CN108264745A - Environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof - Google Patents
Environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof Download PDFInfo
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- CN108264745A CN108264745A CN201810135347.5A CN201810135347A CN108264745A CN 108264745 A CN108264745 A CN 108264745A CN 201810135347 A CN201810135347 A CN 201810135347A CN 108264745 A CN108264745 A CN 108264745A
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- lip gloss
- maize
- ear
- cotton head
- single tube
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- 239000000463 material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 229920000742 Cotton Polymers 0.000 claims abstract description 54
- 240000008042 Zea mays Species 0.000 claims abstract description 47
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims abstract description 47
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 47
- 235000009973 maize Nutrition 0.000 claims abstract description 47
- 230000007613 environmental effect Effects 0.000 claims abstract description 20
- 210000003205 muscle Anatomy 0.000 claims description 17
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 12
- 239000002667 nucleating agent Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000015556 catabolic process Effects 0.000 claims description 8
- 238000006731 degradation reaction Methods 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 7
- 239000004014 plasticizer Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 5
- -1 dioctyl ester Chemical class 0.000 claims description 5
- 229910021389 graphene Inorganic materials 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 4
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 235000019628 coolness Nutrition 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 239000004970 Chain extender Substances 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 2
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 claims description 2
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920003232 aliphatic polyester Polymers 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical class OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 claims description 2
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 2
- 150000005690 diesters Chemical class 0.000 claims description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 150000008301 phosphite esters Chemical class 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 4
- 230000003026 anti-oxygenic effect Effects 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 12
- 235000006708 antioxidants Nutrition 0.000 description 10
- 239000002994 raw material Substances 0.000 description 8
- 238000007731 hot pressing Methods 0.000 description 7
- 229920000747 poly(lactic acid) Polymers 0.000 description 7
- 239000004626 polylactic acid Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000001291 vacuum drying Methods 0.000 description 6
- 239000006071 cream Substances 0.000 description 5
- 229920002961 polybutylene succinate Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- PESZCXUNMKAYME-UHFFFAOYSA-N Citroflex A-4 Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)C(C(C)=O)C(=O)OCCCC PESZCXUNMKAYME-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 240000000377 Tussilago farfara Species 0.000 description 2
- 235000004869 Tussilago farfara Nutrition 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000004631 polybutylene succinate Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
- A45D40/262—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a brush or the like
- A45D40/265—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a brush or the like connected to the cap of the container
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof, lead to assemble that use is more inconvenient, and stability is poor for existing similar product structure design is not good enough, it is more difficult to the technical issues of environmental protection recycles and design.Its main points is that the cotton head of the single tube lip gloss and the fastening end of ear of maize are equipped with to fasten and enclose, and the buckling end side of cotton head is equipped with the inclined-plane of taper fitting, and the inclined-plane of cotton head is bonded with the centering of the fastening stomidium outer inclined-plane of ear of maize, and the opposite side end of cotton head is equipped with slanting horseshoe face；Salient point is equipped at the fastening circle of the cotton head, the salient point of cotton head and the location hole of ear of maize fasten；The caput outer diameter of the ear of maize is equipped with arrow equipped with antiskid groove, the caput of ear of maize, and the horseshoe of arrow and cotton head faces together.The cotton head is made with ear of maize of the environmentally friendly high heat proof material of high rigidity.Its assembling use is more convenient, and service life is long, environmental protection；It is suitable as the use of single tube lip gloss, and it is good to prepare counter-bending material, thermal deformation resistant, antioxygenic property.
Description
Technical field
The present invention relates to single tube lip glosses, are high heat proof material single tube lip glosses of a kind of environmentally friendly high rigidity and preparation method thereof.
Background technology
Lip gloss tube is a kind of cosmetics for placing liquid lip gloss, wherein using single tube structure or being generally single tube lip gloss.
