CN108455904A - A kind of parian and its manufacture craft - Google Patents
A kind of parian and its manufacture craft Download PDFInfo
- Publication number
- CN108455904A CN108455904A CN201810161369.9A CN201810161369A CN108455904A CN 108455904 A CN108455904 A CN 108455904A CN 201810161369 A CN201810161369 A CN 201810161369A CN 108455904 A CN108455904 A CN 108455904A
- Authority
- CN
- China
- Prior art keywords
- parian
- mountain flour
- polyester resin
- unsaturated polyester
- titanium dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
- C04B2111/545—Artificial marble
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of parian and its manufacture crafts, belong to parian technical field, which includes unsaturated polyester resin, mountain flour, titanium dioxide, paint；The ratio between parts by weight of unsaturated polyester resin and mountain flour are 1:1‑1.5；The ratio of the parts by weight of unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 39.6 40.2:1；The ratio of the parts by weight of unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6 100.3:1.The parian obtained through the invention has the advantages that production cost is low, natural with lines and lines.
Description
Technical field
The present invention relates to parian technical fields, more specifically, it relates to a kind of parian and its manufacture craft.
Background technology
Marble, original, which refers to, originates in limestone of the white of Dali of Yunnan with black decorative pattern, and section can form a width
Natural wash landscape painting, ancient times often choose the marble with molding decorative pattern and are used for making painted screen or mosaic.In the modern times,
More and more families are used as indoor exterior finish using marble, not only good decorating effect, but also have preferable durability, so
And marmorean cost is higher, and larger limitation is caused for its application.
Therefore, a kind of low cost, carry lines and the natural marbling of lines, have wide commercialization before
Scape.
Invention content
In view of the deficienciess of the prior art, the purpose of the present invention one is to provide a kind of parian, there is cost just
Preferably, the advantage with lines and lines nature.
To achieve the above object one, the present invention provides following technical solutions：
A kind of parian, including unsaturated polyester resin, mountain flour, titanium dioxide, paint；
The ratio between parts by weight of the unsaturated polyester resin and mountain flour are 1: 1-1.5；
The ratio of the parts by weight of the unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 39.6-40.2: 1；
The ratio of the parts by weight of the unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6-
100.3∶1。
Through the above technical solutions, mountain flour, titanium dioxide be as main filler, and the main component in mountain flour is carbonic acid
Calcium cooperates with titanium dioxide, helps to improve the hardness for the parian to be formed；And unsaturated polyester resin is as adhesion
Component, and paint and be used as main lines source.Wherein, unsaturated polyester resin has lower surface tension, easily flows,
When being mixed with mountain flour, titanium dioxide, paint, surface tension is adjusted, to eliminate mixed bubble in said components mixed process,
Improve the uniformity of the parian obtained.Painting color type is various and beautiful in colour, as lines in parian
Main source, therefore, the lines of the parian finally obtained is naturally, be more nearly natural marmorean lines.
In addition, the price of unsaturated polyester resin, mountain flour, titanium dioxide, paint is relatively low, therefore, making for parian is produced
Valence is relatively low, is more conducively received by more consumers.
Further preferably：The ratio between parts by weight of the unsaturated polyester resin and mountain flour are 1: 1-1.3；
The ratio of the parts by weight of the unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 39.9-40.2: 1；
The ratio of the parts by weight of the unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6-
100.1∶1。
Through the above technical solutions, finding, the parian obtained within the above range have more through research (experiment one)
Add appearance true to nature and exquisite.
Further preferably：The fineness of the mountain flour is 550-650 mesh；The fineness of the titanium dioxide is 550-650 mesh.
Through the above technical solutions, the mountain flour and titanium dioxide of above-mentioned fineness have larger specific surface area, and quality is more
Uniformly, with unsaturated polyester resin, paint during being mutually mixed, mountain flour and titanium dioxide are more easy to fully be coated, to
Keep the quality of the parian of acquisition more closely knit, and surface is smooth.
Further preferably：Further include reinforcing agent, the reinforcing agent is that Carbon fibe network reinforcement is formed with polypropylene
Composite material, the unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and reinforcing agent the ratio of parts by weight be
998-1000∶1。
Through the above technical solutions, the composite material that Carbon fibe network reinforcement is formed with polypropylene is with higher rigid
Property, lower dilatancy, higher intensity and resistance capacity to deformation, are cooperating and are being formed with raw materials such as mountain flour, titanium dioxides
After parian, it can make parian that there is better intensity and ability to bear.
