CN109576974A - A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique - Google Patents
A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique Download PDFInfo
- Publication number
- CN109576974A CN109576974A CN201811378398.7A CN201811378398A CN109576974A CN 109576974 A CN109576974 A CN 109576974A CN 201811378398 A CN201811378398 A CN 201811378398A CN 109576974 A CN109576974 A CN 109576974A
- Authority
- CN
- China
- Prior art keywords
- blended yarn
- yarn weaved
- weaved fabric
- dyeing
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 85
- 238000004043 dyeing Methods 0.000 title claims abstract description 66
- 239000000835 fiber Substances 0.000 title claims abstract description 49
- 229920000742 Cotton Polymers 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000004677 Nylon Substances 0.000 title claims abstract description 33
- 229920001778 nylon Polymers 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000975 dye Substances 0.000 claims abstract description 34
- 238000009990 desizing Methods 0.000 claims abstract description 33
- 238000012545 processing Methods 0.000 claims abstract description 28
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 24
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002351 wastewater Substances 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 10
- 238000002386 leaching Methods 0.000 claims abstract description 8
- 238000002347 injection Methods 0.000 claims abstract description 7
- 239000007924 injection Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 239000000986 disperse dye Substances 0.000 claims description 21
- 238000010792 warming Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000002216 antistatic agent Substances 0.000 claims description 17
- 239000007921 spray Substances 0.000 claims description 17
- 238000005809 transesterification reaction Methods 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 150000002148 esters Chemical group 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 7
- 239000006004 Quartz sand Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 7
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 7
- GTHDFYARNWTZJG-UHFFFAOYSA-N ethyl 2-[2-(2-ethoxy-2-oxoethyl)phenyl]acetate Chemical compound CCOC(=O)CC1=CC=CC=C1CC(=O)OCC GTHDFYARNWTZJG-UHFFFAOYSA-N 0.000 claims description 7
- 239000004571 lime Substances 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical class S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 7
- 238000001728 nano-filtration Methods 0.000 claims description 7
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 7
- 238000009287 sand filtration Methods 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 7
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 6
- 238000009298 carbon filtering Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical class COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 230000008595 infiltration Effects 0.000 claims description 5
- 238000001764 infiltration Methods 0.000 claims description 5
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- 230000003134 recirculating effect Effects 0.000 claims description 5
- 238000010186 staining Methods 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 18
- 238000013461 design Methods 0.000 abstract description 4
- 241000219146 Gossypium Species 0.000 description 23
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 9
- 239000012535 impurity Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000004321 preservation Methods 0.000 description 8
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 6
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 6
- 230000006837 decompression Effects 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 6
- 239000001814 pectin Substances 0.000 description 5
- 229920001277 pectin Polymers 0.000 description 5
- 235000010987 pectin Nutrition 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 210000002435 tendon Anatomy 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- ANBZTKMYPDMODS-YPKPFQOOSA-N (z)-n,n-diethyloctadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CC)CC ANBZTKMYPDMODS-YPKPFQOOSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BAQSIYCDSSZDHG-UHFFFAOYSA-K calcium;sodium;carbonate;hydroxide Chemical compound [OH-].[Na+].[Ca+2].[O-]C([O-])=O BAQSIYCDSSZDHG-UHFFFAOYSA-K 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004661 hydrophilic softener Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention discloses few watermark dyeing technique of a kind of cotton, nylon fibre blended yarn weaved fabric, selects including fabric: selection specification 1/2.5Nm, 56-60 inches of breadth, the blended yarn weaved fabric being made of 50% cotton fiber and 50% nylon fibre；It singes；Desizing: carrying out two leachings two using the soda bath of 3-5g/L first and roll processing, later 70-80 DEG C of hot water injection, reuses the dilute sulfuric acid processing of 5-7g/L, banks up 1-3h, and 40-50 DEG C of warm water washing completes desizing；Dyeing；Antistatic finish.Design is scientific and reasonable for the dyeing and printing process, greatly reduce the use of water and the generation of dyeing waste water, it is dyed in dyeing course using temperature programmed control, facilitate the combination of dyestuff and blended yarn weaved fabric, color fastness can be improved, save water, reduce cost, vividness, coloured light are good after printing and dyeing arrange, and comfortable ventilating is antistatic, are suitble to promote the use of.
Description
Technical field
The present invention relates to shell-fabric dyeing and finishing technical fields, and in particular to few watermark dye of Yi Zhongmian, nylon fibre blended yarn weaved fabric
Technique.
Background technique
Cotton spinning and its dyeing are largest, best, the time-honored industries in basis in China's textile industry.By
It will affect following process process and product quality containing a large amount of natural impurity in cotton fiber, need to add using chemical method
With removal, the binding force of cotton fiber and dyestuff relies primarily on Van der Waals force and hydrogen bond, the active class of the dyestuff used, reduction class,
Direct class, vulcanization class etc., but have that dye-uptake is low, residual quantity is high in water, the highly concentrated disadvantage of Wastewater Pollutant.In cotton fibre
Dimension mainly uses disperse dyes, the dyestuff dye-uptake is higher, but filling additive with the blended yarn weaved fabric of terylene or nylon fibre
It is more, it is more toxic, also brings difficulty to waste water treatment.
