CN109123997A - Antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method - Google Patents
Antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method Download PDFInfo
- Publication number
- CN109123997A CN109123997A CN201811071928.3A CN201811071928A CN109123997A CN 109123997 A CN109123997 A CN 109123997A CN 201811071928 A CN201811071928 A CN 201811071928A CN 109123997 A CN109123997 A CN 109123997A
- Authority
- CN
- China
- Prior art keywords
- mouth
- antiultraviolet
- pearl
- eyebrow pencil
- resin material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004709 eyebrow Anatomy 0.000 title claims abstract description 34
- 229920005989 resin Polymers 0.000 title claims abstract description 27
- 239000011347 resin Substances 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 210000003205 muscle Anatomy 0.000 claims abstract description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 39
- 239000002216 antistatic agent Substances 0.000 claims description 24
- 239000003963 antioxidant agent Substances 0.000 claims description 23
- 230000003078 antioxidant effect Effects 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 239000000945 filler Substances 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910021389 graphene Inorganic materials 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 6
- 239000012745 toughening agent Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 150000003673 urethanes Chemical class 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 210000004209 hair Anatomy 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- 150000008301 phosphite esters Chemical class 0.000 claims description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229960004050 aminobenzoic acid Drugs 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 5
- 239000004640 Melamine resin Substances 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229940068984 polyvinyl alcohol Drugs 0.000 description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 3
- 206010007134 Candida infections Diseases 0.000 description 2
- 208000007027 Oral Candidiasis Diseases 0.000 description 2
- 241000287411 Turdidae Species 0.000 description 2
- 201000003984 candidiasis Diseases 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 208000025157 Oral disease Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/20—Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
- A45D40/205—Holders for stick-shaped cosmetics whereby the stick can move axially relative to the holder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/20—Pencil-like cosmetics; Simple holders for handling stick-shaped cosmetics or shaving soap while in use
- A45D40/205—Holders for stick-shaped cosmetics whereby the stick can move axially relative to the holder
- A45D2040/208—Holders for stick-shaped cosmetics whereby the stick can move axially relative to the holder the relative movement being made by a rotating action, e.g. effected by a screw
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Pens And Brushes (AREA)
Abstract
The present invention relates to a kind of antiultraviolet triangle mouth eyebrow pencil and its resin material preparation methods, it is not good enough for ejector sleeve structure design in existing similar product is solved, more difficult applicable automated production, component lack the technical issues of preparation of antiultraviolet resin material produces and design.Its main points is that the bar slot outer diameter between the pen core set of pearl in the eyebrow pencil and screw rod is symmetrically arranged with elastic slice, the elastic slice of pearl and the inner wall of mouth offset, limit chamber is equipped with below mouthpiece in mouth, the lower section inner wall of limit chamber is equipped with the muscle position item of protrusion, pearl is limited in the limit chamber in a mouth, and the outer cover inner wall above mouth is equipped with three flange collar muscle being equally spaced；The pen core set of pearl is in isosceles triangle, the inner wall of pen core set is equipped with the on-slip rib of protrusion, pen body one end port outside diameter of mouth is symmetrically arranged with salient point, square circle muscle bottom side is symmetrically arranged with catch point under the bar slot of pearl, the screw top hole of spiral shell retaining ring is equipped with corresponding retaining ring, above-mentioned pen body and outer cover and is made of the resin material of antiultraviolet.
Description
Technical field
It is a kind of antiultraviolet triangle mouth eyebrow pencil and its resin material preparation method the present invention relates to pushing type eyebrow pencil.
Background technique
Eyebrow pencil is a kind of cosmetics for thrush, and there are two types of forms for modern eyebrow pencil, another one is pencil formula
Kind it is pushing type, pen core is released into thrush when use.The advantages of eyebrow pencil be it is convenient and efficient, be suitable for sketching the contours camber, draw
Short pinniform eyebrow sketches the contours eyebrow tail.Application number of such pushing type eyebrow pencil products as disclosed in Chinese patent literature
201320186700.5 authorized announcement date 2013.10.16, utility model title " cosmetic eyebrow pencil with rotating device "；For another example
The application number 201520088508.1 disclosed in Chinese patent literature, authorized announcement date the 2015.07.15, " rotation of utility model title
Dynamic formula cosmetic eyebrow pencil "；But the use of the said goods and similar product rotates more difficult effective control, produces the degree of automation of assembly
Lower, leakproofness is poor.
