CN108486899A - A kind of fabric softener and preparation method thereof - Google Patents
A kind of fabric softener and preparation method thereof Download PDFInfo
- Publication number
- CN108486899A CN108486899A CN201810363311.2A CN201810363311A CN108486899A CN 108486899 A CN108486899 A CN 108486899A CN 201810363311 A CN201810363311 A CN 201810363311A CN 108486899 A CN108486899 A CN 108486899A
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- China
- Prior art keywords
- fabric softener
- preparation
- fabric
- organic solvent
- silicon oil
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/65—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of fabric softeners and preparation method thereof, include the following steps：3 [3 (2 H benzotriazole, 2 base) 4 hydroxyl, 5 tert-butyl-phenyl] propionic acid Liquid Macrogol esters are dissolved in organic solvent and form solution, epoxy silicon oil and catalyst is added thereto afterwards, it is stirred to react 8 10 hours at 70 80 DEG C of nitrogen or atmosphere of inert gases, revolving removes organic solvent afterwards, obtains fabric softener.Fabric softener disclosed by the invention has good hydrophilic property, combined in the form of valence bond when being acted on fabric it is more secured, it is more washable, soft effect more preferably, non yellowing, slipping, the good feature of antistatic property.
Description
Technical field
The present invention relates to technical field of textile printing more particularly to a kind of fabric softener and preparation method thereof.
Background technology
With Chinese society rapid development of economy and the improvement of people's living standards, there is new want to wearing dress ornament
Ask, no longer only simply required fabric have moisture absorption, breathe freely, wear it is comfortable, also require its have it is soft, smooth, float
The style of ease.Soft finishing agent is exactly to come into being under these circumstances.Softening agent is a kind of to change the quiet, dynamic of fiber and rub
Wipe the chemical substance of coefficient.When changing confficient of static friction, feel touch has smooth sense, is easy to move on fiber or fabric；
When changing the coefficient of kinetic friction, the fine structure between fiber and fiber is easy to be mutually shifted, that is, fiber or fabric it is easy
In deformation.The comprehensive of the two feels to be exactly soft, the fine or not softness that directly decide fabric of performance and comfortable and easy to wear
Sense.
Currently, most common soft finishing agent be amino-silicone oil softening agent, due to amino can be with fabric surface hydroxyl, carboxylic
The interactions such as base enable siloxanes to be directionally attached to the surface of fabric, can generate excellent feel, make between fabric fibre
Frictional decrease, to reach good soft-touch finish.But there is also some problems, ammonia in use
Base silicone oil does not often have self-dispersed characteristic, after being configured to amino silicon oil emulsion, is susceptible to during storage and use
Floating oil or roll banding phenomenon.Meanwhile through common amino silicon oil emulsion treated fabric, hydrophily declines, and then influence is handled
The comfort of textile fabric dress afterwards.In addition, fabric will appear xanthochromia after high temperature or ultraviolet light.
Therefore, it is the big hot subject studied in the industry at present to develop the new fabric softener haveing excellent performance.
Invention content
In order to overcome the defects of the prior art, a kind of fabric softener of present invention offer and preparation method thereof, should
Preparation method is simple, and raw material is easy to get, cheap, not high to reaction condition and equipment requirement, is suitble to industrialized production；It is logical
Cross the fabric softener that the preparation method is prepared overcome it is expensive existing for common amido silicon oil in the prior art,
Finish fabric will present hydrophobicity, fabric will appear xanthochromia, lotion after high temperature or ultraviolet light and floating oil or roll banding easily occurs
The defect of phenomenon has good hydrophilic property, is combined more secured, more washable, softness when being acted on fabric in the form of valence bond
It is better, non yellowing, slipping, the good feature of antistatic property.
To achieve the above object of the invention, the technical solution adopted by the present invention is a kind of preparation side of fabric softener
Method includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-polyethylene glycol
300 esters, which are dissolved in organic solvent, forms solution, after epoxy silicon oil and catalyst are added thereto, in nitrogen or atmosphere of inert gases
It is stirred to react at 70-80 DEG C 8-10 hours, rear revolving removes organic solvent, obtains fabric softener.
Preferably, the poly- second of 3- [3- (2-H- benzotriazole -2- bases) -4- hydroxyl -5- the tert-butyl-phenyls]-propionic acid-two
300 ester of alcohol, organic solvent, epoxy silicon oil, catalyst mass ratio be 1:(8-12):(3-4):(0.2-0.5).
