CN108411637A - A kind of preparation method of effective corrosion-resistant high-temperature compound fabric - Google Patents

A kind of preparation method of effective corrosion-resistant high-temperature compound fabric Download PDF

Info

Publication number
CN108411637A
CN108411637A CN201810284928.5A CN201810284928A CN108411637A CN 108411637 A CN108411637 A CN 108411637A CN 201810284928 A CN201810284928 A CN 201810284928A CN 108411637 A CN108411637 A CN 108411637A
Authority
CN
China
Prior art keywords
parts
compound fabric
dressing liquid
preparation
resistant high
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810284928.5A
Other languages
Chinese (zh)
Inventor
王海燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Jia Xin New Mstar Technology Ltd
Original Assignee
Dongguan Jia Xin New Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Jia Xin New Mstar Technology Ltd filed Critical Dongguan Jia Xin New Mstar Technology Ltd
Priority to CN201810284928.5A priority Critical patent/CN108411637A/en
Publication of CN108411637A publication Critical patent/CN108411637A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D06M10/10—Macromolecular compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/22—Polymers or copolymers of halogenated mono-olefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses a kind of preparation methods of effective corrosion-resistant high-temperature compound fabric, specifically include following steps：First using ethylene tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning, using ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber as raw material, compound fabric is made, the first dressing liquid is prepared as raw material using polyurethane resin, acrylic modified epoxy resin and deionized water, cordierite powder, crosslinking agent, Tea Saponin, argy wormwood powder, Cocoamidopropyl betaine；Using calcium chloride, chitosan and deionized water, α sodium olefin sulfonates, nano-titanium oxide the second dressing liquid is prepared as raw material；Last finish fabric.Compound fabric soft comfortable produced by the present invention, antiseptic property is excellent, high temperature resistant.

