CN107141917A - A kind of automobile-used cleansing composition - Google Patents

A kind of automobile-used cleansing composition Download PDF

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Publication number
CN107141917A
CN107141917A CN201710389016.XA CN201710389016A CN107141917A CN 107141917 A CN107141917 A CN 107141917A CN 201710389016 A CN201710389016 A CN 201710389016A CN 107141917 A CN107141917 A CN 107141917A
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CN
China
Prior art keywords
mass parts
automobile
cleansing composition
calcium ascorbate
graphene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710389016.XA
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Chinese (zh)
Inventor
刘海勇
王勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Kaidu New Mstar Technology Ltd
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Ningbo Kaidu New Mstar Technology Ltd
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Priority to CN201710389016.XA priority Critical patent/CN107141917A/en
Publication of CN107141917A publication Critical patent/CN107141917A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a kind of automobile-used cleansing composition, including:The film forming matter of 20~25 mass parts;The emulsifying agent of 5~10 mass parts;The photocatalysis micro mist of 3~5 mass parts;The negative ion powder of 5~15 mass parts;The inserts of 10~15 mass parts;The Calcium Ascorbate of 0.1~0.5 mass parts;The graphene of 1~5 mass parts;The deionized water of 30~40 mass parts.The present invention adds Calcium Ascorbate and graphene in the composition including negative ion powder, significantly improve the ability that negative ion powder discharges anion, result of the test shows, the in-car negative ion concentration of composition that the present invention is provided is higher than 12000/cubic centimetre, the composition of Calcium Ascorbate and graphene is significantly larger than not added with, and only adds the composition of one of which.In addition, the composition that the present invention is provided can also remove the penetrating odors such as in-car benzene, formaldehyde, ketone ammonia and other peculiar smell.

