CN108443597A - A kind of basalt fibre hybrid composite manner pipe and preparation method thereof - Google Patents
A kind of basalt fibre hybrid composite manner pipe and preparation method thereof Download PDFInfo
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- CN108443597A CN108443597A CN201810394025.2A CN201810394025A CN108443597A CN 108443597 A CN108443597 A CN 108443597A CN 201810394025 A CN201810394025 A CN 201810394025A CN 108443597 A CN108443597 A CN 108443597A
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- Prior art keywords
- basalt
- layer
- basalt fibre
- resin
- hybrid composite
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/06—Protection of pipes or objects of similar shape against external or internal damage or wear against wear
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/22—Tubes or pipes, i.e. rigid
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The present invention provides a kind of basalt fibre hybrid composite manner pipes, belong to composite pipe technical field.Include resin layer, the first basalt fiber, the first glass layer and the second basalt fiber being cascading from inside to outside.Basalt fibre is a kind of fiber with preferable corrosion resistance, water resistance, high and low temperature resistance in the present invention, solves the problems, such as that multiple tube corrosion resistance is bad in the prior art.The test data of embodiment shows that basalt fibre hybrid composite manner pipe provided by the invention has excellent corrosion resistance.
Description
Technical field
The present invention relates to composite pipe technical field more particularly to a kind of basalt fibre hybrid composite manner pipe and its preparation sides
Method.
Background technology
Pipeline be we it is daily be commonly used article, has many uses general, be used primarily in water supply, draining, heat supply, give gas,
In long distance delivery oil and natural gas, agricultural irrigation, hydraulic engineering and various commercial plants, with the continuous development of society,
The specification of pipeline is also to be developed constantly.
In the selection of prior art pipeline, multiple tube usually is prepared using metal, plastics or metal and plastic composition, such as
It is compound that CN103062521A discloses a kind of PE being combined by HDPE core pipes, stainless steel stratum reticulare, PE binder courses, modified PE layer
Pipe, CN104676134A disclose a kind of steel-plastics composite pipe, including steel pipe, and the outer surface of steel pipe is equipped with insulating layer, steel pipe it is interior
Surface is equipped with plastic layer.But multiple tube obtained all has that corrosion resistance is bad.
Invention content
In view of this, the purpose of the present invention is to provide a kind of basalt fibre hybrid composite manner pipe, there is good coating
Adhesive force and acid-alkali-corrosive-resisting performance.
In order to achieve the above-mentioned object of the invention, the present invention provides following technical scheme：
A kind of basalt fibre hybrid composite manner pipe includes resin layer, the first basalt being cascading from inside to outside
Fibrous layer, glass layer and the second basalt fiber.
Preferably, further include setting gradually glass outer fibrous layer and third basalt in the second basalt fibre layer surface
Fibrous layer.
Preferably, the resin layer is that phenolic resin-basalt scale resin-rich layer or epoxy resin-basalt scale are rich
Resin layer.
Preferably, the mass content of phenolic resin is 31.15% in the phenolic resin-basalt scale resin-rich layer；
The mass content of the epoxy resin-basalt scale resin-rich layer epoxy resin is 29.21%.
Preferably, the thickness of first basalt fiber is 2mm, and basalt is fine in first basalt fiber
A diameter of 4.25mm of dimension.
Preferably, the thickness of the glass layer is 1.5~5mm, the diameter of glass fibre in the glass layer
For 3.22mm~10.22mm.
Preferably, the thickness of second basalt fiber is 1.5~5mm, profound in second basalt fiber
A diameter of 3.25mm~10.25mm of military rock fiber.
Preferably, second basalt fiber is replaced with into carbon fiber layer.
Preferably, further include setting gradually glass outer fibrous layer and outer layer basalt fiber on carbon fiber layer surface.
