CN108465122A - A kind of graphene anion tea perfume device - Google Patents

A kind of graphene anion tea perfume device Download PDF

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Publication number
CN108465122A
CN108465122A CN201810516578.0A CN201810516578A CN108465122A CN 108465122 A CN108465122 A CN 108465122A CN 201810516578 A CN201810516578 A CN 201810516578A CN 108465122 A CN108465122 A CN 108465122A
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China
Prior art keywords
parts
graphene
inner cylinder
coating
anion
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Chinese (zh)
Inventor
秦建
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Jinan District Of Fuzhou City Tian Fang Electronic Products Co Ltd
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Jinan District Of Fuzhou City Tian Fang Electronic Products Co Ltd
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Priority to CN201810516578.0A priority Critical patent/CN108465122A/en
Publication of CN108465122A publication Critical patent/CN108465122A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultra-violet radiation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/12Apparatus, e.g. holders, therefor
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22Ionisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0028Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions provided with antibacterial or antifungal means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0036Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The present invention relates to a kind of graphene anion tea perfume devices, it includes shell, inner cylinder and cover assembly, the cover assembly removably covers the opening closed and be equipped at the top of inner cylinder, cover assembly has air inlet able to turn on or off, tea stalk is filled in the inner cylinder, the inner cylinder is mounted on by fixing piece gap in shell, gap between inner tank theca and inner walls forms wind chamber, gap between inner cylinder top and shell top edge forms air outlet, and inner cylinder bottom is equipped with the wind turbine for air in inner cylinder to be drained into wind chamber;The inner cylinder is equipped with heater, and the surface of shell is equipped with graphene anion coating, and inner cylinder inner wall is equipped with antimycotic antiseptic coating.

Description

A kind of graphene anion tea perfume device
Technical field
The present invention relates to a kind of graphene anion tea perfume devices.
Background technology
The fragrance of plant can calm nerves, loosen mood effect, volatility odoramentum drifts in air, penetrates Smell, to people generate it is pleasant, loosen, stimulating effect, also capable of purifying air, sterilization eliminates the unusual smell and calmness and other effects.For this purpose, market There is various kind of sample substitute, e.g., chemical synthesis essential oil, air freshener etc. flood market, it is clear that not as good as natural plants friend It is good.Rich in tea polyphenols etc. in the fragrance of tea, calmness can be played, loosen, restoring consciouness, eliminate the unusual smell, resisting by being absorbed by olfactory organ and skin Bacterium and other effects.
Invention content
It is simple in structure the purpose of the present invention is to provide a kind of reasonable design, the strong graphene of air purification ability bear from Sub- tea perfume device.
To achieve the above object, the present invention uses following technical scheme:
A kind of graphene anion tea perfume device comprising shell, inner cylinder and cover assembly, the cover assembly removably cover conjunction The opening being equipped at the top of inner cylinder, cover assembly have air inlet able to turn on or off, and tea stalk is filled in the inner cylinder, described interior Cylinder is mounted on by fixing piece gap in shell, and gap between inner tank theca and inner walls forms wind chamber, inner cylinder top with Gap between shell top edge forms air outlet, and inner cylinder bottom is equipped with the wind turbine for air in inner cylinder to be drained into wind chamber;Institute It states surface of shell and is equipped with graphene anion coating, inner cylinder inner wall is equipped with antimycotic antiseptic coating.
Preferably, the cover assembly includes for covering the cover board closed in opening, air inlet is opened in the middle part of cover board, Cover board lower surface is equipped with tray deck, has air intake passage between cover board lower surface and tray deck upper surface, and tray deck, which is equipped with, to be used In the upper cover for opening and closing air inlet.
Preferably, be equipped with ultraviolet radiator in the air intake passage, cover board lower surface and inner cylinder contact position set that there are two fixed Position groove, is respectively equipped with a sheet metal in two positioning grooves, two sheet metals respectively with the anode of ultraviolet radiator and negative electricity Connection, inner cylinder top edge are set there are two metal thimble, and what two metal thimbles can contact respective metal piece respectively is plugged on two In positioning groove.
