CN108384650A

CN108384650A - A kind of surface activator composition

Info

Publication number: CN108384650A
Application number: CN201810146579.0A
Authority: CN
Inventors: 蒋赞; 郑翔龙; 潘东
Original assignee: GUANGZHOU BLUEMOON INDUSTRY Co Ltd
Current assignee: GUANGZHOU BLUEMOON INDUSTRY Co Ltd
Priority date: 2018-02-12
Filing date: 2018-02-12
Publication date: 2018-08-10
Anticipated expiration: 2038-02-12
Also published as: CN108384650B

Abstract

The invention discloses a kind of surface activator compositions.This surface activator composition includes following component：(a) amine surfactants are aoxidized；(b) alkyl benzene anion surfactant；(c) non-alkyl benzene anion surfactant；(d) the other surfaces activating agent in addition to (a), (b) and (c)；The mass percent that the active matter total content of ingredient a, b, c and d account for surface activator composition is 1%~60%；The mass percent that the content of ingredient a accounts for active matter content in ingredient a, b, c and d is 67%~95%；The mass percent that the content of ingredient b accounts for active matter content in ingredient a, b, c and d is 4%~15%.The present invention is by compounding and optimizing in using easily biological-degradable, environmentally protective and natural amine oxide as the system of primary surfactant, the stripping ability that composition greasy dirt can be significantly improved meets the use demand that consumer easily deoils, quickly deoils.

Description

A kind of surface activator composition

Technical field

The present invention relates to a kind of surface activator compositions.

Background technology

The cleaning or washing of oily dirt on the surface of solids generally include the processes such as wetting, stripping, emulsification.For washing For agent aqueous solution, because of the surfactant containing sufficient amount, usually there is lower surface and interface tension, therefore soak to be not present and ask Topic；The stripping process of dirt directly affects the speed degree and ease of decontamination；Emulsification can be to liquid greasy dirt and solid Body grease even tiny particles content etc. realizes good emulsion dispersion, is an important factor for influencing detergent detergency ability.For For detergent, it is totally the key factor for determining consumer experience and experiencing that whether dirt, which can easily and quickly remove, therefore such as What is obtained to the good formula system of greasy dirt peeling effect, is that current washing field is continued for paying close attention to and it is expected that is solved asks Topic.

Engineer is formulated during seeking to greasy dirt stripping ability good composition system, the selection of surfactant It is most important, although seeming to give the exploitation that a large amount of alternative surfactants are used for detergent in literature review, Actually many raw materials are not suitable for single wash detergent used in everyday combination at low cost because of its special chemical constitution In object.In fact, considering in terms of due to economy, most of detergent composition still selects one or more traditional EO bases Nonionic surfactant and sulfonic group or sulfate anion surfactant are as primary surfactant, but the type surface Activating agent can not achieve the purpose that quickly to remove greasy dirt or thoroughly remove.Detergent compositions engineer is also by various environmental protection The challenge of factor, such as：Some ingredients for not having biodegradability cannot be considered, some ingredients with bio-toxicity It is used by limitation, the reason of efficient phosphate builder is because of body eutrophication is disabled in many countries.In addition, many Surfactant both from non-renewable energy resources petrochemical material, the type raw material in compound composition also more and more not by It advocates, but more considers the surfactant of biological source, such as the raw material in natural oil source, to obtain more green ring The composition of guarantor.

Wherein amine oxide, especially alkyl amidopropyldimethyl amine oxide are former using natural oil as the one kind in source Material arrives the patent of amine oxide at present involved in overwhelming majority detergent composition, addition is very low, by the matter of active matter Percentage is measured to indicate, generally to be less than 5%, is more existed with the content less than 2%, frequently as Babassuamidopropylamine and foam Stabilizer exists.

Currently, the oxidation amine component of high-content has only been used in only a few patent, such as the US 5698505 in the U.S..The U.S. US5698505 be related to a kind of light duty liquid or gel detergent compositions with high bubble and automatic emulsified solid grease, It includes following components by mass percentage：

(a) 10%~70% detersive surfactant, the detersive surfactant are selected from polyhydroxy fatty acid amide, non- Ionic aliphatic poly glucoside, C8-22 alkyl sulfates, C9-15 alkylbenzene sulfonates, C8-22 alkyl sulfates, C8-22 alkene sulfonates, C8-22 paraffin sulfate, C8-22 alkyl glyceryl ether sulfonates, fatty acid ester sulfonate, secondary alcohol sulphur Hydrochlorate, amphoteric detersive surfactants and their mixture；

(b) 8%~25% C10-22 amine oxides, the range of the pH of the composition 6~9, amine oxide and decontamination table The ratio of face activating agent is about 2:1 to 1:3 range；

(c) include 1%~10% Babassuamidopropylamine；

(d) include 0.001%~5% enzyme；

(e) and the mixture of 0.01%~4% magnesium ion or calcium ion or the two.

