CN114149176A - Method for manufacturing high-strength toughened glass - Google Patents
Method for manufacturing high-strength toughened glass Download PDFInfo
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- CN114149176A CN114149176A CN202111674304.2A CN202111674304A CN114149176A CN 114149176 A CN114149176 A CN 114149176A CN 202111674304 A CN202111674304 A CN 202111674304A CN 114149176 A CN114149176 A CN 114149176A
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- wollastonite
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- 239000005341 toughened glass Substances 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 55
- 238000003756 stirring Methods 0.000 claims abstract description 49
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000010456 wollastonite Substances 0.000 claims abstract description 42
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 238000005507 spraying Methods 0.000 claims abstract description 34
- 238000003723 Smelting Methods 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 31
- 239000000440 bentonite Substances 0.000 claims abstract description 29
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 29
- 239000002131 composite material Substances 0.000 claims abstract description 25
- 238000005406 washing Methods 0.000 claims abstract description 23
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000010922 glass waste Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims abstract description 8
- 238000007493 shaping process Methods 0.000 claims abstract description 8
- 238000002791 soaking Methods 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000007921 spray Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims description 66
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 44
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 22
- 239000003822 epoxy resin Substances 0.000 claims description 21
- 229920000647 polyepoxide Polymers 0.000 claims description 21
- 238000011282 treatment Methods 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- 229920001661 Chitosan Polymers 0.000 claims description 14
- 229910021389 graphene Inorganic materials 0.000 claims description 14
- 238000002715 modification method Methods 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 11
- 229960000583 acetic acid Drugs 0.000 claims description 7
- 239000012362 glacial acetic acid Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 description 6
- 239000005336 safety glass Substances 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a method for manufacturing high-strength toughened glass, which comprises the following steps: firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 1-5%, soaking, washing with water and drying; secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 1-3% of bentonite composite modified graphene material in the total amount of the smelting materials; step three, cooling and shaping are carried out, and then the mixture is reserved; step four, adding the mixture into a mixer, stirring at the rotation speed of 200 and 500r/min for 1-2h to obtain a spray coating; and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 1-3mm, and drying for later use after spraying. The invention adopts the glass waste material to prepare the product, and the strength performance of the product is improved by adding the modified wollastonite and bentonite composite modified graphene material.
Description
Technical Field
The invention relates to the technical field of toughened glass, in particular to a manufacturing method of high-strength toughened glass.
Background
The toughened glass belongs to safety glass. The tempered glass is actually prestressed glass, and in order to improve the strength of the glass, a chemical or physical method is usually used to form compressive stress on the surface of the glass, and the glass firstly counteracts surface stress when bearing external force, so that the bearing capacity is improved, and the wind pressure resistance, the cold and hot property, the impact property and the like of the glass are enhanced. The bearing capacity of the toughened glass is increased, the brittleness is improved, small fragments without acute angles are formed even if the toughened glass is damaged, and the damage to a human body is greatly reduced. Is one of safety glass. The safety of qualified materials is guaranteed for high-rise buildings.
The existing tempered glass has poor strength and performance, is easy to damage and influences the service life of the glass, and therefore the invention provides the manufacturing method of the high-strength tempered glass.
Disclosure of Invention
The invention aims to provide a method for manufacturing high-strength toughened glass, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
a method for manufacturing high-strength toughened glass comprises the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 1-5%, soaking, washing with water and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 1-3% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotation speed of 200 and 500r/min for 1-2h to obtain a spray coating;
and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 1-3mm, and drying for later use after spraying.
Preferably, the modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture for stirring treatment, then adding activated bentonite accounting for 1-2 times of the total amount of the graphene, grinding in a grinding machine, grinding at 500-;
preparing 1-3% of chitosan solution by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into 2 times of the chitosan solution for stirring and dispersing treatment, and after stirring, washing and drying to obtain the bentonite composite modified graphene material.
Preferably, the rotation speed of the stirring dispersion treatment is 100-500r/min, and the stirring time is 20-30 min.
Preferably, the rotating speed of the stirring dispersion treatment is 300r/min, and the stirring time is 25 min.
Preferably, the activated bentonite is calcined in a calcining furnace at the temperature of 600-800 ℃, then air-cooled to 150-200 ℃, and then oil-cooled to room temperature.
Preferably, the modification method of the modified wollastonite is as follows: and (2) sending the wollastonite into a grinding machine for grinding at the grinding speed of 500-1000r/min for 10-20min, then adding the nano calcium carbonate, continuing grinding for 20-30min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
Preferably, the addition amount of the nano calcium carbonate is 10-20% of the wollastonite.
Preferably, the particle diameter of the nano calcium carbonate is 5-10 nm.