Preferably, the cover assembly further includes elevating lever, gear and micromotor, elevating lever upper end and top cap It connects, elevating lever lower end is equipped with rack and pinion engagement connection, and gear is driven by micromotor and rotated, to drive top cover lifting to open Close air inlet.The design is by micromotor positive and negative rotation, band moving gear positive and negative rotation, with band carry-over bar and lifter rod lifting, To drive top cover lifting to open and close in air inlet.
Preferably, the cover assembly is interior or inner cylinder is equipped with heater.The design can be by heating Cylinder side wall is to heat tea stalk, to strengthen tea stalk effect.
Preferably, the distance between inner cylinder top and shell top edge are 3-10mm.
Further, more than a position in the air inlet and inner cylinder bottom it is equipped with graphene filter layer;
The graphene filter layer includes following components and its parts by weight:
100 parts of aqueous polyurethane;
0.5-1.5 parts of graphene oxide;
0.1-1.5 parts of nanometer titanium dioxide carbon;
0.3-2 parts of 3- aminopropyl triethoxysilanes;
Wherein, the solid content of the aqueous polyurethane is 29-31 weight %, and viscosity is 24-26 mPas, pH value 7.5- 8.5;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, with 1500-2000 revs/min Speed clipping stirs 20 minutes, obtains batch mixing;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1000-1500 revs/min of speed clipping, obtains graphite Alkene coating;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 50-60 DEG C, obtains graphene filter layer;Wherein, porous base Material is porous, expanded plastics, non-woven fabrics or fiber filter cotton.
Preferably, the graphene anion coating includes following components and its parts by weight:
5-8 parts of graphene negative ion powder;
25-40 parts of feldspar;
10-25 parts of calcite;
20-30 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
15-25 parts of tourmaline;
65-80 parts of nano-cerium oxide;
1-5 parts of graphene;
1-3 parts of nano-titanium dioxide.
Preferably, the graphene anion coating includes the following steps in the forming method of surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
Preferably, being equipped with graphene anion coating in the housing exterior walls and inner walls.
Preferably, the antimycotic antiseptic coating includes following components and its parts by weight:
10-40 parts of acrylic acid ester emulsion;
0.05-1.5 parts of mould inhibitor;
2-6 parts of silver-based inorganic antibacterial agent;
5-10 parts of nano-titanium dioxide;
0.5-2 parts of graphene;
15-35 parts of precipitated calcium carbonate;
10-30 parts of powdered whiting;
2-4 parts of dispersant;
0.5-4 parts of coalescents;
0.05-1.5 parts of antifoaming agent;
1-2 parts of wetting agent;
0.5-2 parts of pH adjusting agent;
10-55 parts of deionized water.
Preferably, forming method of the antimycotic antiseptic coating on inner cylinder inner wall, includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
Preferably, the mould inhibitor is dichlofluanid or thiabendazole;The dispersant is polyacrylic acid sodium salt;Institute It is Lauryl Alcohol ester or pentanediol mono isobutyrate to state coalescents;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether; The wetting agent is nonionic polyoxyalkylene modifying agent.
The present invention uses above technical scheme, when cover assembly lid is closed the opening being equipped at the top of inner cylinder, on inner cylinder Two metal thimbles that edge is equipped with, respectively contraposition are plugged in two positioning grooves, not only act as the effect of positioning, Er Qiejin Belong to thimble to contact with respective metal piece in positioning groove, also acts as the effect conducted;In use, being powered and starting wind turbine, wind Machine works so that generating negative pressure in inner cylinder, drive air enters from cover board intaking air at middle part mouth, and sequentially approach air intake passage, inner cylinder It is discharged from air outlet with after wind chamber;Period, the ultraviolet radiator being equipped in air intake passage can not only sterilize air, and And the setting of its position can cause beneficiating ingredient in tea stalk to be destroyed to avoid ultraviolet light direct irradiation on tea stalk;In inner cylinder Tea stalk has very strong adsorption capacity, can carry out physisorptive filter to air, cross the pollutants such as the dust in air filtering, The fragrance such as tea polyphenols can not only be discharged, as air-flow is to external diffusion, purify air, environmentally protective, cost is relatively low;On inner cylinder inner wall The antimycotic antiseptic coating being equipped with, can not only improve tea stalk storage environment, avoid tea stalk mouldy, and go out with excellent sterilization Bacterium acts on;The graphene anion coating that inner walls are equipped with can discharge anion to wind chamber, and anion is in fan action Under drained into ambient atmosphere from air outlet with air-flow, purify air, and the graphene that housing exterior walls are equipped with to provide high quality Anion coating can directly discharge in anion to ambient atmosphere;The design of graphene filter layer can give full play to The excellent adsorption capacity of graphene and decontamination effect, and cross air filtering when can kill air in harmful bacteria.