Description

A kind of automobile-used cleansing composition
Technical field
The invention belongs to purify technical field of coatings, more particularly to a kind of automobile-used cleansing composition.
Background technology
With the development of life, automobile turns into part indispensable during people live.But, automotive trim is typically used Resin is prepared, the problem of there is release formaldehyde.Moreover, during driving or riding in an automobile trip, unavoidably by ring The ambient influnence such as formaldehyde, PM2.5 in border.
Medical research shows that anion is a kind of material being highly profitable to human body health, and it can reduce and come from The active oxygen of the generations such as the contaminated area of air is straight, nitrogen oxides, cigarette, reduces harm of the active oxygen to human body, neutralizes positively charged Floating dust in air, be purified air.
Prior art has been disclosed for many negative ion paints and even disclosed that the automotive trim panel of anion can be discharged, Such as Chinese patent CN105313796A discloses a kind of automotive trim panel capable of releasing negative ion, and it can in general-utility car trim panel The slurry coating that coating is made up of vermiculite, tourmaline and adhesive on the inside of ventilative decorative layer, so as to reach release anion Function.But, the number of coating release anion is less.
Based on this, the purpose of applicant is to study a kind of in-car purification coating, realizes the every pollutant of purification, degraded two Carbonoxide, improves the driving energy and driving safety of driver, using in motor bus can pre- anti-virus the mesh such as cross-infection 's.In addition, with the improvement of people's quality of life, self-driving travel increase still, during self-driving travel, is gone on a highway Sailing can be attacked by strong electric radiation, and the harm of supervoltage radiation can be greatly reduced in the case where the in-car purifies the protection of coating.
The content of the invention
In view of this, it is an object of the invention to provide a kind of automobile-used cleansing composition, the purification combination that the present invention is provided Thing is used for automotive interior, can discharge a large amount of anions.
The invention provides a kind of automobile-used cleansing composition, including:
The film forming matter of 20~25 mass parts;
The emulsifying agent of 5~10 mass parts;
The photocatalysis micro mist of 3~5 mass parts;
The negative ion powder of 5~15 mass parts;
The inserts of 10~15 mass parts;
The Calcium Ascorbate of 0.1~0.5 mass parts;
The graphene of 1~5 mass parts;
The deionized water of 30~40 mass parts.
The automobile-used cleansing composition that the present invention is provided includes film forming matter, and the film forming matter is water-soluble resin, for example Acrylic resin.The content of the film forming matter is 20~25 mass parts.
The automobile-used cleansing composition that the present invention is provided includes emulsifying agent, and the emulsifying agent is PEG type emulsifying agents, such as PEG- 1000th, PEG-1500 etc..The content of the emulsifying agent is 5~10 mass parts.
The automobile-used cleansing composition that the present invention is provided includes photocatalysis micro mist, and the photocatalysis micro mist is selected from nanometer titanium dioxide One or more in titanium, nano zine oxide, nano tin dioxide, nanometer di-iron trioxide and nanometer tungsten oxide, preferably nanometer Titanium dioxide.The content of the photocatalysis micro mist is 3~5 mass parts.
The automobile-used cleansing composition that the present invention is provided includes negative ion powder, the effect of the negative ion powder be release bear from Son, commercially available negative ion powder.In the present invention, the content of the negative ion powder is 5~15 mass parts.
The automobile-used cleansing composition that the present invention is provided includes inserts, and the inserts is selected from kaolin, titanium dioxide, nanometer One or more in rare earth miberal powder, ethyl cellulose and methyl hydroxybenzoate, preferably kaolin.In the present invention, the filling The content of material is 10~15 mass parts.
The automobile-used cleansing composition that the present invention is provided includes Calcium Ascorbate and graphene, and Calcium Ascorbate and graphene are common With negative ion powder release anion is promoted, so as to greatly improve in-car negative ion concentration.In the present invention, the Calcium Ascorbate Content is 0.1~0.5 mass parts, and the content of graphene is 1~5 mass parts.
The automobile-used cleansing composition that the present invention is provided also includes deionized water, and the content of the deionized water is 30~40 matter Measure part.
The automobile-used cleansing composition that the present invention is provided includes antibacterial powder, and the antibacterial powder is selected from zinc oxide, cupric oxide or oxygen Change the one or more in tin.The content of the antibacterial powder is 0.01~0.1 mass parts.
Present invention also offers a kind of preparation method of the automobile-used cleansing composition described in above-mentioned technical proposal, including it is following Step:
A) emulsifying agent, stirring mixing are added after film forming matter is mixed with deionized water stirring;
B) the first mass is added after the Calcium Ascorbate of the first mass parts is mixed with the mixture stirring that step a) is obtained Part graphene, stirring mixing;
C) inserts, stirring mixing are added after photocatalysis micro mist is mixed with the mixture stirring that step c) is obtained;
D) mixture for obtaining 20% step c), with negative ion powder, the second mass parts Calcium Ascorbate and the second mass Part graphene mixing, the homogeneous in homogenizer;
E) mixture for obtaining step d) is mixed with the stirring of step c) remaining mixtures, obtains automobile-used purification combination Thing.
Wherein, the mass ratio of the first mass parts Calcium Ascorbate and the second mass parts Calcium Ascorbate is 4: 6;It is described The mass ratio of first mass parts graphene and the second mass parts graphene is 6: 4.
In above process, each step stirring mixing speed is preferably 1500~2500 revs/min, more preferably 2000 turns/ Minute, it is stirred until homogeneous.
The automobile-used cleansing composition that the present invention is provided is used in accordance with the following methods:
The position sprayed is needed to clean up (standard for reaching automotive trim fine purifiation) automotive trim, windowing is fully dried To without cleaning agent taste, then the part that need not be sprayed is wrapped up;The automobile-used cleansing composition stirring that the present invention is provided is equal Sprayed after even, before the non-surface drying of paint film, surface lacquer pearl is gently swept with fine wool brush, it is small then to stand 8 at 25~30 degrees Celsius When parch.