In the prior art, the general technology process of cotton fiber and its blended fabric dyeing and printing process includes singing, desizing, boiling
White silk, bleaching, mercerising, dyeing, stamp, final finishing step.The waste water generated in dyeing and printing process generally includes pre-treatment waste water and dye
Color, printing waste water, major pollutants have artificial synthetic organic materials and part natural organic matter in waste water, and containing a large amount of difficult raw
Object degradation material.The patent of application number 201510358001.8 disclose a kind of printing and dyeing agent suitable for washing nitrile cotton blended fabric and
Its dyeing and printing process, printing and dyeing agent include disperse dyes, cationic blue SD-BL 100% (B-159), acid dyes, dispersion dye leveller,
Acid dye leveller, hydrophilic softener, suspending agent, glacial acetic acid, surplus are water.It is knitted using the printing and dyeing agent to nitrile cotton blend is washed
When object dyes, the dyeing of three kinds of fibers can be completed by one-bath one-step dyeing, it is easy to operate, and even dyeing.But it grinds
Study carefully discovery, however it remains following problems: 1, the water consumption for agent of printing and dyeing is larger, and dye component is complicated and expensive, and whens printing and dyeing is most of
It is all dissolved in water, waste is serious；2, nylon fibre is chemical synthetic fiber, is easy in external influence such as friction or various energy
Electrostatic is generated under the action of form, in dyeing and finishing technology lack antistatic finish measure, with cotton fiber it is blended made of fabric hold
It is easy to produce static electricity, it causes harm to the human body.
Summary of the invention
In order to overcome above-mentioned technical problem, the purpose of the present invention is to provide a kind of cottons, nylon fibre blended yarn weaved fabric
Few watermark dyeing technique, using cotton fiber, nylon fibre physicochemical characteristics as foundation, devise and select, singe including fabric, moving back
Slurry, dyeing, antistatic finish process flow, technological design is scientific and reasonable, greatly reduces use and the dyeing waste water of water
It generates, is dyed in dyeing course using temperature programmed control, facilitate the combination of dyestuff and blended yarn weaved fabric, which can be improved
Color fastness saves water, reduces cost, and vividness, coloured light are good after printing and dyeing arrange, and comfortable ventilating is antistatic, are suitble to promote the use of.
The purpose of the present invention can be achieved through the following technical solutions:
The present invention provides a kind of cottons, few watermark dyeing technique of nylon fibre blended yarn weaved fabric, comprising the following steps:
1) fabric selects: selecting specification 1/2.5Nm, 56-60 inches of breadth, by 50% cotton fiber and 50% nylon fibre group
At blended yarn weaved fabric；
2) it singes: blended yarn weaved fabric is run through into three burner gassing frames with open width state, carry out two forward one-reverses and singe processing；
3) desizing: carrying out two leachings two using the soda bath of 3-5g/L first and roll processing, later 70-80 DEG C of hot water injection,
The dilute sulfuric acid processing for reusing 5-7g/L, banks up 1-3h, and 40-50 DEG C of warm water washing completes desizing；Collect that treated that caustic soda is molten
Liquid and waste water；
4) dye: blended yarn weaved fabric is put into impregnating mangle, and disperse dyes heating dip dyeing, dispersion dye are passed through under nitrogen protection atmosphere
The liquid level of material is higher than pre-staining blended yarn weaved fabric 2-3cm, completes to dye using temperature programmed control, adds ammonium sulfate in dyeing course
Salt keeps pH value 4-5；Wherein, the detailed process of temperature programmed control are as follows: be warming up to 60 DEG C with the rate of 1-2 DEG C/min, heat preservation
20min；100 DEG C are warming up to the rate of 2-3 DEG C/min, keeps the temperature 10min；With 1-2 DEG C/min water-cooled cooling to 60 DEG C, heat preservation
10min；With 3-4 DEG C/min water-cooled cooling to room temperature, 30min is kept the temperature；
5) antistatic finish: the blended yarn weaved fabric for dyeing completion is dried under vacuum to surface dripless in 50-60 DEG C, is placed in low temperature
It is spraying using two with 450-550W Power Processing 5-10min under vacuum degree 10-20Pa, nitrogen atmosphere in plasma
Device sprays antistatic finishing agent to the tow sides of blended yarn weaved fabric simultaneously, makes the infiltration of blended yarn weaved fabric surface in acidproof antistatic finish
In agent；Mangle removes excessive moisture after infiltrating 5-10min, and then the dry 3-5min at 80-100 DEG C, fixed in 160-180 DEG C of heat
Type 1-2min.
The present invention is when designing the dyeing and printing process of cotton, nylon fibre blended yarn weaved fabric, from the hygroscopic moisture absorption of solution cotton fiber, wrinkle
After be not easy to arrange, nylon fibre is easy to produce static electricity, dyeing course water consumption is big and waste water does not allow easy to handle problem to set out, normal
On the dyeing and printing process process base of rule, desizing processes have used sour alkali desizing method.The fabric cotton fiber content that the present invention selects is high,
Contain the impurity such as a large amount of cotton seed hulls, starch, pectin, cellulose when untreated.Processing first is padded using soda bath, it can be with
Make the washing removal of the extrudings such as cotton seed hulls, starch, cellulose, the natural impuritys such as itrogenous organic substance, pectin on cotton fiber are also a large amount of
It decomposes；During dilute sulfuric acid processing, a part can neutralize remaining caustic soda in blended yarn weaved fabric, and a part can aoxidize miscellaneous
Matter.Not only desizing is at low cost for the desizing method, but also natural impurity removal rate is high, and cotton seed hulls removal is complete.