Further preferably：In the composite material that the Carbon fibe network reinforcement is formed with polypropylene, Carbon fibe network
Reinforcement accounts for 25-26wt%.
Through the above technical solutions, being found through research (experiment two), when carbon fiber network reinforcement accounts in composite material
When stating weight ratio range, it can make parian that there is better intensity and ability to bear.
The purpose of the present invention two is to provide a kind of manufacture craft of parian.
To achieve the above object two, the present invention provides following technical solutions：
A kind of manufacture craft of parian, includes the following steps：
Unsaturated polyester resin, mountain flour, titanium dioxide are sufficiently mixed by step 1, form the first mixture；
Paint is added in the first mixture obtained in step 1, carries out soft hybrid manipulation by step 2, and the operating time is
3-5s forms the second mixture；
Step 3, in the environment that temperature is -10-45 DEG C, after the second mixture curing molding, successively through alkali cleaning processing, one
After secondary cleaning, deburring, polishing, secondary cleaning, parian is obtained.
Through the above technical solutions, the temperature range for making parian is wider, it is not easily susceptible to limit, contributes to industry
Change.In step 1, first three kinds of unsaturated polyester resin, mountain flour, titanium dioxide components are sufficiently mixed, in unsaturated polyester (UP) tree
Under the action of the preferable mobility of fat, mixed process is more light, and the first uniformity of mixture obtained is preferable.Step
In two, paint is added into more uniform first mixture of quality, by soft hybrid manipulation, paint is made to be mixed with first
Mixing between object is more naturally, show certain lines.In step 3, make the second mixture curing molding, formation imitative
Marmorean preliminary configuration cleans the impurity on the parian surface preliminarily formed after alkali cleaning is handled, by primary clear
After washing, further remaining impurity and lye are removed, after deburring, polishing, secondary cleaning, parian is formed, has
The advantage that surface gloss is good and flatness is good.
Further preferably：In the step 1, reinforcing agent is added, is sufficiently mixed.
Through the above technical solutions, the mixing improved between reinforcing agent and unsaturated polyester resin, mountain flour, titanium dioxide is imitated
Fruit.
Further preferably：Well-mixed rotating speed is 580-650rpm in the step 1, and the mixed time is 25-
40min。
Through the above technical solutions, above-mentioned rotating speed, incorporation time mutual cooperation under, help to improve the first mixture
Mixing adequacy.
Further preferably：In the step 2, soft hybrid manipulation is hand operated mixing.
Through the above technical solutions, helping the paint of addition suitably to be mixed, to make in parian
Lines has natural effect, to further reduce its gap between natural marble.
Further preferably：In the step 3, the lye that alkali cleaning uses when handling is sodium hydroxide solution, the hydrogen-oxygen
Change a concentration of 96-99% of sodium solution, the temperature of the sodium hydroxide solution is 12-14 DEG C, and the time of the alkali cleaning processing is
10-15min。
Through the above technical solutions, the sodium hydroxide solution using above-mentioned specification carries out alkali cleaning, to the parian of formation
The removing of the impurity on surface has better effect.
In conclusion the invention has the advantages that：
1. unsaturated polyester resin, mountain flour, titanium dioxide is cheap, to reduce production cost；
2. the main source using paint as the color of parian, and be added to paint to have and use soft hand operated mixing, make
Lines is carried in parian and lines is naturally, close with natural marble；
3. since unsaturated polyester resin will be bonded between mountain flour, titanium dioxide preferably, to improve the parian to be formed
Globality；
4. the composite material that Carbon fibe network reinforcement is formed with polypropylene is added to, with unsaturated polyester resin, mountain flour, titanium
White powder directly forms good mating reaction, improves the mechanical strength of parian, and the ability to bear of parian is made to increase.
Specific implementation mode
With reference to embodiment, the present invention will be described in detail.
Embodiment 1：A kind of parian, including unsaturated polyester resin, mountain flour, titanium dioxide, paint, wherein mountain flour
Fineness is 550 mesh；The fineness of titanium dioxide is 650 mesh.The ratio between parts by weight of unsaturated polyester resin and mountain flour are 1: 1；Insatiable hunger
Ratio with the parts by weight of polyester resin, the total weight number of mountain flour and titanium dioxide is 39.6: 1；Unsaturated polyester resin, stone
The ratio of the parts by weight of powder, the total weight number of titanium dioxide and paint is 99.6: 1.
