CN108289442A - Insects repellant and use its pest repelling method - Google Patents
Insects repellant and use its pest repelling method Download PDFInfo
- Publication number
- CN108289442A CN108289442A CN201680066634.4A CN201680066634A CN108289442A CN 108289442 A CN108289442 A CN 108289442A CN 201680066634 A CN201680066634 A CN 201680066634A CN 108289442 A CN108289442 A CN 108289442A
- Authority
- CN
- China
- Prior art keywords
- ring type
- solution
- insects repellant
- ingredient
- repellant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
- A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
- A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
Abstract
The issue of the present invention is to provide a kind of insects repellant and its pest repelling method is used, which has prolonged duration, and safe mainly with indoor floor and wall etc. for object.Solves the above subject using following insects repellants, which is to make to contain made of natural origin ingredient penetrates into as the solution of active ingredient in base material, which is characterized in that it is used by the way that the solution is applied to processed surface.It is preferred for solving the above subject if especially the solution is to contain (A) ring type monoterpenol and/or (B) ring type monoterpene ketenes and contain solution of (C) the ring type sesquiterpene as natural origin ingredient.
Description
Technical field
The present invention relates to insects repellants, in more detail, are related to that solution is made to penetrate into the base materials such as non-woven fabrics, this is molten
The insects repellant that liquid is applied to processed surface to use.The invention further relates to the pest repelling sides for having used the insects repellant
Method.
Background technology
For the pests such as cockroach, mosquito, fly, they occur in house etc. and so that hygienic conditions is deteriorated, scathing
Class makes one mood discomfort due to being ugly in appearance, and brings various harm.
As the method for control for preventing from endangering caused by these pests, the side using various medicaments is had developed
Method.
The medicament of insect-pest exterminating has：With the insecticide for murdering worm effect and have the function of keeping pest close
Repellant (insect-proof agent).
As having the function of making the example of repellant (insect-proof agent) that pest will not be close, it is widely used for DEET
The medicament (patent document 1) of (n,N-diethyl-toluamide) as active ingredient, but from the side of the safety to human body
It sets out in face, it is proposed that with terpene compound (patent document 2, patent document 3), saponin (the patent text contained in natural essential oil
Offer the repellant 4) as active ingredient.In addition, in order to reduce stimulations of the DEET to human body, having developed combination has DEET and day
The repellant (patent document 5) of right essential oil.
As the pest repelling method based on repellant, it can enumerate and the solution containing active ingredient is sprayed at closing sky
In method, the setting method etc. that has been impregnated with the solid content of active ingredient and active ingredient is made to evapotranspire.
In addition, as the repellant for the thorns such as mosquito stinging property pest, also has and directly attach active ingredient on the skin
Repellant further developed the human body of wet tissue type repellant (patent text other than aerosol (patent document 5), emulsifiable paste
Offer 1, patent document 6, patent document 7), in terms of the use feeling smearing easiness of medicament (, to stimulation/stickness etc. of skin)
It sets out and has carried out various improvement.
But these prior arts are predominantly from safety, the improvement of use feeling aspect, the repellent effect of pest
Duration it is insufficient.
So that medicament is dispersed into the method in the enclosure spaces such as interior by spraying, is wasting the medicament used and tend to
Increase, and the effect of medicament disappears quickly, needs the medicament that continually disperses.The solid of active ingredient has been impregnated with for setting
Object simultaneously makes for the method that active ingredient evapotranspires, and effect is easy in closet/wardrobe etc. is than narrow enclosure space continues, but
Make pest not close to it is entire it is indoor in the case of, effect disappears quickly.
In addition, the human bodies such as wet tissue type are to imagine the repellant that when outgoing or h.d. temporarily uses with repellant, originally
Also need not make effect long lasting for.
Therefore, it is intended that develop a kind of repellent effect of pest can it is entire it is indoor long lasting for novel pest drive
Keep away method.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 6-321705 bulletins
Patent document 2：Japanese Unexamined Patent Publication 7-112907 bulletins
Patent document 3：Japanese Unexamined Patent Publication 11-060421 bulletins
Patent document 4：Japanese Unexamined Patent Publication 2013-155116 bulletins
Patent document 5：Japanese Unexamined Patent Publication 11-171703 bulletins
Patent document 6：Japanese Unexamined Patent Publication 2001-270802 bulletins
Patent document 7：Japanese Unexamined Patent Publication 2003-040703 bulletins
Invention content
Problems to be solved by the invention
The present invention makes in view of the aforementioned technical background, and project is to provide a kind of insects repellant and use
Its pest repelling method, the insects repellant have prolonged continue mainly with indoor floor or wall etc. for object
Property, and it is safe.
