CN108338482A - Environmentally friendly high rigidity antistatic single tube eyebrow pencil and preparation method thereof - Google Patents
Environmentally friendly high rigidity antistatic single tube eyebrow pencil and preparation method thereof Download PDFInfo
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- CN108338482A CN108338482A CN201810136112.8A CN201810136112A CN108338482A CN 108338482 A CN108338482 A CN 108338482A CN 201810136112 A CN201810136112 A CN 201810136112A CN 108338482 A CN108338482 A CN 108338482A
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- head cap
- pen body
- pen
- single tube
- eyebrow pencil
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/20—Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
- A45D40/262—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a brush or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/20—Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
- A45D2040/201—Accessories
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Toys (AREA)
Abstract
The present invention relates to a kind of environmentally friendly high rigidity antistatic single tube eyebrow pencils and preparation method thereof, cause leakproofness poor for existing similar product structure design is not good enough, air guide is poor, it is more difficult to the technical issues of environmental protection recycles and design.Pen body one end pen core mouth of the single tube eyebrow pencil is fastened with head cap, and rotation pen body drives band handle pearl to move up and down；Its main points is that the cap mouth internal diameter of the head cap is equipped with head cap groove, internal diameter is equipped with head cap fixing muscle above the head cap groove of head cap, while the head cap groove of head cap and the body mouth outer diameter pen body fixing muscle of pen body fasten, outer diameter pen body groove fastens above the head cap fixing muscle of head cap and the pen body fixing muscle of pen body, the head cap fixing muscle of head cap is equipped with four symmetrical head cap air slots and intermediate cavity with the intermediate region of head cap groove, the pen body fixing muscle of pen body is equipped with coarse section with the intermediate region of pen body groove, and the intermediate region of head cap and the intermediate region of pen body are fitted close.The head cap and pen body are made of environmentally friendly high rigidity antistatic material.
Description
Technical field
It is a kind of environmentally friendly high rigidity antistatic single tube eyebrow pencil and preparation method thereof the present invention relates to single tube eyebrow pencil.
Background technology
Single tube eyebrow pencil is widely used in cosmetic package field, is all to take with oneself all the time because of its distinctive portable characteristics
One of cosmetics indispensability type of band.Application number 201521054770.0 as disclosed in Chinese patent literature, authorized announcement date
2016.10.05 utility model title " a kind of cosmetic pencil "；Including penholder, the penholder is separated into one by intermediate partition board
The left and right cavity of end opening is equipped with eye shadow brush holder in left cavity and forms the cavity for placing liquid in bottom, and spongy top is in eye shadow
The end position of brush holder is simultaneously sleeved in the interior pen cap, and eye shadow set is sleeved on the interior pen cap and is threadedly coupled with eye shadow brush holder, eye shadow
Spring A is equipped between brush holder bottom and the interior pen cap；The bottom of right cavity is connected with pen tip fixed seat, and spiral shell is equipped in pen tip fixed seat
Coil is connected with screw rod in helix tube, and one end of spring B is connected in the blind hole of pen tip fixed seat bottom, and the other end supports
It is pressed on the end face of helix tube；Pen tip is equipped with solid-state eyebrow pencil socket, solid-state eyebrow pencil pass through solid-state eyebrow pencil socket and screw rod one
It holds affixed.Since product structure and principle need, the part of well known single tube eyebrow pencil uses different raw material, i.e., by plastics,
Metal, glass composition, the reworked material of parts need to sort rear recoverable.This complex steps to energy-saving and environmental protection, is given up
The recycling again of gurry is extremely inconvenient.Green, environmentally friendly, low-carbon life style have become current mainstream at present, in the market
The single tube eyebrow pencil of appearance mostly uses material not environmentally and is made, and production process has pollution, the pollutant of generation to be difficult to degrade, with
Upper production content does not comply with the relevant regulations of country, and the demand to environment-friendly type manufacturing enterprise greatly develops.It is existing simultaneously
Pen body, pen cover in single tube eyebrow pencil are made using general plastic raw materials, and rigidity is insufficient in actual use, flexible, easily
Deformation, and whole container leakproofness can be caused to be deteriorated after deforming；In addition antistatic property difference can lead to dust accretions, cause to produce
The service life of product is substantially reduced.