The JP6051111B of Japan is related to a kind of liquid detergent for kitchen use, it discloses：Including (A) at least one sulfuric acid Salt form or sulfonate type anion surfactant, (B) amine oxide surfactant, (C) weight average molecular weight are 400,000-four hundred Ten thousand polyethylene glycol, (D) carbon atom number are 2-10 and the water-soluble solvent containing a hydroxyl, (E) water, the mass ratio D/ of each component Ranges of the C 5~150, ranges of (the A+B)/C 10~150, ranges of (the A+B)/D 1~5；(A+B) content 10~ 50wt%, the preferably range of 15-35wt%.This document is mentioned in the description, range of the A/B ratios 0.5~15, preferably 0.5~10, more preferable 0.5~5, most preferably 1~3 range.

The CN 103249827B of China are related to a kind of liquid detergent composition, wherein the liquid detergent composition Contain following (a)~(c) ingredients：(a) it is selected from the compound of aliphatic acid and its one or more of salt that carbon atom number is 8~14 0.5~10wt%, and containing fatty acid salt, which is the conversion amount of aliphatic acid；(b) there is 1 carbon original 0.5~the 18wt% of amine oxide type surfactant for the hydroxyl that subnumber is 8~16；And it is 4~8 (c) to be selected from carbon atom number 1 kind in alkene and styrene with 0.1~10wt% of copolymer of maleic acid；The mass ratio of a ingredients/b ingredients be 1/10~ Total content of 10/1, a ingredient and b ingredients be 4~20wt%, and the mass ratio of c ingredients/(a+b) ingredient be 1/100~ 2.5/1。

The CN 101981171A of China are related to substantially anhydrous concentrate composition, including (a) amine oxide surfactants Agent, (b) substantially water-soluble solvent, (c) alkaline source, (d) substantially free of water；Preferably, substantially anhydrous concentration combination Object, including (a) 60-75wt% amine oxides, (b) 8-20wt% substantially water-soluble solvents, (c) 3-10wt% alkaline sources, (d) 5- 10% chelating agent, (e) 0.5-5wt% hydrotropic solvents (f) are less than the water of 10wt%；Preferably, substantially anhydrous concentration combination Object, including (a) 10-20wt% amine oxides, (b) 50-75wt% substantially water-soluble solvents, (c) 5-15wt% alkaline sources, (d) 0.1-7% chelating agents, (e) substantially free of water；The concentrate composition is water-soluble, and can be used for preparing stable contain Water application solution.

As it can be seen that the prior art generally with the content of amine oxide surfactant be not higher than total surfactant content 2/3, Or it is node to be not higher than 1/2, to provide good foaming properties and/or grease emulsifying performance.In disclosed patent document, oxidation Why the content of amine is not directed to 2/3 range higher than total surfactant content, it may be possible to due to aoxidizing for a long time Amine is used mainly as Babassuamidopropylamine, foam stabiliser, and when as such use, amine oxide is in total surfactant Preferable amount be below 2/3, or be less than 1/2, be more preferably added with the dosage less than 1/10.

In conclusion how to improve the emulsifiability and greasy dirt of detergent composition on the basis of green, environmental protection, economy Peeling effect is still that detergent compositions engineer develops the key content that Modern laundry compositions are studied.

Invention content

Present inventor is had found by long-term research when amine oxide surfactant in surface activator composition Content be higher than total surfactant content 2/3 when, the emulsifying capacity of greasy dirt is remarkably reinforced.In turn, the present invention provides A kind of surface activator composition, by compounding other surfaces activating agent in using amine oxide as the system of primary surfactant, The composition excellent to greasy dirt peeling effect can be obtained, the light quick stripping to greasy dirt is realized, promotes the experience of consumer Impression.

The technical solution used in the present invention is：

A kind of surface activator composition, including following component：

(a) amine surfactants are aoxidized；

(b) alkyl benzene anion surfactant；

(c) non-alkyl benzene anion surfactant；

(d) the other surfaces activating agent in addition to (a), (b) and (c)；

Ingredient (a), (b), (c) and (d) active matter total content to account for the mass percent of surface activator composition be 1% ~60%；

Also, the mass percent that the content of ingredient (a) accounts for active matter content in ingredient (a), (b), (c) and (d) is 67%~95%；The mass percent that the content of ingredient (b) accounts for active matter content in ingredient (a), (b), (c) and (d) is 4%~ 15%；The mass percent that the total content of ingredient (b) and (c) account for ingredient (a), (b), (c) and active matter content in (d) is 25% ~33%；

Wherein, the oxidation amine surfactants of ingredient (a) are by least one of general formula A1, A2 compound represented group At：

In formula A1 or A2, R₁、R₄Independently indicate that carbon atom number is the alkyl or hydroxyalkyl of C8~C22；R₂、R₃、R₅、R₆ Independently indicate that carbon atom number is the low alkyl group or hydroxyalkyl of C1~C4；The value of m is 2~6.

