CN102031692A - Multifunctional organic silicon finishing agent and preparation method thereof - Google Patents
Multifunctional organic silicon finishing agent and preparation method thereof Download PDFInfo
- Publication number
- CN102031692A CN102031692A CN 201010547101 CN201010547101A CN102031692A CN 102031692 A CN102031692 A CN 102031692A CN 201010547101 CN201010547101 CN 201010547101 CN 201010547101 A CN201010547101 A CN 201010547101A CN 102031692 A CN102031692 A CN 102031692A
- Authority
- CN
- China
- Prior art keywords
- finishing agent
- organic silicon
- preparation
- deionized water
- tetramethyl piperidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a multifunctional organic silicon finishing agent and a preparation method thereof. The multifunctional organic silicon finishing agent comprises the following components in percentage by mass: anti-ultraviolet polyether organic silicon oil, isobutyl alcohol, composite emulsifier of phosphate betaine type gemini surfactant and fatty alcohol-polyoxyethylene ether in a ratio of 1:1, pH buffering agent and deionized water. The preparation method for the multifunctional organic silicon finishing agent comprises the following steps of: modifying organic silicon by adopting a special heterocyclic hindered ammonia compound, substituting the conventional amino, introducing a polyether functional unit on the main chain of the organic silicon, introducing the hindered ammonia compound on the branched chain, and synthesizing multifunctional organic silicon oil. The finishing agent keeps the original advantages of the amino silicon oil, and is particularly suitable for soft finishing and anti-ultraviolet finishing of bleached fabrics and light color fabrics; and the finishing agent can be prepared into silicon oil micro-emulsion of various proper concentrations by full emulsifying and has strong usability.
Description
Technical field
The present invention relates to a kind of multifuncitonal organosilicon finishing agent and preparation method thereof.
Background technology
Organic silicon emulsion is a kind of important finishing agent in the fabric treatment procedure, and it can significantly improve the feel of fabric, makes it have feels such as smooth, softness.The fabric sofetening smoothing processing agent that more on the market in recent years is based on amido silicon oil.At present, also fewer for the exploitation of comprehensive functions such as organic silicone finishing agent uvioresistant, anti-xanthochromia, flexible smooth.
Summary of the invention
Goal of the invention: the present invention provides a kind of multifuncitonal organosilicon finishing agent with uvioresistant and anti-yellowing function in order to solve the deficiencies in the prior art.
Another object of the present invention is for the preparation method of above-mentioned multifuncitonal organosilicon finishing agent is provided.
The technical solution used in the present invention: a kind of multifuncitonal organosilicon finishing agent, it comprises following component by mass percent: uvioresistant polyethers organic silicone oil 8-20%, isobutanol 8-12%, phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent 8-10%, pH value buffer 2-5%, surpluses are deionized water.
The preparation method of above-mentioned multifuncitonal organosilicon finishing agent may further comprise the steps:
1, in containing the water-soluble organic silicon of epoxy radicals, adds material N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compound with light stabilization, temperature is to 70-90 ℃ of reaction 4-5h, be warming up to 120-130 ℃, reaction 6-8h, blowing get colourless to little yellow transparent finished product uvioresistant polyethers modified silicon oil;
The reaction equation of the water-soluble organic silicon of N-butyl-tetramethyl piperidine amine and epoxy radicals is:
The reaction equation of the water-soluble organic silicon of tetramethyl piperidine alcohol compound and epoxy radicals is:
2, in homogenizer, add deionized water and phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent, solvent and buffers, under high-speed stirred, the above-mentioned uvioresistant polyethers of very long adding modified silicon oil, with the vinegar acid for adjusting pH value to 6-7, replenish deionized water, being adjusted to silicone oil content is 8-15%, can obtain described multifuncitonal organosilicon finishing agent.
The mass ratio of the butyl of the water-soluble organic silicon of epoxy radicals and N-described in the above-mentioned steps 1-tetramethyl piperidine amine or tetramethyl piperidine alcohol compound is 1-3: 1.
