CN108456408A - Environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof - Google Patents
Environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof Download PDFInfo
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- CN108456408A CN108456408A CN201810136131.0A CN201810136131A CN108456408A CN 108456408 A CN108456408 A CN 108456408A CN 201810136131 A CN201810136131 A CN 201810136131A CN 108456408 A CN108456408 A CN 108456408A
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- fork
- antistatic
- lipstick tube
- high rigidity
- environmental protection
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/06—Casings wherein movement of the lipstick or like solid is a screwing movement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof, lead to rotate that feel is poor, and stability is poor for existing similar product structure design is not good enough, it is more difficult to the technical issues of environmental protection recycles and design.The pearl of the lipstick tube is inserted in the centre bore of fork, and the lift points of the symmetrical protrusion of fork outer diameter stretch out the fork track of fork；Its main points be the pearl outer diameter lift points between be equipped with the fixed point of distribution protrusion up and down, positioning groove is equipped between raised fixed point both ends；One end outer diameter of the fork is equipped with the spline item of protrusion, and the bottom prong internal diameter of fork is equipped with gear ring, and the ring of fork end face is equipped with location hole；The outer diameter of the spiral is cased with middle beam.The pearl, fork and spiral are made of environmentally friendly high rigidity antistatic material.Its environmental protection, it is antistatic, good hand touch is rotated, service life is long；It is suitable as lipstick tube use, prepares material high temperature resistant, wear-resisting, corrosion resistant, high rigidity, antistatic.
Description
Technical field
It is a kind of environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof the present invention relates to lipstick tube.
Background technology
Lipstick tube is widely used in the color make-ups packaging field such as lipstick, lipstick, since product structure and principle need, well known mouth
The part of red pipe is made of different raw material, i.e., is made of plastics, metal, and the reworked materials of parts can after need to sorting
It recycles.This complex steps, it is extremely inconvenient to the recycling again of energy-saving and environmental protection, waste.Currently, green, environmental protection, low-carbon
Life style have become current mainstream, the material that the lipstick tube occurred in the market mostly uses non-environmental protection is made, production
Process has pollution, the pollutant of generation to be difficult to degrade, and the above production content does not comply with the relevant regulations of country, and to environmental protection
The demand that type manufacturing enterprise greatly develops.Application number 201420129066.6 as disclosed in Chinese patent literature, Granted publication
Day 2014.10.08, utility model title " a kind of environmental protection lipstick tube "；The lipstick tube between spiral and tube body by being arranged bullet
Piece and the pedestal and spiral are being connected using keyway arrangements and snap ring notch, is replacing grease to generate using shrapnel fixed
The torsion of position is fixedly connected by mechanical structure and original glue is replaced to connect, and is not only reduced and is smeared grease and glue, wipes more
The problem of remaining glue, while effectively avoiding grease and the issuable pollution of glue.For another example the Shen disclosed in Chinese patent literature
Please numbers 201220460727.4, authorized announcement date 2013.04.24, utility model title " a kind of Oil-free middle bundle core of lipstick tube "；
Meanwhile existing lipstick tube is made using general plastic raw materials, is met high temperature in actual use and is easily deformed, so as to cause production
The service life of product is substantially reduced.
Invention content
To overcome above-mentioned deficiency, the purpose of the present invention is to this field provide a kind of environmentally friendly high rigidity antistatic lipstick tube and
Preparation method, so that it is solved, existing similar product structure design is not good enough to cause rotation feel poor, and stability is poor, it is more difficult to ring
Protect the technical issues of recycling.The purpose is to what is be achieved through the following technical solutions.