The means to solve the problem
Further investigation has been repeated in the present inventor in order to solve the above problems, as a result, it has been found that, if using making containing having
Insects repellant made of the solution of the ingredient of pest repelling effect penetrates into the base materials such as non-woven fabrics makes base material and floor or wall
The processed surface such as wall contact and wipe to be handled, then contain with pest repelling effect ingredient solution be applied to by
Process face, after the evaporation of the ingredients such as the water or alcohol that contain in the solution, active ingredient remains on the surface of processed surface, and pest drives
Avoiding effect can be long lasting for so as to complete the present invention.
The present inventors have additionally discovered that forming combination specifically by using specific natural origin ingredient and then with specific
Natural origin ingredient, pest repelling effect is especially high, duration extension, so as to complete the present invention.
That is, the present invention provides a kind of insects repellant, it is to make to contain solution of the natural origin ingredient as active ingredient
Made of penetrating into base material, which is characterized in that, by making the base material should with processed surface contact
Solution is applied to the processed surface to be used.
In addition, the present invention provides above-mentioned insects repellant, wherein it contains (A) ring type monoterpenol and/or (B) ring
Formula monoterpene ketenes and contain (C) ring type sesquiterpene as above-mentioned natural origin ingredient.
In addition, the present invention provides a kind of pest repelling method, which is characterized in that will be above-mentioned using above-mentioned insects repellant
Solution is applied to processed surface.
The effect of invention
In accordance with the invention it is possible to provide a kind of insects repellant, have bys being applied to indoor floor or wall etc.
There is prolonged duration, and safe.
The insects repellant of the present invention be make containing having the solution of the ingredient of pest repelling effect to penetrate into base material and
At, by wiping the processed surface such as floor or wall, pest repelling ingredient penetrates into processed surface.
Therefore, medicament will not disperse as the insects repellant of existing aerosol (spraying) type to surrounding, can subtract
The active ingredient being wasted less.
In addition, in the insects repellant of the present invention, since solution penetrates into base material, it is thus possible to which it is right not omit
Processed surface is handled (wiping), so as to which pest repelling ingredient is spread evenly over being handled in roomy room
Face.
The insects repellant of the present invention crawls to do harm to especially for cockroach, ant etc what processed surface was crawled
Worm plays effect.Indoor narrow gap etc. is particularly easy to the pest that crawls as appearance, but the insects repellant of the present invention
Processing also can easily be done for such narrow gap.
For the insects repellant of the present invention, by wiping processed surface, pest repelling ingredient is penetrated into processed surface,
In the present specification, " wiping " is not limited to " wiped clean removes dirt ", also includes by clean processed surface base
The case where material handles and solution is made to spread all over.
In the present invention, the main purpose for wiping processed surface is to make the solution containing pest repelling ingredient spread over to be located
Reason face, can be made while removing dirt by being wiped to dirty processed surface pest repelling ingredient spread over by
Process face.That is, in the case where processed surface is dirty, using the insects repellant of the present invention, has to be carried out at the same time and be located
The advantages of cleaning in reason face and the distribution of pest repelling ingredient.
The insects repellant of the present invention can use the material of the low cost such as non-woven fabrics as base material, and base material can be primary
Property.Base material (solution be applied to processed surface after base material) after use is discarded in dustbin etc., but after use
Base material be in infiltration and have and be not applied to processed surface and the state of remaining pest repelling ingredient.Therefore, the base material after use
Itself has pest repelling effect.In general, be the state of pest that is susceptible in dustbin etc., but in the pest using the present invention
In the case of being discarded into dustbin etc. after repellant, pest can be made not close to dustbin etc..
Description of the drawings
Fig. 1 is the configuration diagram in the chamber in embodiment 1,3~4.
Fig. 2 is the configuration diagram in the chamber in embodiment 2.
Specific implementation mode
The present invention will be described below, but the present invention is not limited to the following embodiments and the accompanying drawings, can arbitrarily deform and
Implement.
The insects repellant of the present invention is the solution (abbreviation sometimes below for making to contain natural origin ingredient as active ingredient
For " solution ") penetrate into base material made of, which is applied to processed surface to use.
In addition, the pest repelling method of the present invention using the insects repellant of the present invention make base material contact with processed surface from
And solution is applied to processed surface.
As insects repellant, it has been known that there is the type of aerosol type, mounting solid content based on aerosol agent, the present invention in the past
Insects repellant be by using infiltration have solution base material wiping the processed surface such as floor or wall and solution is applied to
Processed surface is a kind of insects repellant of novel type come what is used.
<Solution>
The solution of the insects repellant of the present invention contains natural origin ingredient as active ingredient." natural origin ingredient " is
It refers to through the ingredient obtained from being extracted in animals and plants present in nature etc., specifically, being in essential oil etc.
The chemical composition contained.
As long as can be as the ingredient obtained from being extracted in animals and plants present in nature etc., even logical
The ingredient that chemical synthesis obtains is crossed, the scope of " natural origin ingredient " is also included into.Although not limiting, due to the present invention
Insects repellant the processed surface such as floor or wall are wiped and are used, thus as this " natural origin at
Point ", preferably from ingredient obtained from actual extracting in animals and plants existing for nature etc..