The present invention also provides the preparation method of basalt fibre hybrid composite manner pipe described in above-mentioned technical proposal, including it is following
Step：
(1) resin raw material is sprayed on tubular die surface, obtains resin layer；
(2) in the resin layer outer surface that the step (1) obtains successively the first Wet Winding Process basalt fibre, Wet Winding Process
Glass fibre and the second Wet Winding Process basalt fibre obtain molding multiple tube；
(3) the molding multiple tube for obtaining the step (2) cures, and obtains basalt fibre hybrid composite manner pipe.
The present invention provides a kind of basalt fibre hybrid composite manner pipes, include the resin being cascading from inside to outside
Layer, the first basalt fiber, glass layer and the second basalt fiber.Basalt fibre, which is one kind, in the present invention has
The fiber of preferable corrosion resistance, water resistance, high and low temperature resistance, solves multiple tube corrosion resistance in the prior art
Bad problem.The test data of embodiment show basalt fibre hybrid composite manner pipe density provided by the invention be 1.73~
2.19g/cm3, resin content is 29.21~31.22%, and maximum shear stress is up to 206MPa, axial tensile strength is 111~
153MPa, hoop tensile strength be 247~463MPa, bending strength be 312~573MPa, maximum functional internal pressure be 21~
45Mpa impregnates 10 days in following medium, and above-mentioned strength retention ratio is as follows：Distilled water：>99.9%, acetone：>99.7%, satisfy
And sodium carbonate liquor：>97.3%, 10% sodium hydroxide solution：>87.5%, 10% ammonia spirit：>85.7%, 5% hydrochloric acid：>
91.2%, 5% nitric acid：>90.3%, rigidity property is almost unchanged in above-mentioned medium.
Also, the invention also includes set gradually glass outer fibrous layer and third is profound in the second basalt fibre layer surface
The basalt fibre hybrid composite manner pipe of military rock fibrous layer not only has excellent corrosion resistance, while also having at low cost, anti-
Radiation, wear-resisting performance.
The invention also includes the basalt fibre hybrid composite manners that second basalt fiber is replaced with to carbon fiber layer
Pipe not only has excellent corrosion resistance, while also high, conductive, radiation protection the performance with rigidity.
The invention also includes set gradually glass outer fibrous layer and outer layer basalt fiber on carbon fiber layer surface
Basalt fibre hybrid composite manner pipe not only has excellent corrosion resistance, while also having at low cost, radiation protection performance.
Description of the drawings
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is the structural schematic diagram of basalt fibre hybrid composite manner pipe cross section made from the embodiment of the present invention 1；
Fig. 2 is the structural schematic diagram of basalt fibre hybrid composite manner pipe cross section made from the embodiment of the present invention 4.
Specific implementation mode
The present invention provides a kind of basalt fibre hybrid composite manner pipes, include the resin being cascading from inside to outside
Layer, the first basalt fiber, glass layer and the second basalt fiber.
In the present invention, the resin layer is preferably phenolic resin-basalt scale resin-rich layer or epoxy resin-Black Warrior
Rock scale resin-rich layer.In the present invention, the thickness of the resin layer is preferably 0.5mm.
In the present invention, the mass content of phenolic resin is preferably in the phenolic resin-basalt scale resin-rich layer
31.15%；The mass content of the epoxy resin-basalt scale resin-rich layer epoxy resin is preferably 29.21%.
In the present invention, the thickness of first basalt fiber is preferably 2mm, in first basalt fiber
The diameter of basalt fibre is preferably 4.25mm.
In the present invention, the thickness of the glass layer is preferably 1.5~5mm, more preferably 2~4mm, the glass
The diameter of glass fibre is preferably 3.22mm~10.22mm in fibrous layer, more preferably 4.22mm~8.22mm.