At present, the part of single tube lip gloss uses different raw material, i.e., is made of plastics, metal, glass, as draped over one's shoulders in Chinese patent literature
The application number 201520687426.9 of dew, authorized announcement date 2016.01.27, utility model title " a kind of lip gloss tube "；The lip gloss
Pipe includes blowing bottle, hair bar, lid, and the bottom end of the hair bar is located in the front end of lid, on the front end center position of this mao of bar
It is provided with lip gloss；The bottom end inner wall of hair bar is provided with thread groove, and the thread groove is corresponding blows on bottle front end outer wall
Screw thread convex block is provided with, the bottle that blows is tightened by screw thread convex block and the thread groove of hair bar；In the front end for blowing bottle
Interior plug is provided between inner wall and hair bar bottom end, the interior plug sleeve is on hair bar bottom end；Advantage is：By the lip gloss tube,
During using lip gloss, main screw out blows bottle, just can apply lip gloss, have the advantages that easy to use, easy to carry, good seal performance.Its
The reworked material of parts need to sort rear recoverable, this complex steps, to the recycling pole again of energy-saving and environmental protection, waste
It is inconvenient.The single tube lip gloss occurred in the market is mostly made of the material of non-environmental protection, and production process has pollution, the pollution of generation
Object is difficult to degrade, more than production content do not comply with the relevant regulations of country and environment-friendly type manufacturing enterprise greatly developed
Demand.Meanwhile ear of maize, the interior plug in existing single tube lip gloss are made using general plastic raw materials, it is rigid in actual use
Deficiency, it is flexible, it meets high temperature and is easily deformed, and whole container leakproofness can be caused to be deteriorated after deforming, lotion can be leaked, be caused
The service life of product is substantially reduced.
Invention content
To overcome above-mentioned deficiency, the purpose of the present invention is provide a kind of environmentally friendly high rigidity high heat proof material single tube to this field
Lip gloss and preparation method thereof, solving it, existing similar product structure design is not good enough to cause assembling use more inconvenient, stability
It is poor, it is more difficult to the technical issues of environmental protection recycles.The purpose is to what is be achieved through the following technical solutions.
A kind of environmental protection high rigidity high heat proof material single tube lip gloss, ear of maize one end of the single tube lip gloss are lip gloss tube, lip gloss tube
Side end be equipped with cotton head, the caput of the other end of lip gloss tube and ear of maize connects, and the bottleneck of blow molded bottle is equipped with interior plug, ear of maize
Cotton head is stretched by interior plug in blow molded bottle；Its structure design main points is that the fastening end of cotton head and ear of maize is equipped with and fastens circle,
The buckling end side of cotton head is equipped with the inclined-plane of taper fitting, and the inclined-plane of cotton head is bonded with the centering of the fastening stomidium outer inclined-plane of ear of maize,
The opposite side end of cotton head is equipped with slanting horseshoe face.The ramp structure of inclined-plane centering cooperation cotton head is by use strong of cotton head
Degree is more preferable, not easily to fall off.
Salient point is equipped at the fastening circle of the cotton head, the salient point of cotton head and the location hole of ear of maize fasten.Location hole and salient point
Cooperation ensure in use cotton head will not rotate.
The caput outer diameter of the ear of maize is equipped with antiskid groove, and the caput of ear of maize is equipped with arrow, the horseshoe face of arrow and cotton head
Alignment.Above structure is convenient for determining the position and direction of cotton head, and the horseshoe face of cotton head is made just to correspond to arrow direction on ear of maize,
So that consumer is known that the orientation in horseshoe face under lip gloss bottle closed state, do not need to find horse again when taking out ear of maize use
The orientation in hoof face avoids the unnecessary pollution caused by falling of lip gloss cream/drop.
The interior vertical circle muscle of protrusion is additionally provided at the fastening circle of the cotton head, the fastening end outer diameter above at circle is fastened and sets
There is the upper vertical circle muscle of protrusion.Above structure further fixes convenient for cotton head with ear of maize.