Invention content
To overcome above-mentioned deficiency, the purpose of the present invention is provide a kind of environmentally friendly high rigidity antistatic single tube eyebrow pencil to this field
And preparation method thereof, so that it is solved, existing similar product structure design is not good enough to cause leakproofness poor, and air guide is poor, it is more difficult to ring
Protect the technical issues of recycling.The purpose is to what is be achieved through the following technical solutions.
A kind of environmental protection high rigidity antistatic single tube eyebrow pencil, pen body one end pen core mouth and the head cap of the single tube eyebrow pencil fasten, pen
Pen core in body is set to the band handle pearl in fork pedestal, and the pearl with handle pearl mouthful internal diameter is equipped with the positioning bar of protrusion, pitches pedestal
O-ring is equipped between pen body, the band handle pearl outer diameter pitched in pedestal is equipped with thread segment, and band handle pearl is driven by rotating pen body
It moves up and down；Its structure design main points is that the cap mouth internal diameter of the head cap is equipped with head cap groove, above the head cap groove of head cap in
Diameter is equipped with head cap fixing muscle, while the head cap groove of head cap and the body mouth outer diameter pen body fixing muscle of pen body fasten, the head of head cap
Outer diameter pen body groove fastens above the pen body fixing muscle of cap fixing muscle and pen body, in the head cap fixing muscle and head cap groove of head cap
Between region be equipped with four symmetrical head cap air slots and intermediate cavity, the pen body fixing muscle of pen body and the intermediate region of pen body groove and set
There is coarse section, the intermediate region of head cap and the intermediate region of pen body are fitted close.The effect of above-mentioned head cap air slot is to work as head cap
When being pressed into pen body, the additional air in head cap is exported by head cap air slot, avoids head cap air pressure inside excessively high, plastic is made
At damage；Meanwhile multistage sealing function is realized in the intermediate region of head cap and the intermediate region of pen body, makes the whole air-tightness of eyebrow pencil
Reach 100%.
Internal diameter is equipped with four symmetrical pen body air slots below the body mouth of the pen body.Consequently facilitating eyebrow pencil refill exists in pen body
Air guide when use.
The fork pedestal of the pen body other end is equipped with lash curler, and lash curler is set to the end aperture of fork pedestal by brush holder
Interior, the pen body outer diameter at lash curler is fastened with outer cover.To make the single tube eyebrow pencil be used together with lash curler.
The head cap and pen body are using following preparation method：100 parts by weight of the degradation polymer, degradation polymer include
It is a variety of in polylactic acid, poly-succinic fourth diester and polyhydroxyalkanoate；Nucleating agent 0.1-10 parts by weight, the nucleating agent
For hydrazide kind compound；Maleic anhydride 0-2 parts by weight；Antistatic agent 1-3 parts by weight；Coupling agent 0.1-1 parts by weight, coupling agent are
Aluminium titanium composite coupler；Activated carbon 1-3 parts by weight；Other auxiliary agents 0.5-10 parts by weight, other described auxiliary agents include antioxidant, increase
It moulds one or more in agent, chain extender, lubricant；The wherein described antioxidant packages include Hinered phenols antioxidant or phosphorous acid esters
One or more in antioxidant, the content of the antioxidant is 0.5-1 parts by weight；The plasticizer includes polyethylene glycol, 1,
2- cyclohexane dicarboxylic acids diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, dioctyl terephthalate, citrate,
It is one or more in aliphatic polyester or polyurethane；The lubricant includes from white oil, stearic acid or vinyl stearic bicine diester
It is one or more in amine.
The antistatic agent is HDC-102 antistatic agents or HBS-510 antistatic agents.
The antioxidant is the compound of one or more of age resisters in 3114, DSTP, DLTP, 168,1010.
Processing is dried in the degradation polymer and nucleating agent respectively, and the temperature of drying process is 60-100 DEG C, degradation
The time that polymer is dried is 8-12 hour, and the temperature of the drying process of nucleating agent is 80-120 DEG C, drying process when
Between be 2-5 hours；It is blended with remaining component melts after drying, after being squeezed out at screw machine head, is molded by injection molding manner；At
Cleaned through 80 DEG C of surface conditioning agents and organic solvent after type, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, equal
After changing concussion, 80 DEG C of drying and processings, final finished is obtained.