In the present invention, the thickness of second basalt fiber is preferably 1~5mm, and more preferably 2~3mm is described
The diameter of basalt fibre is preferably 3.25mm~10.25mm in second basalt fiber, and more preferably 4.25mm~
6.25mm。
In one embodiment of the invention, the basalt fibre hybrid composite manner pipe, including the ring that is cascading
Oxygen resin-basalt scale resin-rich layer, the first basalt fiber, glass layer and the second basalt fiber.This hair
Bright middle basalt fibre is a kind of fiber with preferable corrosion resistance, water resistance, high and low temperature resistance, is solved existing
There is a problem that multiple tube corrosion resistance is bad in technology, basalt fibre hybrid composite manner pipe made from the present embodiment has excellent
Corrosion resistance.
In another embodiment of the present invention, the basalt fibre hybrid composite manner pipe, including be cascading
Phenolic resin-basalt scale resin-rich layer, the first basalt fiber, glass layer and the second basalt fiber.This
Basalt fibre hybrid composite manner pipe made from embodiment not only has excellent corrosion resistance, while also having flame retardant property.
Basalt fibre hybrid composite manner pipe provided by the invention be preferably also included in the second basalt fiber outer surface according to
Secondary setting glass outer fibrous layer and third basalt fiber.In the present invention, the thickness of the glass outer fibrous layer is excellent
It is selected as 2mm, the thickness of the third basalt fiber is preferably 2mm.
In one embodiment of the invention, the basalt fibre hybrid composite manner pipe, including the ring that is cascading
Oxygen resin-basalt scale resin-rich layer, the first basalt fiber, glass layer, the second basalt fiber, outer layer glass
Glass fibrous layer and third basalt fiber.Basalt fibre hybrid composite manner pipe made from the present embodiment not only has excellent resistance to
Corrosive nature, while also there is at low cost, radiation protection, wear-resisting performance.
In the present invention, second basalt fiber is replaced with into carbon fiber layer.In the present invention, the carbon fiber
The thickness and the second basalt of the diameter and above-mentioned second basalt fiber of carbon fiber in the thickness and carbon fiber layer of layer
The diameter of basalt fibre is consistent in fibrous layer, and details are not described herein.Basalt fibre hybrid composite manner pipe made from the present embodiment
Not only there is excellent corrosion resistance, while also with conductive, rigidity is high, radiation protection performance.
In embodiments of the present invention, the basalt fibre hybrid composite manner pipe, including the epoxy resin-that is cascading
Basalt scale resin-rich layer, the first basalt fiber, glass layer and carbon fiber layer.
In the present invention, it is preferred to further include setting gradually glass outer fibrous layer and outer layer basalt on carbon fiber layer surface
Fibrous layer.In the present invention, the thickness of the glass outer fibrous layer is preferably 1.5mm, the outer layer basalt fiber
Thickness is preferably 2mm.
In embodiments of the present invention, the basalt fibre hybrid composite manner pipe, including the epoxy resin-that is cascading
Basalt scale resin-rich layer, the first basalt fiber, glass layer, carbon fiber layer, glass outer fibrous layer and outer
Layer basalt fiber.Basalt fibre hybrid composite manner pipe made from the present embodiment not only has excellent corrosion resistance, together
When also have at low cost, radiation protection performance.
The present invention does not have special restriction to the source of each raw material, using commercially available quotient well known to those skilled in the art
Product.
The present invention also provides the preparation method of basalt fibre hybrid composite manner pipe described in above-mentioned technical proposal, including it is following
Step：
(1) resin raw material is sprayed on tubular die surface, obtains resin layer；
(2) in the resin layer outer surface that the step (1) obtains successively the first Wet Winding Process basalt fibre, Wet Winding Process
Glass fibre and the second Wet Winding Process basalt fibre obtain molding multiple tube；
(3) the molding multiple tube for obtaining the step (2) cures, and obtains basalt fibre hybrid composite manner pipe.