The insects repellant of the present invention is made of so that solution is penetrated into base material, by solution by wiping processed surface
Processed surface is applied to be used, it is contemplated that effect can continue for a long time.Therefore, the ingredient in solution needs safe,
In the present invention, as the active ingredient of solution, natural origin ingredient is used.
As the concrete example of the natural origin ingredient contained in solution, ring type monoterpenol, ring type monoterpene can be enumerated
Ketone, ring type sesquiterpene, chain type monoterpenol, monoterpene olefine aldehydr, terpenic acid, terpene oxide etc..
Solution is particularly preferably containing selected from (A) ring type monoterpenol, (B) ring type monoterpene ketenes and (C) ring type sesquiterpene
One or more of be used as natural origin ingredient.
In this case, more preferred if containing (C) ring type sesquiterpene in solution.That is, solution further preferably (A)
Ring type monoterpenol and/or (B) ring type monoterpene ketenes and contain (C) ring type sesquiterpene as natural origin ingredient.
(C) ring type sesquiterpene be used alone when pest repelling effect it is small, but by with (A) ring type monoterpenol, (B)
Ring type monoterpene ketenes combines to use, and the pest repelling effect of strength, and the synergistic effects such as speed of evapotranspiring are played in collaboration, should
Effect long lasting for.
In addition, the quality in (A) the ring type monoterpenol that will contain in solution is set as the quality of a, (B) ring type monoterpene ketenes
It is set as b, when the quality of (C) ring type sesquiterpene is set as c, preferably (a+b):C=1:9~9:1, particularly preferred (a+b):C=3:7
~7:3.
If above range, then pest repelling effect long lasting for.
In the case where solution does not contain (A) ring type monoterpenol (in the case of a=0), preferably b:C=1:9~9:1,
Particularly preferably b:C=3:7~7:3.
In addition, in the case where solution does not contain (B) ring type monoterpene ketenes (in the case of b=0), preferably a:C=1:9~
9:1, particularly preferred a:C=3:7~7:3.
As the concrete example of (A) the ring type monoterpenol contained in solution, isopulegol, menthol, terpin can be enumerated
It is alcohol, dihydro-terpineol, 4- terpineols, carveol, dihydrocarveol, perilla alcohol, myrtenol, nopol, pinocarveol, small
Anise alcohol, borneol, isoborneol, thujanol etc., they can be used alone, and can also be used in mixed way two or more.
As the concrete example of (B) ring type monoterpene ketenes contained in solution, carvol, menthones, different peppermint can be enumerated
Ketone, camphor etc., they can be used alone, and can also mix two or more to use.
As the concrete example of (C) the ring type sesquiterpene contained in solution, bisabolence, carypohyllene, Wahlen can be enumerated
Alkene, guaiene, cedrene, cadinene, thujopsene and longifolene etc., they can be used alone, can also be by 2 kinds
It is above to mix to use.
Solution will not hampered significantly other than containing the natural origin ingredient as active ingredient (pest repelling ingredient)
Solvent, emulsifier, dispersant, fixative, preservative etc. can be contained in the range of effect of the present invention by hindering.
As the solvent contained in solution, can enumerate：Water；The monohydric alcohols such as methanol, ethyl alcohol, propyl alcohol, isopropanol, butanol；
The polyalcohols such as ethylene glycol, propylene glycol；The ketone such as acetone, methyl ethyl ketone；The ethers such as tetrahydrofuran, dioxane, diethyl ether；Hexane,
The aliphatic hydrocarbons such as kerosene, paraffin；The aromatic hydrocarbons such as benzene, toluene；The halogenated hydrocarbons such as chloroform, dichloroethanes；Ethyl acetate, butyl acetate
Equal esters；Etc., they can be used alone, and can also mix two or more to use.
The insects repellant of the present invention is applied to processed surface to use, therefore to solvent requirement safety, preferably
Water, monohydric alcohol, polyalcohol or combination thereof.The mixture of particularly preferred water, ethyl alcohol or water and ethyl alcohol.
In solution, natural origin ingredient is preferably contained with 0.1 mass % or more, 10 mass % ratios below, more preferably with
0.3 mass % or more, 7 mass % ratios below contain, and are particularly preferably contained with 0.5 mass % or more, 5 mass % ratios below
Have.
Natural origin ingredient be above range when, speed of evapotranspiring is appropriate, pest repelling effect long lasting for.
<Base material>
The insects repellant of the present invention is made of so that solution is penetrated into base material.So-called " infiltration " for solution as long as infilter
State in base material, it may be considered that be impregnated with base material in the solution, solution is applied to the methods of base material by spraying etc..For
So that solution is fully infiltered in base material, is preferably impregnated with base material in the solution.
In the present invention, the base material as solution infiltration can enumerate non-woven fabrics, cloth, towel, gauze, degreasing silk floss, threadiness
Body etc..Consider from the infiltration easiness of solution, cost etc., preferably non-woven fabrics.
