CN108414469A - Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device and method is scanned based on TDLAS - Google Patents
Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device and method is scanned based on TDLAS Download PDFInfo
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- CN108414469A CN108414469A CN201810254957.7A CN201810254957A CN108414469A CN 108414469 A CN108414469 A CN 108414469A CN 201810254957 A CN201810254957 A CN 201810254957A CN 108414469 A CN108414469 A CN 108414469A
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- 238000000041 tunable diode laser absorption spectroscopy Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000010521 absorption reaction Methods 0.000 claims abstract description 20
- 230000008878 coupling Effects 0.000 claims abstract description 17
- 238000010168 coupling process Methods 0.000 claims abstract description 17
- 238000005859 coupling reaction Methods 0.000 claims abstract description 17
- 239000011505 plaster Substances 0.000 claims abstract description 17
- 230000003287 optical effect Effects 0.000 claims abstract description 4
- 235000019504 cigarettes Nutrition 0.000 claims description 25
- 238000012545 processing Methods 0.000 claims description 17
- 238000005259 measurement Methods 0.000 claims description 15
- 230000001133 acceleration Effects 0.000 claims description 8
- 239000000779 smoke Substances 0.000 claims description 6
- DGJPPCSCQOIWCP-UHFFFAOYSA-N cadmium mercury Chemical compound [Cd].[Hg] DGJPPCSCQOIWCP-UHFFFAOYSA-N 0.000 claims description 4
- 238000012937 correction Methods 0.000 claims description 4
- 230000007613 environmental effect Effects 0.000 claims description 4
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000011088 calibration curve Methods 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 3
- 238000004458 analytical method Methods 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000010606 normalization Methods 0.000 claims description 2
- 229910000661 Mercury cadmium telluride Inorganic materials 0.000 claims 1
- MCMSPRNYOJJPIZ-UHFFFAOYSA-N cadmium;mercury;tellurium Chemical compound [Cd]=[Te]=[Hg] MCMSPRNYOJJPIZ-UHFFFAOYSA-N 0.000 claims 1
- 238000012360 testing method Methods 0.000 abstract description 6
- 230000003595 spectral effect Effects 0.000 abstract description 4
- 230000035945 sensitivity Effects 0.000 abstract description 2
- 238000000691 measurement method Methods 0.000 description 4
- ORQBXQOJMQIAOY-UHFFFAOYSA-N nobelium Chemical compound [No] ORQBXQOJMQIAOY-UHFFFAOYSA-N 0.000 description 3
- 238000003915 air pollution Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N21/49—Scattering, i.e. diffuse reflection within a body or fluid
- G01N21/53—Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
- G01N2021/396—Type of laser source
- G01N2021/399—Diode laser
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- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
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- Optics & Photonics (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
The present invention relates to one kind scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device and method based on TDLAS,It is set to go out the target absorption peak that optical wavelength covers under test gas by the temperature and current control of laser,Realize that the height of multiple beam is coaxial or overlaps by free light output multi-wavelength coupling unit,Light beam after coupling realizes transceiving integrated and light beam the scanning of light beam by off axis paraboloidal mirror and the hexagonal mirror of rotation,The hexagonal mirror of rotation makes the scanning of coupling light beam reach the strip reflection plaster for being layed in ground by exhaust emissions plume,The reflected light of reflection plaster is focused into detector by transceiver structure again,Detector signal is received and is handled by acquisition process unit,Obtain exhaust emissions information,It further include the wavelength real-time lock that wavelength locking unit realizes each laser in device,Without carrying out frequent calibration to system.This measuring device can realize that high sensitivity, high spectral resolution, real-time, efficient exhaust emissions measure.
Description
Technical field
It is specifically that one kind scanning transceiver based on TDLAS the present invention relates to motor-vehicle tail-gas remote sensing survey field
Formula motor-vehicle tail-gas remote sensing survey device and method.