The mouth internal diameter of the interior plug is equipped with the small muscle of protrusion of a ring shape, the lip gloss pipe outside diameter of ear of maize and the protrusion of interior plug
Small muscle interference fitting is equipped with two symmetrically arranged ventilating grooves between the small muscle of protrusion of interior plug.Ventilating groove is entering dress by ear of maize
When having the bottle of lip gloss cream/liquid, air will not be pressed into, lip gloss cream/liquid is caused to spray；The small muscle of circle annular protrusion of interior plug is in stick
When son extracts the bottle equipped with lip gloss cream/liquid, hanging fascia is attached to lip gloss cream/liquid of ear of maize, avoids unnecessary pollution.
The cotton head replaces with brush head.Use when i.e. the single tube lip gloss is as lip gloss liquid.
The cotton head uses following preparation method with ear of maize：100 parts by weight of degradation polymer, degradation polymer include
It is a variety of in polylactic acid, poly-succinic fourth diester and polyhydroxyalkanoate；Graphene 1-2 parts by weight；Nucleating agent 0.1-10
Parts by weight, the nucleating agent are hydrazide kind compound；Maleic anhydride 0-2 parts by weight；Other auxiliary agents 0.5-10 parts by weight, it is described its
His auxiliary agent includes one or more in antioxidant, plasticizer, chain extender, lubricant；Wherein described antioxidant packages include hindered phenol
One or more in kind antioxidant or phosphite ester kind antioxidant, the content of the antioxidant is 0.5-1 parts by weight；The increasing
Mould agent include polyethylene glycol, 1,2- cyclohexane dicarboxylic acids diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, to benzene two
It is one or more in formic acid dioctyl ester, citrate, aliphatic polyester or polyurethane；The lubricant is included from white oil, firmly
It is one or more in resin acid or vinyl bis-stearamides.
The antioxidant is the compound of one or more of age resisters in 3114, DSTP, DLTP, 168,1010.
Processing is dried in the degradation polymer and nucleating agent respectively, and the temperature of drying process is 60-100 DEG C, degradation
The time that polymer is dried, the temperature of the drying process of nucleating agent was 80-120 DEG C for 8-12 hour, drying process when
Between be 2-5 hours；It is blended with remaining component melts after drying, after being squeezed out at screw machine head, is molded by injection molding manner；Into
Cleaned after type through 80 DEG C of surface conditioning agents and organic solvent, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, equal
After changing concussion, 80 DEG C of drying and processings, final finished is obtained.
The surface conditioning agent includes coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone
One kind, the proportioning of two kinds of components is 5：80-95.
The present invention is reasonable in design, and assembling use is more convenient, and service life is long, environmental protection；It is suitable as single tube lip
Coloured silk uses, and it is good to prepare counter-bending material, thermal deformation resistant, antioxygenic property.
Description of the drawings
Fig. 1 is the ear of maize of the present invention and cotton head configuration schematic diagram, and confining part in figure is exaggerated.
Fig. 2 is the ear of maize head schematic cross-sectional view of the present invention, and part is confined in figure and is exaggerated.
Fig. 3 is the interior plug schematic cross-sectional view of the present invention, and part is confined in figure and is exaggerated.
Fig. 4 is the interior plug dimensional structure diagram of the present invention, and part is confined in figure and is exaggerated.
Fig. 5 is the embodiment of the present invention schematic cross-sectional view.
Figure number and title：1st, cotton head, 101, salient point, 102, horseshoe face, 103, inclined-plane, 2, ear of maize, 201, location hole,
202nd, arrow, 203, inclined-plane centering, 3, interior plug, 301, ventilating groove, 302, the small muscle of protrusion, 4, blow molded bottle.