The type of non-woven fabrics to being used as base material is not particularly limited, can be used for example using air laid,
The non-woven fabrics that method produces well known to spun lacing (spunlace) method, spun-bond process, meltblown, needle point method etc..
In the present invention, it is disposable as the non-woven fabrics most cases of base material, preferably by the cheap water of manufacturing cost
The non-woven fabrics that acupuncture manipulation produces.
In addition, non-woven fabrics can be that (synthetic rubber system hot melt, is gathered at EVA systems hot melt using for example well known adhesive
Olefin-based hot melt, polyamide-based hot melt, hot-melt adhesive polyester, polyurethane series hot melt etc.) be bonded.
In the case of using non-woven fabrics as base material, form as common wet tissue can be made.I.e., it is possible to by appropriate
The non-woven fabrics of size is filled in the container of the hermetic types such as bottle-type, pouch-type, takes out used one by one when in use.
It operates in this way, in general family etc., can only take out necessary amount when needed to be used, use
After abandon.In addition, capableing of the evaporation of suppression solution, the pest repelling ingredient (active ingredient) in solution can be made to fall in above-mentioned model
It encloses, the duration of effect is maintained.
In turn, even the insects repellant of wet tissue type can also be easy to smear solution in narrow access etc..Ventilation fan,
Discharge outlet etc. is the position for being particularly easy to become the route of entry of pest, but using the insects repellant of wet tissue type, even
The position of complicated shape also can easily smear solution in this way, can obtain sufficient repellent effect.
In addition, by thering is the base material of solution to be assigned to handle etc. infiltration, additionally it is possible to general cleaning apparatus etc be made
Form uses.For example, handle can be connected on the threadlike body using threadlike body as base material, to as mop
The insects repellant of form uses.
By doing so, processing (the smearing solution) operation on floor of large area etc. can be effectively performed.In addition, can
The smearing (distribution of pest repelling ingredient) that solution is carried out whiles cleaning floor etc., plays the role of killing two birds with one stone.
<Processed surface>
The processed surface for being handled (to be wiped to smear solution) for the insects repellant using the present invention does not have
It is particularly limited to, the building parts such as floor, wall, ceiling, window lattice, closet, window, railing can be enumerated；Kitchen stand, pond, bath
The contents such as slot, commode, closet, luminaire；Desk, chair, kitchen cabinet, bed, washing machine, drying machine, dustbin, bookcase,
The furniture such as shelf；The device for cooking such as chopping board, food container, micro-wave oven, refrigerator；The buildings adjunct such as ventilation fan, discharge outlet；Deng
Surface.Wherein, consider from for large area etc., effect is especially played in above-mentioned building part.
It is believed that the insects repellant about the present invention removes after solution is coated in processed surface by evaporating
Pest repelling ingredient (natural origin ingredient) remains in processed surface after water, alcohol equal solvent, and pest repelling ingredient evapotranspires at leisure,
Thus pest repelling effect long lasting for.
Processed surface is not easy to penetrate into internal material if pest repelling ingredient, then evapotranspires to stable effective ingredients,
Pest repelling effect long lasting for.
<Pest>
The type of the pest of the applicable object of insects repellant as the present invention is not particularly limited, can be enumerated
Unpleasant pest, sanitary insect pest, wood borers, clothes pest, food pest, historical relic pest, house pest, pet pest
Deng as example.
As the example of unpleasant pest, ant, thousand-legger, ball pillworm, centipede, spider, coarse mouse can be enumerated
Woman (ワ ラ ジ system シ), stinkbug, moth fly.
As the example of sanitary insect pest, fly, mosquito, buffalo gnat, flea, lice, cockroach, family mite, room dust mite can be enumerated
Insects etc..
As the example of wood borers, bark beetle, longicorn, death watch beetle, termite, long moth, powder moth etc. can be enumerated.
As the example of clothes (fiber) pest, khapra beetle, casemaking clothes moth, curtain casemaking clothes moth etc. can be enumerated.
As the example of food pest, can enumerate pillworm, casemaking clothes moth, curtain casemaking clothes moth, India rain moth, red flour beetle, sitophilus zea-mais,
Moth, acarid, psocid, cockroach, ant, death watch beetle etc..
As the example of historical relic pest, can enumerate moth-eaten death watch beetle, khapra beetle, psocid, sitophilus zea-mais, powder, long moth, moth (シ ミ),
Leopard line worm (ヒ ョ ウ モ Application system シ), termite etc..
As the example of house (building) pest, the small flat longicorn (ヒ メ ス ギ カ ミ キ リ) of termite, red wing can be enumerated, stolen
Moth, thousand-legger, moth, casemaking clothes moth, khapra beetle, moth fly etc..
As the example of pet pest, flea, acarid, Dermanyssus gallinae, mosquito etc. can be enumerated.