Background technology
With the rapid development of economy, automotive emission has become the important sources of urban air pollution, Chinese Ministry of Environmental Protection
The first batch of PM2.5 source resolutions that carry out the result shows that, the PM2.5 in the cities such as Beijing, Shanghai has 15% ~ 52% contribution of concentration to be originated from machine
Motor-car exhaust emissions.And from 2012, diesel exhaust was clearly carcinogenic substance scope by health organization.Therefore, quickly true
Measuring automotive emission is very important to prevention and cure of air pollution.Country《Air method》Clearly stipulate that from 2016, it can
Tail gas telemetering is carried out to the motor vehicle travelled in road under conditions of not influencing traffic, then in March, 2017, Chinese Ministry of Environmental Protection's needle
Remote sensing detection method is write《Exhaust emission limit value and measurement method》Preliminary version, automotive emission standard control
System is increasingly stringenter, this also proposed tail gas telemetry system the requirement of higher standard, it is especially desirable to it is highly sensitive to be suitable for high-precision
The rectilinear remote exhaust emission detection device of degree.
Existing emission measuring equipment, in order to realize measurement of multi-components, it usually needs will be infrared（For measuring CO and CO2）With
Ultraviolet source（For measuring NOX and CH）It is combined, NOx and CH is measured mostly using wideband light source, this can be limited
The spectral resolution of system is unfavorable for the further promotion of systematic survey accuracy.In addition, being set for rectilinear emission measuring
It is standby, it mainly is laid with catoptric arrangement on ground, realizes V-arrangement or W-shaped reflective measurement.However, different types of automobile exhausting
Pipeline location is different, and along with the randomness of vehicle traveling-position in the road, these can all further increase measurement knot
The fault rate and misdetection rate of fruit.
Invention content
In view of the above-mentioned problems, the present invention is intended to provide a kind of scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing based on TDLAS
Synchronous, efficient, the accurate measurement of multicomponent in exhaust emission may be implemented in measuring device and method.
Device of the present invention adopts the following technical scheme that：One kind scanning transmitting-receiving integrated motor-driven vehicle based on TDLAS
Gas remote sensing survey device, the system include：Multi-wavelength coupled laser emitter, center open porose concave mirror, rotation it is just more
Face body speculum, strip reflection plaster, detector, detector control unit, acquisition and processing unit, industrial personal computer；The concave mirror
On the emitting light path of multi-wavelength coupled laser emitter and the emergent light of multi-wavelength coupled laser emitter is across recessed
The centre bore of face mirror is incident to rotation regular polygon speculum；The strip reflection plaster is located under rotation regular polygon speculum
Side；The reflecting surface of concave mirror is located at towards regular polygon speculum and detector in the focus of concave mirror；Detector control unit
Signal output end be connected with the control terminal of detector, the signal output end of detector and acquisition are defeated with the signal of processing unit
Enter end to be connected；Acquisition is connected with the signal output end of processing unit with the signal input part of industrial personal computer；Concave mirror and rotation
The position relationship of regular polygon speculum can make the laser irradiation passed through through concave mirror centre bore extremely rotation regular polygon speculum,
The incident laser is reflexed to strip reflection plaster by rotation regular polygon speculum, is being revolved through the irreflexive laser of strip reflection plaster
Detector is converged to by concave mirror after polygonal mirror of becoming a full member reflection.
By multi-wavelength coupled laser emitter outgoing be highly coupled after light beam pass through the concave mirror centre bore to
Up to the rotation regular polygon mirror surface, the reflected beams of the regular polygon speculum are arrived across motor-vehicle tail-gas plume
Up to the strip reflection plaster, the reflection plaster diffuses again by the rotation regular polygon speculum and the concave mirror
The detector is reflected and focuses to, the detector control unit controls the detector and ensures its steady operation, the spy
The photoelectric output signal for surveying device carries out the exhaust smoke group concentration value that processing calculates discharge by described acquire with processing unit, described to adopt
Collection carries out control data with the concentration information of processing unit and the output information of the subsidiary unit by the industrial personal computer
Upload and preservation.
Further, described that transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned including assisting survey based on TDLAS
Unit is measured, which includes speed and acceleration analysis, meteorologic parameter measurement, Car license recognition measurement module, difference
Speed and acceleration, the environment weather parameter and candid photograph by vehicle when for measuring, survey motor vehicle passes through measuring device
And identification, control is carried out by the system control unit and uploads and preserves with data.