Preferably, the catalyst is in benzyl dimethylamine, benzyltriethylammoinium chloride, potassium carbonate, potassium hydroxide
It is one or more of.
Preferably, the organic solvent be selected from methyl iso-butyl ketone (MIBK), dimethylbenzene, dimethyl sulfoxide, n,N-Dimethylformamide,
One or more of N-Methyl pyrrolidone.
Preferably, the epoxy silicon oil is selected from one or more of end epoxy silicon oil, side group epoxy silicone oil.
Preferably, the inert gas is selected from one or more of helium, neon, argon gas.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
It is using advantageous effect caused by above-mentioned technical proposal：
1) fabric softener provided by the invention, preparation method is simple, and raw material is easy to get, cheap, to anti-
It answers condition and equipment requirement not high, is suitble to industrialized production.
2) it is high to overcome price existing for common amido silicon oil in the prior art for fabric softener provided by the invention
Expensive, finish fabric will present hydrophobicity, fabric will appear xanthochromia, lotion after high temperature or ultraviolet light and floating oil or viscous easily occurs
The defect of roller phenomenon, has good hydrophilic property, combined in the form of valence bond when being acted on fabric it is more secured, it is more washable, it is soft
It is soft better, non yellowing, slipping, the good feature of antistatic property.
3) fabric softener provided by the invention the advantages of with amido silicon oil, epoxy silicon oil, polyethers, has
Self-emulsifying ability avoids floating oil or roll banding phenomenon, good with its processed textile fabric flexibility and flatness.
Specific implementation mode
In order to make those skilled in the art more fully understand technical scheme of the present invention, and make the present invention features described above,
Purpose and advantage are more clear understandable, and with reference to embodiment, the present invention is described further.Embodiment is only used for
It is bright the present invention rather than limit the scope of the invention.
Epoxy silicon oil used in the following embodiments of the present invention is purchased from Anhui Ai Yueta silicone oil Co., Ltd, other raw materials
Come from Haiquan sunrise foreign trade Co., Ltd, wherein 3- [3- (2-H- benzotriazole -2- bases) -4- hydroxyl -5- tertiary butyls
Phenyl]-propionic acid-Liquid Macrogol ester is commercially available known substance.
Embodiment 1
A kind of preparation method of fabric softener, includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -
4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester 10g is dissolved in methyl iso-butyl ketone (MIBK) 80g and forms solution, backward
End epoxy silicon oil 30g and benzyl dimethylamine 2g is wherein added, is stirred to react 8 hours at 70 DEG C of nitrogen atmosphere, rear revolving removes
Organic solvent obtains fabric softener.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
Embodiment 2
A kind of preparation method of fabric softener, includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -
4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester 10g is dissolved in dimethylbenzene 90g and forms solution, after thereto plus
Enter side group epoxy silicone oil 33g and benzyltriethylammoinium chloride 3g, is stirred to react 8.5 hours at 73 DEG C of helium atmosphere, it is rear to rotate
Organic solvent is removed, fabric softener is obtained.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
Embodiment 3
A kind of preparation method of fabric softener, includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -
4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester 10g is dissolved in n,N-Dimethylformamide 100g and forms solution,
End epoxy silicon oil 35g and potassium carbonate 3.5g is added thereto afterwards, is stirred to react 9 hours at 75 DEG C of neon atmosphere, rear revolving is removed
Organic solvent is removed, fabric softener is obtained.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
Embodiment 4
A kind of preparation method of fabric softener, includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -
4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester 10g is dissolved in organic solvent 110g and forms solution, after thereto
Epoxy silicon oil 37g and catalyst 4.5g is added, is stirred to react 8-10 hour at 70-80 DEG C of argon atmosphere, rear revolving removing has
Solvent obtains fabric softener；The catalyst is benzyl dimethylamine, benzyltriethylammoinium chloride, potassium carbonate by matter
Measure ratio 2:3:4 mixtures mixed；The organic solvent be methyl iso-butyl ketone (MIBK), dimethylbenzene, dimethyl sulfoxide in mass ratio
1:2:3 mixtures mixed；The epoxy silicon oil is end epoxy silicon oil, side group epoxy silicone oil in mass ratio 3:4 mixing and
At mixture.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
Embodiment 5
A kind of preparation method of fabric softener, includes the following steps：By 3- [3- (2-H- benzotriazole -2- bases) -
4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester 10g is dissolved in N-Methyl pyrrolidone 120g and forms solution, after
Side group epoxy silicone oil 40g and potassium hydroxide 5g is added thereto, is stirred to react 10 hours at 80 DEG C of nitrogen atmosphere, rear revolving is removed
Organic solvent is removed, fabric softener is obtained.