Preferably, in surface activator composition, ingredient (a), (b), (c) and (d) active matter total content account for surface work Property agent composition mass percent be 3%~45%.

Preferably, in surface activator composition, the content of ingredient (a) accounts for ingredient (a), (b), (c) and active matter in (d) The mass percent of content is 67%~85%.

Preferably, in surface activator composition, the total content of ingredient (b) and (c) account for ingredient (a), (b), (c) and (d) The mass percent of middle active matter content is 27%~32%.

Preferably, in surface activator composition, the content of ingredient (b) accounts for ingredient (a), (b), (c) and active matter in (d) The mass percent of content is 5%~10%.

Preferably, in the general formula A1 or A2 of ingredient (a) oxidation amine surfactants, R₁、R₄Independently indicate carbon atom Number is the alkyl or hydroxyalkyl of C10~C18；R₂、R₃Independently indicate that carbon atom number is the low alkyl group or hydroxyl alkane of C1~C2 Base；R₅、R₆Independently indicate that carbon atom number is the low alkyl group of C1~C2；The value of m is 2~4.

Preferably, in surface activator composition, the general formula of ingredient (b) is as shown in formula B：

In formula B, R₇It is the alkyl or alkoxy that carbon atom number is C8~C22；X be carbon atom number be C0~C4 alkyl or Alkoxy；Y is selected from sulfonate, sulfate, phosphate, at least one of carboxylate, the counter ion of the salt be selected from sodium ion, At least one of potassium ion, ammonium ion, hydramine radical ion.

Preferably, in surface activator composition, ingredient (d) is zwitterionic surfactant, non-ionic surface active At least one of agent.

A kind of detergent, including above-mentioned surface activator composition.

Compared with prior art, the present invention has the advantages that：

The present invention, can by compounding and optimizing in using amine oxide as the surfactant system of primary surfactant To significantly improve the stripping ability of composition greasy dirt, meet the use demand that consumer easily deoils, quickly deoils.

It is specific as follows：

1, the present invention preferably amine oxide surfactant and the other surfaces activating agent in addition to amine oxide surfactant Compounding forms detergent composition, when total surfactant content is higher than 67wt%, preferably 67wt% to amine oxide in the composition When~85wt%, there is excellent greasy dirt emulsifying capacity.

2, the type and dosage of preferred surfactant of the present invention, when amine oxide total surfactant content in the composition It is preferred that 67wt%~75wt%, and anionic surfactant concentration [(b)+(c)] total surfactant [(a)+(b)+(c)+ (d)] content in is by mass percentage in 25%~33% range, and ingredient (b) alkyl benzene anion surfactant is total Content in surfactant [(a)+(b)+(c)+(d)] is by mass percentage in 4%~15%, preferably 5%~10%, i.e., excellent When choosing is more than or equal to 5% less than or equal to 10%, the stripping ability of composition greasy dirt can be significantly improved, meets consumer and easily goes Oil, the use demand quickly deoiled.

3, the surfactant added in detergent composition provided by the invention, selected from easily biological-degradable, environmentally protective And natural amine oxide, the detergent composition with other surfaces activating agent compounding is in the case of high oxidation amine content With good greasy dirt stripping ability, and it is more environmentally protective, and it is widely used in fabric detergent, dishwashing detergent In the fields such as agent, hard surface detergent, kitchen ventilator detergent.

Specific implementation mode

A kind of surface activator composition, including following component：(a) amine surfactants are aoxidized；(b) alkyl benzene is cloudy Ionic surface active agent；(c) non-alkyl benzene anion surfactant；(d) other surfaces in addition to (a), (b) and (c) are lived Property agent；Ingredient (a), (b), (c) and (d) active matter total content account for the mass percent of surface activator composition be 1%~ 60%；Also, the mass percent that the content of ingredient (a) accounts for active matter content in ingredient (a), (b), (c) and (d) is 67%~ 95%；The mass percent that the content of ingredient (b) accounts for ingredient (a), (b), (c) and active matter content in (d) is 4%~15%； The mass percent that the total content of ingredient (b) and (c) account for active matter content in ingredient (a), (b), (c) and (d) is 25%~ 33%.

In the present invention, the content of all the components and the additive amount of surfactant are calculated with active matter content.

Preferably, in surface activator composition, ingredient (a), (b), (c) and (d) active matter total content account for surface work Property agent composition mass percent be 3%~45%；It is further preferred that ingredient (a), (b), the active matter of (c) and (d) are total The mass percent that content accounts for surface activator composition is 15%~40%.