Specifically, the composition that the present invention is provided can be used for:Automobile ceiling surface, automobile interior base surface, automobile Boot etc..
Compared with prior art, the automobile-used cleansing composition that the present invention is provided, including:The film forming matter of 20~25 mass parts Matter;The emulsifying agent of 5~10 mass parts;The photocatalysis micro mist of 3~5 mass parts;The negative ion powder of 5~15 mass parts;10~15 matter Measure the inserts of part;The Calcium Ascorbate of 0.1~0.5 mass parts;The graphene of 1~5 mass parts;30~40 mass parts go from Sub- water.The present invention adds Calcium Ascorbate and graphene in the composition including negative ion powder, significantly improves negative ion powder Discharge the ability of anion, result of the test shows, the in-car negative ion concentration of the composition that the present invention is provided higher than 12000/it is vertical Square centimetre, the composition of Calcium Ascorbate and graphene is significantly larger than not added with, and only adds the composition of one of which.Separately Outside, the composition that the present invention is provided can also remove the penetrating odors such as in-car benzene, formaldehyde, ketone ammonia and other peculiar smell.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.
Embodiment 1
Formula:
The water soluble acrylic resin of 20 mass parts;
The PEG-1500 of 8 mass parts;
The nano titanium oxide of 5 mass parts;
The negative ion powder of 15 mass parts;
The kaolin of 13 mass parts;
The Calcium Ascorbate of 0.1 mass parts;
The graphene of 5 mass parts;
The deionized water of 40 mass parts.
Prepare in accordance with the following methods:
A) PEG-1500 is added after being uniformly mixed water soluble acrylic resin and deionized water, stirring mixing is equal It is even;
B) 3 mass are added after the obtained mixture of the Calcium Ascorbate of 0.04 mass parts and step a) is uniformly mixed Part graphene, is uniformly mixed;
C) inserts, stirring mixing are added after the obtained mixture of nano titanium oxide and step c) is uniformly mixed Uniformly;
D) mixture for obtaining 20% step c), with negative ion powder, 0.06 mass parts Calcium Ascorbate and 2 mass parts stones Black alkene mixing, the homogeneous in homogenizer;
E) mixture for obtaining step d) is uniformly mixed with the remaining mixtures of step c), obtains automobile-used purification group Compound.
Embodiment 2
Formula:
The water soluble acrylic resin of 25 mass parts;
The PEG-1000 of 9 mass parts;
The nano titanium oxide of 5 mass parts;
The negative ion powder of 5 mass parts;
The kaolin of 13 mass parts;
The Calcium Ascorbate of 0.5 mass parts;
The graphene of 1 mass parts;
The deionized water of 35 mass parts.
Prepare in accordance with the following methods:
A) PEG-1000 is added after being uniformly mixed water soluble acrylic resin and deionized water, stirring mixing is equal It is even;
B) 0.6 matter is added after the obtained mixture of the Calcium Ascorbate of 0.2 mass parts and step a) is uniformly mixed Part graphene is measured, is uniformly mixed;
C) inserts, stirring mixing are added after the obtained mixture of nano titanium oxide and step c) is uniformly mixed Uniformly;
D) mixture for obtaining 20% step c), with negative ion powder, 0.3 mass parts Calcium Ascorbate and 0.4 mass parts Graphene is mixed, the homogeneous in homogenizer;
E) mixture for obtaining step d) is uniformly mixed with the remaining mixtures of step c), obtains automobile-used purification group Compound.
Embodiment 3
Formula:
The water soluble acrylic resin of 23 mass parts;
The PEG-1500 of 8 mass parts;
The nano titanium oxide of 5 mass parts;
The negative ion powder of 10 mass parts;
The kaolin of 13 mass parts;
The Calcium Ascorbate of 0.3 mass parts;
The graphene of 3 mass parts;
The deionized water of 30 mass parts.
Prepare in accordance with the following methods:
A) PEG-1500 is added after being uniformly mixed water soluble acrylic resin and deionized water, stirring mixing is equal It is even;
B) 1.8 matter are added after the obtained mixture of the Calcium Ascorbate of 0.12 mass parts and step a) is uniformly mixed Part graphene is measured, is uniformly mixed;
C) inserts, stirring mixing are added after the obtained mixture of nano titanium oxide and step c) is uniformly mixed Uniformly;
D) mixture for obtaining 20% step c), with negative ion powder, 0.18 mass parts Calcium Ascorbate and 1.2 mass parts Graphene is mixed, the homogeneous in homogenizer;
E) mixture for obtaining step d) is uniformly mixed with the remaining mixtures of step c), obtains automobile-used purification group Compound.
Comparative example 1
It is with the difference of embodiment 1 without Calcium Ascorbate and graphene, the kaolin of 5.1 mass parts of many additions.
Comparative example 2
It is with the difference of embodiment 2 without Calcium Ascorbate, the graphene of 0.5 mass parts of many additions.
Comparative example 3
It is with the difference of embodiment 2 without graphene, the Calcium Ascorbate of 1 mass parts of many additions.
The composition for respectively obtaining embodiment 1~3, comparative example 1~3 is sprayed at automotive trim surface, and 25~30 DEG C quiet Putting 8h parches paint film.Under vehicle windowing ventilation state, the in-car anion concentration of measurement, as a result referring to table 1, table 1 is the present invention The composition that embodiment is provided is sprayed at the in-car anion concentration (unit of different time in automotive trim:Individual/cubic centimetre).
The composition of table 1 is sprayed at anion concentration in-car in automotive trim
0h 24h 1 month 3 months 6 months
Embodiment 1 15000 15000 16000 15000 15000
Embodiment 2 13000 13500 13500 13000 13500
Embodiment 3 13500 13000 13500 13000 13000
Comparative example 1 6000 6500 6200 5800 5500
Comparative example 2 8000 8300 8400 8200 8000
Comparative example 3 7500 7800 7600 7300 7500
In table 1, started at after 0h, 24h, 1 month, 3 months and 6 monthly 8h with paint film placement.
As shown in Table 1, while adding after Calcium Ascorbate and graphene, the ability of composition release anion is carried significantly Height, without Calcium Ascorbate and graphene, and only adds one of which, can not greatly improve composition release anion Ability.
Finally it should be noted that:The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;To the greatest extent The present invention is described in detail with reference to the foregoing embodiments for pipe, it will be understood by those within the art that:It is still Technical scheme described in foregoing embodiments can be modified, or which part technical characteristic is equally replaced Change;And these modifications or replacement, the essence of appropriate technical solution is departed from the essence of various embodiments of the present invention technical scheme God and scope.