Further, the multi-wavelength coupled laser emitter include laser control unit, multiple laser elements,
Multi-wavelength beam coupling unit and wavelength locking unit；The laser control unit controls each laser element；It is each to swash
The laser of light device unit outgoing enters the coupling output of multi-wavelength beam coupling unit to wavelength locking unit, by wavelength locking list
Output after after first wavelength locking；The signal output end of wavelength locking unit is connected with the signal input part of industrial personal computer, laser
The signal input part of control unit is connected with the signal output end of industrial personal computer.
By the laser in the laser control unit control laser element, make each laser output wavelength
The absorption peak that scanning passes through under test gas.The multichannel light beam of each laser output passes through multi-wavelength beam in the laser element
Coupling unit realizes being highly coupled for light beam.
Further, the laser element includes near-infrared infrared Distributed Feedback Laser in, can be according to HITRAN data
Under test gas absorbs analog case to select suitable laser in library.
Further, concave mirror uses off axis paraboloidal mirror, rotation regular polygon speculum to use hexagonal mirror；Institute
The off axis paraboloidal mirror stated and rotary hexahedral mirror structure composition scan transmitting-receiving integrated structure, complete beam emissions
With reception same light path.
Further, the laser control unit includes temperature control and the current control of laser, is on the one hand protected
Target wavelength range can normally be exported under different environmental conditions by demonstrate,proving each laser in the laser element, on the other hand
The laser control unit can also give each laser load-modulate signal in the laser element, and modulating frequency can be
KHz magnitudes are advantageously implemented the quick measurement of tail gas.
Further, the detector is thermoelectric cooling working method, can be the infrared tellurium cadmium of single broadband response
Mercury probe device can also be the form of narrow bandwidth mercury-cadmium tellurid detector and near-infrared indium gallium arsenic combinations of detectors.The detector
Ensure the normal work of the detector into trip temperature and current control by the detector control unit.
Further, the multi-wavelength beam coupling unit is made of a variety of optical elements, and speculum and grating can be used
The form of combination.The wavelength locking unit includes the components such as spectroscope, absorption cell and detector, to the laser control
Unit carries out feedback control, realizes the wavelength real-time lock of each laser in the laser element, is not necessarily to the frequent mark of system
Fixed and calibration.The strip reflection plaster is a kind of catoptric arrangement being coated with reflectorized material, for across the unrestrained of tail gas plume light beam
Reflection, it is horizontal to be layered on the underface that the rotary hexahedral speculum is placed in institute's measuring car road.
The acquisition is to handle the photoelectric conversion signal of detector, and inhaled according to the spectrum of acquisition with processing unit
The collection of letters number, the temperature information that surveyed cigarette is rolled into a ball is released in conjunction with Infrared spectra adsorption theory, is carried out temperature adjustmemt to measurement result, is improved
The accuracy of measurement result.
The method of the invention adopts the following technical scheme that：One kind scanning transmitting-receiving integrated motor-driven vehicle based on TDLAS
Gas remote sensing survey method, includes the following steps：
1) each light intensity normalization harmonic spike calibration curve for measuring gas is obtained first；
2）Then the theoretical temperature correction curve for obtaining each component harmonic spike；
3) cigarette of each gas rolls into a ball background value before record vehicle arrives；
4) it measures vehicle and situation of change is worth by each component cigarette group in emission in limiting time behind monitoring place, and utilize survey
The absorption signal of any component of amount is finally inversed by gas temperature, to which each component cigarette group value to acquisition carries out temperature adjustmemt, tool
Body way is：The Absorption Line width values of the component are obtained using the modulation absorption signal of arbitrary component, and according to formulaThe further temperature value of the surveyed tail gas of assessment, wherein T is the temperature for discharging cigarette group, T0For standard
Temperature value 296K, Δv（T0）For the Absorption Line width values under normal temperature, Δv（T）For at a temperature of the T of acquisition Absorption Line width values,
N is that temperature-independent coefficient can be by checking in HITRAN databases；According to the temperature for the discharge cigarette group that above formula obtains, in conjunction with step 2
In temperature correction curve, to obtain each component cigarette group value after temperature adjustmemt；5) temperature that will be obtained in limiting time
Revised each component cigarette group value carries out Integral Processing respectively, then acquire respectively after each component cigarette group value integral resulting value with
CO2Concentration proportion, and calculate the concentration information by each component in Vehicular exhaust in conjunction with burning equation；
6) smoke intensity information is obtained by computer control subsidiary unit and is believed by speed and acceleration, the number-plate number of vehicle
Breath, environment weather parameter；
7) each gas concentration measured is effectively judged in conjunction with subsidiary information, and is sentenced according to concentration control standard
Whether the measuring car discharge of disconnected institute is exceeded.