Summary of the invention
To overcome above-mentioned deficiency, the purpose of the present invention is to this field provide a kind of antiultraviolet triangle mouth eyebrow pencil and its
Resin material preparation method, solving it mainly in existing similar product, the design of ejector sleeve structure is not good enough, it is more difficult to be applicable in automatic metaplasia
It produces, leakproofness is poor, and main component lacks the technical issues of preparation of antiultraviolet resin material produces.It is as follows the purpose is to pass through
What technical solution was realized.
A kind of antiultraviolet triangle mouth eyebrow pencil, pen body one end outer diameter button muscle of the eyebrow pencil and the lid mouth internal diameter buckle ring of outer cover
It fastens, above structure ensure that the close-fitting of pen body and outer cover, and the whole branch eyebrow pencil is made to have tight function.The outer cover port of pen body is set
There is a mouth, pearl is equipped in mouth, the pen core of pearl one end is arranged with reservoir hole, and the other end of pearl is equipped with screw rod, protrudes into pen
Caliber inner screw thread connects in spiral shell retaining ring in outer screw diameter and pen body in mouth, the gear ring of spiral shell retaining ring outer diameter and the convex ribs of pen body inner wall
Engagement is fixed, to make the eyebrow pencil, spiral shell retaining ring does not have loose phenomenon in use；Its structure designing points is the pearl
Son pen core set screw rod between bar slot outer diameter be symmetrically arranged with elastic slice, the elastic slice of pearl and the inner wall of mouth offset, make its
Pearl does not have shaking phenomenon in use process, while the inner wall of the elastic slice of pearl and mouth bumps against common generation sound, pearl
It is that there is damping sense in rotation, does not easily cause pen core to waste.Limit chamber is equipped with below mouthpiece in mouth, in the lower section of limit chamber
Wall is equipped with the muscle position item of protrusion, and pearl is limited in the limit chamber in a mouth, and the outer cover inner wall above mouth, which is equipped with, to be equally spaced
Three flange collar muscle make a mouth preceding mould not easy to stick in injection moulding process.
The pen core set of the pearl is in isosceles triangle, and pen core covers inner wall below the limit chamber and limit chamber of corresponding mouth and is in
Isosceles triangle, pearl interference are inserted in a mouth, and are limited at the limit chamber of a mouth, and the channel in mouth play the guiding role,
The inner wall of pen core set is equipped with the on-slip rib of protrusion；The other end of pen body is equipped with blocking chamber, the plug of blocking and the blocking of pen body
Chamber fitting, so that it is not easily to fall off to block the eyebrow pencil in use.
Pen body one end port outside diameter of described mouth is symmetrically arranged with salient point, the salient point of mouth with it is straight above pen body inner convex rib
Slot is risen to fasten.To which mouth is fixed on pen body by the salient point of mouth and the slot of going straight up to of pen body, and make the eyebrow pencil in rotary course
In feeling is better.
Square circle muscle bottom side is symmetrically arranged with catch point under the bar slot of the pearl, and the screw top hole of spiral shell retaining ring, which is equipped with, to be corresponded to
Retaining ring.The catch point of pearl and spiral shell retaining ring, which bumps against, in rotation generates sound, and user is reminded to have rotated to top.
The pen body, outer cover are made of the resin material of antiultraviolet, the starting components proportion of the resin material
Are as follows: polyethylene 80-90%, 23% sodium hydrate aqueous solution 6%-10%, graphene oxide 5%-7%, toughener 3%-5%, uvioresistant
Agent 2%-4%, antistatic agent 1%-2%, environmentally friendly Masterbatch 3-6%, propylene glycol 5-8%, filler 2-5%, antioxidant 0.3%-1 %, filling
Agent 0.1%-1%；The filler is partial size 20nm, specific surface area >=230m2The Nano-sized Alumina Powder of/g.
The toughener is polyvinyl alcohol, thiocarbamide, urethanes, dibutyl phthalate, phthalic acid two
Monooctyl ester, polyurethane resin, alkyd resin, acrylic resin, diethylene glycol (DEG) it is one or more.