Preferably, the mixture is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to the weight ratio of 1: 5.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the product is prepared from the glass waste material, the strength performance of the product is improved by adding the modified wollastonite and bentonite composite modified graphene material, the spraying material is formed by matching with the mixture, and the spraying material is sprayed on the toughened glass, so that the strength performance of the prepared toughened glass can be obviously improved; the modification method of the modified wollastonite comprises the following steps: the wollastonite is sent into a grinding machine for grinding, the grinding speed is 500-1000r/min, the grinding time is 10-20min, then the nano calcium carbonate is added, the grinding is continued for 20-30min, the grinding is finished, the water washing and the drying are carried out, the modified wollastonite is obtained, the modified wollastonite has high activity and is easier to be matched with recycled materials, and meanwhile, the bentonite is matched with the modified graphene material in a composite mode, so that the overall performance of the product is improved.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below with reference to specific embodiments, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The manufacturing method of the high-strength tempered glass comprises the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 1-5%, soaking, washing with water and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 1-3% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotation speed of 200 and 500r/min for 1-2h to obtain a spray coating;
and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 1-3mm, and drying for later use after spraying.
The modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture for stirring treatment, then adding activated bentonite accounting for 1-2 times of the total amount of the graphene, grinding in a grinding machine, grinding at 500-;
preparing 1-3% of chitosan solution by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into 2 times of the chitosan solution for stirring and dispersing treatment, and after stirring, washing and drying to obtain the bentonite composite modified graphene material.
The rotation speed of the stirring dispersion treatment in this embodiment is 100-500r/min, and the stirring time is 20-30 min.
The rotation speed of the stirring dispersion treatment in this example was 300r/min, and the stirring time was 25 min.
The activated bentonite in the embodiment is calcined in a calcining furnace at the calcining temperature of 600-800 ℃, then air-cooled to 150-200 ℃, and finally oil-cooled to room temperature.
The modification method of the modified wollastonite in this example is as follows: and (2) sending the wollastonite into a grinding machine for grinding at the grinding speed of 500-1000r/min for 10-20min, then adding the nano calcium carbonate, continuing grinding for 20-30min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
The addition amount of the nano calcium carbonate in the embodiment is 10-20% of the wollastonite.
The particle diameter of the nano calcium carbonate of the embodiment is 5-10 nm.
The mixture of the embodiment is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
Example 1:
the manufacturing method of the high-strength tempered glass comprises the following steps:
firstly, feeding the glass waste into a sodium carbonate solution with the mass fraction of 1% for soaking, washing and drying;
secondly, feeding the materials into a smelting furnace for smelting till the materials are completely smelted, and adding 1% of modified wollastonite and 1% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotating speed of 200r/min for 1h to obtain a spray coating;
and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 1mm, and drying for later use after spraying.
The modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture for stirring treatment, then adding activated bentonite accounting for 1 time of the total amount of the graphene, grinding in a grinding machine, grinding for 500-;
preparing a chitosan solution with the mass fraction of 1% by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into the chitosan solution with the mass fraction of 2 times, stirring and dispersing, and washing and drying after stirring to obtain the bentonite composite modified graphene material.
The rotation speed of the stirring dispersion treatment in this example was 100r/min, and the stirring time was 20 min.
Activated bentonite according to this example bentonite was calcined by feeding it into a calciner at 600 c, then air cooled to 150 c, and then oil cooled to room temperature.
The modification method of the modified wollastonite in this example is as follows: and (2) feeding wollastonite into a grinding machine for grinding at the grinding speed of 500r/min for 10min, then adding nano calcium carbonate, continuing grinding for 20min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
The addition amount of the nano calcium carbonate in the embodiment is 10 percent of wollastonite.
The particle diameter of the nano calcium carbonate of the present example is 5 nm.
The mixture of the embodiment is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
Example 2:
the manufacturing method of the high-strength tempered glass comprises the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 5%, soaking, washing and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 3% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring for 2 hours at a rotating speed of 500r/min to obtain a spray coating;
and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 3mm, and drying for later use after spraying.
The modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture for stirring treatment, then adding activated bentonite accounting for 1-2 times of the total amount of the graphene, grinding in a grinder for 1000r/min, and finishing grinding;
preparing a chitosan solution with the mass fraction of 3% by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into the chitosan solution with the mass fraction of 2 times, stirring and dispersing, and washing and drying after stirring to obtain the bentonite composite modified graphene material.
The rotation speed of the stirring dispersion treatment in this example was 500r/min, and the stirring time was 30 min.
Activated bentonite according to this example bentonite was calcined by feeding it into a calciner at 800 c, then air cooled to 200 c and then oil cooled to room temperature.