In dyeing course, since nylon fibre belongs to hydrophobic fiber, contains amino and carboxyl on fiber, lack energy and dyestuff
In conjunction with group, it is not easy to colour, cannot be dyed using water-soluble dye, and dye structure is close when low temperature, can not
Diffuse into fibrous inside.Using the reaction condition of temperature programmed control, the macromolecular chain segment of cotton, nylon fibre can be made to occur acutely
The molecular gap of movement, nylon fibre and cotton fiber increases, and free volume increases, and improves dyeing efficiency.And temperature programmed control mistake
Cheng Zhong first slowly expands fiber molecule gap with low heating rate, then increases fiber molecule gap, dyestuff point with high heating rate
Subbase group is easily accessible the combination of fiber molecule gap, then by temperature-reduction at constant speed, tightens fiber molecule gap, can greatly improve mixed
The Percentage bound and color fastness of textile fabric fiber and disperse dyes.
In antistatic treatment process, Low Temperature Plasma Treating can be formed on blended yarn weaved fabric surface and be etched, and increase fabric
The active oxygen-containing group content and roughness on surface, the antistatic agent molecule one in antistatic finishing agent after the even application of two sides
Aspect is intermolecular mobile convenient for proton since the locomitivity of strand is stronger, and fabric is conducted and discharged by ionic conduction
The electrostatic charge of generation, another aspect antistatic agent molecule are distributed on fabric surface layer in fine stratiform or tendon shape, constitute conductive shape
Surface layer, it is conductive without relying on water suction moisture absorption, reduce the water consumption during antistatic finish.
As a further solution of the present invention, the step 4) disperse dyes the preparation method is as follows: by weight, claim
Take the dry filter cake of 60-75 parts of permanent bordeaux F3RK/F5RK, 5-12 parts of lauric acid amide of ethanol, 4-8 parts of PEG400,1-3 parts of tricresyl phosphates
Butyl ester, 0.2-0.6 part disodium ethylene diamine tetraacetate are dispersed into slurry using dispersion machine high-speed stirred, and investment is equipped with polytetrafluoro
In the recirculating ball mill machine of ethylene material mill tube, 40-60 parts of acetonitriles are added, high speed wet ball grinding is at disperse dyes.
Disperse dyes of the invention well compound the nonionic surfactant coconut palm of synergistic effect with having using permanent bordeaux
Oleic acid diethyl amide, tributyl phosphate, antioxidant synergist disodium ethylene diamine tetraacetate mixing and ball milling are prepared, and permanent bordeaux can
To cooperate with the coordination atom on disodium ethylene diamine tetraacetate, improve the compatibility with blended yarn weaved fabric, and play antioxidant effect,
Improve the dispersibility and antioxygen property of the disperse dyes.
As a further solution of the present invention, the step 5) antistatic finishing agent the preparation method is as follows:
(1) prepared by transesterification object: by weight, by 16 parts to phenylenediacetic Acid diethylester, 55 parts of 1,3-PDs, 26 parts
Polyethylene glycol mixing, is heated to molten condition, adds 6 parts of nano molybdenum disulfides, 4 parts of antimony oxides, be warming up to 100 DEG C,
It is passed through nitrogen protection, keeps the temperature 3 hours, the gas in reaction system is discharged, continues to keep the temperature 1 hour completion ester exchange reaction, obtain
Transesterification product；
(2) prepared by antistatic agent: by weight, 3 parts of trimethyl phosphates, 5 parts of calcium zinc stabilizers being added to transesterification
In product, 160 DEG C are warming up to, is reacted 2 hours under the conditions of 2MPa nitrogen pressure, then heats to 200 DEG C, it is 3 small that the reaction was continued
Shi Hou is discharged gas, obtains antistatic agent；
(3) prepared by antistatic finishing agent: antistatic agent and deionized water are mixed evenly i.e. according to mass ratio 1:1
It can.
Antistatic finishing agent of the invention, with to based on phenylenediacetic Acid diethylester, 1,3-PD, heating melting condition
It is lower to react to obtain antistatic transesterification product with lubricant nano molybdenum disulfide, fire retardant antimony oxide, then with tricresyl phosphate
Methyl esters, calcium zinc stabilizer mixing, on the basis of keeping thermal stability, when antistatic finish in the fine stratiform in fabric surface layer or
Tendon shape distribution, constitutes electric conductivity surface layer, conductive without relying on water suction moisture absorption, reduces the water consumption during antistatic finish.
As a further solution of the present invention, the spray head of step 5) sprayer aperture of gathering is 10-20 μm, is divided into
20-30 μm of spray hole.
Gather on sprayer and spacing uniform spray hole design, can make antistatic finishing agent uniformly spray infiltrate through it is mixed
Antistatic finish is carried out in the fibre gap of textile fabric, is eliminated traditional " two leachings two are rolled " finishing technique, is greatly saved whole
The dosage for managing agent, reduces water consumption and cost.
As a further solution of the present invention, the step 3) soda bath of collecting that treated by quartz sand filtration,
After active carbon filtering, nanofiltration membrane, white lime processing, decompression filter, the sodium hydroxide solution of high-purity is obtained for multiple
Desizing uses.