Preferably, in surface activator composition, the content of ingredient (a) accounts for ingredient (a), (b), (c) and active matter in (d) The mass percent of content is 67%~85%；It is further preferred that the content of ingredient (a) accounts for ingredient (a), (b), (c) and (d) The mass percent of middle active matter content is 67%~80%.

Each ingredient of Surfactant composition is further detailed below：

One, the surfactant of ingredient (a)

The oxidation amine surfactants of ingredient (a) are made of at least one of general formula A1, A2 compound represented.Table The commercialized raw materials of face activating agent A1 and surfactant A 2 are often contained with 25wt%~35wt%, preferably 28wt%~32wt% admittedly The aqueous solution of amount exists.

1.1 surfactant As 1

SurfactantIn, R₁It is the alkyl or hydroxyalkyl that carbon atom number is C8~C22, preferably C10 The alkyl of~C18, the alkyl of more preferable C12~C14；R₂、R₃Independently indicate carbon atom number be C1~C4 low alkyl group or Hydroxyalkyl, preferably methyl or ethyl or ethoxy, more preferable methyl or ethoxy, most preferable.

1.2 surfactant As 2

SurfactantIn, R₄It is the alkyl or hydroxyalkyl that carbon atom number is C8~C22, It is preferred that the alkyl of C10~C18, the alkyl of more preferable C12~C14；R₅、R₆Independently indicate that carbon atom number is the low of C1~C4 Grade alkyl or hydroxyalkyl, preferably methyl or ethyl or ethoxy, more preferable methyl；The value of m is 2~6, preferably 2~4, more Preferably 3.

Two, the surfactant of ingredient (b)

Ingredient (b) is alkyl benzene surfactant, and general formula is as shown in formula B：

In formula B, R₇It is the alkyl or alkoxy that carbon atom number is C8~C22, the preferred alkyl of C10~C18, more preferably The alkyl of C12~C12；X is the alkyl or alkoxy that carbon atom number is C0~C4, the alkyl or alkane that preferably carbon atom number is 0~2 Oxygroup；Y is selected from least one of sulfonate, sulfate, phosphate, carboxylate；The counter ion of the salt can be selected from sodium ion, Potassium ion, ammonium ion, hydramine radical ion and their mixture.Further, the alkyl benzene surfactant of ingredient (b) Preferably linear alkylbenzene sulfonate (LAS) or branch-alkylbenzene sulfonate, more preferably linear alkylbenzene sulfonate (LAS).

Three, the surfactant of ingredient (c)

The surfactant of ingredient (c) is non-alkyl benzene anion surfactant, the anion surfactant It is chosen as carboxylic acid type, sulfate type, sulfonate surfactant.Optional anion surfactant includes alcohol ether carboxylate Salt, alkyl sulfate, alkyl ethoxylated sulfate, ɑ-alkenyl sulfonate, aliphatic alcohol sulfate, fatty alcohol sulfonate, fat Ether alcohol sulfate, fatty acid methyl ester ethoxylation sulfonate etc., optimizing alkyl ethoxylated sulfate, alkylsulfonate and ɑ-alkene Base sulfonate.

Four, the surfactant of ingredient (d)

The surfactant of ingredient (d) is the other surfaces activating agent in addition to (a), (b) and (c), can be selected from amphoteric ion At least one of surfactant, nonionic surfactant.

The zwitterionic surfactant that 4.1 ingredients (d) are related to

Ingredient (c) zwitterionic surfactant includes fatty acid quaternary ammonium salt, phosphonate, sulfonium compound, wherein fat Fat chain part is the linear chain or branched chain of C8~C24, while including anionic water soluble group, and preferably amphoteric surfactant is Alkyl betaine, alkyl hydroxy sulfo lycine, alkylamide propyl-betaine, alkylamide propyl hydroxy sulfo lycine, carboxylic acid Type imidazoline etc., more preferable alkylamide propyl-betaine and alkyl hydroxy sulfo lycine.

The nonionic surfactant that 4.2 ingredients (d) are related to

Ingredient (c) nonionic surfactant is linear or branched alkyl group nonionic surfactant, is chosen as alkane Base glucoside, alkyl ethoxylated glucoside, alkyl polyoxyethylene ether, alkyl polyoxyethylene polyethenoxy ether, polyoxygenated Allylic alkylation aliphatic ester, alkyl fatty acid alkanolamide or nitrogen-alkyl -2-Pyrrolidone etc., optimizing alkyl glucoside and nitrogen - Alkyl -2-Pyrrolidone.

Preferably, the anion surfactant described in ingredient (c) or the nonionic surfactant described in ingredient (d), In amphoteric surfactant, the length of the alkyl carbon chain of surfactant is C8~C22, more preferably C10~C18.

The present invention also provides a kind of detergent, this detergent includes above-mentioned surface activator composition.