Description

A kind of preparation method of effective corrosion-resistant high-temperature compound fabric
Technical field：
The present invention relates to textile preparation fields, are specifically related to a kind of preparation side of effective corrosion-resistant high-temperature compound fabric Method.
Background technology：
With the improvement of living standards, people tend to diversification to the performance requirement of textile, pure textile material is insufficient Meets the needs of people.So many people's researchs now obtain a kind of compound fabric by each fiber or other materials are compound, this The performance that kind compound fabric had both maintained basic material a little, is learnt from other's strong points to offset one's weaknesses, to meet people's further through compound other materials Different demands.And as people are to physical performance increasingly higher demands of weaving, the functional treatment of textile also receives more Carry out more concerns.
Invention content：
It is multiple made from this method the object of the present invention is to provide a kind of preparation method of effective corrosion-resistant high-temperature compound fabric Closing fabric not only has excellent mechanical property, and high temperature resistant, antiseptic property is good, soft comfortable.
To achieve the above object, the present invention uses following technical scheme：
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 2-6h is cooled to room temperature after reaction, continuously adds Tea Saponin, Chinese mugwort Wormwood artemisia powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1-3h takes out, and microwave irradiation processing is placed in the first dressing liquid, and soak at room temperature 1-5h takes out, at 60-70 DEG C It dries, is baked at 100-110 DEG C, compound fabric is made.
As a preferred embodiment of the above technical solution, in step (2), the ETFE fibers, acid fiber by polylactic, cotton fiber and flax The mass ratio of fiber is 1:1：(3-6)：7.
As a preferred embodiment of the above technical solution, in step (3), the particle size of the cordierite powder is 200-500nm.
As a preferred embodiment of the above technical solution, in step (3), each component dosage is distinguished in parts by weight in the first dressing liquid For：20-35 parts of polyurethane resin, 5-15 parts of acrylic modified epoxy resin, 30-60 parts of deionized water, cordierite powder 3-6 Part, 0.8-2.5 parts of crosslinking agent, 1-4 parts of Tea Saponin, 2-6 parts of argy wormwood powder, 1-2 parts of Cocoamidopropyl betaine.
As a preferred embodiment of the above technical solution, in step (3), the crosslinking agent is polysilane coupling agent.
As a preferred embodiment of the above technical solution, in step (4), the parts by weight of each component are with weight in second dressing liquid Part is counted：5-10 parts of calcium chloride, 3-8 parts of chitosan, 15-30 parts of deionized water, α -0.1-0.5 parts of sodium olefin sulfonate are received 0.5-1 parts of titanium oxide of rice.
As a preferred embodiment of the above technical solution, in step (5), the power of the microwave irradiation is 300W, microwave irradiation Time is 15-35min.
As a preferred embodiment of the above technical solution, in step (5), the solid-liquid ratio of the immersion treatment is 1：(30-50).
The invention has the advantages that：
The present invention is mixed to prepare compound fabric with homemade ETFE fibers and acid fiber by polylactic, cotton fiber and flax fiber, ETFE fibers have excellent wear-resisting, high temperature resistance, and acid fiber by polylactic has certain anti-microbial property, and mechanical property is excellent Different, fabric is made using various fiber composites in the present invention, and compound fabric obtained has certain anti-corrosion, high temperature resistance；
Suitable cordierite powder is added using polyurethane resin, acrylic modified epoxy resin as film forming matter in the present invention It is modified, Tea Saponin, argy wormwood powder, Cocoamidopropyl betaine is then added, dressing liquid is made；Cordierite can effectively change The high temperature resistance of kind fabric, and can assign fabric excellent antiseptic property；Second dressing liquid produced by the present invention can be effectively fluffy Loose fabric, when arranging, the present invention uses microwave irradiation to handle first, effective bulked fabric so that the second arrangement liquid energy is more preferable Ground penetrates into fabric, to soften bulked fabric fiber, is dipped into the first dressing liquid so that first arranges liquid energy and fabric Fiber fully soaks, and is uniformly attached to fabric fibre surface, is effectively improved the corrosion-resistant high-temperature performance of fabric.
Specific implementation mode：
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：3：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 2h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：20 parts of polyurethane resin, 5 parts of acrylic modified epoxy resin, 30 parts of deionized water, violet 3 parts of green stone powder, 0.8 part of crosslinking agent, 1 part of Tea Saponin, 2 parts of argy wormwood powder, 1 part of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：5 parts of calcium chloride, 3 parts of chitosan, 15 parts of deionized water, 0.1 part of α-sodium olefin sulfonate, 0.5 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1h, solid-liquid ratio 1：30, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 1h, solid-liquid ratio It is 1：30, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the work(of the microwave irradiation Rate is 300W, and the time of microwave irradiation is 15min.
Embodiment 2
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：6：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 6h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：35 parts of polyurethane resin, 15 parts of acrylic modified epoxy resin, 60 parts of deionized water, 6 parts of cordierite powder, 2.5 parts of crosslinking agent, 4 parts of Tea Saponin, 6 parts of argy wormwood powder, 2 parts of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：10 parts of calcium chloride, 8 parts of chitosan, 30 parts of deionized water, 0.5 part of α-sodium olefin sulfonate, 1 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 3h, solid-liquid ratio 1：50, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 5h, solid-liquid ratio It is 1：50, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the work(of the microwave irradiation Rate is 300W, and the time of microwave irradiation is 35min.
Embodiment 3
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：3.5：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 3h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：23 parts of polyurethane resin, 7 parts of acrylic modified epoxy resin, 35 parts of deionized water, violet 3.5 parts of green stone powder, 1 part of crosslinking agent, 2 parts of Tea Saponin, 3 parts of argy wormwood powder, 1.2 parts of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：6 parts of calcium chloride, 4 parts of chitosan, 20 parts of deionized water, 0.2 part of α-sodium olefin sulfonate, 0.7 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1.5h, solid-liquid ratio 1：35, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 2h, feed liquid Than being 1：35, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the microwave irradiation Power is 300W, and the time of microwave irradiation is 20min.
Embodiment 4