A kind of fabric softener is prepared using the preparation method of the fabric softener.
Comparative example 1
This example provides a kind of fabric softener, and formula and preparation method refer to Chinese invention patent CN10180599
6B embodiments 1.
Comparative example 2
Commercially available common amido silicon oil.
Fabric softener obtained by above-described embodiment 1-5 and comparative example 1-2 is tested, test method：It will be with
Upper hydrophilic silicon oil is configured to 20% aqueous solution, and it is that pure white is knitted cotton, dosage 10gL to compare cloth specimen, and a leaching one is pricked,
It is dried at 100 DEG C；Evaluation method：Feel is mainly investigated in terms of flexibility and flatness, is touched by several experts are blind, 5 grades are
Preferably, 1 grade is worst.The hydrophily of fabric is by being that one drop water of unit measurement is determined by the time that fabric absorbs completely with the second (s)
Justice, test result are shown in Table 1.
Table 1
As can be seen from the above table, fabric softener hydrophily disclosed by the invention is more preferable, and feel is more preferably.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention
Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and
Improvement is both fallen in the range of claimed invention.The present invention claims protection domain by appended claims and its
Equivalent defines.
Claims (7)
1. a kind of preparation method of fabric softener, which is characterized in that include the following steps：By 3- [3- (2-H- benzos three
Azoles -2- bases) -4- hydroxyl -5- tert-butyl-phenyls]-propionic acid-Liquid Macrogol ester is dissolved in organic solvent and forms solution, it is backward its
Middle addition epoxy silicon oil and catalyst are stirred to react 8-10 hours at 70-80 DEG C of nitrogen or atmosphere of inert gases, and rear revolving is removed
Organic solvent is removed, fabric softener is obtained.
2. a kind of preparation method of fabric softener according to claim 1, which is characterized in that the 3- [3- (2-
H- benzotriazole -2- bases) -4- hydroxyl -5- tert-butyl-phenyls] it-propionic acid-Liquid Macrogol ester, organic solvent, epoxy silicon oil, urges
The mass ratio of agent is 1:(8-12):(3-4):(0.2-0.5).
3. a kind of preparation method of fabric softener according to claim 1, which is characterized in that the catalyst choosing
From one or more of benzyl dimethylamine, benzyltriethylammoinium chloride, potassium carbonate, potassium hydroxide.
4. a kind of preparation method of fabric softener according to claim 1, which is characterized in that the organic solvent
One kind or several in methyl iso-butyl ketone (MIBK), dimethylbenzene, dimethyl sulfoxide, N,N-dimethylformamide, N-Methyl pyrrolidone
Kind.
5. a kind of preparation method of fabric softener according to claim 1, which is characterized in that the epoxy silicon oil
Selected from one or more of end epoxy silicon oil, side group epoxy silicone oil.
6. a kind of preparation method of fabric softener according to claim 1, which is characterized in that the inert gas
Selected from one or more of helium, neon, argon gas.