The antiultraviolet antioxidant includes one of Hinered phenols antioxidant or phosphite ester antioxidant or a variety of,
The antistatic agent is HDC-102 antistatic agent or HBS-510 antistatic agent.
The antistatic agent is HDC-102 antistatic agent or HBS-510 antistatic agent.
The antioxidant is one or both of antioxidant 246,300,1010,1035, CA, 3114,168, DLTDP.
The filler is calcium carbonate, washes one's hair and at least one of powder, talcum powder, barium sulfate, carbon black.
Rationally, easy to use, long service life, handle effect is good when use, leakproofness and stabilization for structure of the invention design
Property it is good, automated production assembly it is feasible, the preparation method of antiultraviolet resin material is feasible；It is suitable as similar eyebrow pencil products
It uses and the structure of similar product is improved.
Detailed description of the invention
Fig. 1 is configuration schematic diagram of the invention, and section components have made section view in figure.
Fig. 2 is pearl schematic perspective view of the invention, confines part-structure in figure and is exaggerated.
Fig. 3 is a mouth structure schematic diagram of the invention.
Fig. 4 is screw socket ring structure schematic diagram of the invention.
Fig. 5 is schematic cross-sectional view of the invention, and arrow is that pearl rotation moves down direction in figure.
Figure number and title: 1, outer cover, 101, flange collar muscle, 2, pearl, 201, elastic slice, 202, catch point, 203, pen core set,
204, screw rod, 3, mouth, 301, limit chamber, 302, muscle position item, 303, salient point, 4, pen body, 401, button muscle, 402, go straight up to slot,
403, convex ribs, 5, spiral shell retaining ring, 501, retaining ring, 502, internal screw thread, 503, gear ring, 6, blocking.
Specific embodiment
Now in conjunction with attached drawing, structure of the invention and use are further described.As Figure 1-Figure 5, the pen body 4 of the eyebrow pencil
The lid mouth internal diameter buckle ring of one end outer diameter button muscle 401 and outer cover 1 fastens, and the outer cover port of upper pen body is equipped with a mouth 3, is equipped in mouth
Pearl 2, the pen core set 203 of pearl one end are equipped with reservoir hole, and the other end of pearl is equipped with screw rod 204, protrudes into the screw rod in a mouth
Outer diameter is connect with caliber inner screw thread 502 in the spiral shell retaining ring 5 in pen body, the gear ring 503 of spiral shell retaining ring outer diameter and the convex ribs 403 of pen body inner wall
Engagement is fixed.Its specific structure is as follows: the bar slot outer diameter between the pen core set and screw rod of pearl is symmetrically arranged with elastic slice 201, pearl
The inner wall of elastic slice and mouth offset, limit chamber 301 is equipped with below the mouthpiece in mouth, the lower section inner wall of limit chamber is equipped with protrusion
Muscle position item 302, pearl is limited in the limit chamber in a mouth, and the outer cover inner wall above mouth is equipped with three flange collars being equally spaced
Muscle 101.The pen core set of pearl is in isosceles triangle, and it is in isosceles three that pen core, which covers inner wall below the limit chamber and limit chamber of corresponding mouth,
Angular, the inner wall of pen core set is equipped with the on-slip rib of protrusion；The other end of pen body is equipped with blocking chamber, blocks 6 plug and pen body
Blocking chamber fitting.Pen body one end port outside diameter of mouth is symmetrically arranged with salient point 303, above the salient point and pen body inner convex rib of mouth
Go straight up to slot 402 fastening.Square circle muscle bottom side is symmetrically arranged with catch point 202, the screw top hole of spiral shell retaining ring under the bar slot of pearl
Equipped with corresponding retaining ring 501.
Above-mentioned pen body, outer cover are made of the resin material of antiultraviolet, the starting components proportion of the resin material
Are as follows: polyethylene 80-90%, 23% sodium hydrate aqueous solution 6%-10%, graphene oxide 5%-7%, toughener 3%-5%, uvioresistant
Agent 2%-4%, antistatic agent 1%-2%, environmentally friendly Masterbatch 3-6%, propylene glycol 5-8%, filler 2-5%, antioxidant 0.3%-1 %, filling
Agent 0.1%-1%；The filler is partial size 20nm, specific surface area >=230m2The Nano-sized Alumina Powder of/g.The toughener is poly-
Vinyl alcohol, thiocarbamide, urethanes, dibutyl phthalate, dioctyl phthalate, polyurethane resin, alcohol
Acid resin, acrylic resin, diethylene glycol (DEG) it is one or more；The antiultraviolet antioxidant includes Hinered phenols antioxidant or Asia
One of phosphoric acid ester antioxidant is a variety of, and the antistatic agent is HDC-102 antistatic agent or HBS-510 antistatic agent；
The antistatic agent is HDC-102 antistatic agent or HBS-510 antistatic agent；The antioxidant be antioxidant 246,300,
1010,1035, one or both of CA, 3114,168, DLTDP；The filler be calcium carbonate, wash one's hair with powder, talcum powder,
At least one of barium sulfate, carbon black.