The modification method of the modified wollastonite in this example is as follows: and (2) feeding wollastonite into a grinding machine for grinding at the grinding speed of 1000r/min for 20min, then adding nano calcium carbonate, continuing grinding for 30min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
The addition amount of the nano calcium carbonate in the embodiment is 20% of the wollastonite.
The particle diameter of the nano calcium carbonate of the present example was 10 nm.
The mixture of the embodiment is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
Example 3:
the manufacturing method of the high-strength tempered glass comprises the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 3%, soaking, washing with water, and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 1-3% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotating speed of 350r/min for 1.5h to obtain a spray coating;
and fifthly, spraying the spray paint on the toughened glass, wherein the spraying thickness is 2mm, and drying for later use after spraying.
The modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture, stirring, adding activated bentonite accounting for 1.5 times of the total amount of the graphene, grinding in a grinder at 600r/min, and finishing grinding;
preparing a chitosan solution with the mass fraction of 2% by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into the chitosan solution with the mass fraction of 2 times to carry out stirring dispersion treatment, and after stirring, washing and drying to obtain the bentonite composite modified graphene material.
The rotation speed of the stirring dispersion treatment in this example was 300r/min, and the stirring time was 25 min.
Activated bentonite according to this example bentonite was calcined by feeding it into a calciner at 700 c, then air cooled to 175 c, and then oil cooled to room temperature.
The modification method of the modified wollastonite in this example is as follows: and (2) feeding wollastonite into a grinding machine for grinding at the grinding speed of 750r/min for 15min, then adding nano calcium carbonate, continuing grinding for 25min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
The addition amount of the nano calcium carbonate in the embodiment is 15% of the wollastonite.
The particle diameter of the nano calcium carbonate of the present example was 7.5 nm.
The mixture of the embodiment is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
Example 4:
the manufacturing method of the high-strength tempered glass comprises the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 2%, soaking, washing with water, and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 2% of modified wollastonite and 1.2% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotating speed of 220r/min for 1.2h to obtain a spray coating;
and fifthly, spraying the spray paint on the toughened glass, wherein the spraying thickness is 1.2mm, and drying for later use after spraying.
The modification method of the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture, stirring, adding activated bentonite accounting for 1.2 times of the total amount of the graphene, grinding in a grinder at 600r/min, and finishing grinding;
preparing a chitosan solution with the mass fraction of 1.2% by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into the chitosan solution with the mass fraction of 2 times to carry out stirring and dispersing treatment, and washing and drying after stirring to obtain the bentonite composite modified graphene material.
The rotation speed of the stirring dispersion treatment in this example was 200r/min, and the stirring time was 22 min.
Activated bentonite according to this example bentonite was calcined by feeding it into a calciner at 650 c, then air cooled to 160 c, and then oil cooled to room temperature.
The modification method of the modified wollastonite in this example is as follows: and (2) feeding wollastonite into a grinding machine for grinding at the grinding speed of 600r/min for 12min, then adding nano calcium carbonate, continuing grinding for 22min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
The addition amount of the nano calcium carbonate in the embodiment is 12 percent of the wollastonite.
The particle diameter of the nano calcium carbonate of the embodiment is 6 nm.
The mixture of the embodiment is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (9)
1. The manufacturing method of the high-strength toughened glass is characterized by comprising the following steps:
firstly, feeding the glass waste material into a sodium carbonate solution with the mass fraction of 1-5%, soaking, washing with water and drying;
secondly, feeding the mixture into a smelting furnace for smelting till the smelting is complete, and adding 1-5% of modified wollastonite and 1-3% of bentonite composite modified graphene material in the total amount of the smelting materials;
step three, cooling and shaping are carried out, and then the mixture is reserved;
step four, adding the mixture into a mixer, stirring at the rotation speed of 200 and 500r/min for 1-2h to obtain a spray coating;
and fifthly, spraying the spray paint onto the toughened glass, wherein the spraying thickness is 1-3mm, and drying for later use after spraying.
2. The method for manufacturing the high-strength toughened glass according to claim 1, wherein the method for modifying the bentonite composite modified graphene material comprises the following steps:
feeding graphene into the mixture for stirring treatment, then adding activated bentonite accounting for 1-2 times of the total amount of the graphene, grinding in a grinding machine, grinding at 500-;
preparing 1-3% of chitosan solution by adopting glacial acetic acid with the mass fraction of 2%, then adding the grinding material into 2 times of the chitosan solution for stirring and dispersing treatment, and after stirring, washing and drying to obtain the bentonite composite modified graphene material.
3. The method as claimed in claim 2, wherein the rotation speed of the stirring dispersion process is 100-500r/min, and the stirring time is 20-30 min.