The soda bath that the present invention generates in desizing processes, using above-mentioned treatment process, quartz sand filtration, active carbon mistake
Filter can filter out the cotton seed hulls impurity after extruding, and nanofiltration membrane can remove pectin, nitrogenous small molecular weight impurity after decomposing, ripe
The sodium carbonate that lime can be generated with rotten rear caustic soda, which reacts, generates sodium hydroxide and precipitation of calcium carbonate, and decompression filters removing carbonic acid
The sodium hydroxide solution of available high-purity after calcium precipitate can use for multiple desizing, save the dosage and cost of water.
Beneficial effects of the present invention:
1, cotton of the invention, nylon fibre blended yarn weaved fabric few watermark dyeing technique, devise select, singe including fabric,
Desizing, dyeing, antistatic finish process flow, technological design is scientific and reasonable, greatly reduces use and the dyeing waste water of water
Generation, dyed using temperature programmed control in dyeing course, facilitate the combination of dyestuff and blended yarn weaved fabric, which can mention
High color fastness saves water, reduces cost, and vividness, coloured light are good after printing and dyeing arrange, and are suitble to promote the use of.
2, in desizing processes, processing first is padded using soda bath, the extrudings water such as cotton seed hulls, starch, cellulose can be made
It washes away and removes, the natural impuritys such as itrogenous organic substance, pectin on cotton fiber also largely decompose；During dilute sulfuric acid processing, one
Remaining caustic soda in blended yarn weaved fabric can be neutralized by dividing, and a part can be with oxidation impurities.Not only desizing is at low cost for the desizing method, and
And natural impurity removal rate is high, cotton seed hulls removal is complete.
3, the reaction condition that temperature programmed control is used in dyeing course can be such that the macromolecular chain segment of cotton, nylon fibre occurs
The molecular gap of strenuous exercise, nylon fibre and cotton fiber increases, and free volume increases, and improves dyeing efficiency；First with low heating
Rate slowly expands fiber molecule gap, then increases fiber molecule gap with high heating rate, and dye molecule group is easily accessible
Fiber molecule gap combines, then by temperature-reduction at constant speed, tightens fiber molecule gap, can greatly improve blended yarn weaved fabric fiber and divide
Dissipate the Percentage bound and color fastness of dyestuff.
4, antistatic finishing agent, with to based on phenylenediacetic Acid diethylester, 1,3-PD, under the conditions of heating melting with profit
Lubrication prescription nano molybdenum disulfide, fire retardant antimony oxide react to obtain antistatic transesterification product, are trimethyl phosphate, calcium
After zinc stabilizer mixing, on the basis of keeping thermal stability, when antistatic finish the stratiform or tendon shape fine on fabric surface layer
Distribution constitutes electric conductivity surface layer, conductive without relying on water suction moisture absorption, reduces the water consumption during antistatic finish.
5, the soda bath generated in desizing processes, quartz sand filtration, active carbon filtering can filter out the cottonseed after extruding
Shell impurity, nanofiltration membrane can remove pectin, nitrogenous small molecular weight impurity after decomposing, and white lime can be produced with rotten rear caustic soda
Raw sodium carbonate reaction generates sodium hydroxide and precipitation of calcium carbonate, and decompression filters available high-purity after removing precipitation of calcium carbonate
Sodium hydroxide solution, can be used for multiple desizing, save the dosage and cost of water.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, all other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique, comprising the following steps:
1) fabric selects: selecting specification 1/2.5Nm, 56-60 inches of breadth, by 50% cotton fiber and 50% nylon fibre group
At blended yarn weaved fabric；
2) it singes: blended yarn weaved fabric is run through into three burner gassing frames with open width state, carry out two forward one-reverses and singe processing；
3) desizing: two leachings two are carried out using the soda bath of 4g/L first and roll processing, 75 DEG C of hot water injections, reuse later
The dilute sulfuric acid of 6g/L is handled, and banks up 2h, and 46 DEG C of warm water washings complete desizing；Collect treated soda bath and waste water；Wherein,
It collects treated soda bath and passes through quartz sand filtration, active carbon filtering, nanofiltration membrane, white lime processing, decompression suction filtration
Afterwards, the sodium hydroxide solution of high-purity is obtained to use for multiple desizing.
4) dye: blended yarn weaved fabric is put into impregnating mangle, and disperse dyes heating dip dyeing, dispersion dye are passed through under nitrogen protection atmosphere
The liquid level of material is higher than pre-staining blended yarn weaved fabric 2-3cm, completes to dye using temperature programmed control, adds ammonium sulfate in dyeing course
Salt keeps pH value 4-5；Wherein, the detailed process of temperature programmed control are as follows: be warming up to 60 DEG C with the rate of 1-2 DEG C/min, heat preservation
20min；100 DEG C are warming up to the rate of 2-3 DEG C/min, keeps the temperature 10min；With 1-2 DEG C/min water-cooled cooling to 60 DEG C, heat preservation
10min；With 3-4 DEG C/min water-cooled cooling to room temperature, 30min is kept the temperature.Wherein, disperse dyes the preparation method is as follows: by weight
Part meter, weighs the dry filter cake of 72 parts of permanent bordeaux F3RK/F5RK, 9 parts of lauric acid amide of ethanol, 6 parts of PEG400,2 parts of tricresyl phosphate fourths
Ester, 0.4 part of disodium ethylene diamine tetraacetate are dispersed into slurry using dispersion machine high-speed stirred, and investment is equipped with polytetrafluoroethylene (PTFE) material
In the recirculating ball mill machine of matter mill tube, 55 parts of acetonitriles are added, high speed wet ball grinding is at disperse dyes.