Beneficial effect: the present invention adopts the ammoniac compounds that is obstructed of special heterocyclic that organosilicon has been carried out modification, replace conventional amino, on the organosilicon main chain, introduced the polyethers functional unit, on side chain, introduced the ammoniac compounds that is obstructed, synthesized the multifuncitonal organosilicon finishing agent, has fine and smooth flexible smooth effect, antistatic, hydrophily, the self-emulsifying function, be applicable to the hand feel finishing of each off-white color and light fabric, the fabric of wherethrough reason has good whiteness, good uvioresistant performance and outstanding yellowing resistance energy, fabric is once put in order through this project product, can possess multiple function, water saving, energy-conservation, reduce cost.
The specific embodiment
The invention will be further described below in conjunction with specific embodiment:
Embodiment 1
A kind of multifuncitonal organosilicon finishing agent, it comprises following component by mass percent: uvioresistant polyethers organic silicone oil 20%, isobutanol 8%, phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent 8%, pH value buffer 5%, deionized water 59%.
The preparation method of above-mentioned multifuncitonal organosilicon finishing agent may further comprise the steps:
1, gets 100 parts of water-soluble organic silicons that contain epoxy radicals, add 100 parts of material-N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compounds with light stabilization, after temperature to 70 ℃ is with reaction 4h, be warming up to 120 ℃, reaction 6h, blowing get colourless extremely little yellow transparent finished product and are uvioresistant polyethers modified silicon oil;
2, deionized water and phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent, solvent and buffers of in homogenizer, adding metering, under high-speed stirred, the ultraviolet polyether modified silicon oil of the above-mentioned metering of very long adding, with the vinegar acid for adjusting pH value to 6-7, it is 8% that additional deionized water is adjusted to silicone oil content, can obtain described multifuncitonal organosilicon finishing agent.
Embodiment 2
A kind of multifuncitonal organosilicon finishing agent, it comprises following component by mass percent: uvioresistant polyethers organic silicone oil 14%, isobutanol 10%, phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent 9%, pH value buffer 3.5%, deionized water 63.5%.
The preparation method of above-mentioned multifuncitonal organosilicon finishing agent may further comprise the steps:
1, gets 100 parts of water-soluble organic silicons that contain epoxy radicals, add 200 parts of material N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compounds with light stabilization, behind temperature to 80 ℃ reaction 4.5h, be warming up to 125 ℃, reaction 7h, blowing get colourless extremely little yellow transparent finished product and are uvioresistant polyethers modified silicon oil;
2, deionized water and phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent, solvent and buffers of in homogenizer, adding metering, under high-speed stirred, the ultraviolet polyether modified silicon oil of the above-mentioned metering of very long adding, with the vinegar acid for adjusting pH value to 6-7, it is 11% that additional deionized water is adjusted to silicone oil content, can obtain described multifuncitonal organosilicon finishing agent.
Embodiment 3
A kind of multifuncitonal organosilicon finishing agent, it comprises following component by mass percent: uvioresistant polyethers organic silicone oil 8%, isobutanol 12%, phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent 10%, pH value buffer 2%, deionized water 68%.
The preparation method of above-mentioned multifuncitonal organosilicon finishing agent may further comprise the steps:
1, gets 100 parts of water-soluble organic silicons that contain epoxy radicals, add 300 parts of material-N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compounds with light stabilization, after temperature to 90 ℃ is with reaction 5h, be warming up to 130 ℃, reaction 8h, blowing get colourless extremely little yellow transparent finished product and are uvioresistant polyethers modified silicon oil;
2, deionized water and phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether (10) 1: 1 compound emulsifying agent, solvent and buffers of in homogenizer, adding metering, under high-speed stirred, the ultraviolet polyether modified silicon oil that slowly adds above-mentioned metering, with the vinegar acid for adjusting pH value to 6-7, it is 15% that additional deionized water is adjusted to silicone oil content, can obtain described multifuncitonal organosilicon finishing agent.