The concentration information of each component in tail gas can be fast and accurately obtained in conjunction with step 3,4,5, and fully considered
The case where amendment of temperature and tail gas are spread at any time so that measurement result is more accurate.Step 2）Middle acquisition temperature adjustmemt is bent
Line is the common knowledge of this field；Step 5）It is the known normal of this field that middle combination burning equation, which obtains each component concentration information,
Know.
Measuring device of the present invention can realize that high sensitivity, high spectral resolution, real-time, efficient exhaust emissions are surveyed
Amount.It also can be widely used in motor-vehicle tail-gas remote sensing survey, be particularly suited for rectilinear multi-lane motor vehicle tail gas discharge measuring.
The measurement method can fast and accurately obtain the cigarette group value of vehicle exhaust, greatly reduce in current vehicle exhaust measurement
Fault rate and misdetection rate.
Description of the drawings
Fig. 1 is of the present invention a kind of based on the transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device knot of TDLAS scannings
Structure schematic diagram.
101- laser control units, 102- laser elements, 103- multi-wavelength beams coupling unit, 104- wavelength locking
Unit, 105- concave mirrors, 106- rotations regular polygon speculum, 107- tail gas plume, 108- strips reflection plaster, the road surfaces 109-,
110- detectors, 111- detectors control unit, 112- acquisitions and processing unit, 113- subsidiaries unit, 114- industrial personal computers.
Specific implementation mode
Technical scheme of the present invention is described in detail with reference to the accompanying drawings and examples, here only to facilitate
Understand, it is not as a limitation of the invention.
Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey dress is scanned based on TDLAS as shown in Figure 1, the present invention provides one kind
Set, including laser control unit 101, laser element 102, multi-wavelength beam coupling unit 103, wavelength locking unit 104,
Concave mirror 105（Using off axis paraboloidal mirror）, rotation regular polygon speculum 106（Rotary hexahedral speculum）, strip it is reflective
Patch 108, detector 110, detector control unit 111, acquisition and processing unit 112, subsidiary unit 113, industrial personal computer
114.By the laser in the laser control unit control laser element, each laser output wavelength is made to scan
Pass through " fingerprint " absorption peak of under test gas.
The multichannel light beam of each laser output realizes light by multi-wavelength beam coupling unit 103 in laser element 102
Beam is highly coupled, and the light beam after coupling passes through off axis paraboloidal mirror to reach rotary hexahedral speculum, hexagonal mirror
The reflected beams reach the horizontal strip reflection plaster 108 being layered on road surface 109, strip reflection plaster 108 across motor-vehicle tail-gas plume 107
Diffuse and reflect and focus to detector 110 by rotary hexahedral speculum and off axis paraboloidal mirror again, detector control
Unit 111 processed ensure detector 110 can steady operation, the photosignal that detector 110 exports is by acquisition and processing unit 112
Handled and calculated the exhaust smoke group concentration value of discharge, concentration information and subsidiary information（Including smoke intensity, speed and acceleration
Degree, meteorologic parameter etc.）The upload and preservation for carrying out data are controlled by industrial personal computer 114.
Laser element 102 includes near-infrared and mid-infrared laser device, and can be according under test gas in HITRAN databases
Analog case is absorbed to select suitable laser scans to cover " fingerprint " absorption peak of under test gas, and laser is preferably close red
The outer infrared Distributed Feedback Laser in.
Detector 110 is thermoelectric cooling working method, can be the infrared mercury-cadmium tellurid detector of single broadband response, also may be used
In the form of being narrow bandwidth mercury-cadmium tellurid detector and near-infrared indium gallium arsenic combinations of detectors.
Multi-wavelength beam coupling unit 103 is made of a variety of optical elements, can be the form of speculum and grating combination,
It can also be the form of other elements combination.Wavelength locking unit 104 includes that components, the strips such as absorption cell and detector are reflective
Patch 108 is a kind of catoptric arrangement being coated with reflectorized material, horizontal to be layered on institute's measuring car road for the diffusing reflection across tail gas plume light beam
Inside it is placed in the underface of rotary hexahedral speculum.