5) antistatic finish: the blended yarn weaved fabric for dyeing completion is dried under vacuum to surface dripless in 56 DEG C, is placed in low temperature etc.
It is same using two sprayers with 450-550W Power Processing 7min under vacuum degree 10-20Pa, nitrogen atmosphere in gas ions instrument
When to the tow sides of blended yarn weaved fabric spray antistatic finishing agent, make blended yarn weaved fabric surface infiltration in acidproof antistatic finishing agent
It is interior；Mangle removes excessive moisture after infiltrating 6min, then the dry 5min at 95 DEG C, in 170 DEG C of thermal finalization 1min.It is spraying
The spray head of device aperture of gathering is 10-20 μm, is divided into 20-30 μm of spray hole.
Wherein, antistatic finishing agent the preparation method is as follows:
(1) prepared by transesterification object: by weight, by 16 parts to phenylenediacetic Acid diethylester, 55 parts of 1,3-PDs, 26 parts
Polyethylene glycol mixing, is heated to molten condition, adds 6 parts of nano molybdenum disulfides, 4 parts of antimony oxides, be warming up to 100 DEG C,
It is passed through nitrogen protection, keeps the temperature 3 hours, the gas in reaction system is discharged, continues to keep the temperature 1 hour completion ester exchange reaction, obtain
Transesterification product；
(2) prepared by antistatic agent: by weight, 3 parts of trimethyl phosphates, 5 parts of calcium zinc stabilizers being added to transesterification
In product, 160 DEG C are warming up to, is reacted 2 hours under the conditions of 2MPa nitrogen pressure, then heats to 200 DEG C, it is 3 small that the reaction was continued
Shi Hou is discharged gas, obtains antistatic agent；
(3) prepared by antistatic finishing agent: antistatic agent and deionized water are mixed evenly i.e. according to mass ratio 1:1
It can.
Embodiment 2
A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique, comprising the following steps:
1) fabric selects: selecting specification 1/2.5Nm, 56-60 inches of breadth, by 50% cotton fiber and 50% nylon fibre group
At blended yarn weaved fabric；
2) it singes: blended yarn weaved fabric is run through into three burner gassing frames with open width state, carry out two forward one-reverses and singe processing；
3) desizing: two leachings two are carried out using the soda bath of 5g/L first and roll processing, 80 DEG C of hot water injections, reuse later
The dilute sulfuric acid of 5g/L is handled, and banks up 1.6h, and 50 DEG C of warm water washings complete desizing；Collect treated soda bath and waste water；Its
In, it collects treated soda bath and passes through quartz sand filtration, active carbon filtering, nanofiltration membrane, white lime processing, decompression pumping
After filter, obtains the sodium hydroxide solution of high-purity and used for multiple desizing.
4) dye: blended yarn weaved fabric is put into impregnating mangle, and disperse dyes heating dip dyeing, dispersion dye are passed through under nitrogen protection atmosphere
The liquid level of material is higher than pre-staining blended yarn weaved fabric 2-3cm, completes to dye using temperature programmed control, adds ammonium sulfate in dyeing course
Salt keeps pH value 4-5；Wherein, the detailed process of temperature programmed control are as follows: be warming up to 60 DEG C with the rate of 1-2 DEG C/min, heat preservation
20min；100 DEG C are warming up to the rate of 2-3 DEG C/min, keeps the temperature 10min；With 1-2 DEG C/min water-cooled cooling to 60 DEG C, heat preservation
10min；With 3-4 DEG C/min water-cooled cooling to room temperature, 30min is kept the temperature.Wherein, disperse dyes the preparation method is as follows: by weight
Part meter, weighs the dry filter cake of 72 parts of permanent bordeaux F3RK/F5RK, 9 parts of lauric acid amide of ethanol, 7 parts of PEG400,2 parts of tricresyl phosphate fourths
Ester, 0.5 part of disodium ethylene diamine tetraacetate are dispersed into slurry using dispersion machine high-speed stirred, and investment is equipped with polytetrafluoroethylene (PTFE) material
In the recirculating ball mill machine of matter mill tube, 60 parts of acetonitriles are added, high speed wet ball grinding is at disperse dyes.
5) antistatic finish: the blended yarn weaved fabric for dyeing completion is dried under vacuum to surface dripless in 60 DEG C, is placed in low temperature etc.
In gas ions instrument, with 450-550W Power Processing 5-10min under vacuum degree 10-20Pa, nitrogen atmosphere, two sprayers are used
Antistatic finishing agent is sprayed to the tow sides of blended yarn weaved fabric simultaneously, makes the infiltration of blended yarn weaved fabric surface in acidproof antistatic finishing agent
It is interior；Mangle removes excessive moisture after infiltrating 8min, then the dry 5min at 95 DEG C, in 172 DEG C of thermal finalization 1.5min.Spray
The spray head of day with fog aperture of gathering is 10-20 μm, is divided into 20-30 μm of spray hole.