Further, this detergent further includes auxiliary agent；The auxiliary agent is chelating agent, preservative, dyestuff, essence, dye Expect in transfer inhibitor, enzyme, enzyme stabilizers, anti redeposition agent, anti-colour contamination agent, brightening agent, foam inhibitor, carrier, inorganic salts extremely Few one kind.

(1) chelating agent

In the present invention, the chelating agent is selected from amino carboxylic acid compounds and/or organo-aminophosphonic acid compound and/or lemon Lemon acid sodium, the amino carboxylic acid compounds include but not limited to：Ethylenediamine tetra-acetic acid (EDTA), N- hydroxy-ethylenediamine tetrems Acid, nitrilotriacetic acid (NTA), diethylenetriamine pentaacetic acid (DEPTA)；The organo-aminophosphonic acid compound includes but not limited to： Ethylenediaminetetrakis (methylenephosphonic acid), 1- hydroxyl ethane 1,1- di 2 ethylhexyl phosphonic acids (HEDP) and amino three (methylene phosphonic acid).Such as use chela Mixture, it is usually 0.1~15wt% that the content of these chelating agents, which accounts for the detergent composition mass percentage, preferably 1~ 15wt%.

(2) preservative

In the present invention, the preservative is selected from Kathon CG (2-methyl-4-isothiazolin-3-one and 5- chloro-2-methyls -4- The mixture of isothiazoline -3- ketone), 2-methyl-4-isothiazolin-3-one, in 5-Chloro-2-methyl-4-isothiazolin-3-one It is at least one.Preservative, the content of these preservatives is such as used to account for the detergent composition mass percentage and be usually 0.01~1wt%, preferably 0.02~0.2wt%.

(3) dyestuff

In the present invention, the dyestuff is selected from direct dyes, and the content of the direct dyes is enough to provide coloring, suitable Dyestuff includes but not limited to：The acid dyes of a variety of colors, the basic dye of a variety of colors and 4-nitro-o-phenylenediamine, 2- Nitro p-phenylenediamine, 4- amino-3-nitro phenols, the chloro- 4- nitrophenols of 2- amino -6-, 4- nitro-phenylaminos hydantoic acid, 6- Nitro -2,5- pyridines diamines, the sodium salt of the monosulfonic acid of quinophthalone or 2- indandione rodenticides and disulphonic acid mixtures, 2- hydroxyl -1,4- naphthalenes Quinone, nail premium, indigo, alkermes and their mixture.Dyestuff, the content of these dyestuffs is such as used to account for the washing Agent composition quality percentage composition is usually 0.01~5wt%.

(4) essence

In the present invention, the essence is selected from draft pastil, such as minty note, spearmint, rosemary, thyme, Salvia japonica With atom pine tree, dragon spruce and other trees with forest smell；Fruit pastil, as apple, almond, grape, cherry, pineapple, Pears, honey peach, mango, orange, strawberry, blueberry, citrus；Fragrance of a flower agent, such as rose sample, lavender sample, carnation sample；And it is fragrant Grass, cape jasmine, hawthorn, chypre, honeysuckle, cyclamen, hyacinth, fiddlehead, cloves, jasmine, lily, sensitive plant, magnolia, orchid Flower, daffodil, flores aurantii, Radix Glycyrrhizae, reseda green, clover, violet, Lathyrus odoratus, English wallflower etc. (" Perfumes The Cosmetics and Soaps " second editions, nineteen fifty-nine are published by W.A.Poucher).The content of these essence accounts for the washing Agent composition quality percentage composition is usually 0.01~5wt%, preferably 0.05~2wt%.

(5) dye transfer inhibitor

In the present invention, the dye transfer inhibitor is selected from polyvinylpyrrolidone, polyamine N-oxide, N- ethylene pyrroles Copolymer, polyvinyl imidazole, Ju Yi Xi oxazolidones and their mixture of pyrrolidone-N- vinyl imidazols.Such as using dye Expect transfer inhibitor, it is usually 0.01 that the content of these dye transfer inhibitors, which accounts for the detergent composition mass percentage, ~10wt%, preferably 0.1~5wt%.

(6) enzyme

In the present invention, the enzyme is selected from protease, cellulase, lipase, amylase, pectase, zytase, oxygen Change enzyme, reductase, peroxidase and their mixture, is preferably typically combined as protease, cellulase, starch One or more kinds of mixtures in enzyme, lipase.Enzyme, the content of these enzymes is such as used to account for the detergent composition matter It is usually 0.01~15wt% to measure percentage composition, preferably 0.1~10wt%.

(7) enzyme stabilizers

In the present invention, the enzyme stabilizers are selected from calcium chloride, calcium formate, calcium gluconate and their mixture. Such as use enzyme stabilizers, the contents of these enzyme stabilizers account for the detergent composition mass percentage be usually 0.001~ 5wt%, preferably 0.005~3wt%.

