聚甘油脂肪酸0.4～0.6，松焦油3～4，2-氨基-2-甲基-1-丙醇1～2，高耐磨炭黑2～4，硅油4～6，植酸2～3，乙酰丙酮2～3，山梨糖醇1～2，硫脲2～3，二异丙醇胺0.4～0.7，消泡剂0.2～0.4以及水40～50。
本发明同时提供一种抗氧化防锈润滑切削液的生产工艺：包括如下步骤：
(1)助剂的制备
步骤一、将分散剂NNO、聚甘油脂肪酸、山梨糖醇加到水中，加热至50～60℃，搅拌均匀后加入消泡剂备用；
步骤二、将松焦油、硅油、植酸、高耐磨炭黑、乙酰丙酮混合加热至40～50℃，搅拌均匀后将步骤一中的产物缓慢加入，以300～400r/min的转速搅拌，加料结束后加热至70～80℃，并在1800～2000r/min下高速搅拌10～15min，再加入2-氨基-2-甲基-1-丙醇，硫脲以及二异丙醇胺，继续搅拌5～10min即可；
(2)抗氧化防锈润滑切削液的制备
步骤三、将妥尔油酸钠盐、三乙醇胺油酸皂、聚山梨酯-80和双十四碳醇酯混合，加热至30～50℃，搅拌反应20～40min后得到混合物A；
步骤四、将水煮沸后迅速冷却至70～80℃，再加入二硬酯胺和月桂酸搅拌均匀，然后加入助剂在800～900r/min下搅拌反应40～60min，得到混合物B；
步骤五、将步骤四中的混合物B边搅拌边缓慢加入至步骤三种的混合物A中，将温度控制在40～55℃，搅拌均匀后加入乙二醇，二壬基萘磺酸锌，二甲基硅油以及助剂，在1400～1600r/min下高速搅拌20～30min后过滤即可。
以上所述的实施例仅仅是对本发明的优选实施方式进行描述，并非对本发明的范围进行限定，在不脱离本发明设计精神的前提下，本领域普通技术人员对本发明的技术方案作出的各种变形和改进，均应落入本发明权利要求书确定的保护范围内。

Claims (2)

1.一种抗氧化防锈润滑切削液，其特征是：由以下质量份的原料组成：乙二醇3～5，妥尔油酸钠盐4～5，聚山梨酯-80 2～3，二壬基萘磺酸锌2～3，三乙醇胺油酸皂1～2，二硬酯胺2～3，二甲基硅油0.6～1.2，双十四碳醇酯3～4，月桂酸2～3，助剂4～6以及水150～180；助剂由以下质量份的原料组成：分散剂NNO 1～2，聚甘油脂肪酸0.4～0.6，松焦油3～4，2-氨基-2-甲基-1-丙醇1～2，高耐磨炭黑2～4，硅油4～6，植酸2～3，乙酰丙酮2～3，山梨糖醇1～2，硫脲2～3，二异丙醇胺0.4～0.7，消泡剂0.2～0.4以及水40～50。
2.一种制备如权利要求1所述抗氧化防锈润滑切削液的方法，其特征是，包括如下步骤：
(1)助剂的制备
步骤一、将分散剂NNO、聚甘油脂肪酸、山梨糖醇加到水中，加热至50～60℃，搅拌均匀后加入消泡剂备用；
步骤二、将松焦油、硅油、植酸、高耐磨炭黑、乙酰丙酮混合加热至40～50℃，搅拌均匀后将步骤一中的产物缓慢加入，以300～400r/min的转速搅拌，加料结束后加热至70～80℃，并在1800～2000r/min下高速搅拌10～15min，再加入2-氨基-2-甲基-1-丙醇，硫脲以及二异丙醇胺，继续搅拌5～10min即可；
(2)抗氧化防锈润滑切削液的制备
步骤三、将妥尔油酸钠盐、三乙醇胺油酸皂、聚山梨酯-80和双十四碳醇酯混合，加热至30～50℃，搅拌反应20～40min后得到混合物A；
步骤四、将水煮沸后迅速冷却至70～80℃，再加入二硬酯胺和月桂酸搅拌均匀，然后加入助剂在800～900r/min下搅拌反应40～60min，得到混合物B；
步骤五、将步骤四中的混合物B边搅拌边缓慢加入至步骤三种的混合物A中，将温度控制在40～55℃，搅拌均匀后加入乙二醇，二壬基萘磺酸锌，二甲基硅油以及助剂，在1400～1600r/min下高速搅拌20～30min后过滤即可。
CN201810294939.1A 2018-03-30 2018-03-30 抗氧化防锈润滑切削液及其制备方法 Withdrawn CN108504433A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810294939.1A CN108504433A (zh) 2018-03-30 2018-03-30 抗氧化防锈润滑切削液及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810294939.1A CN108504433A (zh) 2018-03-30 2018-03-30 抗氧化防锈润滑切削液及其制备方法

Publications (1)

Publication Number Publication Date
CN108504433A true CN108504433A (zh) 2018-09-07

Family

ID=63380153

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810294939.1A Withdrawn CN108504433A (zh) 2018-03-30 2018-03-30 抗氧化防锈润滑切削液及其制备方法

Country Status (1)

Country Link
CN (1) CN108504433A (zh)

Similar Documents

Publication Publication Date Title
CN107629765B (zh) 发动机无水冷却液及其制备方法
CN104726071B (zh) 一种复合低温蓄冷剂及其制备方法和应用
CN103992853A (zh) 一种不锈钢拉丝用拉丝油
CN103966005B (zh) 一种铜线快速拉拔用拉丝液
CN107057379A (zh) 一种实心轮胎用橡胶软化剂及制备方法
CN105062642B (zh) 防锈微量润滑油及其制备方法
CN108504433A (zh) 抗氧化防锈润滑切削液及其制备方法
CN106244113A (zh) 一种环保热泵工质及其制备方法
CN108641796A (zh) 金属加工用全合成切削液及其制备方法
CN111925778A (zh) 钻井液用防塌降滤失剂白沥青
CN104004572B (zh) 一种含二氧化钛的铜拉丝油
CN108060003A (zh) 一种自乳化型植物油/脂肪酸铝/三乙醇胺复合体系高效脱模剂
CN108341952A (zh) 一种有机硅耐低温润滑油及其制备方法
CN106085380A (zh) 一种高寿命耐用冷却液
CN103351931B (zh) 一种防锈水基切削液及其制备方法
CN104357847A (zh) 一种用于船舶发动机除硫缓蚀剂及其制备方法
CN106190057A (zh) 一种绿色环保型冷却液
CN111647390A (zh) 一种控温冷却母液、其制备方法及其应用
CN106811181A (zh) 一种汽车发动机防冻液
CN108531230A (zh) 一种汽车尾气清洁剂
CN108485781A (zh) 抗磨效果优异的水性切削液及其制备方法
CN110317666A (zh) 一种长效缓蚀切削用冷却液制备方法
CN103966008A (zh) 一种废液易处理的水基拉丝液
CN108641797A (zh) 金属加工水性切削液及其制备方法
CN101914410B (zh) 一种金属切削液及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180907