Description of the drawings
In conjunction with attached drawing, the present invention is further elaborated:
Fig. 1 is the structural schematic diagram of graphene anion tea perfume device of the present invention;
Fig. 2 is partial enlarged view at A in figure;
Fig. 3 is the circuit connection diagram of graphene anion tea perfume device of the present invention.
Specific implementation mode
As shown in one of Fig. 1-3, graphene anion tea perfume device of the invention comprising shell 1, inner cylinder 2 and upper cover group Part 3, removably lid closes the opening being equipped at the top of inner cylinder 2 to the cover assembly 3, cover assembly 3 have it is able to turn on or off into Air port 41, the inner cylinder 2 is interior to be filled with tea stalk 5, and the inner cylinder 2 is mounted on by 6 gap of fixing piece in shell 1,2 outer wall of inner cylinder Gap between 1 inner wall of shell forms wind chamber 42, and the gap between 1 top edge of 2 top of inner cylinder and shell forms air outlet 43, 2 bottom of inner cylinder is equipped with the wind turbine 44 for air in inner cylinder 2 to be drained into wind chamber 42;1 surface of the shell equipped with graphene bear from Sub- coating 11,2 inner wall of inner cylinder are equipped with antimycotic antiseptic coating 21.
Preferably, the fixing piece 6 is bolt.
Preferably, the cover assembly 3 includes for covering the cover board 31 closed in opening, air inlet 41 is opened in cover board 31 middle parts, 31 lower surface of cover board are equipped with tray deck 32, have air intake passage between 32 upper surface of 31 lower surface of cover board and tray deck 45, tray deck 32 is equipped with the upper cover 33 for opening and closing air inlet 41.
Preferably, ultraviolet radiator 8 can also be equipped in the air intake passage 45,31 lower surface of cover board connects with inner cylinder 2 Synapsis is set there are two positioning groove 34, is respectively equipped with a sheet metal 35 in two positioning grooves 34, two sheet metals 35 respectively with Anode and the cathode electrical connection of ultraviolet radiator 8,2 top edge of inner cylinder are set there are two metal thimble 22, and two metal thimbles 22 are distinguished Accessible respective metal piece 35 is plugged in two positioning grooves 34;Two metal thimbles 22 respectively with the anode of external power It is electrically connected with cathode.Or two metal thimbles 22 can also be arranged in 31 lower surface of cover board, by two 34 Hes of positioning groove Two settings of sheet metal 35 are electrically connected with the anode and cathode of external power respectively in 2 top edge of inner cylinder, two sheet metals 35.
Preferably, the cover assembly 3 further includes elevating lever 36, gear and micromotor 37,36 upper end of elevating lever It is connect with upper cover, 36 lower end of elevating lever is equipped with rack and pinion engagement connection, and gear is driven by micromotor 37 and rotated, with band Dynamic top cover lifting opens and closes air inlet.
Preferably, heater 7 can also be equipped in the cover assembly 3 or on inner cylinder 2.The design can By heating 2 side wall of inner cylinder to be heated to tea stalk 5, to strengthen 5 effect of tea stalk.
Preferably, the distance between 2 top of the inner cylinder and 1 top edge of shell are 3-10mm.
Further, more than position that can also be at the air inlet 41 and in 2 bottom of inner cylinder it is equipped with graphene mistake Filtering layer 9;
The graphene filter layer includes following components and its parts by weight:
100 parts of aqueous polyurethane;
0.5-1.5 parts of graphene oxide;
0.1-1.5 parts of nanometer titanium dioxide carbon;
0.3-2 parts of 3- aminopropyl triethoxysilanes;
Wherein, the solid content of the aqueous polyurethane is 29-31 weight %, and viscosity is 24-26 mPas, pH value 7.5- 8.5;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, with 1500-2000 revs/min Speed clipping stirs 20 minutes, obtains batch mixing;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1000-1500 revs/min of speed clipping, obtains graphite Alkene coating;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 50-60 DEG C, obtains graphene filter layer;Wherein, porous base Material is porous, expanded plastics, non-woven fabrics or fiber filter cotton.