(8) clay and dirt removal/anti redeposition agent

In the present invention, the clay and dirt removal/anti redeposition agent are selected from maleic-acrylic acid polymer, carboxylic first Base cellulose, hydroxyethyl cellulose and their mixture.Clay and dirt removal/anti redeposition agent are such as used, these are viscous It is usually 0.1~15wt% that the content of soil and dirt removal/anti redeposition agent, which accounts for the detergent composition mass percentage, It is preferred that 0.2~10wt%.

(9) anti-colour contamination agent

In the present invention, the anti-colour contamination agent is selected from aliphatic poly amine derivative, polyvinylpyrrolidone, N- ethylene pyrroles Copolymer, polyvinyl imidazole, Ju Yi Xi oxazolidones and their mixture of alkanone-N- vinyl imidazols.Such as use anti-string Toner, it is usually 0.5~2wt% that the content of these anti-colour contamination agent, which accounts for the detergent composition mass percentage, and preferably 0.4 ~1.5wt%.

(10) brightening agent

In the present invention, the brightening agent is selected from fluorescent whitening agent, preferably CBS-X.Such as use brightening agent, these brightening agents Content to account for the detergent composition mass percentage be usually 0.01~10wt%, preferably 0.1~3wt%.

(11) foam inhibitor

In the present invention, the foam inhibitor is selected from organic silicon defoamer.Foam inhibitor, the content of these foam inhibitors is such as used to account for The surface activator composition mass percentage is usually 0.001~10wt%, preferably 0.005~3wt%.

(12) carrier

In the present invention, the carrier is selected from polar solvent, including but not limited to water, ethylene glycol, propylene glycol, poly- second two Alcohol, glycerine and/or nonpolar solvent, including but not limited to mineral oil, silicone oil, paraffin oil and their mixture.Such as make With carrier, it is usually 0.1~15wt% that the content of these carriers, which accounts for the detergent composition mass percent, preferably 1~ 15wt%.

(13) inorganic salts

In the present invention, the inorganic salts be selected from chloride, bromide, iodide, nitrate, sulfate, sulphite, At least one of phosphate, dibasic alkaliine, dihydric phosphate；It is preferred that at least one in chloride, nitrate, sulfate Kind；Metal ion in inorganic salts is selected from Section II A, IB, IIB, VIII race's element in third, period 4 corresponding metal ion, It is preferred that Zn²⁺、Mg²⁺、Ca²⁺At least one of；The content of these inorganic salts accounts for the surface activator composition mass percent Usually 0.1~8wt%, preferably 1~4wt%.

Preferably, this detergent is liquid, including but not limited to liquid, iquid capsule.

Further, this detergent further includes pH adjusting agent；The pH adjusting agent be citric acid, hydrochloric acid, sulfamic acid, At least one of sodium hydroxide, sodium carbonate, monoethanolamine, triethanolamine.

Further, the pH of this detergent is 5~13, preferably 5~9.

In the present invention, the detergent has the effect of decontamination and greasy dirt emulsification within the scope of wider pH；But detergent The skin or hard surface of the too strong easy stimulation user of alkalinity, damages skin and hard surface, it is possible to according to reality Using reasonably selecting within the above range.

Further, the ingredient of detergent of the present invention, surplus is solvent, such as deionized water.

The preparation method of this liquid state detergent is to mix above-mentioned surface activator composition and auxiliary agent, and be dissolved in In solvent, the pH of mixed liquor being adjusted with pH adjusting agent, adds solvent to 100wt%, the detergent is obtained after stirring evenly.

This detergent can be used as fabric detergent, dish washing detergent, hard surface detergent or kitchen ventilator detergent.

Present disclosure is described in further detail below by way of specific embodiment.It is former used in embodiment Material unless otherwise specified, can be obtained from routine business approach.In example, the content of all the components and adding for surfactant Dosage is in terms of active matter content.

Embodiment：

The raw material composition ratio of embodiment and comparative example is shown in Table 1~2.Alkyl benzene surfactant accounts for total surface work in each example Property agent content, anion surfactant account for total surfactant content, amine oxide accounts for the content and oxygen of total surfactant Change amine to account for the content of composition solid content also correspondence is listed in table 1~2.Test method is respectively described below：

One, solid content is tested

Solid content refers to the mass percent that remainder accounts for total amount after sample is dried under prescribed conditions.Its test process For：1) the 250mL beakers of clean dried are put into 105 DEG C of baking ovens after constant temperature 1.5h, taking-up is weighed, record quality m1；2) accurate Really weigh 2g (being accurate to 0.0001g) homogeneous sample, record quality m, be put in the beaker of constant weight, keep sample evenly laid out in Bottom of bottle；3) beaker for filling sample is put into constant temperature 3h in 105 DEG C of baking ovens, taking-up is weighed, record quality m2；4) solid content is calculated =(m2-m1)/m, unit %.