Technical target of the product
Hydrophily low-yellowing amino-modified silicone oil technical indicator
| Index name | Index |
| Outward appearance | The transparent or semitransparent emulsion of micro white |
| 1% aqueous ph value | 4.5-5.5 |
| Non-volatile component, % | 29-30 |
| The ion attribute | Weak cation/nonionic |
Application: cotton brightened goods, cotton DYED FABRICS.
Ultraviolet polyether modified silicon oil 30g/L
Technique for applying: two soak two roll (pick-up rate 100%) → oven dry (80 ℃ * 3-5min) → bake (160-180 ℃ * 60-90S) → washing → oven dry
Product application quality index
Uvioresistant polyethers modified organic silicon application quality index
| Index name | Index |
| Hydrophily, S≤ | 1 |
| Yellowing resistance energy Δ Y≤ | 0.5 |
| Changes of shade 〉= | 4 grades |
| The light fastness level | Improve 0.5-1 |
| Rate of ultraviolet shield 〉= | 90 |
| Protecting factor UPF 〉= | 50 |
Claims (3)
1. multifuncitonal organosilicon finishing agent, it is characterized in that: it comprises following component by mass percent: uvioresistant polyethers organic silicone oil 8-20%, isobutanol 8-12%, phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether 1: 1 compound emulsifying agent 8-10%, pH value buffer 2-5%, surplus are deionized water.
2. the preparation method of multifuncitonal organosilicon finishing agent according to claim 1 is characterized in that: may further comprise the steps:
(1) in containing the water-soluble organic silicon of epoxy radicals, adds material N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compound with light stabilization, temperature is to 70-90 ℃ of reaction 4-5h, be warming up to 120-130 ℃, reaction 6-8h, blowing get colourless to little yellow transparent finished product uvioresistant polyethers modified silicon oil;
(2) in homogenizer, add deionized water and phosphate betaine type gemini surface-activity and fatty alcohol-polyoxyethylene ether 1: 1 compound emulsifying agent, solvent and buffer, under high-speed stirred, the above-mentioned uvioresistant polyethers of very long adding modified silicon oil, with the vinegar acid for adjusting pH value to 6-7, replenish deionized water, being adjusted to silicone oil content is 8-15%, can obtain described multifuncitonal organosilicon finishing agent.
3. according to the preparation method of the described multifuncitonal organosilicon finishing agent of claim 2, it is characterized in that: the mass ratio of the water-soluble organic silicon of epoxy radicals described in the above-mentioned steps (1) and N-butyl-tetramethyl piperidine amine or tetramethyl piperidine alcohol compound is 1-3: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010547101A CN102031692B (en) | 2010-11-16 | 2010-11-16 | Multifunctional organic silicon finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010547101A CN102031692B (en) | 2010-11-16 | 2010-11-16 | Multifunctional organic silicon finishing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102031692A true CN102031692A (en) | 2011-04-27 |
| CN102031692B CN102031692B (en) | 2012-09-26 |
Family
ID=43885099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010547101A Expired - Fee Related CN102031692B (en) | 2010-11-16 | 2010-11-16 | Multifunctional organic silicon finishing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102031692B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243364A (en) * | 2016-08-03 | 2016-12-21 | 广东工业大学 | A kind of organic silicon modified by polyether emulsion and preparation method thereof |
| CN108486899A (en) * | 2018-04-21 | 2018-09-04 | 湖南辰砾新材料有限公司 | A kind of fabric softener and preparation method thereof |
| CN111155316A (en) * | 2020-01-19 | 2020-05-15 | 珠海华大浩宏化工有限公司 | Alkali-resistant high-temperature-resistant organic silicon finishing agent |
| CN112708096A (en) * | 2020-12-14 | 2021-04-27 | 淮安凯悦科技开发有限公司 | Multifunctional foaming water-based resin and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007046171A (en) * | 2005-08-05 | 2007-02-22 | Nicca Chemical Co Ltd | Silicone-based softening finishing agent |
| EP1865016B1 (en) * | 2002-08-23 | 2008-11-26 | Wacker Chemie AG | Organosilicon compounds comprising cyclodextrin radicals |