In addition, the insects repellant about the present invention, processed surface is applied to by solution, after making water, the evaporation of alcohol equal solvent,
The pest repelling ingredient remained in processed surface evapotranspires at leisure, to play pest repelling effect.
Therefore, insects repellant of the invention crawls for cockroach, ant, ball pillworm, coarse pillworm, centipede, thousand-legger etc.
Crawl pest is particularly effective.
For the insects repellant of the present invention, the duration of pest repelling effect is excellent, it is safe be due to,
It uses natural origin ingredient as pest repelling ingredient, and so that solution is penetrated into base material, make pest repelling ingredient spread all over by
Process face.
In addition, containing (A) ring type monoterpenol and/or (B) ring type monoterpene ketenes in solution and containing (C) ring type sesquialter
In the case of terpenes, the duration of pest repelling effect is especially excellent.It is believed that this is to be forced down by steam, individually hardly played
(C) the ring type sesquiterpene of pest repelling effect and (A) ring type monoterpenol and/or the synergistic effect of (B) ring type monoterpene ketenes
Caused.
Embodiment
Embodiment is enumerated below and comparative example further illustrates the present invention, but as long as without departing from its main points, the present invention is simultaneously
It is not limited to these embodiments and comparative example.
(embodiment 1)
The non-woven fabric plate for preparing the size that 2 groups cut into 300mm × 400mm, according to 1.0g/m in a piece of2Equably contain
Each substances shown in the diluted table 2 of leaching acetone.It is only impregnated with acetone in another.
The polypropylene container of 600mm × 400mm × 210mm (height) is used as chamber.In order to prevent for test worm
The escape of (cockroach) smears shortening in the entire surface of container inner wall.
Sheet above is air-dried about 1 hour respectively, the side setting in the bottom of container contains the piece for being soaked with each substances, makees
For treatment region.In the other side of container bottom, setting contains only the piece for being soaked with acetone, as no treatment area.
As shown in Figure 1, the container of prey and water equipped with cockroach is placed respectively in treatment region and no treatment area, as examination
Worm, adult 10 (5 male, 5 female), the larva 10 that America man Lian is put into chamber are 20 total, timely observe
The number of individuals for test worm hidden respectively in treatment region and no treatment area in chamber.
In the pilot study that left and right is no treatment area, confirming cockroach has the tendency that concentrating on right side.It is managed in detail
By indefinite, it is believed that be caused by indoor direction of illumination etc..
Therefore, in order to eliminate the deviation caused by place, the position relationship for the treatment of region and no treatment area is overturned to carry out
Same experiment is timely observed and inhabites number for test worm what treatment region and no treatment area were hidden respectively.
For result by the borneol used as substances the case where, it is listed in table 1.
[table 1]
As shown in Table 1, when treatment region is left side, no treatment area is right side, apparent repellent effect is strong, has cockroach
It is easy to concentrate on the tendency on right side.
For each substances, adds up in the case that treatment region is right side and treatment region is each area in the case of left side
Number is inhabited, scattering ratio is calculate by the following formula out.Result is listed in table 2.
[number 1]
[table 2]
In the case of independent ring type monoterpenol (No.1~6), independent ring type monoterpene ketenes (No.7~9), at 6 hours
Afterwards, any moment after 24 hours, after 48 hours has confirmed pest repelling effect.In independent ring type sesquiterpene (No.10
~13) in the case of, although very weak, pest repelling effect is also shown as time goes by.Ring type sesquiterpene with
The case where ring type monoterpenol shares (No.14~19), ring type sesquiterpene and ring type monoterpene ketenes share (No.20~23)
Under, the case where repellent effect is better than independent ring type monoterpenol (No.1~6), independent ring type monoterpene ketenes (No.7~9), with
Time elapses, and pest repelling effect is high, repellent effect is still very strong (after 48 hours) after long-time.
(embodiment 2)
The drum that the polypropylene of 340mm × 260mm × 110mm (height) manufactures is used as chamber.In order to prevent for examination
The escape of worm (cockroach) smears vaseline to the top 1/2 of inner wall.
As shown in Fig. 2, wooden sanctuary (12mm × 10mm × 8mm (height)) is arranged in chamber in advance and water is housed
Culture dish (diameter 60mm, height 15mm), as test worm, be put into chamber Groton bug adult 60 (male 30,
Female 30), it is raised and train in chamber.
Prepare 2 groups of circular 2 non-woven fabric plates for being cut into diameter 125mm, only according to 1.0g/m in a piece of2Uniformly
Ground is impregnated with each substances shown in table 3.Each is oppositely disposed in chamber, make be containing the piece for being soaked with each substances
Treatment region, the piece without any impregnation are no treatment area.The appearance for being added and having the solid feed after weighing is placed in each central portion
Device (diameter 30mm, height 6mm) measures the food ration for the treatment of region and the solid feed of no treatment area daily.