Two, total surfactant content is tested

With reference to gross activity object content assaying method in national standard GB 9985-2000, activity is obtained using chloroform extraction method Object content, deduct urea content after be gross activity object content.In chloroform energy dissolved composition all surface activating agent and Other organic matters and insoluble inorganic salts, sample extract repeatedly after drying and dehydrating, with chloroform, collect extract, removal Chloroform dries, weighs, and calculates active matter content.But if can be also partly solubilized containing urea in composition, therefore must Urea content must be measured with quantitative dissolved matter, and the side of being deducted is real gross activity object content.In addition, chloroform is molten It solves in object, solvent or oil components that may be comprising no surface-active can be with Japanese JIS K3362-2008《Home-use conjunction At detergent test method》In further deduct the content of petroleum ether dissolution object, acquired results are total surfactant content. Therefore total surfactant content (%)=chloroform dissolved matter content (%)-urea content (%)-petroleum ether in composition Dissolved matter content (%).

Three, amine oxide assay in composition

The oxidation amine content in chemical analysis method or chromatography determination composition may be used, it is preferred to use efficient liquid phase The content of amine oxide surfactant in chromatography determination composition.Optimize chromatographic condition first, make amine oxide surfactant, The amphoteric surfactantes such as beet alkali surface activator, amino acid surfactant have distinction on appearance time；Then Lauryl amidopropyl dimethyl amine, cocamide dimethylamine oxide, dodecyl dimethyl oxidation is added Amine, tetradecyldimethylamine oxide, lauryl amidopropyl betaine, cocamide propyl betaine, cocoyl base two Ethoxy glycine betaine, coco alkyl azochlorosulfonate propyl lycine, coco alkyl Hydroxypropyl phosphate ester glycine betaine, cocoyl glutamate The amphoteric surfactantes such as sodium, cocoyl Sodium Glycinate obtain the guarantor under its each comfortable chromatography optimal conditions as reference substance Stay the time；By the solid content sample in composition take it is a certain amount of be made into deionized water 10% solution, then sampling carries out high Effect liquid phase chromatogram is analyzed, and the surfactant types of component are obtained by retention time, and containing for each component is obtained by peak area How much is amount, while calculating the content of amine oxide surfactant in the composition.

Table 1

Table 2

Physics and chemistry and application performance compare：

The composition of above-described embodiment and comparative example is tested for the property, the result is shown in tables 3~4.The tool of dependence test Body operating method is as follows：

One, cold-resistant and heat-resistant stability

With reference to fluid sample stability test method in national standard GB 9985-2000, the cold-resistant and heat-resisting steady of composition is measured It is qualitative.

Cold-resistant stability：At -5 DEG C ± 2 DEG C constant temperature for 24 hours, restore to after room temperature with compared before experiment, seen whether bright Aobvious variation；Heat-resistant stability：At 40 DEG C ± 2 DEG C constant temperature for 24 hours, restore to after room temperature with compared before experiment, seen whether bright Aobvious variation.

Two, greasy dirt emulsification experiment

1) 200 milliliters of the 250ppm hard water solutions of 2% detergent composition are added in 250 milliliters of beakers, are dripped with dropper Add 1mL rapeseed oils；2) 500 turns of magnetic agitations are used 2 minutes, then stands 2 minutes and observes；3) pass through the turbidity of resolution solution With the mode for measuring the light transmittance of beaker central liquid at 550 nm, emulsifying capacity of the comparison detergent composition to greasy dirt.Breast It is low to change the good then light transmittance of effect, then light transmittance is high for emulsifying effectiveness difference.Emulsifying effectiveness is divided into four grades, respectively：Good, preferable, It is bad, poor.

Three, greasy dirt peel test

0.2 gram of ready-mixed oil (0.25% oil red stirring being added in ready-mixed oil, oil red dissolves rear and can be used) is uniformly applied In polypropylene tray, 30 minutes are stood；350 milliliters of the deionized water solution of 0.2% composition is slowly added to the pp after defiling In disk, 5min, the speed that observation ready-mixed oil is crispaturaed with oil slick are impregnated, and record the time that greasy dirt occurs curling and is completely exfoliated； It is compared, is taken pictures with the result after impregnating 15 minutes, be used in combination Photoshop softwares by the way that how much calculating of rear pixel washed before washing Area ratio.

In above formula：Wash preceding pixel --- preceding pixel i.e. Layer Order pixel is washed, is interpreted as applying the comprehensive of greasy dirt in pp coils Product, that is, greasy dirt area before washing；Wash rear pixel --- it washes rear pixel and is converted into smart object pixel, be interpreted as being left oil after impregnating Soiled surface product is only to be left the area that red greasy dirt accounts for after impregnating；

The pixel refers to being formed the least unit of picture, normally sees that an image is apparent from, after image method For image just at being made of several multiple small side's points, one small side's point is exactly a pixel.