Off axis paraboloidal mirror and rotary hexahedral mirror structure composition scan transmitting-receiving integrated structure, and are laid on road
In the combination of strip reflection plaster, it can be achieved that the scan-type transmitting of light beam and diffusing and receiving same light path, in this way regardless of institute's measuring car
That position of track travel, can obtain light beam scanning cross section in diffusion plume absorption spectrum information, thus into
One step obtains the plume concentration situation of different location in scanning cross section.The emission measuring device of this structure, on the one hand can be with
Avoid V-type reflect and W type catoptric arrangements false pass rate and False Rate, on the other hand can also be according to the different location of inverting at
Plume concentration distribution situation further infers that whether measured result is influenced by adjacent lane discharge.
Acquisition is handled the photoelectric conversion signal of detector with processing unit 112, and according to the spectral absorption of acquisition
Signal is released the temperature information that surveyed cigarette is rolled into a ball in conjunction with Infrared spectra adsorption theory, is repaiied into trip temperature to gas plume measurement result
Just.Because the harmonic signal of surveyed gas is related with the temperature of gas and pressure, and under open state, the pressure of gas
An about atmospheric pressure, and for the temperature of gas, the exhaust temperature of exhaust pipe discharge is very high, and tail gas plume dispersion is non-
It is often fast, so surveyed plume temperature is greater than environment temperature actually and not equal to ambient air temperature when plume measures,
So being needed when accurate tail gas measurement of concetration modified in real time into trip temperature.
The present invention use specific measurement method for：Each calibration curve for measuring gas is obtained first；It measures in tail gas plume
The cigarette group value of each gas, and the absorption signal of any gas is handled, the Absorption Line width values of the gas are obtained, into one
Step, which obtains, measures the corresponding gas temperature angle value of tail gas plume, and temperature adjustmemt is carried out to the cigarette group value measured；Record vehicle arrives it
Preceding each gas cigarette rolls into a ball background value；It measures vehicle and situation of change is rolled into a ball by the cigarette in limiting time behind monitoring place；It will be when limiting
Each component cigarette group value after the temperature adjustmemt of interior acquisition carries out Integral Processing respectively, then acquires each component cigarette group value product respectively
Resulting value and CO after point2Concentration proportion, go out through each gas in Vehicular exhaust in conjunction with burning equation Inversion Calculation appropriate
Absolute concentration information；Subsidiary unit is controlled to obtain smoke intensity information and by speed and acceleration, the number-plate number of vehicle believe
Breath, environment weather parameter etc.；Each gas concentration measured is effectively judged in conjunction with subsidiary information, and combines concentration control
Standard processed is judged whether institute's measuring car discharge is exceeded.
Above each implementation is only used for the description of the invention and description, and apparatus structure of the present invention and measurement method are simultaneously
It is not limited to this, it is every carry out on the basis of the present invention it is same replacement and improvement, should all protection scope of the present invention it
It is interior.
Claims (9)
1. one kind scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device based on TDLAS, it is characterised in that the device includes：
Porose concave mirror is opened at multi-wavelength coupled laser emitter, center（105）, rotation regular polygon speculum（106）, strip it is anti-
Light pastes（108）, detector（110）, detector control unit（111）, acquisition and processing unit（112）, industrial personal computer（114）；Institute
State concave mirror（105）On the emitting light path of multi-wavelength coupled laser emitter and multi-wavelength coupled laser emitter
Emergent light passes through concave mirror（105）Centre bore be incident to rotation regular polygon speculum（106）；The strip reflection plaster
（108）Positioned at rotation regular polygon speculum（106）Lower section road surface（109）On；Concave mirror（105）Reflecting surface towards just
Polygonal mirror（106）And detector（110）Positioned at concave mirror（105）Focus on；Detector control unit（111）Letter
Number output end and detector（110）Control terminal be connected, detector（110）Signal output end and acquisition and processing unit
（112）Signal input part be connected；Acquisition and processing unit（112）Signal output end and industrial personal computer（114）Signal it is defeated
Enter end to be connected；Concave mirror（105）With rotation regular polygon speculum（106）Position relationship can make through concave mirror（105）In
The laser irradiation that heart hole passes through extremely rotation regular polygon speculum（106）, rotate regular polygon speculum（106）The incidence is swashed
Light reflection is to strip reflection plaster（108）, through strip reflection plaster（108）Irreflexive laser is by rotation regular polygon speculum
（106）By concave mirror after reflection（105）Converge to detector（110）.
2. scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device based on TDLAS as described in claim 1, feature exists
In further including and industrial personal computer（114）The subsidiary unit that signal input part is connected（113）；The subsidiary unit
（113）It is measured including speed and acceleration analysis, meteorologic parameter, Car license recognition measurement module, is respectively used to survey motor-driven
Speed and acceleration, environment weather parameter and candid photograph and identification by vehicle when vehicle passes through measuring device, by the work
Control machine（114）Control is carried out to upload and preserve with data.
3. scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device based on TDLAS as claimed in claim 2, feature exists
In the multi-wavelength coupled laser emitter includes laser control unit（101）, multiple laser elements（102）, more waves
Long light beam coupling unit（103）And wavelength locking unit（104）；The laser control unit（101）Control each laser
Device unit（102）；Each laser element（102）The laser of outgoing enters multi-wavelength beam coupling unit（103）Coupling output is extremely
Wavelength locking unit（104）, by wavelength locking unit（104）It is exported after wavelength locking；Wavelength locking unit（104）Signal
Output end and industrial personal computer（114）Signal input part be connected, laser control unit（101）Signal input part and industrial personal computer
（114）Signal output end be connected.
4. scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device based on TDLAS as claimed in claim 3, feature exists
In the laser element（102）Including near-infrared and in infrared Distributed Feedback Laser, can be according to be measured in HITRAN databases
Gas absorbs analog case to select the laser of suitable wavelength.
5. transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned as claim 1 ~ 4 any one of them is based on TDLAS,
It is characterized in that, concave mirror（105）Using off axis paraboloidal mirror, regular polygon speculum is rotated（106）It is reflected using hexahedron
Mirror；The off axis paraboloidal mirror and rotary hexahedral mirror structure composition scan transmitting-receiving integrated structure, complete light
Beam is transceiving integrated and the scanning of light beam.
6. scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device based on TDLAS as claimed in claim 3, feature exists
In the laser control unit（101）Temperature control including laser and current control, on the one hand ensure the laser
Device unit（102）In each laser can normally export target wavelength range under different environmental conditions, described in another aspect
Laser control unit（101）The laser element can also be given（102）In each laser load-modulate signal, modulating frequency can
Think kHz magnitudes, is advantageously implemented the quick measurement of tail gas.
7. transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned as claim 1 ~ 4 any one of them is based on TDLAS,
It is characterized in that, the detector（110）It is thermoelectric cooling working method, can is the infrared mercury cadmium telluride of single broadband response
Detector can also be the form of narrow bandwidth mercury-cadmium tellurid detector and near-infrared indium gallium arsenic combinations of detectors；The detector
（110）By the detector control unit（111）Ensure the normal work of the detector into trip temperature and current control.
8. transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned based on TDLAS as described in claim 3 or 4 or 6,
It is characterized in that, the multi-wavelength beam coupling unit（103）It is made of a variety of optical elements, speculum and grating combination can be used
Form；The wavelength locking unit（104）Including spectroscope, absorption cell and detector component, each laser is carried out real
When wavelength locking, the strip reflection plaster（108）It is a kind of catoptric arrangement being coated with reflectorized material, for across tail gas plume light
The diffusing reflection of beam, horizontal be layered in institute's measuring car road are placed in the rotation regular polygon speculum（106）Underface.