The surface conditioning agent includes coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone
The proportioning of one kind, two kinds of components is 5：80-95.
Structure of the invention reasonable design, environmental protection, antistatic, multistage good airproof performance, service life are long；It is suitable as lipstick
Pipe uses, and prepares counter-bending material, antistatic, anti-oxidant, antistatic.
Description of the drawings
Fig. 1 is one configuration schematic diagram of the embodiment of the present invention, partly confines and is exaggerated in figure.
Fig. 2 is the head cap partial cross-sectional structural diagram of Fig. 1, partly confines and is exaggerated in figure.
Fig. 3 is two schematic cross-sectional view of the embodiment of the present invention.
Figure number and title：1, head cap, 101, head cap fixing muscle, 102, head cap groove, 103, head cap air slot, 104,
Intermediate cavity, 2, pen body, 201, pen body groove, 202, pen body fixing muscle, 203, coarse section, 3, band handle pearl, 4, O-ring, 5, fork
Pedestal, 6, brush holder, 7, lash curler, 8, outer cover.
Specific implementation mode
In conjunction with attached drawing, structure of the invention is further described.Embodiment one and embodiment as shown in FIG. 1 to FIG. 3
Two, 2 one end pen core mouth of pen body and the head cap 1 of the single tube eyebrow pencil fasten, and the pen core in pen body is set to the band handle pearl in fork pedestal 5
Son 3, the pearl with handle pearl mouthful internal diameter are equipped with the positioning bar of protrusion, pitch and be equipped with O-ring 4 between pedestal and pen body, pitch in pedestal
Band handle pearl outer diameter is equipped with thread segment, drives band handle pearl to move up and down by rotating pen body.The cap mouth internal diameter of head cap is equipped with head
The head cap groove top internal diameter of cap groove 102, head cap is equipped with head cap fixing muscle 101, the head cap groove of head cap and the body mouth of pen body
While outer diameter pen body fixing muscle 202 fastens, outer diameter pen body is recessed above the head cap fixing muscle of head cap and the pen body fixing muscle of pen body
Slot 201 fastens, the head cap fixing muscle of head cap and the intermediate region of head cap groove be equipped with four symmetrical head cap air slots 103 and in
Between chamber 104, the pen body fixing muscle of pen body and the intermediate region of pen body groove be equipped with coarse section 203, the intermediate region of head cap and pen
The intermediate region of body is fitted close.Meanwhile internal diameter is equipped with four symmetrical pen body air slots below the body mouth of pen body, pen body is another
The fork pedestal at end is equipped with lash curler 7, and lash curler is set to by brush holder 6 in the end aperture of fork pedestal, outside the pen body at lash curler
Diameter is fastened with outer cover 8.
Above-mentioned head cap and pen body are using following preparation method：
Embodiment 1
Raw materials and consumption is respectively：50 grams of polylactic acid, 1 gram of activated carbon, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25
Gram antioxidant 1010,1.25 grams of lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Polylactic acid
It is 12 hours dry in 80 DEG C of vacuum drying oven；TMC-300 nucleating agents are 2 hours dry in 80 DEG C of vacuum drying oven.Then will
Melting mixing in mixer is added in raw material after mixing, and the temperature of mixer three parts is respectively 190 DEG C, 195 DEG C and 190
DEG C, rotating speed 35rmp, mixing time is 10 minutes.After being squeezed out at screw machine head, the resin after melting mixing is in a mold
It is hot-forming, it preheats 5 minutes；Upper and lower mould hot pressing temperature is 190 DEG C, pressure 10MPa；Hot pressing time is 5 minutes.It is obtained
End properties：Tensile strength is 47MPa, and heat distortion temperature is 80 DEG C.