Table 3

Table 4

By table 3 and table 4 it is found that the peeling effect of 1~11 pair of greasy dirt of embodiment is excellent or good, and qualified stability, it can Satisfaction easily deoils, quickly deoils and up-to-standard use demand.The peeling effect of 1~5 pair of greasy dirt of comparative example is not as good as implementation Example 1~11, and in comparative example 4 and comparative example 5 composition stability it is bad.Comparative example 1 and comparative example 2 are to greasy dirt peeling effect It is bad may be related not in preferred scope with ratio of the anion surfactant in total surfactant；Comparative example 3 is to oil Dirty peeling effect is bad may be not high enough related with the content of alkyl benzene surfactant；And the stripping of 4~5 pairs of greasy dirts of comparative example From ineffective, on the one hand may with the content of alkyl benzene surfactant not in preferred scope, on the other hand may with combine It is related that object gelation or split-phase cause effect that can not play.

The present invention is based on a unexpected discoveries, i.e., when the content of amine oxide surfactant is higher than total surface activity Agent content 2/3 when, when preferably 2/3~4/5 range, the emulsifying capacity of greasy dirt is remarkably reinforced；When further to combination When other surfaces activating agent in object in addition to amine oxide surfactant carries out preferred, it can obtain excellent to greasy dirt peeling effect Composition, realize light quick stripping to greasy dirt, promoted the experience sense of consumer by.

More than, embodiments of the present invention are illustrated.But the present invention is not limited to the above embodiments.It is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention Within the scope of shield.

Claims

1. a kind of surface activator composition, it is characterised in that：Including following component：(a) amine surfactants are aoxidized；(b) Alkyl benzene anion surfactant；(c) non-alkyl benzene anion surfactant；(d) in addition to (a), (b) and (c) Other surfaces activating agent；Ingredient (a), (b), (c) and (d) active matter total content account for the quality percentage of surface activator composition Than being 1%~60%；

Also, the mass percent that the content of ingredient (a) accounts for active matter content in ingredient (a), (b), (c) and (d) is 67%~ 95%；

The mass percent that the content of ingredient (b) accounts for ingredient (a), (b), (c) and active matter content in (d) is 4%~15%；

The mass percent that the total content of ingredient (b) and (c) account for ingredient (a), (b), (c) and active matter content in (d) is 25% ~33%；

Wherein, the oxidation amine surfactants of ingredient (a) are made of at least one of general formula A1, A2 compound represented：

In formula A1 or A2, R₁、R₄Independently indicate that carbon atom number is the alkyl or hydroxyalkyl of C8~C22；R₂、R₃、R₅、R₆Respectively It is independent to indicate that carbon atom number is the low alkyl group or hydroxyalkyl of C1~C4；The value of m is 2~6.

2. a kind of surface activator composition according to claim 1, it is characterised in that：Ingredient (a), (b), (c) and (d) Active matter total content account for surface activator composition mass percent be 3%~45%.

3. a kind of surface activator composition according to claim 2, it is characterised in that：The content of ingredient (a) accounts for ingredient (a), the mass percent of active matter content is 67%~85% in (b), (c) and (d).

4. a kind of surface activator composition according to claim 3, it is characterised in that：The total content of ingredient (b) and (c) The mass percent for accounting for ingredient (a), (b), (c) and active matter content in (d) is 27%~32%.

5. a kind of surface activator composition according to claim 4, it is characterised in that：The content of ingredient (b) accounts for ingredient (a), the mass percent of active matter content is 5%~10% in (b), (c) and (d).

6. a kind of surface activator composition according to claim 5, it is characterised in that：Ingredient (a) aoxidizes amine surface In the general formula A1 or A2 of activating agent, R₁、R₄Independently indicate that carbon atom number is the alkyl or hydroxyalkyl of C10~C18；R₂、R₃Point It is not independent to indicate that carbon atom number is the low alkyl group or hydroxyalkyl of C1~C2；R₅、R₆Independently indicate that carbon atom number is C1~C2 Low alkyl group；The value of m is 2~4.

7. a kind of surface activator composition according to claim 5, it is characterised in that：The general formula of ingredient (b) such as formula B institutes Show：

In formula B, R₇It is the alkyl or alkoxy that carbon atom number is C8~C22；X is the alkyl or alcoxyl that carbon atom number is C0~C4 Base；Y is selected from sulfonate, sulfate, phosphate, at least one of carboxylate, the counter ion of the salt be selected from sodium ion, potassium from At least one of son, ammonium ion, hydramine radical ion.

8. a kind of surface activator composition according to claim 5, it is characterised in that：Ingredient (d) is amphoteric ion table At least one of face activating agent, nonionic surfactant.

9. a kind of detergent, including claim 1~8 any one of them surface activator composition.