The specific embodiment that it is prepared is as follows:
Embodiment 1:
The 23% sodium hydrate aqueous solution mixing of 80g polyethylene, 6g are taken, and alkaline ph value regulator is added, setting up pH value is 8.8,
90 DEG C are heated to, 20min is stirred, adds 5g graphene oxide, later under the conditions of 50 DEG C, be stirred to react 1h, obtain glue
Resin；By 2g Nano-sized Alumina Powder, 2g antiultraviolet antioxidant, 1g antistatic agent, 5g environmental protection Masterbatch, 0.3g antioxidant,
0.1g filler, 5g mixed with propylene glycol, are uniformly mixing to obtain nano-alumina solution；It will be added in graphene oxide melamine resin
Acid pH value adjustment agent, setting up pH value is 6.0, and 5h is stirred to react under the conditions of 50 DEG C, and the poly- second of 3g is added after starting 20min in reaction
Enol is uniformly mixed, then nano-alumina solution is added after 20min, is uniformly mixed, and reaction will obtain after terminating
Product be put into and be set as in 85 DEG C of baking ovens that drying to constant weight, obtain sold resin.
Embodiment 2:
The 23% sodium hydrate aqueous solution mixing of 90g polyethylene, 7g are taken, and alkaline ph value regulator is added, setting up pH value is 8.8,
100 DEG C are heated to, 25min is stirred, adds 5.5g graphene oxide, later under the conditions of 55 DEG C, be stirred to react 1.5h, obtain
Colloidal resin；3g Nano-sized Alumina Powder, 3g antiultraviolet antioxidant, 1g antistatic agent, 5g environmental protection Masterbatch, 0.5g are resisted
Oxygen agent, 0.5g filler, 6g mixed with propylene glycol, are uniformly mixing to obtain nano-alumina solution；By graphene oxide melamine resin
The acid pH value adjustment agent of middle addition, setting up pH value is 6.0, and 5h is stirred to react under the conditions of 50 DEG C, and reaction is added after starting 30min
4g ratio is that the polyvinyl alcohol of 1:3 and compound are uniformly mixed, then nano-alumina solution is added after 30min, is stirred
Mix uniformly mixed, obtained product is put by reaction after terminating is set as in 85 DEG C of baking ovens that drying to constant weight, obtains finished product tree
Rouge.
Embodiment 3:
Take 100g polyethylene, the mixing of 23% sodium hydrate aqueous solution of 8g, and alkaline ph value regulator is added, setting up pH value is
9.0,100 DEG C are heated to, 30min is stirred, adds 6g graphene oxide, later under the conditions of 60 DEG C, be stirred to react 1.5h, obtain
To colloidal resin；By 3.5g Nano-sized Alumina Powder, 4g antiultraviolet antioxidant, 2g antistatic agent, 6g environmental protection Masterbatch, 1g
Antioxidant, 1g filler, 6g mixed with propylene glycol, are uniformly mixing to obtain nano-alumina solution；By graphene oxide melamine resin
The acid pH value adjustment agent of middle addition, setting up pH value is 6.2, and 5h is stirred to react under the conditions of 55 DEG C, and reaction is added after starting 30min
4g urethanes is uniformly mixed, then nano-alumina solution is added after 30min, is uniformly mixed, after reaction terminates
Obtained product is put into and is set as in 85 DEG C of baking ovens that drying to constant weight, obtains sold resin.