A kind of environmental protection high rigidity antistatic lipstick tube, the pearl of the lipstick tube are inserted in the centre bore of fork, fork outer diameter
The lift points of symmetrical protrusion stretch out the fork track of fork, and vertical fork track both ends are respectively equipped with lateral locating notch,
The lift points for stretching out fork track are located at the helical orbit of fork outer diameter spiral, and the internal diameter of pearl is equipped with positioning bar, the bottom of fork
Portion's prong outer diameter is equipped with antislip ring；Its structure design main points be the pearl outer diameter lift points between be equipped with up and down distribution protrusion
Fixed point, positioning groove is equipped between raised fixed point both ends.Above-mentioned fixed point is frictional fixed point, makes the liter of pearl
Drop point will not loosen or in place afterwards by the fixed effect that dramatically increases of frictional force because being not intended to touch without reason in use
And the lifting of lotion is caused to generate unnecessary pollution.Meanwhile helical orbit has done some in spiral shell according to ergonomics
The adjustment on lift angle is revolved, preferably to coordinate special track, the lift points on pearl to do non-sphering processing, pearl is made in conjunction with after
It is more stable in uphill process.
One end outer diameter of the fork is equipped with the spline item of protrusion, and the bottom prong internal diameter of fork is equipped with gear ring, fork
The ring of end face is equipped with location hole.Above structure is convenient for the limit of fork rotation position, rotation and observation.
The outer diameter of the spiral is cased with middle beam.Shape of the middle beam for the lipstick tube is more beautiful.
The pearl, fork and spiral are using following preparation method：100 parts by weight of the degradation polymer, degradation polymerization
Object includes a variety of in polylactic acid, poly-succinic fourth diester and polyhydroxyalkanoate；Graphene 1-2 parts by weight；Nucleating agent
0.1-10 parts by weight, the nucleating agent are hydrazide kind compound；Maleic anhydride 0-2 parts by weight；Antistatic agent 1-3 parts by weight；It is even
Join agent 0.1-1 parts by weight, coupling agent is aluminium titanium composite coupler；Other auxiliary agents 0.5-10 parts by weight, other described auxiliary agents include
It is one or more in antioxidant, plasticizer, chain extender, lubricant；The wherein described antioxidant packages include Hinered phenols antioxidant or
One or more in phosphite ester kind antioxidant, the content of the antioxidant is 0.5-1 parts by weight；The plasticizer includes poly-
Ethylene glycol, 1,2- cyclohexane dicarboxylic acids diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, dioctyl terephthalate,
It is one or more in citrate, aliphatic polyester or polyurethane；The lubricant includes from white oil, stearic acid or vinyl
It is one or more in bis-stearamides.To make the table of the track of spiral, the lift points of pearl, the track of fork these parts
Surface roughness is all very low, increases the feel of sliding and the service life of part.
The antistatic agent is HDC-102 antistatic agents or HBS-510 antistatic agents.
The antioxidant is the compound of one or more of age resisters in 3114, DSTP, DLTP, 168,1010.
Processing is dried in the degradation polymer and nucleating agent respectively, and the temperature of drying process is 60-100 DEG C, degradation
The time that polymer is dried is 8-12 hour, and the temperature of the drying process of nucleating agent is 80-120 DEG C, drying process when
Between be 2-5 hours；It is blended with remaining component melts after drying, after being squeezed out at screw machine head, is molded by injection molding manner；At
Cleaned through 80 DEG C of surface conditioning agents and organic solvent after type, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, equal
After changing concussion, 80 DEG C of drying and processings, final finished is obtained.
The surface conditioning agent includes coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone
The proportioning of one kind, two kinds of components is 5：80-95.
Structure of the invention reasonable design, environmental protection is antistatic, rotates good hand touch, and service life is long；It is suitable as lipstick tube
It uses, prepares material high temperature resistant, wear-resisting, corrosion resistant, high rigidity, antistatic.
Description of the drawings
Fig. 1 is the configuration schematic diagram of the present invention, partly confines and is exaggerated in figure.
Fig. 2 is the dimensional structure diagram of the present invention.
Fig. 3 is the pearl schematic cross-sectional view of the present invention, is partly exaggerated in figure.
Fig. 4 is the fork schematic cross-sectional view of the present invention, is partly exaggerated in figure.
Fig. 5 is the spiral schematic cross-sectional view of the present invention.
Figure number and title：1, pearl, 101, lift points, 102, fixed point, 2, fork, 201, fork track, 3, spiral shell
Rotation, 301, helical orbit, 4, middle beam.