| CN101435160A (en) * | 2008-12-18 | 2009-05-20 | 浙江闰土股份有限公司 | Organosilicon fluorine multifunctional fabric finishing agent and preparing method thereof |
-
2010
- 2010-11-16 CN CN201010547101A patent/CN102031692B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1865016B1 (en) * | 2002-08-23 | 2008-11-26 | Wacker Chemie AG | Organosilicon compounds comprising cyclodextrin radicals |
| JP2007046171A (en) * | 2005-08-05 | 2007-02-22 | Nicca Chemical Co Ltd | Silicone-based softening finishing agent |
| CN101435160A (en) * | 2008-12-18 | 2009-05-20 | 浙江闰土股份有限公司 | Organosilicon fluorine multifunctional fabric finishing agent and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《化工进展》 20071231 安秋凤等 织物用抗紫外线整理剂的研究进展 第26卷, 第6期 2 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243364A (en) * | 2016-08-03 | 2016-12-21 | 广东工业大学 | A kind of organic silicon modified by polyether emulsion and preparation method thereof |
| CN106243364B (en) * | 2016-08-03 | 2018-05-01 | 广东工业大学 | A kind of organic silicon modified by polyether lotion and preparation method thereof |
| CN108486899A (en) * | 2018-04-21 | 2018-09-04 | 湖南辰砾新材料有限公司 | A kind of fabric softener and preparation method thereof |
| CN108486899B (en) * | 2018-04-21 | 2020-08-07 | 上海鑫妙纺织助剂有限公司 | Fabric softening finishing agent and preparation method thereof |
| CN111155316A (en) * | 2020-01-19 | 2020-05-15 | 珠海华大浩宏化工有限公司 | Alkali-resistant high-temperature-resistant organic silicon finishing agent |
| CN112708096A (en) * | 2020-12-14 | 2021-04-27 | 淮安凯悦科技开发有限公司 | Multifunctional foaming water-based resin and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102031692B (en) | 2012-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102031692B (en) | Multifunctional organic silicon finishing agent and preparation method thereof | |
| CN104562779B (en) | A kind of dyeing assistant improving textile color stability and preparation method thereof | |
| CN103711011B (en) | Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof | |
| CN104404763B (en) | A kind of preparation method of the wool fabric of antistatic, felt proofing and good dyeability | |
| CN101624742A (en) | Milk protein fiber fabric and production process thereof | |
| CN103061146A (en) | Preparation method of composite antibacterial softening agent | |
| CN100547152C (en) | The yellow chrysanthemum flower dyestuff dyes the method for mercerized wool or mercerized wool fabric | |
| CN107904954A (en) | A kind of cotton well-pressed type softening agent and preparation method thereof | |
| CN108998594B (en) | Chromium-free tanning process based on P (POSS-MAA) composite material and aluminum salt | |
| CN106049102A (en) | Fabric color fixing agent for clothing and preparation method thereof | |
| CN102888755A (en) | Enzyme additive for cotton knitted fabric and preparation method and application thereof | |
| CN108049223B (en) | Color fixing agent for reactive dye dyeing and preparation method thereof | |
| CN111636201A (en) | Fabric softening and caring agent and preparation method thereof | |
| CN108893990A (en) | A kind of multi-functional preparation method containing silk fabric | |
| CN109706727A (en) | A kind of good color-woven fabric of feel and its preparation process | |
| CN102605112A (en) | Combined amino-silicone-oil leather greasing agent and preparation method thereof | |
| CN102965945A (en) | Fabric durable water repellent finishing agent and preparation method thereof | |
| CN106048854A (en) | Production method of hollow thermal fabric | |
| CN105133391A (en) | Dyeing assistant for pure-cashmere products | |
| CN105862477A (en) | Textile auxiliary for improving color fixation effect and preparation method thereof | |
| CN109576974A (en) | A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique | |
| TW200303950A (en) | A process for improving the sun protection factor of cellulosic fibre material | |
| CN109629097B (en) | Antistatic light luxury worsted woolen fabric | |
| CN101845144B (en) | Water-based organic silicon-fluorine resin waterproof agent and preparation method thereof | |
| CN101831772A (en) | Fabric finishing technique |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120926 Termination date: 20161116 |