Claims (10)
1. a kind of antiultraviolet triangle mouth eyebrow pencil, pen body (4) one end outer diameter button muscle (401) of the eyebrow pencil and the lid of outer cover (1)
Mouth internal diameter buckle ring fastens, and the outer cover port of upper pen body is equipped with a mouth (3), is equipped with pearl (2) in mouth, the pen core set of pearl one end
(203) it is equipped with reservoir hole, the other end of pearl is equipped with screw rod (204), protrudes into the spiral shell button in outer screw diameter and pen body in a mouth
Ring (5) interior caliber inner screw thread (502) connection, the gear ring (503) of spiral shell retaining ring outer diameter engage fixation with the convex ribs (403) of pen body inner wall；
It is characterized in that the bar slot outer diameter between the pen core set (203) and screw rod (204) of the pearl (2) is symmetrically arranged with elastic slice (201),
The elastic slice of pearl and the inner wall of a mouth (3) offset, and are equipped with limit chamber (301) below the mouthpiece in mouth, in the lower section of limit chamber
Wall is equipped with the muscle position item (302) of protrusion, and pearl is limited in the limit chamber in a mouth, and the outer cover inner wall above mouth is equipped with equidistant point
Three flange collar muscle (101) of cloth.
2. antiultraviolet triangle mouth eyebrow pencil according to claim 1, it is characterised in that the pen core set of the pearl (2)
It (203) is in isosceles triangle, it is in isosceles triangle that pen core, which covers inner wall below the limit chamber (301) and limit chamber of corresponding mouth (3),
The inner wall of pen core set is equipped with the on-slip rib of protrusion；The other end of pen body (4) is equipped with blocking chamber, blocks the plug and pen body of (6)
Blocking chamber fitting.
3. antiultraviolet triangle mouth eyebrow pencil according to claim 1, it is characterised in that the pen body (4) of described mouth (3)
One end port outside diameter is symmetrically arranged with salient point (303), and the salient point of mouth and go straight up to slot (402) above pen body inner convex rib (403) are detained
It closes.
4. antiultraviolet triangle mouth eyebrow pencil according to claim 1, it is characterised in that below the bar slot of the pearl (2)
Circle muscle bottom side is symmetrically arranged with catch point (202), and the screw top hole of spiral shell retaining ring (5) is equipped with corresponding retaining ring (501).
5. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 1, it is characterised in that institute
State the starting components proportion of resin material are as follows: polyethylene 80-90%, 23% sodium hydrate aqueous solution 6%-10%, graphene oxide
5%-7%, it toughener 3%-5%, UV resistant agent 2%-4%, antistatic agent 1%-2%, environmentally friendly Masterbatch 3-6%, propylene glycol 5-8%, fills out
Expect 2-5%, antioxidant 0.3%-1 %, filler 0.1%-1%；The filler is partial size 20nm, specific surface area >=230m2/ g's receives
Rice alumina powder.
6. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 5, it is characterised in that institute
Stating toughener is polyvinyl alcohol, thiocarbamide, urethanes, dibutyl phthalate, dioctyl phthalate, poly- amino
Benzoic acid resin, alkyd resin, acrylic resin, diethylene glycol (DEG) it is one or more.
7. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 5, it is characterised in that institute
It includes one of Hinered phenols antioxidant or phosphite ester antioxidant or a variety of for stating antiultraviolet antioxidant, described antistatic
Agent is HDC-102 antistatic agent or HBS-510 antistatic agent.
8. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 5, it is characterised in that institute
Stating antistatic agent is HDC-102 antistatic agent or HBS-510 antistatic agent.
9. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 5, it is characterised in that institute
Stating antioxidant is one or both of antioxidant 246,300,1010,1035, CA, 3114,168, DLTDP.
10. the resin material preparation method of antiultraviolet triangle mouth eyebrow pencil according to claim 5, it is characterised in that institute
Filler is stated to be calcium carbonate, wash one's hair and at least one of powder, talcum powder, barium sulfate, carbon black.