Preferably, the graphene anion coating 11 includes following components and its parts by weight:
5-8 parts of graphene negative ion powder;
25-40 parts of feldspar;
10-25 parts of calcite;
20-30 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
15-25 parts of tourmaline;
65-80 parts of nano-cerium oxide;
1-5 parts of graphene;
1-3 parts of nano-titanium dioxide.
Preferably, the graphene anion coating 11 includes the following steps in the forming method on 1 surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
Preferably, being equipped with graphene anion coating 11 on 1 outer wall of the shell and inner wall.
Preferably, the antimycotic antiseptic coating 21 includes following components and its parts by weight:
10-40 parts of acrylic acid ester emulsion;
0.05-1.5 parts of mould inhibitor;
2-6 parts of silver-based inorganic antibacterial agent;
5-10 parts of nano-titanium dioxide;
0.5-2 parts of graphene;
15-35 parts of precipitated calcium carbonate;
10-30 parts of powdered whiting;
2-4 parts of dispersant;
0.5-4 parts of coalescents;
0.05-1.5 parts of antifoaming agent;
1-2 parts of wetting agent;
0.5-2 parts of pH adjusting agent;
10-55 parts of deionized water.
Preferably, forming method of the antimycotic antiseptic coating 21 on 2 inner wall of inner cylinder, includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
Preferably, the mould inhibitor is dichlofluanid or thiabendazole;The dispersant is polyacrylic acid sodium salt;Institute It is Lauryl Alcohol ester or pentanediol mono isobutyrate to state coalescents;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether; The wetting agent is nonionic polyoxyalkylene modifying agent.
The present invention uses above technical scheme, when the lid of cover assembly 3 is closed the opening being equipped at 2 top of inner cylinder, inner cylinder 2 Two metal thimbles 22 that top edge is equipped with, respectively contraposition are plugged in two positioning grooves 34, not only act as the effect of positioning, And metal thimble 22 is contacted with respective metal piece 35 in positioning groove 34, also acts as the effect conducted;In use, being powered simultaneously Starting wind turbine 44, wind turbine 44, which works, to generate negative pressure in inner cylinder 2, and air is driven to enter from 31 intaking air at middle part mouth 41 of cover board, and Sequentially it is discharged from air outlet 43 after approach air intake passage 45, inner cylinder 2 and wind chamber 42;Period is equipped in air intake passage 45 ultraviolet Line lamp 8 can not only sterilize air, but also the setting of its position can be led to avoid ultraviolet light direct irradiation on tea stalk 5 Beneficiating ingredient in tea stalk 5 is caused to be destroyed;Tea stalk 5 in inner cylinder 2 has very strong adsorption capacity, can carry out physics to air Adsorption filtration crosses the pollutants such as the dust in air filtering, can not only discharge the fragrance such as tea polyphenols, as air-flow is to external diffusion, only Change air, environmentally protective, cost is relatively low;The antimycotic antiseptic coating 21 that 2 inner wall of inner cylinder is equipped with can not only improve tea stalk 5 and deposit Environment is stored up, avoids tea stalk 5 mouldy, and there are excellent sterilization sterilization functions;The graphene anion that 1 inner wall of shell is equipped with Coating 11 can discharge anion to wind chamber 42, and anion drains into the external world greatly with air-flow under the effect of wind turbine 44 from air outlet 43 In gas, air is purified to provide high quality, and the graphene anion coating that housing exterior walls are equipped with, can directly discharge bear from In son to ambient atmosphere;The design of graphene filter layer 9 can give full play to the excellent adsorption capacity of graphene and decontamination Effect, and cross air filtering when can kill air in harmful bacteria.
Embodiment 1
In the present embodiment, graphene filter layer 9 is set at the air inlet 41;
The graphene filter layer includes following components and its parts by weight:
100 parts of aqueous polyurethane;
0.5 part of graphene oxide;
0.1 part of nanometer titanium dioxide carbon;
0.3 part of 3- aminopropyl triethoxysilanes;
Wherein, the solid content of the aqueous polyurethane is 29 weight %, and viscosity is 24 mPas, pH value 7.5;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, cut with 1500 revs/min of speed Stirring 20 minutes is cut, batch mixing is obtained;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1000 revs/min of speed clipping, graphene painting is obtained Material;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 50 DEG C, obtains graphene filter layer;Wherein, porous substrate is Porous, expanded plastics, non-woven fabrics or fiber filter cotton.