Resin raw material is sprayed on tubular die surface by the present invention, obtains resin layer.The present invention is specific to the spraying
Condition does not have special restriction, can obtain resin layer.In the present invention, the diameter of the pipe embryo be preferably 20~
200cm。
In the present invention, the resin raw material preferably uses the preparation method system of composition well known to those skilled in the art
, it is specific such as phenolic resin-basalt scale resin-rich layer or epoxy resin-basalt scale resin-rich layer.
After obtaining resin layer, the present invention is described fine in the resin layer outer surface successively the first Wet Winding Process basalt
Dimension, Wet Winding Process glass fibre and the second Wet Winding Process basalt fibre obtain molding multiple tube.The present invention twines the wet method
There is no special restriction around mode and angle, first basalt fiber, glass layer and second Black Warrior can be obtained
Rock fibrous layer, it is specific if winding angle is 51 ± 2 °.
In the present invention, the solvent that the Wet Winding Process uses is preferably epoxy resin, and the present invention is to the epoxy resin
Dosage there is no special restriction, the first basalt fiber, glass layer and the second basalt fiber can be obtained i.e.
It can.
In the present invention, the raw material of first basalt fiber, glass layer and the second basalt fiber exists
Vacuum stewing process is preferably carried out before carrying out Wet Winding Process.The present invention to the temperature of the vacuum stewing process, vacuum degree and
Time does not have special restriction, can remove the bubble in each raw material.
In the present invention, the speed of the Wet Winding Process preferably stands alone as 18~20m/min.
In the present invention, the Wet Winding Process carries out preferably in steeping vat.
After obtaining molding multiple tube, the present invention cures the molding multiple tube, obtains basalt fibre hybrid composite manner pipe.
In the present invention, the cured temperature is preferably 50 DEG C, and the cured time is preferably 150min.
In the present invention, described be solidificated in curing oven carries out.
After the completion of solidification, the present invention preferably cools to cured product with the furnace room temperature and obtains basalt fibre hybrid composite manner
Pipe.
When second basalt fiber is replaced with carbon fiber layer, the basalt fibre hybrid composite manner pipe and packet
The preparation method of basalt fibre hybrid composite manner pipe containing the second basalt fiber is similar, only replaces the second basalt fibre
For carbon fiber.
Basalt fibre hybrid composite manner pipe provided by the invention and preparation method thereof is carried out with reference to embodiment detailed
Explanation, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Fig. 1 is the structural schematic diagram of basalt fibre hybrid composite manner pipe made from the embodiment of the present invention 1, wherein 1 is resin
Layer (0.5mm), 2 be the first basalt fiber (2mm), and 3 be glass layer (4mm), and 4 be the second basalt fiber
(3mm), the resin layer are epoxy resin-basalt scale resin-rich layer.
The preparation process of the present embodiment basalt fibre hybrid composite manner pipe is as follows：
It carries out matching glue according to lining resin layer raw material, is slowly sufficiently stirred 20 minutes, in 20 DEG C of environment temperature, will mix
Good resin layer raw material is sprayed on tubular die surface, forms resin layer.
It carries out matching glue according to structural epoxy resins system, continuously and smoothly is carried out with 300 revs/min of speed with blender and is stirred
It mixes 8 minutes and obtains colloid mixture, vacuum is carried out in 20 DEG C of environment and stands removal to include bubble.
The epoxy-resin systems resin prepared is slowly put into steeping vat.Under tensioner effect, by strip basalt
Fabric, by steeping vat, is wound and is coated on completely with 51 ° of angle and have been coated with resin layer with the speed of 18m/min
Tubular die surface, carry out Wet Winding Process.
Under the conditions of same winding process, Wet Winding Process glass fibre and basalt fibre, obtain being molded compound successively
Pipe.
Molding multiple tube is removed from wrapping machine, is put into curing oven and cure up to product.Curing process is 50
DEG C, 150 minutes, room temperature is dropped to stove, obtains basalt fibre hybrid composite manner pipe.