In addition, in order to eliminate the deviation caused by place, it is same to carry out to exchange the position for the treatment of region and no treatment area
Experiment measures the food ration for the treatment of region and the solid feed of no treatment area daily.In the case that accumulative treatment region is right side and locate
The food ration in each area, is calculate by the following formula out scattering ratio in the case of area is managed as left side.Result is listed in table 3.
[number 2]
[table 3]
Tendency same as Example 1 as can be seen from Table 3.That is, in the feelings of independent ring type sesquiterpene (No.10~13)
Under condition, almost without repellent effect is observed, ring type sesquiterpene shares (No.14~19), ring type times with ring type monoterpenol
Half terpenes is better than independent ring type monoterpenol with the repellent effect in the case that ring type monoterpene ketenes shares (No.20~23)
The case where (No.1~6), independent ring type monoterpene ketenes (No.7~9), has confirmed the collaboration effect caused by containing 2 kinds of ingredients
It answers.
(embodiment 3)
As chamber, held using the polypropylene system of 600mm × 400mm same as Example 1 × 210mm (height)
Device.In order to prevent for the escape of test worm (cockroach), shortening is smeared in the entire surface of container inner wall.
Prepare 2 groups of pieces that PET resin plate is cut into 300mm × 400mm, by the surface of a resin plate with containing being immersed in
Non-woven fabrics after in the solution of each substances shown in table 4 containing 2.0 mass % equably wipes, as treatment region.
The surface of another resin plate does not carry out any processing, as no treatment area.
As shown in Figure 1, the resin plate of the resin plate and treatment region of setting no treatment area, places be equipped with as shown in Figure 1
The container of prey and water, as adult 10 (5 male, 5 female), the larva for for test worm, being put into Peroplaneta fluligginosa in chamber
10 20 total, timely observes and inhabites number for test worm what treatment region and no treatment area were hidden respectively in chamber.
In addition, in order to eliminate the deviation caused by place, it is same to carry out to exchange the position for the treatment of region and no treatment area
The number of individuals for test worm hidden respectively in treatment region and no treatment area is timely observed in experiment.
The case where accumulative treatment region is right side and treatment region are that number for test worm is inhabited in each area in the case of left side, are passed through
Following formula calculates scattering ratio.Result is listed in table 4.
[number 3]
[table 4]
Confirmed by the result of table 4, independent ring type monoterpenol (No.1~3), independent ring type monoterpene ketenes (No.4~
5) in the case of, as time goes by, pest repelling decreased effectiveness, but still observe that pest repelling is imitated after 2~4 hours
Fruit.In the case of independent ring type sesquiterpene (No.6~7), although very weak, pest is also shown as time goes by
Repellent effect.(No.8~11), ring type sesquiterpene and ring type monoterpene are shared in ring type sesquiterpene and ring type monoterpenol
In the case that ketone shares (No.12~15), with independent ring type monoterpenol (No.1~3), independent ring type monoterpene ketenes (No.4~
5) the case where, is compared, and as time goes by, pest repelling effect is high.It is thought that should be the result is that due to ring type monoterpenol or ring
Formula monoterpene ketenes observed synergistic effect with caused by the synergistic effect of ring type sesquiterpene in any combination.
(embodiment 4)
The polypropylene of 340mm × 260mm similarly to Example 2 × 110mm (height) is used to manufacture as chamber
Drum.In order to prevent for the escape of test worm (cockroach), vaseline is smeared to the top 1/2 of inner wall.
Prepare 2 groups of pieces that PET resin plate is cut into 170mm × 260mm, by the surface of a resin plate with containing being immersed in
Non-woven fabrics after in the solution of each substances shown in table 5 containing 2.0 mass % equably wipes, as treatment region.
The surface of another resin plate does not carry out any processing, as no treatment area.
As shown in Figure 1, the resin plate of the resin plate and no treatment area of setting treatment region, places be equipped with as shown in Figure 1
The container of prey and water, as the adult 60 (30 male, 30 female) for for test worm, being put into Groton bug in chamber, warp
When observe and inhabit number for test worm treatment region and no treatment area are latent respectively in chamber.
In addition, in order to eliminate the deviation caused by place, it is same to carry out to exchange the position for the treatment of region and no treatment area
The number of individuals for test worm hidden respectively in treatment region and no treatment area is timely observed in experiment.
The case where accumulative treatment region is right side and treatment region are that number for test worm is inhabited in each area in the case of left side, are passed through
Following formula calculates scattering ratio.Result is listed in table 5.
[number 4]
[table 5]
Tendency similarly to Example 3 as can be seen from Table 5.That is, in independent ring type sesquiterpene (No.No.6~7)
In the case of, although very weak, pest repelling effect has been confirmed as time goes by, in ring type sesquiterpene and ring type monoterpene
In the case that alcohol shares (No.8~11), ring type sesquiterpene and ring type monoterpene ketenes share (No.12~15), pest repelling effect
Fruit is better than the case where independent ring type monoterpenol (No.1~3), independent ring type monoterpene ketenes (No.4~5), has confirmed because containing
There is the synergistic effect caused by 2 kinds of ingredients.