In the present embodiment, the graphene anion coating 11 of use includes following components and its parts by weight:
5 parts of graphene negative ion powder;
25 parts of feldspar;
10 parts of calcite;
20 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
15 parts of tourmaline;
65 parts of nano-cerium oxide;
1 part of graphene;
1 part of nano-titanium dioxide.
In the present embodiment, the graphene anion coating 11 includes the following steps in the forming method on 1 surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
In the present embodiment, the antimycotic antiseptic coating 21 of use includes following components and its parts by weight:
10 parts of acrylic acid ester emulsion;
0.05 part of mould inhibitor;
2 parts of silver-based inorganic antibacterial agent;
5 parts of nano-titanium dioxide;
0.5 part of graphene;
15 parts of precipitated calcium carbonate;
10 parts of powdered whiting;
2 parts of dispersant;
0.5 part of coalescents;
0.05 part of antifoaming agent;
1 part of wetting agent;
0.5 part of pH adjusting agent;
10 parts of deionized water.
In the present embodiment, forming method of the antimycotic antiseptic coating 21 on 2 inner wall of inner cylinder includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
Preferably, in the present embodiment, the mould inhibitor is dichlofluanid;The dispersant is polyacrylic acid sodium salt;Institute It is Lauryl Alcohol ester to state coalescents;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether;The wetting agent is poly- for nonionic Ether modifying agent.
Embodiment 2
In the present embodiment, at the air inlet 41 and graphene filter layer 9 is respectively set in 2 bottom of inner cylinder;
The graphene filter layer includes following components and its parts by weight:
100 parts of aqueous polyurethane;
1 part of graphene oxide;
1 part of nanometer titanium dioxide carbon;
1.3 parts of 3- aminopropyl triethoxysilanes;
Wherein, the solid content of the aqueous polyurethane is 30 weight %, and viscosity is 25 mPas, pH value 8;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, cut with 1800 revs/min of speed Stirring 20 minutes is cut, batch mixing is obtained;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1300 revs/min of speed clipping, graphene painting is obtained Material;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 55 DEG C, obtains graphene filter layer;Wherein, porous substrate is Porous, expanded plastics, non-woven fabrics or fiber filter cotton.
In the present embodiment, the graphene anion coating 11 of use includes following components and its parts by weight:
6 parts of graphene negative ion powder;
35 parts of feldspar;
20 parts of calcite;
25 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
20 parts of tourmaline;
75 parts of nano-cerium oxide;
3 parts of graphene;
2 parts of nano-titanium dioxide.
In the present embodiment, the graphene anion coating 11 includes the following steps in the forming method on 1 surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
In the present embodiment, the antimycotic antiseptic coating 21 of use includes following components and its parts by weight:
25 parts of acrylic acid ester emulsion;
1.0 parts of mould inhibitor;
4 parts of silver-based inorganic antibacterial agent;
8 parts of nano-titanium dioxide;
1.3 parts of graphene;
25 parts of precipitated calcium carbonate;
20 parts of powdered whiting;
3 parts of dispersant;
2 parts of coalescents;
1.0 parts of antifoaming agent;
1.5 parts of wetting agent;
1 part of pH adjusting agent;
25 parts of deionized water.
In the present embodiment, forming method of the antimycotic antiseptic coating 21 on 2 inner wall of inner cylinder includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
Preferably, in the present embodiment, the mould inhibitor is dichlofluanid;The dispersant is polyacrylic acid sodium salt;Institute It is pentanediol mono isobutyrate to state coalescents;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether;The wetting agent is non- Polyether-modified dose of ion.