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| CN201811071928.3A CN109123997B (en) | 2018-09-14 | 2018-09-14 | Ultraviolet-proof triangular pen nozzle eyebrow pencil and preparation method of resin material thereof |
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| CN201811071928.3A CN109123997B (en) | 2018-09-14 | 2018-09-14 | Ultraviolet-proof triangular pen nozzle eyebrow pencil and preparation method of resin material thereof |
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| CN109123997A true CN109123997A (en) | 2019-01-04 |
| CN109123997B CN109123997B (en) | 2024-04-02 |
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Citations (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06245814A (en) * | 1992-12-28 | 1994-09-06 | Suzuno Kasei Kk | Cartridge for push-out container of stick type cosmetics |
| CN2204123Y (en) * | 1994-06-24 | 1995-08-02 | 梅琳化学股份有限公司 | Improved eyebrow pencil |
| CN2262835Y (en) * | 1996-09-26 | 1997-09-24 | 林莲发 | Cosmetic pencil device |
| CN2266911Y (en) * | 1996-08-02 | 1997-11-12 | 蔡金娇 | Eyebrow pencil |
| JP2003033223A (en) * | 2001-07-23 | 2003-02-04 | Interwork Japan:Kk | Stick cosmetic container |
| TW200420444A (en) * | 2002-10-09 | 2004-10-16 | Cosmolab Inc | Marking instrument housing, and marking instrument made therefrom |
| US20050220527A1 (en) * | 2004-03-31 | 2005-10-06 | Tokiwa Corporation | Stick-shaped cosmetic material feeding container |
| JP3139555U (en) * | 2007-12-04 | 2008-02-21 | エーアンドティー パッケージング カンパニー リミテッド | Multifunctional cosmetic container |
| CN201073072Y (en) * | 2007-07-12 | 2008-06-18 | 真那化妆品(中山)有限公司 | Cosmetic pen mechanism |
| WO2011031583A2 (en) * | 2009-09-11 | 2011-03-17 | Zen Design Solutions Limited | Dispensing mechanism assembly |
| KR20110079997A (en) * | 2010-01-04 | 2011-07-12 | 신기봉 | A cosmetic case |
| JP2011240617A (en) * | 2010-05-19 | 2011-12-01 | Mitsubishi Pencil Co Ltd | Rod-shaped content draw-out container |
| JP2012045152A (en) * | 2010-08-26 | 2012-03-08 | Tokiwa Corp | Stick cosmetic delivery container |
| US20120288321A1 (en) * | 2011-05-11 | 2012-11-15 | Tokiwa Corporation | Rod-shaped cosmetic material feeding container |
| CN204467307U (en) * | 2015-02-09 | 2015-07-15 | 彩丽国际化妆品股份有限公司 | Revolving type cosmetic eyebrow pencil |
| CN205162264U (en) * | 2015-11-20 | 2016-04-20 | 简华 | Double -headed cosmetic pencil |
| US20160157584A1 (en) * | 2014-12-08 | 2016-06-09 | Capicolor International Cosmetics Ltd. | Cosmetic applicator |
| CN205947402U (en) * | 2016-07-15 | 2017-02-15 | 汕头市京华塑胶有限公司 | Multi -functional cosmetic containers |
| CN206238701U (en) * | 2016-12-01 | 2017-06-13 | 余姚市唯美化妆品包装用品有限公司 | Multi-functional eyebrow adornment mechanical pencil is combined a kind of built-in repairing type more |
| CN206659381U (en) * | 2017-03-29 | 2017-11-24 | 苏州佑嘉塑胶科技有限公司 | A kind of pearl bullet type bump structure form of a stroke or a combination of strokes lipstick |
| WO2018048014A1 (en) * | 2016-09-12 | 2018-03-15 | 주식회사 리치코스 | Knock-type cosmetic pencil having pencil lead formed by direct injection and method for manufacturing same knock-type cosmetic pencil |
| CN207236383U (en) * | 2017-09-04 | 2018-04-17 | 苏州瑞模包装科技有限公司 | A kind of automatic rotary pen |
| WO2018074890A2 (en) * | 2016-10-21 | 2018-04-26 | 석종완 | Pen-type cosmetic container |
| CN108338482A (en) * | 2018-02-09 | 2018-07-31 | 浙江正庄实业有限公司 | Environmentally friendly high rigidity antistatic single tube eyebrow pencil and preparation method thereof |