Embodiment 2
Raw materials and consumption is respectively：25 grams of poly butylene succinates, 25 grams of polylactic acid, 1.5 grams of activated carbon, 0.25 gram of TMC-
306 nucleating agents, 0.25 gram of maleic anhydride, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram of antioxidant 1010,1.25 grams
Lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Poly butylene succinate and polylactic acid
It is 12 hours dry in 80 DEG C of vacuum drying oven；TMC-306 nucleating agents are 2 hours dry in 80 DEG C of vacuum drying oven.Then will
Melting mixing in mixer is added in raw material after mixing, and the temperature of mixer three parts is respectively 190 DEG C, 195 DEG C and 190
DEG C, rotating speed 35rmp, mixing time is 10 minutes.After being squeezed out at screw machine head, the resin after melting mixing is in a mold
It is hot-forming, it preheats 5 minutes；Upper and lower mould hot pressing temperature is 190 DEG C, pressure 10MPa；Hot pressing time is 5 minutes.It is obtained
End properties：Tensile strength 41MPa, 95 DEG C of heat distortion temperature.
Embodiment 3
Raw materials and consumption is respectively：15 grams of polyhydroxyalkanoates, 15 grams of poly butylene succinates, 25 grams of polylactic acid, 2 grams
Activated carbon, 0.25 gram of maleic anhydride, 0.25 gram of TMC-306 nucleating agent, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram
Antioxidant 1010,1.25 grams of lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Poly- hydroxyl fat
Fat acid esters, poly butylene succinate and polylactic acid are 12 hours dry in 80 DEG C of vacuum drying oven；TMC-306 nucleating agents are 80
DEG C vacuum drying oven in dry 2 hours.Raw material is added to melting mixing in mixer, the temperature of mixer three parts after mixing
Degree is respectively 190 DEG C, 195 DEG C and 190 DEG C, rotating speed 35rmp, and mixing time is 10 minutes.After being squeezed out at screw machine head,
Resin after melting mixing is hot-forming in a mold, preheats 5 minutes.Upper and lower mould hot pressing temperature is 190 DEG C, and pressure is
10MPa.Hot pressing time is 5 minutes.It anneals 30 minutes at 110 DEG C after hot pressing.The end properties obtained：Tensile strength
38MPa, 98 DEG C of heat distortion temperature.
It cleans, then leads to through 80 DEG C of surface conditioning agents and organic solvent after 3 molding after molding of above example 1- embodiments
Cross 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing are shaken, after 80 DEG C of drying and processings, obtain final finished.
In conclusion the advantages of single tube eyebrow pencil, is as follows：1, the single tube eyebrow pencil is made of the high thermal resistance, high-rigidity material of environmental protection,
Compared with traditional single tube eyebrow pencil, the product have counter-bending, antistatic, anti-oxidant, selling price is moderate, reasonable design, the service life
It is long, meet the advantage of marketing character.2, it is the pen body of the single tube eyebrow pencil in place of the single tube eyebrow pencil and the difference of common single tube eyebrow pencil
After possessing special sealing structure with pen cover and use the high thermal resistance, high-rigidity material of environmental protection, each parts connection is more secured,
Cooperation is accurate, and counter-bending deformation performance enhancing, antistatic performance enhancing, whole air-tightness is enhanced to airtight effect 100%, convenient
User carries, preserves and uses.3, after the single tube eyebrow pencil is made of environmentally friendly high rigidity antistatic material, product plastic part is not easy oxygen
Change aging, after preservation for a long time or use, surface color degree is still as before, while not having dust accumulation and pollution.
Claims (8)
1. a kind of environmental protection high rigidity antistatic single tube eyebrow pencil, the pen body of the single tube eyebrow pencil（2）One end pen core mouth and head cap（1）Button
It closes, the pen core in pen body is set to fork pedestal（5）Interior band handle pearl（3）, pearl with handle pearl mouthful internal diameter is equipped with determining for protrusion
Position muscle, pitches and is equipped with O-ring between pedestal and pen body（4）, the band handle pearl outer diameter in pedestal is pitched equipped with thread segment, passes through pen with rotary
Body drives band handle pearl to move up and down；It is characterized in that the head cap（1）Cap mouth internal diameter be equipped with head cap groove（102）, head cap
Head cap groove above internal diameter be equipped with head cap fixing muscle（101）, the head cap groove and pen body of head cap（2）Body mouth outer diameter pen body it is solid
Determine muscle（202）While fastening, outer diameter pen body groove above the head cap fixing muscle of head cap and the pen body fixing muscle of pen body（201）Button
It closes, the head cap fixing muscle of head cap is equipped with four symmetrical head cap air slots with the intermediate region of head cap groove（103）And intermediate cavity
（104）, the pen body fixing muscle of pen body is with the intermediate region of pen body groove equipped with coarse section（203）, the intermediate region of head cap and pen
The intermediate region of body is fitted close.
2. environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 1, it is characterised in that the pen body（2）Body mouth
Lower section internal diameter is equipped with four symmetrical pen body air slots.
3. environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 1, it is characterised in that the pen body（2）The other end
Fork pedestal（5）Equipped with lash curler（7）, lash curler passes through brush holder（6）It is set in the end aperture of fork pedestal, the pen at lash curler
Body outer diameter and outer cover（8）It fastens.
4. the preparation method of environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 1, it is characterised in that the head
Cap（1）And pen body（2）Using following preparation method：100 parts by weight of the degradation polymer, degradation polymer include polylactic acid,
It is a variety of in poly-succinic fourth diester and polyhydroxyalkanoate；Nucleating agent 0.1-10 parts by weight, the nucleating agent are hydrazides
Class compound；Maleic anhydride 0-2 parts by weight；Antistatic agent 1-3 parts by weight；Coupling agent 0.1-1 parts by weight, coupling agent are multiple for aluminium titanium
Close coupling agent；Activated carbon 1-3 parts by weight；Other auxiliary agents 0.5-10 parts by weight, other described auxiliary agents include antioxidant, plasticizer,
It is one or more in chain extender, lubricant；The wherein described antioxidant packages include Hinered phenols antioxidant or phosphorous acid esters antioxygen
One or more in agent, the content of the antioxidant is 0.5-1 parts by weight；The plasticizer includes polyethylene glycol, 1,2- rings
Hexane dicarboxylic acid's diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, dioctyl terephthalate, citrate, fat
It is one or more in adoption ester or polyurethane；The lubricant includes from white oil, stearic acid or vinyl bis-stearamides
It is one or more.
5. the preparation method of environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 4, it is characterised in that described
Antistatic agent is HDC-102 antistatic agents or HBS-510 antistatic agents.
6. the preparation method of environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 4, it is characterised in that described anti-
Oxygen agent is the compound of one or more of age resisters in 3114, DSTP, DLTP, 168,1010.
7. the preparation method of environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 4, it is characterised in that the drop
It depolymerizes object and processing is dried in nucleating agent respectively, the temperature of drying process is 60-100 DEG C, and degradation polymer is dried
Time be 8-12 hour, the temperature of the drying process of nucleating agent is 80-120 DEG C, and the time of drying process is 2-5 hours；It is dry
It is blended with remaining component melts after dry, after being squeezed out at screw machine head, is molded by injection molding manner；Through 80 DEG C of surfaces after molding
Inorganic agent and organic solvent cleaning, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing concussion, 80 DEG C dry
After dry-cure, final finished is obtained.
8. the preparation method of environmental protection high rigidity antistatic single tube eyebrow pencil according to claim 7, it is characterised in that the table
Surface treatment agent includes one kind of coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone, two kinds of components
Proportioning be 5：80-95.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810136112.8A CN108338482B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic single-tube eyebrow pencil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810136112.8A CN108338482B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic single-tube eyebrow pencil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108338482A true CN108338482A (en) | 2018-07-31 |
| CN108338482B CN108338482B (en) | 2023-09-01 |
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| CN201810136112.8A Active CN108338482B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic single-tube eyebrow pencil and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109123997A (en) * | 2018-09-14 | 2019-01-04 | 浙江正庄实业有限公司 | Antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method |
| CN109335269A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Degradable oil pump of antiultraviolet and preparation method thereof |
| CN109335270A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Antiultraviolet antistatic emulsion pumps and preparation method thereof |
| CN110194306A (en) * | 2019-06-06 | 2019-09-03 | 浙江正庄实业有限公司 | Antibacterial degradable cream bottle and its material preparation method |
| CN115386201A (en) * | 2022-08-15 | 2022-11-25 | 宁波杰立化妆品包装用品有限公司 | Degradable material for cosmetic eyebrow pencil and preparation method thereof |
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