Embodiment 3
In the present embodiment, graphene filter layer 9 is set in 2 bottom of the inner cylinder;
The graphene filter layer includes following components and its parts by weight:
100 parts of aqueous polyurethane;
1.5 parts of graphene oxide;
1.5 parts of nanometer titanium dioxide carbon;
2 parts of 3- aminopropyl triethoxysilanes;
Wherein, the solid content of the aqueous polyurethane is 31 weight %, and viscosity is 26 mPas, pH value 8.5;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, cut with 2000 revs/min of speed Stirring 20 minutes is cut, batch mixing is obtained;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1500 revs/min of speed clipping, graphene painting is obtained Material;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 60 DEG C, obtains graphene filter layer;Wherein, porous substrate is Porous, expanded plastics, non-woven fabrics or fiber filter cotton.
In the present embodiment, the graphene anion coating 11 of use includes following components and its parts by weight:
8 parts of graphene negative ion powder;
40 parts of feldspar;
25 parts of calcite;
30 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
25 parts of tourmaline;
80 parts of nano-cerium oxide;
5 parts of graphene;
3 parts of nano-titanium dioxide.
In the present embodiment, the graphene anion coating 11 includes the following steps in the forming method on 1 surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
In the present embodiment, the antimycotic antiseptic coating 21 of use includes following components and its parts by weight:
40 parts of acrylic acid ester emulsion;
1.5 parts of mould inhibitor;
6 parts of silver-based inorganic antibacterial agent;
10 parts of nano-titanium dioxide;
2 parts of graphene;
35 parts of precipitated calcium carbonate;
30 parts of powdered whiting;
4 parts of dispersant;
4 parts of coalescents;
1.5 parts of antifoaming agent;
2 parts of wetting agent;
2 parts of pH adjusting agent;
55 parts of deionized water.
In the present embodiment, forming method of the antimycotic antiseptic coating 21 on 2 inner wall of inner cylinder includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
Preferably, in the present embodiment, the mould inhibitor is thiabendazole;The dispersant is polyacrylic acid sodium salt;Institute It is pentanediol mono isobutyrate to state coalescents;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether;The wetting agent is non- Polyether-modified dose of ion.
Above description should not have protection scope of the present invention any restriction.

Claims (10)

1. a kind of graphene anion tea perfume device, including shell, inner cylinder and cover assembly, the cover assembly removably cover conjunction The opening being equipped at the top of inner cylinder, cover assembly have air inlet able to turn on or off, are filled with tea stalk in inner cylinder, feature exists In:The inner cylinder is mounted on by fixing piece gap in shell, and the gap between inner tank theca and inner walls forms wind chamber, interior Gap between cylinder top and shell top edge forms air outlet, and inner cylinder bottom is equipped with for air in inner cylinder to be drained into wind chamber Wind turbine;The surface of shell is equipped with graphene anion coating, and inner cylinder inner wall is equipped with antimycotic antiseptic coating.
2. a kind of graphene anion tea perfume device according to claim 1, it is characterised in that:The cover assembly includes using The cover board in opening is closed in lid, air inlet is opened in the middle part of cover board, and cover board lower surface is equipped with tray deck, cover board lower surface and branch There is air intake passage, tray deck to be equipped with the upper cover for opening and closing air inlet between frame disk upper surface.
3. a kind of graphene anion tea perfume device according to claim 2, it is characterised in that:It is equipped in the air intake passage Ultraviolet radiator, cover board lower surface and inner cylinder contact position are set there are two positioning groove, and a metal is respectively equipped in two positioning grooves Piece, two sheet metals respectively with ultraviolet radiator anode and cathode be electrically connected, inner cylinder top edge set there are two metal thimble, two Metal thimble can contact respective metal piece and is plugged in two positioning grooves respectively.
4. a kind of graphene anion tea perfume device according to claim 1, it is characterised in that:The air inlet and inner cylinder More than a position in bottom it is equipped with graphene filter layer;The graphene filter layer includes following components and its parts by weight Number:
100 parts of aqueous polyurethane;
0.5-1.5 parts of graphene oxide;
0.1-1.5 parts of nanometer titanium dioxide carbon;
0.3-2 parts of 3- aminopropyl triethoxysilanes;
The production method of the graphene filter layer, includes the following steps:
1)Graphene oxide, nanometer titanium dioxide carbon and 3- aminopropyl triethoxysilanes are mixed, with 1500-2000 revs/min Speed clipping stirs 20 minutes, obtains batch mixing;
2)Batch mixing is mixed with aqueous polyurethane, is stirred 25 minutes with 1000-1500 revs/min of speed clipping, obtains graphite Alkene coating;
3)Graphene coating is sprayed on porous substrate or porous substrate is impregnated in graphene coating, in porous substrate Surface forms graphene dope layer, then dries, and drying temperature is 50-60 DEG C, obtains graphene filter layer;Wherein, porous base Material is porous, expanded plastics, non-woven fabrics or fiber filter cotton.