The manufacture craft of parian includes the following steps：
Unsaturated polyester resin, mountain flour, titanium dioxide are sufficiently mixed by step 1, rotating speed 580rpm, and the mixed time is
40min forms the first mixture；
Paint is added in the first mixture obtained in step 1 by step 2, carries out gently hand operated mixing, operating time
For 3-5s, the second mixture is formed；
Step 3 after the second mixture curing molding, is handled through alkali cleaning, alkali successively in the environment that temperature is -10-45 DEG C
Liquid is sodium hydroxide solution, a concentration of the 96% of sodium hydroxide solution, the temperature of sodium hydroxide solution is 14 DEG C, alkali cleaning processing
Time is 15min, then after primary cleaning, deburring, polishing, secondary cleaning, obtains parian.
Embodiment 2：A kind of parian, difference lies in the parts by weight of unsaturated polyester resin and mountain flour with embodiment 1
Number the ratio between be 1: 1.2, unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide parts by weight ratio be 40: 1,
The ratio of the parts by weight of unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 100: 1.
Embodiment 3：A kind of parian, difference lies in the parts by weight of unsaturated polyester resin and mountain flour with embodiment 1
The ratio between number is 1: 1.3；The ratio of the parts by weight of unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 40.2:
1；The ratio of the parts by weight of unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 100.1: 1.
Embodiment 4：A kind of parian, difference lies in the fineness of mountain flour and titanium dioxide is 600 mesh with embodiment 1.
Embodiment 5：A kind of parian, difference lies in the fineness of mountain flour is 650 mesh with embodiment 1；Titanium dioxide it is thin
Degree is 550 mesh.
Embodiment 6：A kind of parian, difference lies in further include reinforcing agent, reinforcing agent is Carbon fibe with embodiment 1
The composite material that network reinforcement is formed with polypropylene, total weight number and the enhancing of unsaturated polyester resin, mountain flour, titanium dioxide
The ratio of the parts by weight of agent is 998: 1, wherein Carbon fibe network reinforcement accounts for 26wt%.Reinforcing agent is added in step 1,
It is sufficiently mixed.
Embodiment 7：A kind of parian, difference lies in, unsaturated polyester resin, mountain flour, titanium dioxides with embodiment 6
The ratio of the parts by weight for the composite material that total weight number is formed with Carbon fibe network reinforcement with polypropylene is 999: 1,
In, Carbon fibe network reinforcement accounts for 25wt%.
Embodiment 8：A kind of parian, difference lies in, unsaturated polyester resin, mountain flour, titanium dioxides with embodiment 7
The ratio of the parts by weight for the composite material that total weight number is formed with Carbon fibe network reinforcement with polypropylene is 1000: 1,
In, Carbon fibe network reinforcement accounts for 25.5wt%.
Embodiment 9：A kind of parian, with embodiment 1 difference lies in, in the manufacture craft of parian, step 1
In, well-mixed rotating speed is 600rpm, and the mixed time is 30min, forms the first mixture.
Embodiment 10：A kind of parian, with embodiment 1 difference lies in, in the manufacture craft of parian, step 1
In, well-mixed rotating speed is 650rpm, and the mixed time is 25min, forms the first mixture.
Embodiment 11：A kind of parian, with embodiment 1 difference lies in, in step 3, the concentration of sodium hydroxide solution
It is 99%, the temperature of sodium hydroxide solution is 12 DEG C, and the time of alkali cleaning processing is 10min.
Embodiment 12：A kind of parian, with embodiment 1 difference lies in, in step 3, the concentration of sodium hydroxide solution
It is 98%, the temperature of sodium hydroxide solution is 13 DEG C, and the time of alkali cleaning processing is 12min.
Comparative example 1：A kind of parian, difference lies in the parts by weight of unsaturated polyester resin and mountain flour with embodiment 1
The ratio between number is 1: 5；The ratio of the parts by weight of unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 20: 1；No
The ratio of the parts by weight of saturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6: 1.
Comparative example 2：A kind of parian, difference lies in the fineness of mountain flour and titanium dioxide is 200 mesh with embodiment 1.