The relevant parameter of basalt fibre hybrid composite manner pipe made from embodiment 1 is tested, it is as a result as follows：Density is
1.92g/cm3, resin content 29.21%, maximum shear stress is up to 206MPa, axial tensile strength 113MPa, circumferential to draw
It is 258MPa to stretch intensity, and bending strength 312MPa, maximum functional internal pressure is 23Mpa, is impregnated 10 days in following medium, above-mentioned
Strength retention ratio is as follows：Distilled water：>99.9%, acetone：>99.7%, saturated sodium carbonate solution：>97.3%, 10% hydroxide
Sodium solution：>87.5%, 10% ammonia spirit：>85.7%, 5% hydrochloric acid：>91.2%, 5% nitric acid：>90.3%, rigidity property
It is almost unchanged in above-mentioned medium.
Embodiment 2
With embodiment 1 be made basalt fibre hybrid composite manner pipe structure and preparation method it is similar, differ only in tree
Lipid layer is phenolic resin-basalt scale resin-rich layer, and resin layer 0.5mm, the first basalt fiber is 2mm, glass fibers
Dimension layer is 5mm, and the second basalt fiber is 2mm.
The relevant parameter of basalt fibre hybrid composite manner pipe made from embodiment 2 is tested, it is as a result as follows：Density is
2.19g/cm3, resin content 31.15%, axial tensile strength 121MPa, hoop tensile strength 278MPa, bending is by force
Degree is 328MPa, and maximum functional internal pressure is 23Mpa, is impregnated 10 days in following medium, above-mentioned strength retention ratio is as follows：Distillation
Water：>99.9%, acetone：>99.7%, saturated sodium carbonate solution：>97.3%, 10% sodium hydroxide solution：>87.5%, 10%
Ammonia spirit：>85.7%, 5% hydrochloric acid：>91.2%, 5% nitric acid：>90.3%, rigidity property in above-mentioned medium hardly
Become.
The flame retardant property of basalt fibre hybrid composite manner pipe made from the present embodiment is tested, it is as a result as follows：
Oxygen index (OI) is more than 43.
60s vertical combustions：Self-extinguishing time 0s, burning length 8.9mm, without dripping off object；
60s, 45 ° of burnings：Self-extinguishing time 0s, without dripping off object；
60s, 0 ° of burning：Self-extinguishing time 0s, without dripping off object；
Smoke density：<5.8
Embodiment 3
With embodiment 1 be made basalt fibre hybrid composite manner pipe structure and preparation method it is similar, differ only in by
Second basalt fiber replaces with carbon fiber layer.
The relevant parameter of basalt fibre hybrid composite manner pipe made from embodiment 3 is tested, it is as a result as follows：Density is
1.73g/cm3, resin content 31.15%, axial tensile strength 183MPa, hoop tensile strength 463MPa, bending is by force
Degree is 573MPa, and maximum functional internal pressure is 45Mpa, is impregnated 10 days in following medium, above-mentioned strength retention ratio is as follows：Distillation
Water：>99.9%, acetone：>99.7%, saturated sodium carbonate solution：>97.3%, 10% sodium hydroxide solution：>87.5%, 10%
Ammonia spirit：>85.7%, 5% hydrochloric acid：>91.2%, 5% nitric acid：>90.3%, rigidity property in above-mentioned medium hardly
Become.
It is insulator to basalt fibre hybrid composite manner pipe made from the present embodiment.
The shielding property of basalt fibre hybrid composite manner pipe made from the present embodiment is tested, as a result such as table 1~3
It is shown, by table 1~3 it is found that basalt fibre hybrid composite manner pipe made from the present embodiment has excellent shielding property.
