CN108483906A - The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention - Google Patents

The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention Download PDF

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Publication number
CN108483906A
CN108483906A CN201810453340.8A CN201810453340A CN108483906A CN 108483906 A CN108483906 A CN 108483906A CN 201810453340 A CN201810453340 A CN 201810453340A CN 108483906 A CN108483906 A CN 108483906A
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China
Prior art keywords
tempered glass
parts
preparation
fire prevention
mutually coordinated
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CN201810453340.8A
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Chinese (zh)
Inventor
朱明静
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Hefei Steel Glass Products Co Ltd
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Hefei Steel Glass Products Co Ltd
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Priority to CN201810453340.8A priority Critical patent/CN108483906A/en
Publication of CN108483906A publication Critical patent/CN108483906A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/29Mixtures
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/13Deposition methods from melts

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses the preparation methods that tempered glass is mutually coordinated in a kind of fire prevention of intensity, include the following steps:Step 1 weighs following corresponding weight percent raw material for standby:SiO232 38%, Al2O318 22%, MgO 8 16%, PbO 4 10%, BaO 2 6%, Fe 0.4 0.6%, Ti 0.2 0.4%, Cu 0.02 0.08%, graphene 2 4%, fire proofing additive 4 10%, 24 parts of strength aid, 13 parts of mischmetal mine.The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present invention, and the tempered glass intensity, fire protecting performance are excellent, has higher use value and good application prospect.