Comparative example 3：A kind of parian, difference lies in by unsaturated polyester resin, mountain flour, titanium white with embodiment 1
Powder, paint mix 40min in the case where rotating speed is 580rpm, then carry out curing molding.
Comparative example 4：A kind of parian, difference lies in step 2, using the rotating speed of 600rpm with embodiment 1
Blender stirs 3s.
Experiment one：Appearance is tested
Test specimen：The parian in embodiment 1-11 is chosen as test sample 1-11, chooses the imitative Dali in comparative example 2-4
Masonry is control sample 2-4.
Test method：The appearance in test sample 1-11, control sample 2-4 is observed, and is compared respectively with natural marble,
Compare similarity, record and analyzes.
Test result：The appearance, as shown in table 1 with the similarity degree of natural marble of test sample 1-11, control sample 2-4.
1 test sample 1-11 of table, the appearance of control sample 2-4, the similarity degree with natural marble
As shown in Table 1, the smooth in appearance of test sample 1-11 is smooth, and compared with natural marble, and similarity is high, it is difficult to point
Discern test sample 1-11.And the appearance of control sample 2 is rough, out-of-flatness, and it is relatively low with the similarity of natural marble, mountain flour and
The larger similarity easily led between control sample 2 and natural marble of the fineness of titanium dioxide is told somebody what one's real intentions are.The appearance of control sample 3 is not only
Sliding, out-of-flatness, and it is low with the similarity of natural marble, illustrate unsaturated polyester resin, mountain flour, titanium dioxide, paint together
Mixing, and rotating speed is 580rpm, incorporation time 40min, it is uneven to easily cause mixing, eventually lead to control sample 3 with it is natural big
The similarity of reason stone is low.It is the smooth in appearance of control sample 4, smooth, but lines is fuzzy, it is relatively low with the similarity of natural marble, it says
It is bright after being added and painting, using the mechanical agitation of higher rotation speed, easily lead to that mixing is too abundant, and lines is not enough naturally, final
Cause relatively low with the similarity of natural marble.
Experiment two：Mechanical property test
Test specimen：The parian in embodiment 1-11 is chosen as test sample 1-11, chooses the parian in comparative example 1
Sample 1 as a contrast.
Test method：In test sample 1-11, each test sample prepares three parallel samples, carries out compressive strength experiment respectively
With the experiment of bending strength, prepare three parallel samples in control sample 1, carries out the examination of compressive strength experiment and bending strength respectively
It tests, after experimental data weighted average, records and analyze.
Test result：Test sample 1-11, the compressive strength limit in control sample 1, bending strength are as shown in table 2.
2 test sample 1-11 of table, the compressive strength limit in control sample 1, bending strength
| Sample | Compressive strength limit (MPa) | Bending strength (MPa) |
| Test sample 1 | 89.3 | 57.6 |
| Test sample 2 | 89.7 | 57.8 |
| Test sample 3 | 89.2 | 57.5 |
| Test sample 4 | 89.5 | 57.3 |
| Test sample 5 | 89.3 | 57.2 |
| Test sample 6 | 89.9 | 57.9 |
| Test sample 7 | 90.1 | 58.3 |
| Test sample 8 | 90.2 | 58.1 |
| Test sample 9 | 90.1 | 58.1 |
| Test sample 10 | 89.5 | 57.5 |
| Test sample 11 | 89.3 | 57.3 |
| Test sample 12 | 89.3 | 57.2 |
| Control sample 1 | 72.1 | 43.2 |
As shown in Table 2, the compressive strength limit value in test sample 1-11 is higher than the compressive strength limit value of control sample 1, and
Bending strength in test sample 1-11 is higher than the bending strength of control sample 1.What this explanation was produced using the method in comparative example 1
The compressive strength and bending strength of parian be not ideal enough, illustrates unsaturated polyester resin, mountain flour, titanium dioxide, paint
Ratio has large effect to the compressive strength and bending strength of parian.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of parian, which is characterized in that including unsaturated polyester resin, mountain flour, titanium dioxide, paint；
The ratio between parts by weight of the unsaturated polyester resin and mountain flour are 1:1-1.5；
The ratio of the parts by weight of the unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 39.6-40.2:1；
The ratio of the parts by weight of the unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6-
100.3:1。
2. a kind of parian according to claim 1, which is characterized in that the weight of the unsaturated polyester resin and mountain flour
It is 1 to measure the ratio between number:1-1.3；
The ratio of the parts by weight of the unsaturated polyester resin, the total weight number of mountain flour and titanium dioxide is 39.9-40.2:1；
The ratio of the parts by weight of the unsaturated polyester resin, mountain flour, the total weight number of titanium dioxide and paint is 99.6-
100.1:1。
3. a kind of parian according to claim 1, which is characterized in that the fineness of the mountain flour is 550-650 mesh；Institute
The fineness for stating titanium dioxide is 550-650 mesh.