Specific embodiment
In conjunction with attached drawing, structure of the present invention is further described.As Figure 1-Figure 5, the ear of maize 2 one of the single tube lip gloss
It holds as lip gloss tube, the side end of lip gloss tube is equipped with cotton head 1, and the other end of lip gloss tube and the caput of ear of maize connect, blow molded bottle 4
Bottleneck is equipped with interior plug 3, and the cotton head of ear of maize is stretched by interior plug in blow molded bottle.Its concrete structure is as follows：The fastening of cotton head and ear of maize
End is equipped with to fasten and enclose, and the buckling end side of cotton head is equipped with the inclined-plane 103 of taper fitting, the inclined-plane of cotton head and the buckling end of ear of maize
203 fitting of hole outer inclined-plane centering, the opposite side end of cotton head is equipped with slanting horseshoe face 102.Meanwhile it is set at the fastening circle of cotton head
There is salient point 101, the salient point of cotton head and the location hole 201 of ear of maize fasten；The interior vertical circle of protrusion is additionally provided at the fastening circle of cotton head
Muscle fastens the upper vertical circle muscle for fastening end outer diameter and being equipped with protrusion above at circle.The caput outer diameter of ear of maize is equipped with antiskid groove,
The caput of ear of maize is equipped with arrow 202, and arrow is aligned with the horseshoe face 102 of cotton head.The mouth internal diameter of interior plug is equipped with a ring shape
The small muscle 302 of protrusion, the lip gloss pipe outside diameter of ear of maize and the small muscle interference fitting of protrusion of interior plug are equipped with two between the small muscle of protrusion of interior plug
The symmetrically arranged ventilating groove 301 of item.
Above-mentioned cotton head uses following preparation method with ear of maize：
Embodiment 1
Raw materials and consumption is respectively：50 grams of polylactic acid, 1 gram of graphene, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25
Gram antioxidant 1010,1.25 grams of lubricant stearic acid aluminium.Polylactic acid is 12 hours dry in 80 DEG C of vacuum drying oven；TMC-300
Nucleating agent is 2 hours dry in 80 DEG C of vacuum drying oven.Then raw material is added in melting mixing in mixer after mixing, it is close
The temperature of mill three parts is respectively 190 DEG C, 195 DEG C and 190 DEG C, rotating speed 35rmp, and mixing time is 10 minutes.In screw rod
After being squeezed out at machine head, the resin after melting mixing is hot-forming in a mold, preheats 5 minutes；Mould hot pressing temperature is above and below
190 DEG C, pressure 10MPa；Hot pressing time is 5 minutes.The end properties obtained：Tensile strength is 47MPa, thermal deformation temperature
Spend is 80 DEG C.
Embodiment 2
Raw materials and consumption is respectively：25 grams of poly butylene succinates, 25 grams of polylactic acid, 1.5 grams of graphene, 0.25 gram of TMC-
306 nucleating agents, 0.25 gram of maleic anhydride, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram of antioxidant 1010,1.25 grams
Lubricant stearic acid aluminium.Poly butylene succinate and polylactic acid are 12 hours dry in 80 DEG C of vacuum drying oven；TMC-306 into
Core agent is 2 hours dry in 80 DEG C of vacuum drying oven.Then raw material is added in melting mixing in mixer, mixing after mixing
The temperature of machine three parts is respectively 190 DEG C, 195 DEG C and 190 DEG C, rotating speed 35rmp, and mixing time is 10 minutes.In screw machine
After being squeezed out at head, the resin after melting mixing is hot-forming in a mold, preheats 5 minutes；Upper and lower mould hot pressing temperature is 190
DEG C, pressure 10MPa；Hot pressing time is 5 minutes.The end properties obtained：Tensile strength 41MPa, heat distortion temperature 95
℃。
Embodiment 3
Raw materials and consumption is respectively：15 grams of polyhydroxyalkanoates, 15 grams of poly butylene succinates, 25 grams of polylactic acid, 2 grams
Graphene, 0.25 gram of maleic anhydride, 0.25 gram of TMC-306 nucleating agent, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram
Antioxidant 1010,1.25 grams of lubricant stearic acid aluminium.Polyhydroxyalkanoate, poly butylene succinate and polylactic acid are at 80 DEG C
Vacuum drying oven in dry 12 hours；TMC-306 nucleating agents are 2 hours dry in 80 DEG C of vacuum drying oven.Raw material is mixed equal
Melting mixing in mixer is added in after even, the temperature of mixer three parts is respectively 190 DEG C, 195 DEG C and 190 DEG C, and rotating speed is
35rmp, mixing time are 10 minutes.After being squeezed out at screw machine head, the resin after melting mixing is hot-forming in a mold,
Preheating 5 minutes.Upper and lower mould hot pressing temperature is 190 DEG C, pressure 10MPa.Hot pressing time is 5 minutes.It is moved back after hot pressing at 110 DEG C
Fire 30 minutes.The end properties obtained：Tensile strength 38MPa, 98 DEG C of heat distortion temperature.