Industrial applicibility
The insects repellant for smearing solution in processed surface to use of the present invention can reduce the dosage of medicament, and energy
Enough processed surface for making active ingredient spread over large area without omitting ground, if thus being made into hypothesis in narrow field
Institute, complicated shape field used in wet tissue type etc., then general home-use insects repellant, factory with etc. pest repelling
It can be utilized extensively in agent etc..
Claims (11)
1. it is to make to contain natural origin ingredient to penetrate into base material as the solution of active ingredient to form a kind of insects repellant
, which is characterized in that the solution is applied to this by so that the base material is contacted with processed surface and is handled by the insects repellant
Face is used.
2. insects repellant as described in claim 1, wherein the base material is non-woven fabrics.
3. the insects repellant as described in claim 1 or claim 2, wherein the insects repellant, which contains, is selected from (A) ring
One or more of formula monoterpenol, (B) ring type monoterpene ketenes and (C) ring type sesquiterpene are used as the natural origin ingredient.
4. insects repellant according to any one of claims 1 to 3, wherein the insects repellant contains (A) ring type list
Terpenol and/or (B) ring type monoterpene ketenes and contain (C) ring type sesquiterpene as the natural origin ingredient.
5. the insects repellant as described in claim 3 or claim 4, wherein (A) ring type monoterpenol is selected from by different Pu
Strangle alcohol, menthol, terpineol, dihydro-terpineol, 4- terpineols, carveol, dihydrocarveol, perilla alcohol, myrtenol, promise
Foretell the compound of one or more of group of alcohol, pinocarveol, fenchanol, borneol, isoborneol and thujanol composition.
6. the insects repellant as described in any one of claim 3~5, wherein (B) ring type monoterpene ketenes is selected from by Sheep's-parsley
The compound of one or more of the group of ketone, menthones, isomenthone and camphor composition.
7. the insects repellant as described in any one of claim 3~6, wherein (C) ring type sesquiterpene is selected from not had by sweet tea
One or more of the group of medicine alkene, carypohyllene, valencene, guaiene, cedrene, cadinene, thujopsene and longifolene composition
Compound.
8. the insects repellant as described in any one of claim 3~7, wherein (A) the ring type list that will contain in the solution
When the quality of terpenol is set as a, the quality of (B) ring type monoterpene ketenes is set as b, the quality of (C) ring type sesquiterpene is set as c, (a+
b):C=1:9~9:1.
9. such as insects repellant according to any one of claims 1 to 8, wherein the pest is cockroach.
10. such as insects repellant according to any one of claims 1 to 9, wherein the solution is with 0.1 mass % or more 10
Quality % ratios below contain the natural origin ingredient.
11. a kind of pest repelling method, which is characterized in that utilize the insects repellant described in any one of claim 1~10
The solution is applied to processed surface.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015230248A JP2018039734A (en) | 2015-11-26 | 2015-11-26 | Pest repelling material and method for repelling pest using the same |
| JP2015-230248 | 2015-11-26 | ||
| PCT/JP2016/079958 WO2017090328A1 (en) | 2015-11-26 | 2016-10-07 | Pest repellent material and pest repelling method using same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108289442A true CN108289442A (en) | 2018-07-17 |
Family
ID=58763812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680066634.4A Pending CN108289442A (en) | 2015-11-26 | 2016-10-07 | Insects repellant and use its pest repelling method |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2018039734A (en) |
| CN (1) | CN108289442A (en) |
| HK (1) | HK1256037A1 (en) |
| WO (1) | WO2017090328A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112525756A (en) * | 2020-11-11 | 2021-03-19 | 佛山欧神诺陶瓷有限公司 | Method for testing cockroach prevention effect of ceramic tile |
| CN114503986A (en) * | 2022-02-21 | 2022-05-17 | 北京林业大学 | Long tube plant aphid repellent and application thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03127702A (en) * | 1989-10-13 | 1991-05-30 | Osaka Seiyaku:Kk | Cockroach repellent |
| JP2002114618A (en) * | 2000-10-10 | 2002-04-16 | Toi Kogyo:Kk | Insect repellent composition for animal-breeding farm |
| JP2003164249A (en) * | 2001-11-30 | 2003-06-10 | Matsushita Electric Ind Co Ltd | Repellent apparatus for sanitary insect pest |