1 radiation resistance test result of table
2 anti-Neutron properties test result of table
Mechanical property change rate (irradiation 500kGy) after 3 gamma-ray irradiation of table
| Mechanical property | Change rate (%) |
| Stretch modulus | -3.2 |
| Tensile strength | 7.5 |
| Bending modulus | -2.8 |
| Bending strength | 1.3 |
| Interlaminar shear strength | 0.5 |
| Glass transition temperature | 0 |
Embodiment 4
Fig. 2 is the structural schematic diagram of basalt fibre hybrid composite manner pipe made from the embodiment of the present invention 4, wherein 1 is resin
Layer (0.5mm), 2 be the first basalt fiber (2mm), and 3 be glass layer (2mm), and 4 be the second basalt fiber
(1mm), 5 be glass outer fibrous layer (2mm), and 6 be third basalt fiber (2mm), and the resin layer is that epoxy resin-is profound
Military rock scale resin-rich layer.
The preparation process of the present embodiment basalt fibre hybrid composite manner pipe is as follows：
(1) by resin raw material melting extrusion, pipe embryo is obtained；
(2) the pipe embryo outer surface that the step (1) obtains successively the first basalt fibre of Wet Winding Process, glass fibre,
Second basalt fibre, glass outer fiber and third basalt fibre obtain basalt fibre hybrid composite manner pipe, winding angle
It is 51 °.
The relevant parameter of basalt fibre hybrid composite manner pipe made from embodiment 4 is tested, it is as a result as follows：Density is
1.91g/cm3, resin content 31.22%, axial tensile strength 111MPa, hoop tensile strength 247MPa, bending is by force
Degree is 314MPa, and maximum functional internal pressure is 21Mpa, is impregnated 10 days in following medium, above-mentioned strength retention ratio is as follows：Distillation
Water：>99.9%, acetone：>99.7%, saturated sodium carbonate solution：>97.3%, 10% sodium hydroxide solution：>87.5%, 10%
Ammonia spirit：>85.7%, 5% hydrochloric acid：>91.2%, 5% nitric acid：>90.3%, rigidity property in above-mentioned medium hardly
Become.
The wear-resisting property of basalt fibre hybrid composite manner pipe made from the present embodiment is tested, it is as a result as follows：Friction
Coefficient 0.38, wear rate 0.15 × 10-7cm3/(Nm)。
In the case of equal performance, cost reduction 10%~15%.
Embodiment 5
With embodiment 4 be made basalt fibre hybrid composite manner pipe structure and preparation method it is similar, differ only in profound
The structure of military rock fiber hybrid multiple tube includes the resin layer (0.5mm) stacked gradually, the first basalt fiber (2mm), glass
Glass fibrous layer (1.5mm), carbon fiber layer (2mm), glass outer fibrous layer (1.5mm), outer layer basalt fiber (2mm), institute
It is epoxy resin-basalt scale resin-rich layer to state resin layer.
The relevant parameter of basalt fibre hybrid composite manner pipe made from embodiment 5 is tested, it is as a result as follows：Density is
1.86g/cm3, resin content 30.31%, axial tensile strength 153MPa, hoop tensile strength 375MPa, bending is by force
Degree is 434MPa, and maximum functional internal pressure is 32Mpa, is impregnated 10 days in following medium, above-mentioned strength retention ratio is as follows：Distillation
Water：>99.9%, acetone：>99.7%, saturated sodium carbonate solution：>97.3%, 10% sodium hydroxide solution：>87.5%, 10%
Ammonia spirit：>85.7%, 5% hydrochloric acid：>91.2%, 5% nitric acid：>90.3%, rigidity property in above-mentioned medium hardly
Become.
The shielding property of basalt fibre hybrid composite manner pipe made from the present embodiment is tested, as a result with embodiment
3 result is similar, illustrates that basalt fibre hybrid composite manner pipe made from the present embodiment has excellent shielding property.
In the case of equal performance, cost reduction 10%~15%.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of basalt fibre hybrid composite manner pipe includes the resin layer being cascading, the first basalt fibre from inside to outside
Tie up layer, glass layer and the second basalt fiber.