3 finished product after molding of above example 1- embodiments is cleaned through 80 DEG C of surface conditioning agents and organic solvent, then is passed through
25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing are shaken, after 80 DEG C of drying and processings, obtain final finished.
In conclusion the single tube lip gloss has the following advantages that：1st, the single tube lip gloss is by the high thermal resistance, high-rigidity material system of environmental protection
Into, compared with traditional single tube lip gloss, the product have counter-bending, thermal deformation resistant, anti-oxidant, selling price is moderate, reasonable design,
Long lifespan meets the advantage of marketing character.2nd, it is in place of the single tube lip gloss and the difference of common single tube lip gloss, the single tube lip gloss
After ear of maize and Nei Sai possess special sealing structure and use the high thermal resistance, high-rigidity material of environmental protection, each parts connection is more firm
Gu cooperation is accurate, counter-bending deformation performance enhancing, thermal deformation resistant performance enhancement, whole air-tightness enhancing, user is facilitated to carry,
It preserves and uses.3rd, after the single tube lip gloss is made of the high thermal resistance, high-rigidity material of environmental protection, product plastic article is not easy deterioration by oxidation, long
After time preservation or use, surface color degree is still as before, while do not have leakage and pollution.4th, the single tube lip gloss employs stick
Cotton head horse hoof face position instruction at the top of the location structure and ear of maize of son and cotton head so that product is conveniently sought in use
Cotton head horse hoof face is looked for, avoids unnecessary trouble.
Claims (10)
1. a kind of high heat proof material single tube lip gloss of environmental protection high rigidity, the ear of maize of the single tube lip gloss（2）One end is lip gloss tube, lip gloss tube
Side end be equipped with cotton head（1）, the caput connection of the other end and ear of maize of lip gloss tube, blow molded bottle（4）Bottleneck be equipped with interior plug
（3）, ear of maize cotton head by it is interior plug stretch into blow molded bottle；It is characterized in that the cotton head（1）With ear of maize（2）Fastening end set
There is fastening to enclose, the buckling end side of cotton head is equipped with the inclined-plane of taper fitting（103）, cotton head inclined-plane and ear of maize fastening stomidium in
It feels relieved on inclined-plane（203）Fitting, the opposite side end of cotton head are equipped with slanting horseshoe face（102）.
2. the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that the cotton head（1）'s
It fastens and salient point is equipped at circle（101）, the salient point and ear of maize of cotton head（2）Location hole（201）It fastens.
3. the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that the ear of maize（2）'s
Caput outer diameter is equipped with antiskid groove, and the caput of ear of maize is equipped with arrow（202）, arrow and cotton head（1）Horseshoe face（102）Alignment.
4. the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that the cotton head（1）'s
The interior vertical circle muscle that protrusion is additionally provided at circle is fastened, fastens the upper vertical circle for fastening end outer diameter and being equipped with protrusion above at circle
Muscle.
5. the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that the interior plug（3）'s
Mouth internal diameter is equipped with the small muscle of protrusion of a ring shape（302）, ear of maize（2）Lip gloss pipe outside diameter and interior plug the small muscle interference set of protrusion
It closes, two symmetrically arranged ventilating grooves is equipped between the small muscle of protrusion of interior plug（301）.
6. the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that the cotton head（1）It replaces
It is changed to brush head.