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：4：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 4h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：26 parts of polyurethane resin, 9 parts of acrylic modified epoxy resin, 40 parts of deionized water, violet 4 parts of green stone powder, 1.5 parts of crosslinking agent, 2 parts of Tea Saponin, 4 parts of argy wormwood powder, 1.4 parts of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：7 parts of calcium chloride, 5 parts of chitosan, 22 parts of deionized water, 0.3 part of α-sodium olefin sulfonate, 0.7 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1-3h, solid-liquid ratio 1：35, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 3h, feed liquid Than being 1：40, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the microwave irradiation Power is 300W, and the time of microwave irradiation is 20min.
Embodiment 5
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：5：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 5h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：30 parts of polyurethane resin, 11 parts of acrylic modified epoxy resin, 40 parts of deionized water, 5 parts of cordierite powder, 1.5 parts of crosslinking agent, 3 parts of Tea Saponin, 5 parts of argy wormwood powder, 1.6 parts of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：8 parts of calcium chloride, 4 parts of chitosan, 20 parts of deionized water, 0.4 part of α-sodium olefin sulfonate, 0.8 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1-3h, solid-liquid ratio 1：40, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 4h, feed liquid Than being 1：40, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the microwave irradiation Power is 300W, and the time of microwave irradiation is 30min.
Embodiment 6
A kind of preparation method of effective corrosion-resistant high-temperature compound fabric, includes the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber are mixed and is broken up, combing, twisting, plying are made Then compound fabric is made in yarn；Wherein, the mass ratio of the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber is 1:1：5.5：7；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, cordierite powder, crosslinking agent is added, isothermal reaction 5h is cooled to room temperature after reaction, continuously adds Tea Saponin, argy wormwood Powder, Cocoamidopropyl betaine are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；Wherein, each group Point dosage be respectively in parts by weight：33 parts of polyurethane resin, 13 parts of acrylic modified epoxy resin, 55 parts of deionized water, 5 parts of cordierite powder, 2 parts of crosslinking agent, 3.5 parts of Tea Saponin, 5 parts of argy wormwood powder, 1.8 parts of Cocoamidopropyl betaine；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate is then added, receives Rice titanium oxide, is stirred obtained second dressing liquid；Wherein, the parts by weight of each component are distinguished in parts by weight in the second dressing liquid For：9 parts of calcium chloride, 7 parts of chitosan, 28 parts of deionized water, 0.4 part of α-sodium olefin sulfonate, 0.9 part of nano-titanium oxide；
(5) compound fabric made from step (1) is placed in the second dressing liquid, room temperature after microwave irradiation processing Immersion treatment 1-3h, solid-liquid ratio 1：45, it takes out, microwave irradiation processing is placed in the first dressing liquid, soak at room temperature 5h, feed liquid Than being 1：40, it takes out, dries at 60-70 DEG C, baked at 100-110 DEG C, compound fabric is made；Wherein, the microwave irradiation Power is 300W, and the time of microwave irradiation is 30min.
Compound fabric produced by the present invention is tested for the property below.Compound fabric is embedded in soil, test is passed through The fracture strength of different time sections compound fabric characterizes the excellent of its antiseptic property, and test result is as shown in table 1：
Table 1
From the point of view of above-mentioned test result, compound fabric antiseptic property produced by the present invention is excellent, and high temperature resistance is good.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric, which is characterized in that include the following steps：
(1) using ethylene-tetrafluoroethylene copolymer as raw material, ETFE fibers are made in spinning；
(2) ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber being mixed and is broken up, yarn is made in combing, twisting, plying, Then compound fabric is made；
(3) polyurethane resin, acrylic modified epoxy resin and deionized water are stirred evenly, then heats to 60-80 DEG C, added Enter cordierite powder, crosslinking agent, isothermal reaction 2-6h is cooled to room temperature after reaction, continuously adds Tea Saponin, mugwort powder End, Cocoamidopropyl betaine, are stirred and are placed in milled processed in grinder, and the first dressing liquid is made；
(4) calcium chloride, chitosan and deionized water are stirred obtained solution, α-sodium olefin sulfonate, nano oxygen is then added Change titanium, is stirred obtained second dressing liquid；
(5) compound fabric made from step (1) is placed in the second dressing liquid, soak at room temperature after microwave irradiation processing 1-3h is handled, is taken out, microwave irradiation processing is placed in the first dressing liquid, and soak at room temperature 1-5h takes out, and is dried at 60-70 DEG C, It is baked at 100-110 DEG C, compound fabric is made.
2. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, it is characterised in that：Step (2) in, the ETFE fibers, acid fiber by polylactic, cotton fiber and flax fiber mass ratio be 1:1：(3-6)：7.
3. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, it is characterised in that：Step (3) in, the particle size of the cordierite powder is 200-500nm.
4. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, which is characterized in that step (3) in, each component dosage is respectively in parts by weight in the first dressing liquid：20-35 parts of polyurethane resin, acrylated epoxy 5-15 parts of resin, 30-60 parts of deionized water, 3-6 parts of cordierite powder, 0.8-2.5 parts of crosslinking agent, 1-4 parts of Tea Saponin, mugwort powder 2-6 parts last, 1-2 parts of Cocoamidopropyl betaine.
5. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, it is characterised in that：Step (3) in, the crosslinking agent is polysilane coupling agent.
6. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, which is characterized in that step (4) in, the parts by weight of each component are respectively in parts by weight in second dressing liquid：5-10 parts of calcium chloride, chitosan 3-8 Part, 15-30 parts of deionized water, α -0.1-0.5 parts of sodium olefin sulfonate, 0.5-1 parts of nano-titanium oxide.
7. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, it is characterised in that：Step (5) in, the power of the microwave irradiation is 300W, and the time of microwave irradiation is 15-35min.
8. a kind of preparation method of effective corrosion-resistant high-temperature compound fabric as described in claim 1, it is characterised in that：Step (5) in, the solid-liquid ratio of the immersion treatment is 1：(30-50).
CN201810284928.5A 2018-04-02 2018-04-02 A kind of preparation method of effective corrosion-resistant high-temperature compound fabric Withdrawn CN108411637A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810284928.5A CN108411637A (en) 2018-04-02 2018-04-02 A kind of preparation method of effective corrosion-resistant high-temperature compound fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810284928.5A CN108411637A (en) 2018-04-02 2018-04-02 A kind of preparation method of effective corrosion-resistant high-temperature compound fabric