| JP2006306835A (en) * | 2005-02-15 | 2006-11-09 | Dainippon Jochugiku Co Ltd | House dust mite repelling article |
| CN101370381A (en) * | 2005-08-25 | 2009-02-18 | 贝多吉恩研究公司 | Spatial inhibitors, deterrents and repellents for mosquitoes and midges |
| CN101626689A (en) * | 2006-11-22 | 2010-01-13 | 京都利福来新药有限公司 | Pest repellent |
| CN103974621A (en) * | 2011-10-04 | 2014-08-06 | 0903608B.C.有限公司 | Pest control formulations and methods of making and using same |
| CN105530812A (en) * | 2014-06-05 | 2016-04-27 | 理研香料控股株式会社 | Insect repellent and insect repelling method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1129427A (en) * | 1997-07-09 | 1999-02-02 | Cosmo Ace:Kk | Acaricide including hinoki oil or hiba arborvitae oil-containing composition as active component and controlling of acarids using the same |
| JP3662816B2 (en) * | 2000-06-05 | 2005-06-22 | 株式会社リフレ | Hygiene pest repellent and repellent active wax |
-
2015
- 2015-11-26 JP JP2015230248A patent/JP2018039734A/en active Pending
-
2016
- 2016-10-07 WO PCT/JP2016/079958 patent/WO2017090328A1/en active Application Filing
- 2016-10-07 CN CN201680066634.4A patent/CN108289442A/en active Pending
-
2018
- 2018-11-26 HK HK18115089.0A patent/HK1256037A1/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03127702A (en) * | 1989-10-13 | 1991-05-30 | Osaka Seiyaku:Kk | Cockroach repellent |
| JP2002114618A (en) * | 2000-10-10 | 2002-04-16 | Toi Kogyo:Kk | Insect repellent composition for animal-breeding farm |
| JP2003164249A (en) * | 2001-11-30 | 2003-06-10 | Matsushita Electric Ind Co Ltd | Repellent apparatus for sanitary insect pest |
| JP2006306835A (en) * | 2005-02-15 | 2006-11-09 | Dainippon Jochugiku Co Ltd | House dust mite repelling article |
| CN101370381A (en) * | 2005-08-25 | 2009-02-18 | 贝多吉恩研究公司 | Spatial inhibitors, deterrents and repellents for mosquitoes and midges |
| CN101626689A (en) * | 2006-11-22 | 2010-01-13 | 京都利福来新药有限公司 | Pest repellent |
| CN103974621A (en) * | 2011-10-04 | 2014-08-06 | 0903608B.C.有限公司 | Pest control formulations and methods of making and using same |
| CN105530812A (en) * | 2014-06-05 | 2016-04-27 | 理研香料控股株式会社 | Insect repellent and insect repelling method |
Non-Patent Citations (1)
| Title |
|---|
| 张文富主编: "《新型化工小产品制造技术》", 28 February 2000, 天津大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112525756A (en) * | 2020-11-11 | 2021-03-19 | 佛山欧神诺陶瓷有限公司 | Method for testing cockroach prevention effect of ceramic tile |
| CN114503986A (en) * | 2022-02-21 | 2022-05-17 | 北京林业大学 | Long tube plant aphid repellent and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2018039734A (en) | 2018-03-15 |
| WO2017090328A1 (en) | 2017-06-01 |
| HK1256037A1 (en) | 2019-09-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100220924B1 (en) | Non-hazardous pest control | |
| JP5097390B2 (en) | Pest repellent | |
| DE60114831T2 (en) | HAZARDOUS PEST CONTROL | |
| JP2022062129A (en) | Insect repellent | |
| JP2010126486A (en) | New insect pest repellent | |
| US20120087871A1 (en) | Wasp, hornet, and yellowjacket spray repellant and nest pesticide | |
| JP6663228B2 (en) | Volatile enclosed space pesticide | |
| US20130125451A1 (en) | Method for repelling and/or controlling pests | |
| JP2015515979A6 (en) | Control and repelling of bed bugs | |
| JP2015515979A (en) | Control and repelling of bed bugs | |
| WO2018039376A1 (en) | Insect repellent compounds and compositions, and methods thereof | |
| KR20090103280A (en) | Insect Control Composition Having Insecticidal And Repellent Effects | |
| CN108289442A (en) | Insects repellant and use its pest repelling method | |
| JP6576643B2 (en) | Volatile closed space insecticide | |
| JP6326382B2 (en) | Flying pest repellent | |
| JP2015521171A (en) | Death of bed bugs | |
| JP2015521171A6 (en) | Death of bed bugs | |
| US20160309725A1 (en) | Synergistic composition of geranium oil with other essential oils for bedbug control | |
| JPS59204102A (en) | Insect pest repellent | |
| JPH0436205A (en) | Method for repelling sanitary insect pest | |
| Loke et al. | Evaluation of Sumithion L-40 against Aedes aegypti (L.) and Aedes albopictus Skuse. | |
| KR101591090B1 (en) | Method for preventing odor-spread of creeping pest repelling compound | |
| JP2015229674A (en) | Insect repellant and insect repelling method | |
| Nollet et al. | Essential Oil Mixtures for Pest Control | |
| JP2000297004A (en) | Tick repellent and insecticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1256037 Country of ref document: HK |
|
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180717 |
|
| WD01 | Invention patent application deemed withdrawn after publication |