7. the preparation method of the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 1, it is characterised in that institute
State cotton head（1）With ear of maize（2）Using following preparation method：100 parts by weight of degradation polymer, degradation polymer include poly- breast
It is a variety of in acid, poly-succinic fourth diester and polyhydroxyalkanoate；Graphene 1-2 parts by weight；Nucleating agent 0.1-10 weight
Part, the nucleating agent is hydrazide kind compound；Maleic anhydride 0-2 parts by weight；Other auxiliary agents 0.5-10 parts by weight, described other help
Agent includes one or more in antioxidant, plasticizer, chain extender, lubricant；Wherein described antioxidant packages include Hinered phenols and resist
One or more in oxygen agent or phosphite ester kind antioxidant, the content of the antioxidant is 0.5-1 parts by weight；The plasticizer
Including polyethylene glycol, 1,2- cyclohexane dicarboxylic acids diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, terephthalic acid (TPA)
It is one or more in dioctyl ester, citrate, aliphatic polyester or polyurethane；The lubricant is included from white oil, stearic acid
It is or one or more in vinyl bis-stearamides.
8. the preparation method of the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 7, it is characterised in that institute
State compound of the antioxidant for age resisters one or more of in 3114, DSTP, DLTP, 168,1010.
9. the preparation method of the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 7, it is characterised in that institute
It states degradation polymer and nucleating agent and processing is dried respectively, the temperature of drying process is 60-100 DEG C, degradation polymer drying
The time of processing is 8-12 hours, and the temperature of the drying process of nucleating agent is 80-120 DEG C, and the time of drying process is small for 2-5
When；It is blended with remaining component melts after drying, after being squeezed out at screw machine head, is molded by injection molding manner；Through 80 after molding
DEG C surface conditioning agent and organic solvent cleaning, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing are shaken,
After 80 DEG C of drying and processings, final finished is obtained.
10. the preparation method of the high heat proof material single tube lip gloss of environmental protection high rigidity according to claim 9, it is characterised in that institute
State surface conditioning agent include coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone one kind, two kinds
The proportioning of component is 5：80-95.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810135347.5A CN108264745A (en) | 2018-02-09 | 2018-02-09 | Environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810135347.5A CN108264745A (en) | 2018-02-09 | 2018-02-09 | Environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof |
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| CN108264745A true CN108264745A (en) | 2018-07-10 |
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ID=62774103
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|---|---|---|---|
| CN201810135347.5A Pending CN108264745A (en) | 2018-02-09 | 2018-02-09 | Environmentally friendly high heat proof material single tube lip gloss of high rigidity and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110313696A (en) * | 2019-06-27 | 2019-10-11 | 浙江正庄实业有限公司 | Antibacterial high rigidity round tube lip gloss and its material preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080057013A1 (en) * | 2006-08-31 | 2008-03-06 | Padraig Mcdermott | Lip gloss compositions with enhanced shine |
| CN103772878A (en) * | 2014-01-13 | 2014-05-07 | 杭州伊贝实业有限公司 | Completely biodegradable material and preparation method thereof and cosmetics container |
| CN206648251U (en) * | 2017-02-22 | 2017-11-17 | 深圳创维空调科技有限公司 | A kind of buckle connecting structure and air-conditioning |
| CN206729481U (en) * | 2017-05-04 | 2017-12-12 | 苏州兴广五金制品有限公司 | A kind of transparent lip gloss bottle |
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2018
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080057013A1 (en) * | 2006-08-31 | 2008-03-06 | Padraig Mcdermott | Lip gloss compositions with enhanced shine |
| CN103772878A (en) * | 2014-01-13 | 2014-05-07 | 杭州伊贝实业有限公司 | Completely biodegradable material and preparation method thereof and cosmetics container |
| CN206648251U (en) * | 2017-02-22 | 2017-11-17 | 深圳创维空调科技有限公司 | A kind of buckle connecting structure and air-conditioning |
| CN206729481U (en) * | 2017-05-04 | 2017-12-12 | 苏州兴广五金制品有限公司 | A kind of transparent lip gloss bottle |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110313696A (en) * | 2019-06-27 | 2019-10-11 | 浙江正庄实业有限公司 | Antibacterial high rigidity round tube lip gloss and its material preparation method |
| CN110313696B (en) * | 2019-06-27 | 2023-08-29 | 浙江正庄实业有限公司 | Antibacterial high-rigidity circular tube lip gloss and preparation method of material thereof |
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Application publication date: 20180710 |