5. a kind of graphene anion tea perfume device according to claim 1, it is characterised in that:The graphene anion applies Layer includes following components and its parts by weight:
5-8 parts of graphene negative ion powder;
25-40 parts of feldspar;
10-25 parts of calcite;
20-30 parts of kaolin;
Wherein, graphene negative ion powder includes following components and its parts by weight:
15-25 parts of tourmaline;
65-80 parts of nano-cerium oxide;
1-5 parts of graphene;
1-3 parts of nano-titanium dioxide.
6. a kind of graphene anion tea perfume device according to claim 5, it is characterised in that:The graphene anion applies Layer includes the following steps in the forming method of surface of shell:
1)Grinding:The each component raw material for proportionally weighing graphene anion coating, puts into ball mill after mixing It is ground, obtains glaze powder;Wherein, the grain size of glaze powder is less than or equal to 1 μm;
2)It is aging:Glaze powder plus water are uniformly mixed, aging 48 hours is stood, obtains glaze slurry;Wherein, glaze powder and water Mass ratio be 1:2-5;
3)Glazing:Glaze slurry is overlying on dry surface of shell by glazing mode glaze, obtains the semi-finished product with glaze feed pulp layer;
4)It fires:After semi-finished product are dried, it is to be fired in 1000-1300 DEG C of stove to be sent into temperature, obtains forming graphene negative The shell of ionic coating.
7. a kind of graphene anion tea perfume device according to claim 1, it is characterised in that:The antimycotic antiseptic coating packet Include following components and its parts by weight:
10-40 parts of acrylic acid ester emulsion;
0.05-1.5 parts of mould inhibitor;
2-6 parts of silver-based inorganic antibacterial agent;
5-10 parts of nano-titanium dioxide;
0.5-2 parts of graphene;
15-35 parts of precipitated calcium carbonate;
10-30 parts of powdered whiting;
2-4 parts of dispersant;
0.5-4 parts of coalescents;
0.05-1.5 parts of antifoaming agent;
1-2 parts of wetting agent;
0.5-2 parts of pH adjusting agent;
10-55 parts of deionized water.
8. a kind of graphene anion tea perfume device according to claim 7, it is characterised in that:The antimycotic antiseptic coating exists Forming method on inner cylinder inner wall, includes the following steps:
1)Agitation grinding:By deionized water, mould inhibitor, nano-titanium dioxide, silver-based inorganic antibacterial agent, precipitated calcium carbonate, heavy Calcium carbonate, dispersant and graphene, which are placed in sand mill, carries out high speed dispersion to fineness less than or equal to 50 μm, is disperseed Material;Wherein, the rotating speed of sand mill is 500-1000r/min, jitter time 15-25min;
2)Hybrid modulation;Acrylic acid ester emulsion, coalescents, antifoaming agent and wetting agent are added in disperse materials, is uniformly mixed, obtains To mixed liquor;PH adjusting agent is added in mixed liquor, until the pH value of mixed liquor is 8-13, obtains lotion;
3)Lotion is crossed into 325 mesh sieve, the part that can be crossed overlays on interior tube inner surface using spraying or brushing, dry, is molded There is the inner cylinder of antimycotic antiseptic coating.
9. a kind of graphene anion tea perfume device according to claim 7 or 8, it is characterised in that:The mould inhibitor is Dichlofluanid or thiabendazole;The dispersant is polyacrylic acid sodium salt;The coalescents are Lauryl Alcohol ester or penta Monoisobutyrate;The antifoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether;The wetting agent is nonionic polyoxyalkylene modifying agent.
10. a kind of graphene anion tea perfume device according to claim 1, it is characterised in that:In the cover assembly or Person's inner cylinder is equipped with heater.
CN201810516578.0A 2018-05-25 2018-05-25 A kind of graphene anion tea perfume device Pending CN108465122A (en)

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CN111808466A (en) * 2020-07-17 2020-10-23 成都森态源环保科技有限公司 Anion functional inorganic pigment

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