9. one kind scanning transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey method based on TDLAS, any using such as claim 2-8
Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned based on TDLAS to realize described in, which is characterized in that comprising with
Lower step：
1) each light intensity normalization harmonic spike calibration curve for measuring gas is obtained first；
2）Then the theoretical temperature correction curve for obtaining each component harmonic spike；
3) cigarette of each gas rolls into a ball background value before record vehicle arrives；
4) it measures vehicle and situation of change is worth by each component cigarette group in emission in limiting time behind monitoring place, and utilize survey
The absorption signal of any component of amount is finally inversed by gas temperature, to which each component cigarette group value to acquisition carries out temperature adjustmemt, tool
Body way is：The Absorption Line width values of the component are obtained using the modulation absorption signal of arbitrary component, and according to formulaThe further temperature value of the surveyed tail gas of assessment, wherein T is the temperature for discharging cigarette group, T0For standard
Temperature value 296K, Δv（T0）For the Absorption Line width values under normal temperature, Δv（T）For at a temperature of the T of acquisition Absorption Line width values,
N is that temperature-independent coefficient can be by checking in HITRAN databases；According to the temperature for the discharge cigarette group that above formula obtains, in conjunction with step 2
In temperature correction curve, to obtain each component cigarette group value after temperature adjustmemt；
5) each component cigarette group value after the temperature adjustmemt obtained in limiting time is subjected to Integral Processing respectively, then asked respectively
Obtain resulting value and CO after each component cigarette group value integrates2Concentration proportion, and calculate by Vehicular exhaust in conjunction with burning equation
The concentration information of each component；
6) smoke intensity information is obtained by computer control subsidiary unit and is believed by speed and acceleration, the number-plate number of vehicle
Breath, environment weather parameter；
7) each gas concentration measured is effectively judged in conjunction with subsidiary information, and is sentenced according to concentration control standard
Whether the measuring car discharge of disconnected institute is exceeded.
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110044843A (en) * | 2019-05-24 | 2019-07-23 | 杭州电子科技大学 | Tail gas telemetering equipment based on Near-infrared Tunable diode laser spectrum technology |
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| CN111351769A (en) * | 2018-12-24 | 2020-06-30 | 中国科学院合肥物质科学研究院 | Trace gas concentration field distribution detection method based on wavelength modulation technology |
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Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11337483A (en) * | 1998-05-28 | 1999-12-10 | Mitsubishi Heavy Ind Ltd | Apparatus and method for measuring exhaust gas of running vehicle |
| CN1439880A (en) * | 2003-01-21 | 2003-09-03 | 中国科学院安徽光学精密机械研究所 | Method and apparatus for real time remote determining multiple pollutants in vehicle exhaust |
| US20100328660A1 (en) * | 2009-06-29 | 2010-12-30 | Hager J Stewart | Device for remote sensing of vehicle emission |
| US8269971B1 (en) * | 2009-11-12 | 2012-09-18 | Exelis, Inc. | System and method for simultaneous detection of a gas using a mode-locked based transmitter |
| DE102012004977B3 (en) * | 2012-03-14 | 2013-04-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Apparatus and method for measuring a target gas |
| CN104596987A (en) * | 2015-02-03 | 2015-05-06 | 中国科学院合肥物质科学研究院 | Mid-infrared spectroscopy-based trace gas detection method and device combining long-optical-path open light path with wavelength modulation technique |
| CN105300912A (en) * | 2015-09-16 | 2016-02-03 | 上海安允科技有限公司 | System for monitoring a variety of dangerous gases based on absorption spectrum remote sensing technology |
| CN106845371A (en) * | 2016-12-31 | 2017-06-13 | 中国科学技术大学 | A kind of city road network automotive emission remote sensing monitoring system |
| CN206531778U (en) * | 2016-11-09 | 2017-09-29 | 浙江多普勒环保科技有限公司 | A kind of many light path remote exhaust emission test devices |