Specific implementation mode
In conjunction with attached drawing, structure of the invention is further described.As Figure 1-Figure 5, the pearl 1 of the lipstick tube is inserted in
In the centre bore of fork 2, the lift points 101 of the symmetrical protrusion of fork outer diameter stretch out the fork track 201 of fork, vertical fork rail
Road both ends are respectively equipped with lateral locating notch, and the lift points for stretching out fork track are located at the helical orbit of fork outer diameter spiral 3
301, the internal diameter of pearl is equipped with positioning bar, and the bottom prong outer diameter of fork is equipped with antislip ring.Between the lift points 101 of pearl outer diameter
Equipped with the fixed point 102 that upper and lower distribution is raised, positioning groove is equipped between raised fixed point both ends.One end outer diameter of fork is set
There are the spline item of protrusion, the bottom prong internal diameter of fork to be equipped with gear ring, the ring of fork end face is equipped with location hole.Outside spiral
Diameter is cased with middle beam 4.
Above-mentioned pearl, fork and spiral are using following preparation method：
Embodiment 1
Raw materials and consumption is respectively：50 grams of polylactic acid, 1 gram of graphene, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25
Gram antioxidant 1010,1.25 grams of lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Polylactic acid
It is 12 hours dry in 80 DEG C of vacuum drying oven；TMC-300 nucleating agents are 2 hours dry in 80 DEG C of vacuum drying oven.Then will
Melting mixing in mixer is added in raw material after mixing, and the temperature of mixer three parts is respectively 190 DEG C, 195 DEG C and 190
DEG C, rotating speed 35rmp, mixing time is 10 minutes.After being squeezed out at screw machine head, the resin after melting mixing is in a mold
It is hot-forming, it preheats 5 minutes；Upper and lower mould hot pressing temperature is 190 DEG C, pressure 10MPa；Hot pressing time is 5 minutes.It is obtained
End properties：Tensile strength is 47MPa, and heat distortion temperature is 80 DEG C.
Embodiment 2
Raw materials and consumption is respectively：25 grams of poly butylene succinates, 25 grams of polylactic acid, 1.5 grams of graphene, 0.25 gram of TMC-
306 nucleating agents, 0.25 gram of maleic anhydride, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram of antioxidant 1010,1.25 grams
Lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Poly butylene succinate and polylactic acid
It is 12 hours dry in 80 DEG C of vacuum drying oven；TMC-306 nucleating agents are 2 hours dry in 80 DEG C of vacuum drying oven.Then will
Melting mixing in mixer is added in raw material after mixing, and the temperature of mixer three parts is respectively 190 DEG C, 195 DEG C and 190
DEG C, rotating speed 35rmp, mixing time is 10 minutes.After being squeezed out at screw machine head, the resin after melting mixing is in a mold
It is hot-forming, it preheats 5 minutes；Upper and lower mould hot pressing temperature is 190 DEG C, pressure 10MPa；Hot pressing time is 5 minutes.It is obtained
End properties：Tensile strength 41MPa, 95 DEG C of heat distortion temperature.
Embodiment 3
Raw materials and consumption is respectively：15 grams of polyhydroxyalkanoates, 15 grams of poly butylene succinates, 25 grams of polylactic acid, 2 grams
Graphene, 0.25 gram of maleic anhydride, 0.25 gram of TMC-306 nucleating agent, 2.5 grams of tributyl 2-acetylcitrate plasticizer, 0.25 gram
Antioxidant 1010,1.25 grams of lubricant stearic acid aluminium, 1 gram of aluminium titanium composite coupler, 1 gram of HDC-102 antistatic agent.Poly- hydroxyl fat
Fat acid esters, poly butylene succinate and polylactic acid are 12 hours dry in 80 DEG C of vacuum drying oven；TMC-306 nucleating agents are 80
DEG C vacuum drying oven in dry 2 hours.Raw material is added to melting mixing in mixer, the temperature of mixer three parts after mixing
Degree is respectively 190 DEG C, 195 DEG C and 190 DEG C, rotating speed 35rmp, and mixing time is 10 minutes.After being squeezed out at screw machine head,
Resin after melting mixing is hot-forming in a mold, preheats 5 minutes.Upper and lower mould hot pressing temperature is 190 DEG C, and pressure is
10MPa.Hot pressing time is 5 minutes.It anneals 30 minutes at 110 DEG C after hot pressing.The end properties obtained：Tensile strength
38MPa, 98 DEG C of heat distortion temperature.