Wherein, antistatic finishing agent the preparation method is as follows:
(1) prepared by transesterification object: by weight, by 16 parts to phenylenediacetic Acid diethylester, 55 parts of 1,3-PDs, 26 parts
Polyethylene glycol mixing, is heated to molten condition, adds 6 parts of nano molybdenum disulfides, 4 parts of antimony oxides, be warming up to 100 DEG C,
It is passed through nitrogen protection, keeps the temperature 3 hours, the gas in reaction system is discharged, continues to keep the temperature 1 hour completion ester exchange reaction, obtain
Transesterification product；
(2) prepared by antistatic agent: by weight, 3 parts of trimethyl phosphates, 5 parts of calcium zinc stabilizers being added to transesterification
In product, 160 DEG C are warming up to, is reacted 2 hours under the conditions of 2MPa nitrogen pressure, then heats to 200 DEG C, it is 3 small that the reaction was continued
Shi Hou is discharged gas, obtains antistatic agent；
(3) prepared by antistatic finishing agent: antistatic agent and deionized water are mixed evenly i.e. according to mass ratio 1:1
It can.
Embodiment 3
A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique, comprising the following steps:
1) fabric selects: selecting specification 1/2.5Nm, 56-60 inches of breadth, by 50% cotton fiber and 50% nylon fibre group
At blended yarn weaved fabric；
2) it singes: blended yarn weaved fabric is run through into three burner gassing frames with open width state, carry out two forward one-reverses and singe processing；
3) desizing: two leachings two are carried out using the soda bath of 3g/L first and roll processing, 80 DEG C of hot water injections, reuse later
The dilute sulfuric acid of 7g/L is handled, and banks up 3h, and 50 DEG C of warm water washings complete desizing；Collect treated soda bath and waste water；Wherein,
It collects treated soda bath and passes through quartz sand filtration, active carbon filtering, nanofiltration membrane, white lime processing, decompression suction filtration
Afterwards, the sodium hydroxide solution of high-purity is obtained to use for multiple desizing.
4) dye: blended yarn weaved fabric is put into impregnating mangle, and disperse dyes heating dip dyeing, dispersion dye are passed through under nitrogen protection atmosphere
The liquid level of material is higher than pre-staining blended yarn weaved fabric 2-3cm, completes to dye using temperature programmed control, adds ammonium sulfate in dyeing course
Salt keeps pH value 4-5；Wherein, the detailed process of temperature programmed control are as follows: be warming up to 60 DEG C with the rate of 1-2 DEG C/min, heat preservation
20min；100 DEG C are warming up to the rate of 2-3 DEG C/min, keeps the temperature 10min；With 1-2 DEG C/min water-cooled cooling to 60 DEG C, heat preservation
10min；With 3-4 DEG C/min water-cooled cooling to room temperature, 30min is kept the temperature.Wherein, disperse dyes the preparation method is as follows: by weight
Part meter, weighs the dry filter cake of 75 parts of permanent bordeaux F3RK/F5RK, 9 parts of lauric acid amide of ethanol, 7 parts of PEG400,3 parts of tricresyl phosphate fourths
Ester, 0.6 part of disodium ethylene diamine tetraacetate are dispersed into slurry using dispersion machine high-speed stirred, and investment is equipped with polytetrafluoroethylene (PTFE) material
In the recirculating ball mill machine of matter mill tube, 52 parts of acetonitriles are added, high speed wet ball grinding is at disperse dyes.
5) antistatic finish: the blended yarn weaved fabric for dyeing completion is dried under vacuum to surface dripless in 50-60 DEG C, is placed in low temperature
It is spraying using two with 450-550W Power Processing 5-10min under vacuum degree 10-20Pa, nitrogen atmosphere in plasma
Device sprays antistatic finishing agent to the tow sides of blended yarn weaved fabric simultaneously, makes the infiltration of blended yarn weaved fabric surface in acidproof antistatic finish
In agent；Mangle removes excessive moisture after infiltrating 10min, then the dry 5min at 96 DEG C, in 176 DEG C of thermal finalization 2min.
The spray head of sprayer aperture of gathering is 10-20 μm, is divided into 20-30 μm of spray hole.
Wherein, antistatic finishing agent the preparation method is as follows:
(1) prepared by transesterification object: by weight, by 16 parts to phenylenediacetic Acid diethylester, 55 parts of 1,3-PDs, 26 parts
Polyethylene glycol mixing, is heated to molten condition, adds 6 parts of nano molybdenum disulfides, 4 parts of antimony oxides, be warming up to 100 DEG C,
It is passed through nitrogen protection, keeps the temperature 3 hours, the gas in reaction system is discharged, continues to keep the temperature 1 hour completion ester exchange reaction, obtain
Transesterification product；
(2) prepared by antistatic agent: by weight, 3 parts of trimethyl phosphates, 5 parts of calcium zinc stabilizers being added to transesterification
In product, 160 DEG C are warming up to, is reacted 2 hours under the conditions of 2MPa nitrogen pressure, then heats to 200 DEG C, it is 3 small that the reaction was continued
Shi Hou is discharged gas, obtains antistatic agent；
(3) prepared by antistatic finishing agent: antistatic agent and deionized water are mixed evenly i.e. according to mass ratio 1:1
It can.
Comparative example 1
Compared with Example 1, difference is in the step 3) desizing of this comparative example specifically to use 3- using alkali desizing method
The soda bath of 5g/L carries out two leachings two and rolls processing, and 70-80 DEG C of hot water injection completes desizing later.
Comparative example 2
Compared with Example 1, difference is in the step 4) dyeing of this comparative example that temperature programmed control is used with the speed of 2 DEG C/min
Rate is warming up to 100 DEG C, keeps the temperature 30min, then after being naturally cooling to room temperature, keeps the temperature 30min.
Comparative example 3
Compared with Example 1, difference is that this comparative example lacks step 5) antistatic finish.