| CN206710256U (en) * | 2017-05-03 | 2017-12-05 | 安徽宝龙环保科技有限公司 | A kind of Design of Vehicle Tail Gas Analyzer |
| CN207964624U (en) * | 2018-03-27 | 2018-10-12 | 山西中科华仪科技有限公司 | Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned based on TDLAS |
-
2018
- 2018-03-27 CN CN201810254957.7A patent/CN108414469B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11337483A (en) * | 1998-05-28 | 1999-12-10 | Mitsubishi Heavy Ind Ltd | Apparatus and method for measuring exhaust gas of running vehicle |
| CN1439880A (en) * | 2003-01-21 | 2003-09-03 | 中国科学院安徽光学精密机械研究所 | Method and apparatus for real time remote determining multiple pollutants in vehicle exhaust |
| US20100328660A1 (en) * | 2009-06-29 | 2010-12-30 | Hager J Stewart | Device for remote sensing of vehicle emission |
| US8269971B1 (en) * | 2009-11-12 | 2012-09-18 | Exelis, Inc. | System and method for simultaneous detection of a gas using a mode-locked based transmitter |
| DE102012004977B3 (en) * | 2012-03-14 | 2013-04-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Apparatus and method for measuring a target gas |
| WO2013135611A2 (en) * | 2012-03-14 | 2013-09-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Apparatus and method for measuring a target gas |
| CN104596987A (en) * | 2015-02-03 | 2015-05-06 | 中国科学院合肥物质科学研究院 | Mid-infrared spectroscopy-based trace gas detection method and device combining long-optical-path open light path with wavelength modulation technique |
| CN105300912A (en) * | 2015-09-16 | 2016-02-03 | 上海安允科技有限公司 | System for monitoring a variety of dangerous gases based on absorption spectrum remote sensing technology |
| CN206531778U (en) * | 2016-11-09 | 2017-09-29 | 浙江多普勒环保科技有限公司 | A kind of many light path remote exhaust emission test devices |
| CN106845371A (en) * | 2016-12-31 | 2017-06-13 | 中国科学技术大学 | A kind of city road network automotive emission remote sensing monitoring system |
| CN206710256U (en) * | 2017-05-03 | 2017-12-05 | 安徽宝龙环保科技有限公司 | A kind of Design of Vehicle Tail Gas Analyzer |
| CN207964624U (en) * | 2018-03-27 | 2018-10-12 | 山西中科华仪科技有限公司 | Transmitting-receiving integrated motor-vehicle tail-gas remote sensing survey device is scanned based on TDLAS |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111351769A (en) * | 2018-12-24 | 2020-06-30 | 中国科学院合肥物质科学研究院 | Trace gas concentration field distribution detection method based on wavelength modulation technology |
| CN110044843A (en) * | 2019-05-24 | 2019-07-23 | 杭州电子科技大学 | Tail gas telemetering equipment based on Near-infrared Tunable diode laser spectrum technology |
| CN110887805A (en) * | 2019-11-20 | 2020-03-17 | 上海化工研究院有限公司 | Regional anomalous gas detection device of multiple spot sight |
| US20220172343A1 (en) * | 2020-11-27 | 2022-06-02 | Airbus Operations (S.A.S.) | Method for detecting potential dents in a surface able to reflect light, system and computer program for the implementation thereof |
| US11803956B2 (en) * | 2020-11-27 | 2023-10-31 | Airbus Operations (S.A.S.) | Method for detecting potential dents in a surface able to reflect light, system and computer program for the implementation thereof |
| CN112634358B (en) * | 2020-12-30 | 2022-06-14 | 安徽宝龙环保科技有限公司 | Vehicle tail gas smoke group positioning detection method, device, equipment, storage medium and system |
| CN112782128A (en) * | 2020-12-30 | 2021-05-11 | 安徽宝龙环保科技有限公司 | Optical linearization structure and method for improving smoke intensity nonlinearity of tail gas remote measuring device |
| CN112634358A (en) * | 2020-12-30 | 2021-04-09 | 安徽宝龙环保科技有限公司 | Vehicle tail gas smoke group positioning detection method, device, equipment, storage medium and system |
| CN112748088A (en) * | 2021-01-04 | 2021-05-04 | 安徽中科华仪科技有限公司 | Double-light-path transceiving integrated vertical motor vehicle tail gas remote sensing device |
| CN113324934A (en) * | 2021-06-16 | 2021-08-31 | 深圳市英宝硕科技有限公司 | Gas detection positioning system |
| CN113970523A (en) * | 2021-09-17 | 2022-01-25 | 安徽中科华仪科技有限公司 | Shore-based full-laser ship tail gas remote sensing detection method |
| CN115372313A (en) * | 2022-10-21 | 2022-11-22 | 合肥金星智控科技股份有限公司 | Detection light path and detection system based on TDLAS technology |
| CN115824995A (en) * | 2023-02-22 | 2023-03-21 | 天津市极光创新智能科技有限公司 | Infrared laser diffuse reflection monitoring method and system for gas analysis |
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