7. the fabric that a kind of preparation method using claim 1-6 any one of them fabric softeners is prepared is soft
Soft finishing agent.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010490232.5A CN111648136A (en) | 2018-04-21 | 2018-04-21 | Fabric soft hydrophilic finishing agent |
| CN201810363311.2A CN108486899B (en) | 2018-04-21 | 2018-04-21 | Fabric softening finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810363311.2A CN108486899B (en) | 2018-04-21 | 2018-04-21 | Fabric softening finishing agent and preparation method thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010490232.5A Division CN111648136A (en) | 2018-04-21 | 2018-04-21 | Fabric soft hydrophilic finishing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108486899A true CN108486899A (en) | 2018-09-04 |
| CN108486899B CN108486899B (en) | 2020-08-07 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010490232.5A Withdrawn CN111648136A (en) | 2018-04-21 | 2018-04-21 | Fabric soft hydrophilic finishing agent |
| CN201810363311.2A Active CN108486899B (en) | 2018-04-21 | 2018-04-21 | Fabric softening finishing agent and preparation method thereof |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010490232.5A Withdrawn CN111648136A (en) | 2018-04-21 | 2018-04-21 | Fabric soft hydrophilic finishing agent |
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| Country | Link |
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| CN (2) | CN111648136A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109837759A (en) * | 2019-02-25 | 2019-06-04 | 朱建余 | A kind of denim fabric antibacterial flame-retardant finishing agent and preparation method thereof |
| CN110924174A (en) * | 2019-12-09 | 2020-03-27 | 张礼国 | Fabric softener and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116479653B (en) * | 2023-04-10 | 2023-12-29 | 浙江加佳领带服装有限公司 | Softening treatment process for clothing fabric |
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| CN1259973A (en) * | 1997-06-10 | 2000-07-12 | 拜尔公司 | UV-stabilizers for siloxane systems |
| CN1280151A (en) * | 1999-07-07 | 2001-01-17 | 大日精化工业株式会社 | Polymer-link functional agent |
| JP2001214121A (en) * | 2000-02-04 | 2001-08-07 | Shin Etsu Chem Co Ltd | Coating composition, coating method, and coated article |
| CN101081900A (en) * | 2005-06-01 | 2007-12-05 | 信越化学工业株式会社 | Ultraviolet-absorbing group-containing organopolysiloxane, method for producing the same, and treatment agent compounded with the same |
| CN102031692A (en) * | 2010-11-16 | 2011-04-27 | 南通大学 | Multifunctional organic silicon finishing agent and preparation method thereof |
| CN106883417A (en) * | 2017-03-28 | 2017-06-23 | 传化智联股份有限公司 | A kind of preparation method of organosilicon ternary block polymer |
| CN107287904A (en) * | 2017-06-26 | 2017-10-24 | 苏州威尔德工贸有限公司 | A kind of yellowing-proof finish method of real silk fabric |
| CN107345369A (en) * | 2017-06-26 | 2017-11-14 | 苏州威尔德工贸有限公司 | A kind of silk fabric uvioresistant coloring agent |
-
2018
- 2018-04-21 CN CN202010490232.5A patent/CN111648136A/en not_active Withdrawn
- 2018-04-21 CN CN201810363311.2A patent/CN108486899B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1259973A (en) * | 1997-06-10 | 2000-07-12 | 拜尔公司 | UV-stabilizers for siloxane systems |
| CN1280151A (en) * | 1999-07-07 | 2001-01-17 | 大日精化工业株式会社 | Polymer-link functional agent |
| JP2001214121A (en) * | 2000-02-04 | 2001-08-07 | Shin Etsu Chem Co Ltd | Coating composition, coating method, and coated article |
| CN101081900A (en) * | 2005-06-01 | 2007-12-05 | 信越化学工业株式会社 | Ultraviolet-absorbing group-containing organopolysiloxane, method for producing the same, and treatment agent compounded with the same |
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| CN106883417A (en) * | 2017-03-28 | 2017-06-23 | 传化智联股份有限公司 | A kind of preparation method of organosilicon ternary block polymer |
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| CN107345369A (en) * | 2017-06-26 | 2017-11-14 | 苏州威尔德工贸有限公司 | A kind of silk fabric uvioresistant coloring agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109837759A (en) * | 2019-02-25 | 2019-06-04 | 朱建余 | A kind of denim fabric antibacterial flame-retardant finishing agent and preparation method thereof |
| CN109837759B (en) * | 2019-02-25 | 2021-12-03 | 朱建余 | Antibacterial flame-retardant finishing agent for denim fabric and preparation method thereof |
| CN110924174A (en) * | 2019-12-09 | 2020-03-27 | 张礼国 | Fabric softener and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111648136A (en) | 2020-09-11 |
| CN108486899B (en) | 2020-08-07 |
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Effective date of registration: 20200618 Address after: 201508 Building 8, no.3889, Jinkang East Road, Shanyang Town, Jinshan District, Shanghai Applicant after: Shanghai Xinmiao Textile Auxiliaries Co., Ltd Address before: 410217 Changsha, Changsha City, Hunan Wangcheng economic and Technological Development Zone gold Pioneer Park 4 Building C5 Applicant before: HUNAN CHENLI NEW MATERIAL Co.,Ltd. |
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