Performance test
To the cotton after above-described embodiment, comparative example printing and dyeing, nylon fibre blended yarn weaved fabric, referring to professional standard FZ/T14018-
2010 " polyamide fibre, cotton intertexture dyeing cloths " have carried out washing size changing rate, color fastness is measured, referring to professional standard GB/T
24249-2009 " antistatic clean fabrics " has carried out the measurement of surface resistivity.Specific test result see the table below:
As can be seen from the above table, the cotton after printing and dyeing of the embodiment of the present invention, nylon fibre blended yarn weaved fabric are compared with comparative example, color
Fastness is good, washing size changing rate is small, surface resistivity is high, the blended yarn weaved fabric after illustrating printing and dyeing is fast light, it is resistance to soap, perspiration resistance,
It is water-fastness, have excellent antistatic properties.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Claims (5)
1. few watermark dyeing technique of a kind of cotton, nylon fibre blended yarn weaved fabric, which comprises the following steps:
1) fabric selects: selection specification 1/2.5Nm, 56-60 inches of breadth, being made of 50% cotton fiber and 50% nylon fibre
Blended yarn weaved fabric；
2) it singes: blended yarn weaved fabric is run through into three burner gassing frames with open width state, carry out two forward one-reverses and singe processing；
3) desizing: two leachings two are carried out using the soda bath of 3-5g/L first and roll processing, later 70-80 DEG C of hot water injection, then are made
It is handled with the dilute sulfuric acid of 5-7g/L, banks up 1-3h, 40-50 DEG C of warm water washing completes desizing；Collect treated soda bath and
Waste water；
4) dye: blended yarn weaved fabric is put into impregnating mangle, and disperse dyes heating dip dyeing is passed through under nitrogen protection atmosphere, disperse dyes
Liquid level is higher than pre-staining blended yarn weaved fabric 2-3cm, completes to dye using temperature programmed control, and addition ammonium sulfate is protected in dyeing course
Hold pH value 4-5；Wherein, the detailed process of temperature programmed control are as follows: be warming up to 60 DEG C with the rate of 1-2 DEG C/min, keep the temperature 20min；With
The rate of 2-3 DEG C/min is warming up to 100 DEG C, keeps the temperature 10min；With 1-2 DEG C/min water-cooled cooling to 60 DEG C, 10min is kept the temperature；With 3-
4 DEG C/min water-cooled cooling keeps the temperature 30min to room temperature；
5) antistatic finish: the blended yarn weaved fabric for dyeing completion is dried under vacuum to surface dripless in 50-60 DEG C, be placed in low temperature etc. from
It is same using two sprayers with 450-550W Power Processing 5-10min under vacuum degree 10-20Pa, nitrogen atmosphere in daughter instrument
When to the tow sides of blended yarn weaved fabric spray antistatic finishing agent, make blended yarn weaved fabric surface infiltration in acidproof antistatic finishing agent
It is interior；Mangle removes excessive moisture after infiltrating 5-10min, then the dry 3-5min at 80-100 DEG C, in 160-180 DEG C of thermal finalization
1-2min.
2. few watermark dyeing technique of cotton according to claim 1, nylon fibre blended yarn weaved fabric, which is characterized in that the step
Rapid 4) disperse dyes the preparation method is as follows: by weight, weighing the dry filter cake of 60-75 parts of permanent bordeaux F3RK/F5RK, 5-12 parts
Lauric acid amide of ethanol, 4-8 part PEG400,1-3 part tributyl phosphate, 0.2-0.6 parts of disodium ethylene diamine tetraacetates, using point
It dissipates machine high-speed stirred and is dispersed into slurry, investment is equipped in the recirculating ball mill machine of polytetrafluoroethylene (PTFE) material mill tube, and 40-60 is added
Part acetonitrile, high speed wet ball grinding is at disperse dyes.
3. few watermark dyeing technique of cotton according to claim 1, nylon fibre blended yarn weaved fabric, which is characterized in that the step
Rapid 5) antistatic finishing agent the preparation method is as follows:
(1) prepared by transesterification object: by weight, by 16 parts to phenylenediacetic Acid diethylester, 55 parts of 1,3-PDs, 26 parts of poly- second
Glycol mixing, is heated to molten condition, adds 6 parts of nano molybdenum disulfides, 4 parts of antimony oxides, be warming up to 100 DEG C, be passed through
Nitrogen protection keeps the temperature 3 hours, and the gas in reaction system is discharged, and continues to keep the temperature 1 hour completion ester exchange reaction, obtains ester friendship
Change product；
(2) prepared by antistatic agent: by weight, 3 parts of trimethyl phosphates, 5 parts of calcium zinc stabilizers being added to transesterification product
In, 160 DEG C are warming up to, is reacted 2 hours under the conditions of 2MPa nitrogen pressure, then heats to 200 DEG C, after the reaction was continued 3 hours,
Gas is discharged, obtains antistatic agent；
(3) prepared by antistatic finishing agent: antistatic agent and deionized water are mixed evenly according to mass ratio 1:1.
4. few watermark dyeing technique of cotton according to claim 1, nylon fibre blended yarn weaved fabric, which is characterized in that the step
The spray head of rapid 5) sprayer aperture of gathering is 10-20 μm, is divided into 20-30 μm of spray hole.