Description

The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention
Technical field
The present invention relates to tempered glass preparing technical fields, and in particular to the system of tempered glass is mutually coordinated in a kind of intensity fire prevention Preparation Method.
Background technology
Tempered glass belongs to safety glass, it is a kind of prestressed glass in fact, usually used to improve the intensity of glass Method chemically or physically forms compression in glass surface, and glass bears to offset skin stress first when external force, to improve Bearing capacity, reinforcing glass itself anti-wind pressure, cold and heat, impact etc., with product type and processing technology not Disconnected update, the application range of present tempered glass also become more and more extensive therewith, and usual tempered glass can be applied following Several industries:Building, building template, decoration industry (example:Door and window, curtain wall, interior decoration etc.);2, woodwork industry (glass Tea table, furniture are mating etc.);3, household electrical appliances manufacturing (products such as television set, oven, air-conditioning, refrigerator);4, electronics, instrument industry (a variety of digital products such as mobile phone, MP3, MP4, clock and watch);5, automobile manufacture industry (windshield etc.);6, everyday articles row Industry (glass chopping board etc.).
Tempered glass fire prevention, strength character are not very excellent in the prior art, it is therefore desirable to design a kind of intensity fire prevention phase The tempered glass of coordination.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide the preparations that tempered glass is mutually coordinated in a kind of fire prevention of intensity Method, the tempered glass intensity, fire protecting performance are excellent, have higher use value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that:
The present invention provides the preparation methods that tempered glass is mutually coordinated in a kind of fire prevention of intensity, include the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO232-38%, Al2O318-22%, MgO8- 16%, PbO 4-10%, BaO 2-6%, Fe 0.4-0.6%, Ti 0.2-0.4%, Cu 0.02-0.08%, graphene 2- 4%, fire proofing additive 4-10%, 2-4 parts of strength aid, 1-3 parts of mischmetal mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Preferably, fire proofing additive includes following raw material in the step 1:
32-38 parts of fire resistant resin, 24-28 parts of organic siliconresin, 14-20 parts of unsaturated polyester resin, 8-14 parts of pitch, 6-10 parts of rosin resin, 14-22 parts of mica powder, 4-8 parts of magnesium hydroxide, 6-10 parts of marble chips mountain flour, 3-5 parts of aluminium hydroxide.
Preferably, the fire resistant resin is polyimide resin.
Preferably, strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step 1:2 compositions
Preferably, mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step 1:2:1 composition Mixture.
Preferably, melting condition is that temperature is first risen to 550-650 DEG C in the step 2, keeps the temperature 25-35min, then Temperature is risen to 850-950 DEG C, melting 35-45min.
Preferably, it is 950-1050 DEG C that furnace temperature is melted in the step 2.
Preferably, it is 2-6mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step 2.
Compared with prior art, the present invention has following advantageous effect:
(1) preparation method of tempered glass, SiO are mutually coordinated in a kind of intensity of the invention fire prevention2、Al2O3、MgO、PbO、 BaO, Fe, Ti, Cu, graphene, mischmetal mine, fire proofing additive, strength aid raw material are by suitably matching, by multigroup reality Demonstration is tested, obtained tempered glass intensity, fire protecting performance is best, and fire proofing additive, strength aid are sprayed on slightly using spraying process On tempered glass, intensity, the fire line of tempered glass can be further improved.
(2) preparation method of tempered glass is mutually coordinated in a kind of intensity of the invention fire prevention, and fire proofing additive passes through several resistance to height Warm resin collocation, is helped with fire-proof packing, pitch, the rosin resin of addition make raw material adequately merge on glass, then prevent fires Effect further increases, and strength aid is the mixture of glass fibre, ceramic powder composition, can further improve the strong of tempered glass Degree.
(3) preparation method of tempered glass, tempered glass intensity, the fire line are mutually coordinated in a kind of intensity of the invention fire prevention Can be excellent, there is higher use value and good application prospect.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
Embodiment 1.
The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present embodiment, includes the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO232%, Al2O318%, MgO 8%, PbO 4%, BaO 2%, Fe 0.4%, Ti 0.2%, Cu 0.02%, graphene 2%, fire proofing additive 4%, 2 parts of strength aid, mixed Close 1 part of Rare Earth Mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Fire proofing additive includes following raw material in the step of the present embodiment one:
32 parts of fire resistant resin, 24 parts of organic siliconresin, 14 parts of unsaturated polyester resin, 8 parts of pitch, 6 parts of rosin resin, 14 parts of mica powder, 4 parts of magnesium hydroxide, 6 parts of marble chips mountain flour, 3 parts of aluminium hydroxide.
The fire resistant resin of the present embodiment is polyimide resin.
Strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step of the present embodiment one:2 compositions
Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step of the present embodiment one:2:1 composition Mixture.
Melting condition is that temperature is first risen to 550 DEG C in the step of the present embodiment two, 25min is kept the temperature, then by temperature liter To 850 DEG C, melting 35min.
It is 950 DEG C that furnace temperature is melted in the step of the present embodiment two.
It is 2mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step of the present embodiment two.
Embodiment 2.
The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present embodiment, includes the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO238%, Al2O322%, MgO 16%, PbO 10%, BaO 6%, Fe 0.6%, Ti 0.4%, Cu 0.08%, graphene 4%, fire proofing additive 10%, 4 parts of strength aid, 3 parts of mischmetal mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Fire proofing additive includes following raw material in the step of the present embodiment one:
38 parts of fire resistant resin, 28 parts of organic siliconresin, 20 parts of unsaturated polyester resin, 14 parts of pitch, rosin resin 10 Part, 22 parts of mica powder, 8 parts of magnesium hydroxide, 10 parts of marble chips mountain flour, 5 parts of aluminium hydroxide.
The fire resistant resin of the present embodiment is polyimide resin.
Strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step of the present embodiment one:2 compositions
Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step of the present embodiment one:2:1 composition Mixture.
Melting condition is that temperature is first risen to 650 DEG C in the step of the present embodiment two, 35min is kept the temperature, then by temperature liter To 950 DEG C, melting 45min.
It is 1050 DEG C that furnace temperature is melted in the step of the present embodiment two.
It is 6mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step of the present embodiment two.
Embodiment 3.
The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present embodiment, includes the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO235%, Al2O320%, MgO 12%, PbO 7%, BaO 4%, Fe 0.5%, Ti 0.3%, Cu 0.05%, graphene 3%, fire proofing additive 7%, 3 parts of strength aid, mixed Close 2 parts of Rare Earth Mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Fire proofing additive includes following raw material in the step of the present embodiment one:
35 parts of fire resistant resin, 26 parts of organic siliconresin, 17 parts of unsaturated polyester resin, 11 parts of pitch, rosin resin 8 Part, 18 parts of mica powder, 6 parts of magnesium hydroxide, 8 parts of marble chips mountain flour, 4 parts of aluminium hydroxide.
The fire resistant resin of the present embodiment is polyimide resin.
Strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step of the present embodiment one:2 compositions
Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step of the present embodiment one:2:1 composition Mixture.
Melting condition is that temperature is first risen to 600 DEG C in the step of the present embodiment two, 30min is kept the temperature, then by temperature liter To 900 DEG C, melting 40min.
It is 1000 DEG C that furnace temperature is melted in the step of the present embodiment two.
It is 4mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step of the present embodiment two.
Embodiment 4.
The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present embodiment, includes the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO230%, Al2O316%, MgO 6%, PbO 3%, BaO 1%, Fe 0.3%, Ti 0.1%, Cu 0.01%, graphene 1%, fire proofing additive 3%, 1 part of strength aid, mixed Close 0.5 part of Rare Earth Mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Fire proofing additive includes following raw material in the step of the present embodiment one:
30 parts of fire resistant resin, 22 parts of organic siliconresin, 12 parts of unsaturated polyester resin, 6 parts of pitch, 4 parts of rosin resin, 12 parts of mica powder, 2 parts of magnesium hydroxide, 4 parts of marble chips mountain flour, 2 parts of aluminium hydroxide.
The fire resistant resin of the present embodiment is polyimide resin.
Strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step of the present embodiment one:2 compositions
Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step of the present embodiment one:2:1 composition Mixture.
Melting condition is that temperature is first risen to 500 DEG C in the step of the present embodiment two, 20min is kept the temperature, then by temperature liter To 800 DEG C, melting 30min.
It is 900 DEG C that furnace temperature is melted in the step of the present embodiment two.
It is 1.5mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step of the present embodiment two.
Embodiment 5.
The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention of the present embodiment, includes the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO240%, Al2O320%, MgO 18%, PbO 12%, BaO 8%, Fe 0.8%, Ti 0.6%, Cu 0.10%, graphene 6%, fire proofing additive 12%, 6 parts of strength aid, 4 parts of mischmetal mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine mixing Melting is carried out after uniformly, cast molding in mold is subsequently sent to, obtains thick tempered glass, and fire proofing additive, strength aid are sent into It is melted in melting furnace, obtains spray coating liquor A, be then sprayed on thick tempered glass using spraying process, is cooled to room temperature to get this The tempered glass of invention.
Fire proofing additive includes following raw material in the step of the present embodiment one:
40 parts of fire resistant resin, 30 parts of organic siliconresin, 22 parts of unsaturated polyester resin, 16 parts of pitch, rosin resin 12 Part, 24 parts of mica powder, 10 parts of magnesium hydroxide, 12 parts of marble chips mountain flour, 6 parts of aluminium hydroxide.
The fire resistant resin of the present embodiment is polyimide resin.
Strength aid is glass fibre, ceramic powder according to weight ratio 3 in the step of the present embodiment one:2 compositions
Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in the step of the present embodiment one:2:1 composition Mixture.
Melting condition is that temperature is first risen to 700 DEG C in the step of the present embodiment two, 40min is kept the temperature, then by temperature liter To 1000 DEG C, melting 50min.
It is 1100 DEG C that furnace temperature is melted in the step of the present embodiment two.
It is 8mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in the step of the present embodiment two.
Embodiment 1-5 is some experimental data of the present invention, and the present invention passes through a large amount of experimental demonstration, a kind of intensity fire prevention Mutually coordinate the preparation method of tempered glass, the tempered glass intensity, fire protecting performance are excellent, have higher use value and good Good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (8)

1. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention, which is characterized in that include the following steps:
Step 1 weighs following corresponding weight percent raw material for standby:SiO232-38%, Al2O318-22%, MgO 8- 16%, PbO 4-10%, BaO 2-6%, Fe 0.4-0.6%, Ti 0.2-0.4%, Cu 0.02-0.08%, graphene 2- 4%, fire proofing additive 4-10%, 2-4 parts of strength aid, 1-3 parts of mischmetal mine;
Step 2, by SiO in step 12、Al2O3, MgO, PbO, BaO, Fe, Ti, Cu, graphene, mischmetal mine be uniformly mixed After carry out melting, be subsequently sent to cast molding in mold, obtain thick tempered glass, by fire proofing additive, strength aid be sent into fusing It is melted in stove, obtains spray coating liquor A, be then sprayed on thick tempered glass, be cooled to room temperature to get the present invention using spraying process Tempered glass.
2. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described Fire proofing additive includes following raw material in step 1:
32-38 parts of fire resistant resin, 24-28 parts of organic siliconresin, 14-20 parts of unsaturated polyester resin, 8-14 parts of pitch, rosin 6-10 parts of resin, 14-22 parts of mica powder, 4-8 parts of magnesium hydroxide, 6-10 parts of marble chips mountain flour, 3-5 parts of aluminium hydroxide.
3. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 2, which is characterized in that described Fire resistant resin is polyimide resin.
4. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described Strength aid is glass fibre, ceramic powder according to weight ratio 3 in step 1:2 compositions.
5. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described Mischmetal mine is xenotime, fluorite, huge sum of money stone according to weight ratio 7 in step 1:2:The mixture of 1 composition.
6. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described Melting condition is that temperature is first risen to 550-650 DEG C in step 2, keeps the temperature 25-35min, temperature is then risen to 850-950 DEG C, Melting 35-45min.
7. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described It is 950-1050 DEG C that furnace temperature is melted in step 2.
8. the preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention according to claim 1, which is characterized in that described It is 2-6mm that spray coating liquor A, which is sprayed on thickness on thick tempered glass, in step 2.
CN201810453340.8A 2018-05-14 2018-05-14 The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention Withdrawn CN108483906A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149176A (en) * 2021-12-31 2022-03-08 莱芜连云玻璃股份有限公司 Method for manufacturing high-strength toughened glass

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唐磊等: "《耐高温隔热材料技术》", 31 July 2013, 国防工业出版社 *
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149176A (en) * 2021-12-31 2022-03-08 莱芜连云玻璃股份有限公司 Method for manufacturing high-strength toughened glass

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Application publication date: 20180904