4. The method for manufacturing a high-strength tempered glass according to claim 3, wherein the rotation speed of the stirring dispersion treatment is 300r/min, and the stirring time is 25 min.
5. The method as claimed in claim 2, wherein the activated bentonite is calcined in a calcining furnace at 600-800 ℃, then air-cooled to 150-200 ℃, and then oil-cooled to room temperature.
6. The method for manufacturing the high-strength toughened glass according to claim 5, wherein the modification method of the modified wollastonite comprises the following steps: and (2) sending the wollastonite into a grinding machine for grinding at the grinding speed of 500-1000r/min for 10-20min, then adding the nano calcium carbonate, continuing grinding for 20-30min, and after grinding is finished, washing and drying to obtain the modified wollastonite.
7. The method for manufacturing high-strength toughened glass according to claim 6, wherein the addition amount of the nano calcium carbonate is 10-20% of wollastonite.
8. The method of claim 6, wherein the nano calcium carbonate has a particle diameter of 5 to 10 nm.
9. The method for manufacturing the high-strength toughened glass according to claim 1, wherein the mixture is an epoxy resin solution, and the epoxy resin solution is prepared from epoxy resin and acetone according to a weight ratio of 1: 5.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111674304.2A CN114149176A (en) | 2021-12-31 | 2021-12-31 | Method for manufacturing high-strength toughened glass |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111674304.2A CN114149176A (en) | 2021-12-31 | 2021-12-31 | Method for manufacturing high-strength toughened glass |
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| CN202111674304.2A Pending CN114149176A (en) | 2021-12-31 | 2021-12-31 | Method for manufacturing high-strength toughened glass |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101226255A (en) * | 2007-01-19 | 2008-07-23 | 厦门特朗诗眼镜有限公司 | Method for producing tempered glass polarizing lens |
| CN107986617A (en) * | 2017-12-27 | 2018-05-04 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of abrasion-resistance glass cup preparation process |
| CN108129024A (en) * | 2018-01-24 | 2018-06-08 | 合肥万之景门窗有限公司 | A kind of heat-resisting antifog tempered glass of door and window |
| CN108275877A (en) * | 2018-03-01 | 2018-07-13 | 合肥利裕泰玻璃制品有限公司 | A kind of counnter attack alkali high-temperature-resistant high glass and preparation method thereof |
| CN108483906A (en) * | 2018-05-14 | 2018-09-04 | 合肥钢骨玻璃制品有限公司 | The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention |
| CN110950534A (en) * | 2019-12-10 | 2020-04-03 | 刘新友 | Glass insulator material and preparation method thereof |
| CN111333341A (en) * | 2018-12-19 | 2020-06-26 | Oppo广东移动通信有限公司 | Battery cover, mobile terminal and manufacturing method of battery cover |
| CN111943525A (en) * | 2020-07-04 | 2020-11-17 | 上海博迪装饰材料有限公司 | Preparation process of dustproof toughened glass |
-
2021
- 2021-12-31 CN CN202111674304.2A patent/CN114149176A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101226255A (en) * | 2007-01-19 | 2008-07-23 | 厦门特朗诗眼镜有限公司 | Method for producing tempered glass polarizing lens |
| CN107986617A (en) * | 2017-12-27 | 2018-05-04 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of abrasion-resistance glass cup preparation process |
| CN108129024A (en) * | 2018-01-24 | 2018-06-08 | 合肥万之景门窗有限公司 | A kind of heat-resisting antifog tempered glass of door and window |
| CN108275877A (en) * | 2018-03-01 | 2018-07-13 | 合肥利裕泰玻璃制品有限公司 | A kind of counnter attack alkali high-temperature-resistant high glass and preparation method thereof |
| CN108483906A (en) * | 2018-05-14 | 2018-09-04 | 合肥钢骨玻璃制品有限公司 | The preparation method of tempered glass is mutually coordinated in a kind of intensity fire prevention |
| CN111333341A (en) * | 2018-12-19 | 2020-06-26 | Oppo广东移动通信有限公司 | Battery cover, mobile terminal and manufacturing method of battery cover |
| CN110950534A (en) * | 2019-12-10 | 2020-04-03 | 刘新友 | Glass insulator material and preparation method thereof |
| CN111943525A (en) * | 2020-07-04 | 2020-11-17 | 上海博迪装饰材料有限公司 | Preparation process of dustproof toughened glass |
Non-Patent Citations (2)
| Title |
|---|
| 何志军 等: "《微波冶金新技术》", 30 September 2017, 北京：冶金工业出版社 * |
| 李华: "《主要包装物特性与资源再生实用手册》", 31 October 2010, 北京：中国环境科学出版社 * |
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