5. few watermark dyeing technique of cotton according to claim 1, nylon fibre blended yarn weaved fabric, which is characterized in that the step
It is rapid 3) collect treated soda bath by quartz sand filtration, active carbon filtering, nanofiltration membrane, white lime processing, depressurize
After suction filtration, obtains the sodium hydroxide solution of high-purity and used for multiple desizing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811378398.7A CN109576974A (en) | 2018-11-19 | 2018-11-19 | A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811378398.7A CN109576974A (en) | 2018-11-19 | 2018-11-19 | A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109576974A true CN109576974A (en) | 2019-04-05 |
Family
ID=65922870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811378398.7A Withdrawn CN109576974A (en) | 2018-11-19 | 2018-11-19 | A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109576974A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111926594A (en) * | 2020-08-21 | 2020-11-13 | 绍兴柯桥新都印染有限公司 | Rayon dyeing process |
| CN112030541A (en) * | 2020-08-21 | 2020-12-04 | 绍兴柯桥新都印染有限公司 | Pretreatment process for rayon printing |
| CN112430962A (en) * | 2020-10-12 | 2021-03-02 | 安徽明华纺织科技有限公司 | After-finishing process of polyester fabric |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101092776A (en) * | 2006-06-23 | 2007-12-26 | 绍兴金球纺织整理有限公司 | Manufacturing method of multifunctional protective fabric |
| CN101298739A (en) * | 2008-06-16 | 2008-11-05 | 西安工程大学 | Dacron hydrophilic antistatic agent, preparing method and dacron afterfinish method |
| CN102418286A (en) * | 2011-10-11 | 2012-04-18 | 南通市田园装饰布有限公司 | Dyed fine denier polypropylene fiber chenille sofa fabric |
| CN108570724A (en) * | 2018-04-01 | 2018-09-25 | 于美花 | A kind of protective fabric |
-
2018
- 2018-11-19 CN CN201811378398.7A patent/CN109576974A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101092776A (en) * | 2006-06-23 | 2007-12-26 | 绍兴金球纺织整理有限公司 | Manufacturing method of multifunctional protective fabric |
| CN101298739A (en) * | 2008-06-16 | 2008-11-05 | 西安工程大学 | Dacron hydrophilic antistatic agent, preparing method and dacron afterfinish method |
| CN102418286A (en) * | 2011-10-11 | 2012-04-18 | 南通市田园装饰布有限公司 | Dyed fine denier polypropylene fiber chenille sofa fabric |
| CN108570724A (en) * | 2018-04-01 | 2018-09-25 | 于美花 | A kind of protective fabric |
Non-Patent Citations (1)
| Title |
|---|
| 无: "《化工辞典》", 31 August 1969, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111926594A (en) * | 2020-08-21 | 2020-11-13 | 绍兴柯桥新都印染有限公司 | Rayon dyeing process |
| CN112030541A (en) * | 2020-08-21 | 2020-12-04 | 绍兴柯桥新都印染有限公司 | Pretreatment process for rayon printing |
| CN112430962A (en) * | 2020-10-12 | 2021-03-02 | 安徽明华纺织科技有限公司 | After-finishing process of polyester fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107916518B (en) | Process method for improving wet rubbing fastness of tatted dark cloth | |
| CN108589347B (en) | Based on the cation modifier ink method for sorting ink-jet printed for reactive dye | |
| CN109576974A (en) | A kind of cotton, nylon fibre blended yarn weaved fabric few watermark dyeing technique | |
| WO2021003943A1 (en) | Dyeing and finishing process for highly elastic polyester composite fabric | |
| CN108252130B (en) | Pad dyeing method of alginate fiber/polyester fiber blended fabric | |
| CN106939515B (en) | The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of production of denim fabric | |
| CN101736592B (en) | Method for fabricating color-absorbing cleaning pouches or cleaning strips for washing machines | |
| CN105040485A (en) | Environmental-friendly dyeing and finishing process of real silk fabric | |
| CN109355952A (en) | A kind of dyeing of cotton | |
| CN105821683A (en) | Method for preventing printing-free areas of positive-ion-modified cotton fabric from staining | |
| CN108221413A (en) | Polyester-cotton fabric short route dyeing and finishing processing method | |
| CN113802391A (en) | Dyeing and finishing process of environment-friendly fluorine-free anti-siphon fabric | |
| WO2022262426A1 (en) | Process for dyeing and finishing recycled and regenerated high-density cool chinlon fabric | |
| CN114086406B (en) | Production process for improving left and right chromatic aberration of stock solution colored fabric | |
| CN103556508B (en) | The printing method of the viscose blended camouflage printing fabric of aramid fiber | |
| CN109629097B (en) | Antistatic light luxury worsted woolen fabric | |
| CN110952348A (en) | Processing method for improving dyeing depth of cation modified piece-dyed fabric | |
| CN114000364B (en) | Reactive digital printing pretreatment agent for pure cotton knitted fabric and preparation method thereof | |
| CN113062131B (en) | Short-flow processing technology for polyester-cotton knitted fabric | |
| CN107964812A (en) | A kind of modified cellulose fibre dyeing | |
| CN108396563B (en) | Process for pad dyeing of alginate fiber/cotton fiber blended fabric by polycarboxylic acid type macromolecular dye | |
| CN108330607B (en) | A kind of production method of terylene warp knitting nap discharge printing fabric | |
| CN110258115B (en) | Nano dedusting agent and preparation method and use method thereof | |
| CN109914129A (en) | A kind of clean fabric dyeing and printing process | |
| CN111549546A (en) | Dark continuous dyeing method for nylon-cotton blended fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190405 |