2. basalt fibre hybrid composite manner pipe according to claim 1, which is characterized in that further include in the second basalt fibre
Dimension layer outer surface sets gradually glass outer fibrous layer and third basalt fiber.
3. basalt fibre hybrid composite manner pipe according to claim 1 or 2, which is characterized in that the resin layer is phenolic aldehyde
Resin-basalt scale resin-rich layer or epoxy resin-basalt scale resin-rich layer.
4. basalt fibre hybrid composite manner pipe according to claim 3, which is characterized in that the phenolic resin-basalt
The mass content of phenolic resin is 31.15% in scale resin-rich layer；The epoxy resin-basalt scale resin-rich layer middle ring
The mass content of oxygen resin is 29.21%.
5. basalt fibre hybrid composite manner pipe according to claim 1, which is characterized in that first basalt fiber
Thickness be 2mm, a diameter of 4.25mm of basalt fibre in first basalt fiber.
6. basalt fibre hybrid composite manner pipe according to claim 1 or 5, which is characterized in that the glass layer
Thickness is 1.5~5mm, a diameter of 3.22mm~10.22mm of glass fibre in the glass layer.
7. basalt fibre hybrid composite manner pipe according to claim 1 or 5, which is characterized in that second basalt is fine
The thickness for tieing up layer is 1.5~5mm, a diameter of 3.25mm~10.25mm of basalt fibre in second basalt fiber.
8. basalt fibre hybrid composite manner pipe according to claim 1, which is characterized in that by second basalt fibre
Layer replaces with carbon fiber layer.
9. basalt fibre hybrid composite manner pipe according to claim 8, which is characterized in that further include in the carbon fiber layer
Surface sets gradually glass outer fibrous layer and outer layer basalt fiber.
10. the preparation method of basalt fibre hybrid composite manner pipe, includes the following steps：
(1) resin raw material is sprayed on tubular die surface, obtains resin layer；
(2) in the resin layer outer surface that the step (1) obtains successively the first Wet Winding Process basalt fibre, Wet Winding Process glass
Fiber and the second Wet Winding Process basalt fibre obtain molding multiple tube；
(3) the molding multiple tube for obtaining the step (2) cures, and obtains basalt fibre hybrid composite manner pipe.
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| CN201810394025.2A CN108443597A (en) | 2018-04-27 | 2018-04-27 | A kind of basalt fibre hybrid composite manner pipe and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810394025.2A CN108443597A (en) | 2018-04-27 | 2018-04-27 | A kind of basalt fibre hybrid composite manner pipe and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109458498A (en) * | 2018-12-25 | 2019-03-12 | 浙江鸿盛环保科技集团有限公司 | A kind of high intensity PTFE multiple tube and preparation method thereof |
| CN110454620A (en) * | 2019-08-20 | 2019-11-15 | 蔡樟森 | A kind of anticorrosion water supply line |
| CN110985771A (en) * | 2019-12-26 | 2020-04-10 | 衡水瑞纤新材料科技有限公司 | Basalt fiber reinforced composite pipe |
| CN111022820A (en) * | 2019-12-19 | 2020-04-17 | 江苏众信绿色管业科技有限公司 | Lining pipe for stainless steel pipeline repair and repair process |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008106194A (en) * | 2006-10-27 | 2008-05-08 | Sumitomo Bakelite Co Ltd | Thermosetting resin molding material |