It cleans, then leads to through 80 DEG C of surface conditioning agents and organic solvent after 3 molding after molding of above example 1- embodiments
Cross 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing are shaken, after 80 DEG C of drying and processings, obtain final finished.
In conclusion the advantages of lipstick tube, is as follows：1, the lipstick tube is made of environmentally friendly high rigidity antistatic material, with biography
System plastics lipstick tube is compared, which has high temperature resistant, good toughness, good fluidity, wear-resisting, insulation, chemicals-resistant, corrosion-resistant.
Pole low water absorbable ﹑ is low, and bent ﹑ high dimensionally stables, the thermal stability of sticking up are good, still have high rigidity and high-lubricity under operation at high temperature.With
The nylon of enhancing is compared, and still maintains effective intensity and toughness at higher temperatures.It is having the same under dry and moist
Stretch intensity and toughness.It is antistatic, selling price is moderate, reasonable design, long lifespan, meet the advantage of marketing character.2, the mouth
After red pipe is using environmentally friendly high rigidity antistatic material, anti-extrusion ability is strong, the damage deformation in middle beam core turnover, transportational process,
Security performance improves.3, after the lipstick tube is using environmentally friendly high rigidity antistatic material.In being rotated in use when beam core, no electrostatic production
Raw, rotation feel is more soft smooth.When rotation, the finger extruding force that middle Shu Xin can bear improves twice, is unlikely to deform, prolongs in use
The service life of lipstick tube is grown.4, the lipstick tube have high temperature resistant, good toughness, good fluidity, wear-resisting, insulation, chemicals-resistant,
It is corrosion-resistant；Pole low water absorbable ﹑ is low, and bent ﹑ high dimensionally stables, the thermal stability of sticking up are good, still have high rigidity and Gao Run under operation at high temperature
Slip.
Claims (8)
1. a kind of environmental protection high rigidity antistatic lipstick tube, the pearl of the lipstick tube（1）It is inserted in fork（2）Centre bore in, fork
The lift points of the symmetrical protrusion of outer diameter（101）Stretch out the fork track of fork（201）, vertical fork track both ends are respectively equipped with cross
To locating notch, stretch out fork track lift points be located at fork outer diameter spiral（3）Helical orbit（301）, pearl it is interior
Diameter is equipped with positioning bar, and the bottom prong outer diameter of fork is equipped with antislip ring；It is characterized in that the pearl（1）The lift points of outer diameter
（101）Between be equipped with up and down distribution protrusion fixed point（102）, positioning groove is equipped between raised fixed point both ends.
2. environmental protection high rigidity antistatic lipstick tube according to claim 1, it is characterised in that the fork（2）One end outside
Diameter is equipped with the spline item of protrusion, and the bottom prong internal diameter of fork is equipped with gear ring, and the ring of fork end face is equipped with location hole.
3. environmental protection high rigidity antistatic lipstick tube according to claim 1, it is characterised in that the spiral（3）Outer diameter set
There is middle beam（4）.