4. according to a kind of arbitrary parians of claim 1-3, which is characterized in that further include reinforcing agent, the enhancing
Agent is the composite material that Carbon fibe network reinforcement and polypropylene are formed, the unsaturated polyester resin, mountain flour, titanium dioxide it is total
The ratio of parts by weight and the parts by weight of reinforcing agent is 998-1000：1.
5. a kind of parian according to claim 4, which is characterized in that the Carbon fibe network reinforcement and polypropylene
In the composite material of formation, Carbon fibe network reinforcement accounts for 25-26wt%.
6. a kind of manufacture craft of parian described in any one of claim 1-2, which is characterized in that including walking as follows
Suddenly：
Unsaturated polyester resin, mountain flour, titanium dioxide are sufficiently mixed by step 1, form the first mixture；
Paint is added in the first mixture obtained in step 1, carries out soft hybrid manipulation by step 2, and the operating time is
3-5s forms the second mixture；
Step 3, in the environment that temperature is -10-45 DEG C, after the second mixture curing molding, successively through alkali cleaning processing, one
After secondary cleaning, deburring, polishing, secondary cleaning, parian is obtained.
7. a kind of manufacture craft of parian according to claim 6, which is characterized in that in the step 1, be added
Reinforcing agent is sufficiently mixed.
8. a kind of manufacture craft of parian described according to claim 6 or 7, which is characterized in that filled in the step 1
It is 580-650rpm to divide mixed rotating speed, and the mixed time is 25-40min.
9. a kind of manufacture craft of parian according to claim 8, which is characterized in that in the step 2, softly
Hybrid manipulation is hand operated mixing.
10. a kind of manufacture craft of parian according to claim 6, which is characterized in that in the step 3, alkali cleaning
The lye used when processing is sodium hydroxide solution, a concentration of 96-99% of the sodium hydroxide solution, and the sodium hydroxide is molten
The temperature of liquid is 12-14 DEG C, and the time of the alkali cleaning processing is 10-15min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810161369.9A CN108455904B (en) | 2018-02-27 | 2018-02-27 | Imitated marble and manufacturing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810161369.9A CN108455904B (en) | 2018-02-27 | 2018-02-27 | Imitated marble and manufacturing process thereof |
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| Publication Number | Publication Date |
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| CN108455904A true CN108455904A (en) | 2018-08-28 |
| CN108455904B CN108455904B (en) | 2021-08-24 |
Family
ID=63216572
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810161369.9A Active CN108455904B (en) | 2018-02-27 | 2018-02-27 | Imitated marble and manufacturing process thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111421996A (en) * | 2020-04-22 | 2020-07-17 | 利高工艺品（厦门）有限公司 | Marble-imitated handicraft with transparent layer and preparation method thereof |
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| CN107311520A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of bionical marble formula |
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|---|---|---|---|---|
| CN1045948A (en) * | 1989-03-28 | 1990-10-10 | 广元市实用技术研究所 | Production method of a kind of polyester decorative lamination decoration board and products thereof |
| CN1138535A (en) * | 1995-06-16 | 1996-12-25 | 刘国华 | Decoration board |
| CN1256256A (en) * | 1998-12-07 | 2000-06-14 | 厦门华玉石实业有限公司 | Scagliola and its making process |
| CN1465622A (en) * | 2002-06-28 | 2004-01-07 | 上海开高工贸有限公司 | Marble imitated decoration board and mfg. method thereof |
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| CN105415764A (en) * | 2015-12-04 | 2016-03-23 | 东莞友联建筑材料有限公司 | Composite quartz board and manufacturing process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111421996A (en) * | 2020-04-22 | 2020-07-17 | 利高工艺品（厦门）有限公司 | Marble-imitated handicraft with transparent layer and preparation method thereof |
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| CN108455904B (en) | 2021-08-24 |
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