Publications (1)

Publication Number Publication Date
CN108411637A true CN108411637A (en) 2018-08-17

Family

ID=63134094

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810284928.5A Withdrawn CN108411637A (en) 2018-04-02 2018-04-02 A kind of preparation method of effective corrosion-resistant high-temperature compound fabric

Country Status (1)

Country Link
CN (1) CN108411637A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109662395A (en) * 2019-01-15 2019-04-23 浙江雷马鞋业有限公司 A kind of high-risk chemical industry place corrosion-resistant high-temperature safety shoe production method
CN114775302A (en) * 2022-04-14 2022-07-22 邦特云纤(青岛)新材料科技有限公司 Wide-color-gamut plant dyeing method for animal fibers and fabrics

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1091788A (en) * 1993-10-29 1994-09-07 刘学锋 Ceramic fibre compound textile fabrics and preparation method thereof
CN1575359A (en) * 2001-10-26 2005-02-02 杜邦公司 Lightweight denim fabric containing high strength fibers, process for making the same and clothing formed therefrom
CN102454004A (en) * 2010-10-25 2012-05-16 中国人民解放军总后勤部军需装备研究所 Composite elastic filament core-spun yarn fabric and preparation method thereof
CN107513797A (en) * 2017-08-08 2017-12-26 高密天福家纺有限公司 Long-staple cotton multilayer fabric and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1091788A (en) * 1993-10-29 1994-09-07 刘学锋 Ceramic fibre compound textile fabrics and preparation method thereof
CN1575359A (en) * 2001-10-26 2005-02-02 杜邦公司 Lightweight denim fabric containing high strength fibers, process for making the same and clothing formed therefrom
CN102454004A (en) * 2010-10-25 2012-05-16 中国人民解放军总后勤部军需装备研究所 Composite elastic filament core-spun yarn fabric and preparation method thereof
CN107513797A (en) * 2017-08-08 2017-12-26 高密天福家纺有限公司 Long-staple cotton multilayer fabric and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109662395A (en) * 2019-01-15 2019-04-23 浙江雷马鞋业有限公司 A kind of high-risk chemical industry place corrosion-resistant high-temperature safety shoe production method
CN114775302A (en) * 2022-04-14 2022-07-22 邦特云纤(青岛)新材料科技有限公司 Wide-color-gamut plant dyeing method for animal fibers and fabrics
CN114775302B (en) * 2022-04-14 2023-07-07 邦特云纤(青岛)新材料科技有限公司 Wide-color-gamut plant dyeing method for animal fibers and fabrics

Similar Documents

Publication Publication Date Title
CN104389099B (en) A kind of uvioresistant Anti-static textile fabric and preparation method thereof
CN108754867A (en) A kind of antibacterial nonwoven cloth and preparation method thereof
CN108411637A (en) A kind of preparation method of effective corrosion-resistant high-temperature compound fabric
CN102845844A (en) Method for preparing far infrared healthcare underwear fabric
CN112389040A (en) High-strength waterproof breathable carbon fiber composite fabric and preparation method thereof
CN112878041A (en) High-breathability antibacterial anti-mite fabric and preparation process thereof
CN110079924A (en) A kind of containing graphene fabric and preparation method thereof
CN106835439A (en) A kind of crease-resistant type ultraviolet-resistant fabric and preparation method thereof
CN110592713B (en) Preparation method of antibacterial polyacrylonitrile fiber
CN105544036A (en) Composite copper-ion-modified acrylic fiber blended yarn
CN106400512B (en) A kind of soft finish method of silk hemp fabric
CN104499064B (en) Anti-pilling shell fabric spinning method
CN102392353A (en) Finishing technology of chicken feather regenerated protein fabric printed and dyed cloth
CN104357948A (en) Cotton fiber modified by dead sea black mud and preparation method of cotton fiber
CN108867081A (en) A kind of preparation method of water proof fire retardant luggage cloth
CN107584835A (en) A kind of anti-bacterial flame-retardant fabric
CN103122517A (en) Inflaming-retardant and antimicrobial composite fiber fabric
CN114045679A (en) Antibacterial process of environment-friendly functional composite garment fabric
CN107419359A (en) Heat-resisting chemical fibre silk and preparation method thereof
CN106473239A (en) A kind of production technology of self-heating thermal insulation socks
CN102691206A (en) Tourmaline-containing cloth and production process thereof
CN102174744B (en) Organic/inorganic compound photooxidation resistance protecting agent and application thereof in fiber product
CN112064170A (en) Antibacterial warm-keeping fabric and preparation method thereof
CN106381541A (en) Preparation method of enteromorpha carbon nano material and regenerated cellulose blended fiber
CN105316842A (en) Manufacturing technology for novel cloth

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180817

WW01 Invention patent application withdrawn after publication