| CN108456408A (en) * | 2018-02-09 | 2018-08-28 | 浙江正庄实业有限公司 | Environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof |
| CN209135596U (en) * | 2018-09-14 | 2019-07-23 | 浙江正庄实业有限公司 | Antiultraviolet triangle mouth eyebrow pencil |
-
2018
- 2018-09-14 CN CN201811071928.3A patent/CN109123997B/en active Active
Patent Citations (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06245814A (en) * | 1992-12-28 | 1994-09-06 | Suzuno Kasei Kk | Cartridge for push-out container of stick type cosmetics |
| CN2204123Y (en) * | 1994-06-24 | 1995-08-02 | 梅琳化学股份有限公司 | Improved eyebrow pencil |
| CN2266911Y (en) * | 1996-08-02 | 1997-11-12 | 蔡金娇 | Eyebrow pencil |
| CN2262835Y (en) * | 1996-09-26 | 1997-09-24 | 林莲发 | Cosmetic pencil device |
| JP2003033223A (en) * | 2001-07-23 | 2003-02-04 | Interwork Japan:Kk | Stick cosmetic container |
| TW200420444A (en) * | 2002-10-09 | 2004-10-16 | Cosmolab Inc | Marking instrument housing, and marking instrument made therefrom |
| US20050220527A1 (en) * | 2004-03-31 | 2005-10-06 | Tokiwa Corporation | Stick-shaped cosmetic material feeding container |
| CN201073072Y (en) * | 2007-07-12 | 2008-06-18 | 真那化妆品(中山)有限公司 | Cosmetic pen mechanism |
| JP3139555U (en) * | 2007-12-04 | 2008-02-21 | エーアンドティー パッケージング カンパニー リミテッド | Multifunctional cosmetic container |
| WO2011031583A2 (en) * | 2009-09-11 | 2011-03-17 | Zen Design Solutions Limited | Dispensing mechanism assembly |
| KR20110079997A (en) * | 2010-01-04 | 2011-07-12 | 신기봉 | A cosmetic case |
| JP2011240617A (en) * | 2010-05-19 | 2011-12-01 | Mitsubishi Pencil Co Ltd | Rod-shaped content draw-out container |
| JP2012045152A (en) * | 2010-08-26 | 2012-03-08 | Tokiwa Corp | Stick cosmetic delivery container |
| US20120288321A1 (en) * | 2011-05-11 | 2012-11-15 | Tokiwa Corporation | Rod-shaped cosmetic material feeding container |
| US20160157584A1 (en) * | 2014-12-08 | 2016-06-09 | Capicolor International Cosmetics Ltd. | Cosmetic applicator |
| CN204467307U (en) * | 2015-02-09 | 2015-07-15 | 彩丽国际化妆品股份有限公司 | Revolving type cosmetic eyebrow pencil |
| CN205162264U (en) * | 2015-11-20 | 2016-04-20 | 简华 | Double -headed cosmetic pencil |
| CN205947402U (en) * | 2016-07-15 | 2017-02-15 | 汕头市京华塑胶有限公司 | Multi -functional cosmetic containers |
| WO2018048014A1 (en) * | 2016-09-12 | 2018-03-15 | 주식회사 리치코스 | Knock-type cosmetic pencil having pencil lead formed by direct injection and method for manufacturing same knock-type cosmetic pencil |
| WO2018074890A2 (en) * | 2016-10-21 | 2018-04-26 | 석종완 | Pen-type cosmetic container |
| CN206238701U (en) * | 2016-12-01 | 2017-06-13 | 余姚市唯美化妆品包装用品有限公司 | Multi-functional eyebrow adornment mechanical pencil is combined a kind of built-in repairing type more |
| CN206659381U (en) * | 2017-03-29 | 2017-11-24 | 苏州佑嘉塑胶科技有限公司 | A kind of pearl bullet type bump structure form of a stroke or a combination of strokes lipstick |
| CN207236383U (en) * | 2017-09-04 | 2018-04-17 | 苏州瑞模包装科技有限公司 | A kind of automatic rotary pen |
| CN108338482A (en) * | 2018-02-09 | 2018-07-31 | 浙江正庄实业有限公司 | Environmentally friendly high rigidity antistatic single tube eyebrow pencil and preparation method thereof |
| CN108456408A (en) * | 2018-02-09 | 2018-08-28 | 浙江正庄实业有限公司 | Environmentally friendly high rigidity antistatic lipstick tube and preparation method thereof |
| CN209135596U (en) * | 2018-09-14 | 2019-07-23 | 浙江正庄实业有限公司 | Antiultraviolet triangle mouth eyebrow pencil |
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| CN109123997B (en) | 2024-04-02 |
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