Claims (8)

1. a kind of automobile-used cleansing composition, it is characterised in that including:
The film forming matter of 20~25 mass parts;
The emulsifying agent of 5~10 mass parts;
The photocatalysis micro mist of 3~5 mass parts;
The negative ion powder of 5~15 mass parts;
The inserts of 10~15 mass parts;
The Calcium Ascorbate of 0.1~0.5 mass parts;
The graphene of 1~5 mass parts;
The deionized water of 30~40 mass parts.
2. automobile-used cleansing composition according to claim 1, it is characterised in that the film forming matter is water-soluble resin.
3. automobile-used cleansing composition according to claim 1, it is characterised in that the emulsifying agent is PEG type emulsifying agents.
4. automobile-used cleansing composition according to claim 1, it is characterised in that the photocatalysis micro mist is selected from nano-silica Change the one or more in titanium, nano zine oxide, nano tin dioxide, nanometer di-iron trioxide and nanometer tungsten oxide.
5. automobile-used cleansing composition according to claim 1, it is characterised in that the inserts is selected from kaolin, titanium white One or more in powder, nano rare earth miberal powder, ethyl cellulose and methyl hydroxybenzoate.
6. automobile-used cleansing composition according to claim 1, it is characterised in that anti-also including 0.01~0.1 mass parts Bacterium powder, one or more of the antibacterial powder in zinc oxide, cupric oxide or tin oxide.
7. the preparation method of the automobile-used cleansing composition described in claim 1, it is characterised in that comprise the following steps:
A) emulsifying agent, stirring mixing are added after film forming matter is mixed with deionized water stirring;
B) the first mass parts stone is added after the Calcium Ascorbate of the first mass parts is mixed with the mixture stirring that step a) is obtained Black alkene, stirring mixing;
C) inserts, stirring mixing are added after photocatalysis micro mist is mixed with the mixture stirring that step c) is obtained;
D) mixture for obtaining 20% step c), with negative ion powder, the second mass parts Calcium Ascorbate and the second mass parts stone Black alkene mixing, the homogeneous in homogenizer;
E) mixture for obtaining step d) is mixed with the stirring of step c) remaining mixtures, obtains automobile-used cleansing composition.
8. preparation method according to claim 7, it is characterised in that the first mass parts Calcium Ascorbate and the second matter The mass ratio for measuring part Calcium Ascorbate is 4: 6;The mass ratio of the first mass parts graphene and the second mass parts graphene is 6 ∶4。
CN201710389016.XA 2017-05-27 2017-05-27 A kind of automobile-used cleansing composition Pending CN107141917A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108465122A (en) * 2018-05-25 2018-08-31 福州市晋安区田芳电子产品有限公司 A kind of graphene anion tea perfume device
CN113462240A (en) * 2021-07-27 2021-10-01 梁作霖 Preparation process and use method of negative ion releasing coating
CN115006577A (en) * 2022-05-27 2022-09-06 浙江密森环境科技有限公司 Plant negative oxygen ion air purifying agent and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102993865A (en) * 2012-11-08 2013-03-27 上海凯杜涂装设计工程有限公司 Process for preparing multifunctional biological negative ion coating
CN104592878A (en) * 2015-01-01 2015-05-06 宁波帝杨电子科技有限公司 Environment-friendly water-based paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102993865A (en) * 2012-11-08 2013-03-27 上海凯杜涂装设计工程有限公司 Process for preparing multifunctional biological negative ion coating
CN104592878A (en) * 2015-01-01 2015-05-06 宁波帝杨电子科技有限公司 Environment-friendly water-based paint and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108465122A (en) * 2018-05-25 2018-08-31 福州市晋安区田芳电子产品有限公司 A kind of graphene anion tea perfume device
CN113462240A (en) * 2021-07-27 2021-10-01 梁作霖 Preparation process and use method of negative ion releasing coating
CN115006577A (en) * 2022-05-27 2022-09-06 浙江密森环境科技有限公司 Plant negative oxygen ion air purifying agent and preparation method thereof

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Application publication date: 20170908

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