| WO2010056147A1 (en) * | 2008-11-17 | 2010-05-20 | Закрытое Акционерное Общество "Базальтопластик" | “basalite stone resin” anticorrosion protective coating |
| CN204459508U (en) * | 2015-03-02 | 2015-07-08 | 新疆中石油管业工程有限公司 | A kind of continuous lod thermosetting resin composite pipe with two angle wound structure |
| CN104913185A (en) * | 2015-06-19 | 2015-09-16 | 沈阳中复科金压力容器有限公司 | Basalt fiber and carbon fiber hybrid composite compressed natural gas cylinder and preparation method thereof |
| CN205036310U (en) * | 2015-10-09 | 2016-02-17 | 新疆中石油管业工程有限公司 | Shale is pipeline for gas |
| JP2016210032A (en) * | 2015-04-30 | 2016-12-15 | 宇部エクシモ株式会社 | Fiber-reinforced resin composite tubular structure and method for manufacturing the same |
| CN106590356A (en) * | 2016-11-09 | 2017-04-26 | 安徽梦谷纤维材料科技有限公司 | Basalt flake anticorrosion paint |
| CN107384118A (en) * | 2017-06-15 | 2017-11-24 | 东南大学 | Modified basalt scale solvent-free epoxy resin anticorrosive paint and preparation method thereof |
| CN208565837U (en) * | 2018-04-27 | 2019-03-01 | 施柏山 | A kind of basalt fibre hybrid composite manner pipe |
-
2018
- 2018-04-27 CN CN201810394025.2A patent/CN108443597A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008106194A (en) * | 2006-10-27 | 2008-05-08 | Sumitomo Bakelite Co Ltd | Thermosetting resin molding material |
| WO2010056147A1 (en) * | 2008-11-17 | 2010-05-20 | Закрытое Акционерное Общество "Базальтопластик" | “basalite stone resin” anticorrosion protective coating |
| CN204459508U (en) * | 2015-03-02 | 2015-07-08 | 新疆中石油管业工程有限公司 | A kind of continuous lod thermosetting resin composite pipe with two angle wound structure |
| JP2016210032A (en) * | 2015-04-30 | 2016-12-15 | 宇部エクシモ株式会社 | Fiber-reinforced resin composite tubular structure and method for manufacturing the same |
| CN104913185A (en) * | 2015-06-19 | 2015-09-16 | 沈阳中复科金压力容器有限公司 | Basalt fiber and carbon fiber hybrid composite compressed natural gas cylinder and preparation method thereof |
| CN205036310U (en) * | 2015-10-09 | 2016-02-17 | 新疆中石油管业工程有限公司 | Shale is pipeline for gas |
| CN106590356A (en) * | 2016-11-09 | 2017-04-26 | 安徽梦谷纤维材料科技有限公司 | Basalt flake anticorrosion paint |
| CN107384118A (en) * | 2017-06-15 | 2017-11-24 | 东南大学 | Modified basalt scale solvent-free epoxy resin anticorrosive paint and preparation method thereof |
| CN208565837U (en) * | 2018-04-27 | 2019-03-01 | 施柏山 | A kind of basalt fibre hybrid composite manner pipe |
Non-Patent Citations (2)
| Title |
|---|
| 崔向红: "玄武岩鳞片在防腐防污涂料中的应用及发展", 现代涂料与涂装, vol. 21, no. 4, pages 25 - 26 * |
| 徐竹, 复合材料成型工艺及应用, pages 26 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109458498A (en) * | 2018-12-25 | 2019-03-12 | 浙江鸿盛环保科技集团有限公司 | A kind of high intensity PTFE multiple tube and preparation method thereof |
| CN109458498B (en) * | 2018-12-25 | 2024-02-27 | 浙江鸿盛新材料科技集团股份有限公司 | High-strength PTFE composite pipe and preparation method thereof |
| CN110454620A (en) * | 2019-08-20 | 2019-11-15 | 蔡樟森 | A kind of anticorrosion water supply line |
| CN110454620B (en) * | 2019-08-20 | 2021-02-23 | 江西省共青城润泉供水有限公司 | Anti-corrosion water supply pipeline |
| CN111022820A (en) * | 2019-12-19 | 2020-04-17 | 江苏众信绿色管业科技有限公司 | Lining pipe for stainless steel pipeline repair and repair process |
| CN110985771A (en) * | 2019-12-26 | 2020-04-10 | 衡水瑞纤新材料科技有限公司 | Basalt fiber reinforced composite pipe |
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