4. the preparation method of environmental protection high rigidity antistatic lipstick tube according to claim 1, it is characterised in that the pearl
（1）, fork（2）And spiral（3）Using following preparation method：100 parts by weight of the degradation polymer, degradation polymer include poly-
It is a variety of in lactic acid, poly-succinic fourth diester and polyhydroxyalkanoate；Graphene 1-2 parts by weight；Nucleating agent 0.1-10 weights
Part is measured, the nucleating agent is hydrazide kind compound；Maleic anhydride 0-2 parts by weight；Antistatic agent 1-3 parts by weight；Coupling agent 0.1-1
Parts by weight, coupling agent are aluminium titanium composite coupler；Other auxiliary agents 0.5-10 parts by weight, other described auxiliary agents include antioxidant, increase
It moulds one or more in agent, chain extender, lubricant；The wherein described antioxidant packages include Hinered phenols antioxidant or phosphorous acid esters
One or more in antioxidant, the content of the antioxidant is 0.5-1 parts by weight；The plasticizer includes polyethylene glycol, 1,
2- cyclohexane dicarboxylic acids diisopropyl ester, decanedioic acid two just ester, dibutyl maleate, dioctyl terephthalate, citrate,
It is one or more in aliphatic polyester or polyurethane；The lubricant includes from white oil, stearic acid or vinyl stearic bicine diester
It is one or more in amine.
5. the preparation method of environmental protection high rigidity antistatic lipstick tube according to claim 4, it is characterised in that described is anti-
Electrostatic agent is HDC-102 antistatic agents or HBS-510 antistatic agents.
6. the preparation method of environmental protection high rigidity antistatic lipstick tube according to claim 4, it is characterised in that the antioxygen
Agent is the compound of one or more of age resisters in 3114, DSTP, DLTP, 168,1010.
7. the preparation method of environmental protection high rigidity antistatic lipstick tube according to claim 4, it is characterised in that the degradation
Processing is dried in polymer and nucleating agent respectively, and the temperature of drying process is 60-100 DEG C, what degradation polymer was dried
Time is 8-12 hours, and the temperature of the drying process of nucleating agent is 80-120 DEG C, and the time of drying process is 2-5 hours；It is dry
It is blended with remaining component melts, after being squeezed out at screw machine head, is molded by injection molding manner afterwards；After molding through 80 DEG C of surfaces at
Manage agent and organic solvent cleaning, then by 25 DEG C of waters slot water coolings, it is air-cooled, air-dry dehydration, blank, homogenizing concussion, 80 DEG C dry
After processing, final finished is obtained.
8. the preparation method of environmental protection high rigidity antistatic lipstick tube according to claim 7, it is characterised in that the surface
Inorganic agent includes one kind of coupling agent component NDZ101 and organic solvent constituent chloroform, tetrahydrofuran or acetone, two kinds of components
Proportioning is 5：80-95.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810136131.0A CN108456408B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic lipstick tube and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810136131.0A CN108456408B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic lipstick tube and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108456408A true CN108456408A (en) | 2018-08-28 |
| CN108456408B CN108456408B (en) | 2023-10-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810136131.0A Active CN108456408B (en) | 2018-02-09 | 2018-02-09 | Environment-friendly high-rigidity antistatic lipstick tube and preparation method thereof |
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Cited By (3)
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| CN109123997A (en) * | 2018-09-14 | 2019-01-04 | 浙江正庄实业有限公司 | Antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method |
| CN112743887A (en) * | 2020-12-21 | 2021-05-04 | 安徽裕佳铝塑科技有限公司 | Preparation method of integrated forming-port red tube |
| CN114539729A (en) * | 2022-01-27 | 2022-05-27 | 浙江阿克希龙舜华铝塑业有限公司 | Resin composition for manufacturing middle bundle core, middle bundle core and packaging tube |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109123997A (en) * | 2018-09-14 | 2019-01-04 | 浙江正庄实业有限公司 | Antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method |
| CN109123997B (en) * | 2018-09-14 | 2024-04-02 | 浙江正庄实业有限公司 | Ultraviolet-proof triangular pen nozzle eyebrow pencil and preparation method of resin material thereof |
| CN112743887A (en) * | 2020-12-21 | 2021-05-04 | 安徽裕佳铝塑科技有限公司 | Preparation method of integrated forming-port red tube |
| CN114539729A (en) * | 2022-01-27 | 2022-05-27 | 浙江阿克希龙舜华铝塑业有限公司 | Resin composition for manufacturing middle bundle core, middle bundle core and packaging tube |
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| Publication number | Publication date |
|---|---|
| CN108456408B (en) | 2023-10-13 |
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